Searcharxiv⌕ Search

arXiv subjects

W. Wernsdorfer

Publications and source records attributed to W. Wernsdorfer.

At least 19 recordsLinked to original sources
arXiv2025

The Interplay of Single Ion Anisotropy and Magnetic 3d-4f Interactions in V$^{\rm III}_2$Ln$^{\rm III}_2$ Butterfly Complexes

Within the framework of 3d-4f molecular magnets, the most thoroughly investigated architecture is that of butterfly-shaped coordination clusters as it provides an ideal testbed to study fundamental magnetic interactions. Here, we report the synthesis and characterisation of a series of isostructural V$^{\rm III}_2$Ln$^{\rm III}_2$ butterfly complexes, where Ln = Y (1Y), Tb (2Tb), Dy (3Dy), Ho (4Ho), Er (5Er), Tm (6Tm), Yb (7Yb), which extends the previous study on isostructural butterflies with Cr$^{\rm III}$, Mn$^{\rm III}$ and Fe$^{\rm III}$. In zero external field, compounds 2Tb, 3Dy and 4Ho show clear maxima in the out-of-phase component of the ac susceptibility whereas small magnetic fields are needed to suppress quantum tunneling in 6Tm. Combined high-field electron paramagnetic resonance spectroscopy and magnetisation measurements unambiguously reveal an easy-plane anisotropy of the V$^{\rm III}$ ion and antiferromagnetic Ising-like 3d-4f exchange couplings. The strength of $J_{\rm 3d-4f}$ is shown to decrease upon variation of the 4f ion from Tb to Ho, while increasing antiferromagnetic interaction can be observed from Ho to Tm. The exact inverse chemical trend is found for the relative angle between the 3d and 4f main anisotropy axes, which highlights the important role of the lanthanide 4f electron distribution anisotropy for 3d-4f exchange.

cond-mat.str-el↗
arXiv2025

Kinetic inductance coupling for circuit QED with spins

In contrast to the commonly used qubit resonator transverse coupling via the $\sigma_{xy}$-degree of freedom, longitudinal coupling through $\sigma_z$ presents a tantalizing alternative: it does not hybridize the modes, eliminating Purcell decay, and it enables quantum-non-demolishing qubit readout independent of the qubit-resonator frequency detuning. Here, we demonstrate longitudinal coupling between a {Cr$_7$Ni} molecular spin qubit ensemble and the kinetic inductance of a granular aluminum superconducting microwave resonator. The inherent frequency-independence of this coupling allows for the utilization of a 7.8 GHz readout resonator to measure the full {Cr$_7$Ni} magnetization curve spanning 0-600 mT, corresponding to a spin frequency range of $f_\text{spin}=$0-15 GHz. For 2 GHz detuning from the readout resonator, we measure a $1/e$ spin relaxation time $\tau=$0.38 s, limited by phonon decay to the substrate. Based on these results, we propose a path towards longitudinal coupling of single spins to a superconducting fluxonium qubit.

quant-ph↗
arXiv2025

Spin Environment of a Superconducting Qubit in High Magnetic Fields

Superconducting qubits equipped with quantum non-demolition readout and active feedback can be used as information engines to probe and manipulate microscopic degrees of freedom, whether intentionally designed or naturally occurring in their environment. In the case of spin systems, the required magnetic field bias presents a challenge for superconductors and Josephson junctions. Here we demonstrate a granular aluminum nanojunction fluxonium qubit (gralmonium) with spectrum and coherence resilient to fields beyond one Tesla. Sweeping the field reveals a paramagnetic spin-1/2 ensemble, which is the dominant gralmonium loss mechanism when the electron spin resonance matches the qubit. We also observe a suppression of MHz range fast flux noise in magnetic field, suggesting the freezing of surface spins. Using an active state stabilization sequence, the qubit hyperpolarizes long-lived two-level systems (TLSs) in its environment, previously speculated to be spins. Surprisingly, the coupling to these TLSs is unaffected by magnetic fields, leaving the question of their origin open. The robust operation of gralmoniums in Tesla fields offers new opportunities to explore unresolved questions in spin environment dynamics and facilitates hybrid architectures linking superconducting qubits with spin systems.

