arXiv subjects

Weilu Gao

Publications and source records attributed to Weilu Gao.

At least 19 recordsLinked to original sources

arXiv2026

Chip-Scale Aligned Chiral Carbon Nanotubes Exhibiting Giant Second Harmonic Generation

Chiral carbon nanotubes (CNTs) are direct-gap semiconductors with optical properties governed by one-dimensional excitons with enormous oscillator strengths. Each species of chiral CNTs has an enantiomeric pair of left- and right-handed CNTs with nearly identical properties, but enantiomer-dependent phenomena can emerge, especially in nonlinear optical processes. Theoretical studies have predicted strong second-order nonlinearities in chiral CNTs, but no experimental quantitative verification has been reported due to the lack of macroscopically ordered assemblies of single-enantiomer chiral CNTs. Here, we report the synthesis of centimeter-scale, densely packed, aligned single-enantiomer chiral CNT films that are microfabrication-compatible. We observe giant second harmonic generation (SHG) emission from the chiral CNT film, which originates from the intrinsic chirality and inversion symmetry breaking of the atomic structure of chiral CNTs. The observed nonlinear susceptibility of the as-fabricated film reaches $4.9\times 10^2$\,pm/V at a pump wavelength of 1030\,nm, corresponding to the lowest-energy excitonic resonance, indicating $χ_{xyz} = 1.6\times 10^3$\,pm/V for a perfectly aligned CNT crystal. Our calculations based on many-body theory correctly estimate the spectrum and magnitude of such excitonically enhanced optical nonlinearity. These results are promising for the development of scalable chiral-CNT electronics and nonlinear photonics.

physics.app-ph↗

arXiv2026

All-Optical Segmentation via Diffractive Neural Networks for Autonomous Driving

Semantic segmentation and lane detection are crucial tasks in autonomous driving systems. Conventional approaches predominantly rely on deep neural networks (DNNs), which incur high energy costs due to extensive analog-to-digital conversions and large-scale image computations required for low-latency, real-time responses. Diffractive optical neural networks (DONNs) have shown promising advantages over conventional DNNs on digital or optoelectronic computing platforms in energy efficiency. By performing all-optical image processing via light diffraction at the speed of light, DONNs save computation energy costs while reducing the overhead associated with analog-to-digital conversions by all-optical encoding and computing. In this work, we propose a novel all-optical computing framework for RGB image segmentation and lane detection in autonomous driving applications. Our experimental results demonstrate the effectiveness of the DONN system for image segmentation on the CityScapes dataset. Additionally, we conduct case studies on lane detection using a customized indoor track dataset and simulated driving scenarios in CARLA, where we further evaluate the model's generalizability under diverse environmental conditions.

cs.CV↗

arXiv2026

A wafer-scale ultrasensitive programmable chiroptical sensor

Chiroptical enantioselective sensing is gaining traction across various applications. However, intrinsic molecular chiroptical responses are weak, and existing amplification approaches add synthesis, manufacturing, or operational complexity that limits sensitivity, scalability, and dynamic control. Here, we present a fundamentally new sensing paradigm merging adsorption-driven chirality induction with wafer-scale optical transduction in a programmable heterostructure containing twisted aligned carbon nanotubes (CNTs) and phase change materials (PCMs). Chiral molecules adsorb onto CNTs to form chiroptically active composites that are macroscopically assembled by alignment and rotational stacking, yielding large ultraviolet circular dichroism (CD). We resolve molecule concentration and handedness in a single device without lithography, hotspot delivery, or differential protocols, achieving sub-$μ$M sensitivity for CD-silent glucose and chiral amino acids enabled by $>10^5\,\mathrm{M^{-1}}$ adsorption constants. We validate adsorption using molecular dynamics simulations, reproduce experimental results using chiral transfer matrix simulations, and realize sensor programmability by tuning the PCM layer. This platform enables cost-effective in-situ enantiomer monitoring in aqueous environments.