quant-ph↗
arXiv2023

Fano Interference in Microwave Resonator Measurements

Resonator measurements are a simple but powerful tool to characterize a material's microwave response. The losses of a resonant mode are quantified by its internal quality factor $Q_\mathrm{i}$, which can be extracted from the scattering coefficient in a microwave reflection or transmission measurement. Here we show that a systematic error on $Q_\mathrm{i}$ arises from Fano interference of the signal with a background path. Limited knowledge of the interfering paths in a given setup translates into a range of uncertainty for $Q_\mathrm{i}$, which increases with the coupling coefficient. We experimentally illustrate the relevance of Fano interference in typical microwave resonator measurements and the associated pitfalls encountered in extracting $Q_\mathrm{i}$. On the other hand, we also show how to characterize and utilize the Fano interference to eliminate the systematic error.

quant-ph↗
arXiv2022

Gralmonium: Granular Aluminum Nano-Junction Fluxonium Qubit

Mesoscopic Josephson junctions (JJs), consisting of overlapping superconducting electrodes separated by a nanometer thin oxide layer, provide a precious source of nonlinearity for superconducting quantum circuits and are at the heart of state-of-the-art qubits, such as the transmon and fluxonium. Here, we show that in a fluxonium qubit the role of the JJ can also be played by a lithographically defined, self-structured granular aluminum (grAl) nano-junction: a superconductor-insulator-superconductor (SIS) JJ obtained in a single layer, zero-angle evaporation. The measured spectrum of the resulting qubit, which we nickname gralmonium, is indistinguishable from the one of a standard fluxonium qubit. Remarkably, the lack of a mesoscopic parallel plate capacitor gives rise to an intrinsically large grAl nano-junction charging energy in the range of tens of $\mathrm{GHz}$, comparable to its Josephson energy $E_\mathrm{J}$. We measure average energy relaxation times of $T_1=10\,\mathrm{μs}$ and Hahn echo coherence times of $T_2^\text{echo}=9\,\mathrm{μs}$. The exponential sensitivity of the gralmonium to the $E_\text{J}$ of the grAl nano-junction provides a highly susceptible detector. Indeed, we observe spontaneous jumps of the value of $E_\text{J}$ on timescales from milliseconds to days, which offer a powerful diagnostics tool for microscopic defects in superconducting materials.

quant-ph↗
arXiv2020

Superconducting granular aluminum resonators resilient to magnetic fields up to 1 Tesla

High kinetic inductance materials constitute a valuable resource for superconducting quantum circuits and hybrid architectures. Superconducting granular aluminum (grAl) reaches kinetic sheet inductances in the nH/$\square$ range, with proven applicability in superconducting quantum bits and microwave detectors. Here we show that the single photon internal quality factor $Q_{\mathrm{i}}$ of grAl microwave resonators exceeds $10^5$ in magnetic fields up to 1T, aligned in-plane to the grAl films. Small perpendicular magnetic fields, in the range of 0.5mT, enhance $Q_{\mathrm{i}}$ by approximately 15%, possibly due to the introduction of quasiparticle traps in the form of fluxons. Further increasing the perpendicular field deteriorates the resonators' quality factor. These results open the door for the use of high kinetic inductance grAl structures in circuit quantum electrodynamics and hybrid architectures with magnetic field requirements.