physics.optics↗

arXiv2025

Fracture interactive geodesic active contours for bone segmentation

For bone segmentation, the classical geodesic active contour model is usually limited by its indiscriminate feature extraction, and then struggles to handle the phenomena of edge obstruction, edge leakage and bone fracture. Thus, we propose a fracture interactive geodesic active contour algorithm tailored for bone segmentation, which can better capture bone features and perform robustly to the presence of bone fractures and soft tissues. Inspired by orthopedic knowledge, we construct a novel edge-detector function that combines the intensity and gradient norm, which guides the contour towards bone edges without being obstructed by other soft tissues and therefore reduces mis-segmentation. Furthermore, distance information, where fracture prompts can be embedded, is introduced into the contour evolution as an adaptive step size to stabilize the evolution and help the contour stop at bone edges and fractures. This embedding provides a way to interact with bone fractures and improves the accuracy in the fracture regions. Experiments in pelvic and ankle segmentation demonstrate the effectiveness on addressing the aforementioned problems and show an accurate, stable and consistent performance, indicating a broader application in other bone anatomies. Our algorithm also provides insights into combining the domain knowledge and deep neural networks.

cs.CV↗

arXiv2025

MatterChat: A Multi-Modal LLM for Material Science

Understanding and predicting the properties of inorganic materials is crucial for accelerating advancements in materials science and driving applications in energy, electronics, and beyond. Integrating material structure data with language-based information through multi-modal large language models (LLMs) offers great potential to support these efforts by enhancing human-AI interaction. However, a key challenge lies in integrating atomic structures at full resolution into LLMs. In this work, we introduce MatterChat, a versatile structure-aware multi-modal LLM that unifies material structural data and textual inputs into a single cohesive model. MatterChat employs a bridging module to effectively align a pretrained machine learning interatomic potential with a pretrained LLM, reducing training costs and enhancing flexibility. Our results demonstrate that MatterChat significantly improves performance in material property prediction and human-AI interaction, surpassing general-purpose LLMs such as GPT-4. We also demonstrate its usefulness in applications such as more advanced scientific reasoning and step-by-step material synthesis.

cs.AI↗

arXiv2025

Carbon-Nanotube/$β$-Ga$_2$O$_3$ Heterojunction PIN Diodes

$β$-Ga$_2$O$_3$ is gaining attention as a promising semiconductor for next-generation high-power, high-efficiency, and high-temperature electronic devices, thanks to its exceptional material properties. However, challenges such as the lack of viable p-type doping have hindered its full potential, particularly in the development of ambipolar devices. This work introduces a novel heterojunction diode (HD) that combines p-type carbon nanotubes (CNTs) with i/n-type $β$-Ga$_2$O$_3$ to overcome these limitations. For the first time, a CNT/$β$-Ga$_2$O$_3$ hetero-p-n-junction diode is fabricated. Compared to a traditional Schottky barrier diode (SBD) with the same $β$-Ga$_2$O$_3$ epilayer, the CNT/$β$-Ga$_2$O$_3$ HD demonstrates significant improvements, including a higher rectifying ratio ($1.2 \times 10^{11}$), a larger turn-on voltage (1.96 V), a drastically reduced leakage current at temperatures up to 300 °C, and a 26.7% increase in breakdown voltage. Notably, the CNT/$β$-Ga$_2$O$_3$ HD exhibits a low ideality factor of 1.02, signifying an ideal interface between the materials. These results underline the potential of CNT/$β$-Ga$_2$O$_3$ heterojunctions for electronic applications, offering a promising solution to current limitations in $β$-Ga$_2$O$_3$-based devices.

physics.app-ph↗

arXiv2024

Optical modeling, solver, and design of wafer-scale single-enantiomer carbon nanotube film and reconfigurable chiral photonic device