cond-mat.supr-con↗
arXiv2018

Circuit Quantum Electrodynamics of Granular Aluminum Resonators

The introduction of crystalline defects or dopants can give rise to so-called "dirty superconductors", characterized by reduced coherence length and quasiparticle mean free path. In particular, granular superconductors such as Granular Aluminum (GrAl), consisting of remarkably uniform grains connected by Josephson contacts have attracted interest since the sixties thanks to their rich phase diagram and practical advantages, like increased critical temperature, critical field, and kinetic inductance. Here we report the measurement and modeling of circuit quantum electrodynamics properties of GrAl microwave resonators in a wide frequency range, up to the spectral superconducting gap. Interestingly, we observe self-Kerr coefficients ranging from $10^{-2}$ Hz to $10^5$ Hz, within an order of magnitude from analytic calculations based on GrAl microstructure. This amenable nonlinearity, combined with the relatively high quality factors in the $10^5$ range, open new avenues for applications in quantum information processing and kinetic inductance detectors.

cond-mat.supr-con↗
arXiv2017

Landau-Zener transition in a continuously measured single-molecule spin transistor

We monitor the Landau-Zener dynamics of a single-ion magnet in a spin-transistor geometry. For increasing field-sweep rates, the spin reversal probability shows increasing deviations from that of a closed system. In the low-conductance limit, such deviations are shown to result from a dephasing process. In particular, the observed behaviors are succesfully simulated by means of an adiabatic master equation, with time averaged dephasing (Lindblad) operators. The time average is tentatively interpeted in terms of the finite time resolution of the continuous measurement.

cond-mat.mes-hall↗
arXiv2016

Blocking transport resonances via Kondo entanglement in quantum dots

Many-body entanglement is at the heart of the Kondo effect, which has its hallmark in quantum dots as a zero-bias conductance peak at low temperatures. It signals the emergence of a conducting singlet state formed by a localized dot degree of freedom and conduction electrons. Carbon nanotubes offer the possibility to study the emergence of the Kondo entanglement by tuning many-body correlations with a gate voltage. Here we quantitatively show an undiscovered side of Kondo correlations, which counterintuitively tend to block conduction channels: inelastic cotunneling lines in the magnetospectrum of a carbon nanotube strikingly disappear when tuning the gate voltage. Considering the global \SUT\ $\otimes $ \SUT\ symmetry of a carbon nanotube coupled to leads, we find that only resonances involving flips of the Kramers pseudospins, associated to this symmetry, are observed at temperatures and voltages below the corresponding Kondo scale. Our results demonstrate the robust formation of entangled many-body states with no net pseudospin.

cond-mat.mes-hall↗
arXiv2013

Interplay of Kondo effect and strong spin-orbit coupling in multi-hole ultraclean carbon nanotubes

We report on cotunneling spectroscopy magnetoconductance measurements of multi-hole ultraclean carbon nanotube quantum dots in the SU(4) Kondo regime with strong spin-orbit coupling. Successive shells show a gradual weakening of the Kondo effect with respect to the spin-orbital splittings, leading to an evolution from SU(4) to SU(2) symmetry with a suppressed conductance at half shell filling. The extracted energy level spectrum, overally consistent with negligible disorder in the nanotube, shows in the half filled case large renormalizations due to Coulombian effects.

cond-mat.mes-hall↗
arXiv2011

Hysteresis loops of the magnetoconductance in graphene devices

We report very low temperature magnetoconductance DeltaG measurements on graphene devices with the magnetic field H applied parallel to the carbon sheet. The DeltaG(H) signal depends on the gate voltage Vg and its sign is related with the universal conductance fluctuations. When the magnetic field is swept at fast rates, DeltaG displays hysteresis loops evident for different sizes and at different transport regimes of the devices. We attribute this to the magnetization reversal of paramagnetic centres in graphene layer, which might originate from defects in our devices.

cond-mat.mes-hall↗
arXiv2010

On-chip SQUID measurements in the presence of high magnetic fields

We report a low temperature measurement technique and magnetization data of a quantum molecular spin, by implementing an on-chip SQUID technique. This technique enables the SQUID magnetometery in high magnetic fields, up to 7 Tesla. The main challenges and the calibration process are detailed. The measurement protocol is used to observe quantum tunneling jumps of the S=10 molecular magnet, Mn12-tBuAc. The effect of transverse field on the tunneling splitting for this molecular system is addressed as well.

cond-mat.mes-hall↗
arXiv2010

Spin transition in Gd$_3$N@C$_{80}$, detected by low-temperature on-chip SQUID technique

We present a magnetic study of the Gd$_3$N@C$_{80}$ molecule, consisting of a Gd-trimer via a Nitrogen atom, encapsulated in a C$_{80}$ cage. This molecular system can be an efficient contrast agent for Magnetic Resonance Imaging (MRI) applications. We used a low-temperature technique able to detect small magnetic signals by placing the sample in the vicinity of an on-chip SQUID. The technique implemented at NHMFL has the particularity to operate in high magnetic fields of up to 7 T. The Gd$_3$N@C$_{80}$ shows a paramagnetic behavior and we find a spin transition of the Gd$_3$N structure at 1.2 K. We perform quantum mechanical simulations, which indicate that one of the Gd ions changes from a $^8S_{7/2}$ state ($L=0, S=7/2$) to a $^7F_{6}$ state ($L=S=3, J=6$), likely due to a charge transfer between the C$_{80}$ cage and the ion.

cond-mat.mes-hall↗
arXiv2009

Superconductivity in a single C60 transistor

Single molecule transistors (SMTs) are currently attracting enormous attention as possible quantum information processing devices. An intrinsic limitation to the prospects of these however is associated to the presence of a small number of quantized conductance channels, each channel having a high access resistance of at best $R_{K}/2=h/2e^{2}$=12.9 k$Ω$. When the contacting leads become superconducting, these correlations can extend throughout the whole system by the proximity effect. This not only lifts the resistive limitation of normal state contacts, but further paves a new way to probe electron transport through a single molecule. In this work, we demonstrate the realization of superconducting SMTs involving a single C60 fullerene molecule. The last few years have seen gate-controlled Josephson supercurrents induced in the family of low dimensional carbon structures such as flakes of two-dimensional graphene and portions of one-dimensional carbon nanotubes. The present study involving a full zero-dimensionnal fullerene completes the picture.

cond-mat.mes-hall↗
arXiv2009

Reply to the comment on "Influence of the Dzyaloshinskii-Moriya Exchange Interaction on Quantum Phase Interference of Spins"

First version: del Barco et al. submitted recently a comment [arXiv:0812.4070] on our latest Phys. Rev. Lett. [Phys. Rev. Lett. 101, 237204 (2008)], claiming three basic mistakes. We show here that their claims are unjustified and based on erroneous calculations and hasty conclusions. Second version: reply to the modified version of del Barco et al. submitted to Phys. Rev. Lett.

cond-mat.mes-hall↗
arXiv2008

Influence of the Dzyaloshinskii-Moriya exchange interaction on quantum phase interference of spins

Magnetization measurements of a Mn12mda wheel single-molecule magnet with a spin ground state of S = 7 show resonant tunneling and quantum phase interference, which are established by studying the tunnel rates as a function of a transverse field applied along the hard magnetization axis. Dzyaloshinskii-Moriya (DM) exchange interaction allows the tunneling between different spin multiplets. It is shown that the quantum phase interference of these transitions is strongly dependent on the direction of the DM vector.

cond-mat.mes-hall↗
arXiv2008

Influence of antisymmetric exchange interaction on quantum tunneling of magnetization in a dimeric molecular magnet Mn6

We present magnetization measurements on the single molecule magnet Mn6, revealing various tunnel transitions inconsistent with a giant-spin description. We propose a dimeric model of the molecule with two coupled spins S=6, which involves crystal-field anisotropy, symmetric Heisenberg exchange interaction, and antisymmetric Dzyaloshinskii-Moriya exchange interaction. We show that this simplified model of the molecule explains the experimentally observed tunnel transitions and that the antisymmetric exchange interaction between the spins gives rise to tunneling processes between spin states belonging to different spin multiplets.

cond-mat.mes-hall↗