The interaction of circularly polarized light with chiral matter and functional devices enables novel phenomena and applications. Recently, wafer-scale solid-state single-enantiomer carbon nanotube (CNT) films have become feasible and are emerging as a chiral photonic material platform thanks to their quantum-confinement-induced optical properties and facile scalable assembly. However, optical modeling, solver, and device design tools for such materials are non-existent. Here, we prepare wafer-scale single-enantiomer (6,5) and (11,-5) randomly oriented CNT films and create an optical material model based on measured experimental optical spectra. We also implement a highly-parallel graphic-processing-unit accelerated transfer matrix solver for general bi-anisotropic materials and layered structures. Further, we demonstrate reconfigurable chiral photonic devices in a heterostructure with phase change materials through machine learning-enabled efficient gradient-based inverse design and optimization. Our developed full stack of a chiral photonic material and device hardware platform and a corresponding high-performance differential-programming-enabled solver opens the door for future chiral photonic devices and applications based on single-enantiomer CNT films.

physics.optics↗

arXiv2024

Optical Neural Engine for Solving Scientific Partial Differential Equations

Solving partial differential equations (PDEs) is the cornerstone of scientific research and development. Data-driven machine learning (ML) approaches are emerging to accelerate time-consuming and computation-intensive numerical simulations of PDEs. Although optical systems offer high-throughput and energy-efficient ML hardware, there is no demonstration of utilizing them for solving PDEs. Here, we present an optical neural engine (ONE) architecture combining diffractive optical neural networks for Fourier space processing and optical crossbar structures for real space processing to solve time-dependent and time-independent PDEs in diverse disciplines, including Darcy flow equation, the magnetostatic Poisson equation in demagnetization, the Navier-Stokes equation in incompressible fluid, Maxwell's equations in nanophotonic metasurfaces, and coupled PDEs in a multiphysics system. We numerically and experimentally demonstrate the capability of the ONE architecture, which not only leverages the advantages of high-performance dual-space processing for outperforming traditional PDE solvers and being comparable with state-of-the-art ML models but also can be implemented using optical computing hardware with unique features of low-energy and highly parallel constant-time processing irrespective of model scales and real-time reconfigurability for tackling multiple tasks with the same architecture. The demonstrated architecture offers a versatile and powerful platform for large-scale scientific and engineering computations.

physics.optics↗

arXiv2024

Digitized Phase Change Material Heterostack for Diffractive Optical Neural Network

All-optical and fully reconfigurable diffractive optical neural network (DONN) architectures are promising for high-throughput and energy-efficient machine learning (ML) hardware accelerators for broad applications. However, current device and system implementations have limited performance. This work demonstrates a novel diffractive device architecture, which is named digitized heterostack and consists of multiple layers of nonvolatile phase change materials (PCMs) with different thicknesses. This architecture can both leverage the advantages of PCM optical properties and mitigate challenges associated with implementing multilevel operations in a single PCM layer. Proof-of-concept experiments demonstrate the electrical tuning of one PCM layer in a spatial light modulation device, and thermal analysis guides the design of DONN devices and systems to avoid thermal crosstalk if individual heterostacks are assembled into an array. Further, heterostacks containing three PCM layers are designed to have a large phase modulation range and uniform coverage and the ML performance of DONN systems with designed heterostacks is evaluated. The developed device architecture provides new opportunities for desirable energy-efficient, fast-reconfigured, and compact DONN systems in the future.

physics.optics↗

arXiv2024

A programmable wafer-scale chiroptical heterostructure of twisted aligned carbon nanotubes and phase change materials

The ability to design and dynamically control chiroptical responses in solid-state matter at wafer scale enables new opportunities in various areas. Here we present a full stack of computer-aided designs and experimental implementations of a dynamically programmable, unified, scalable chiroptical heterostructure containing twisted aligned one-dimensional (1D) carbon nanotubes (CNTs) and non-volatile phase change materials (PCMs). We develop a software infrastructure based on high-performance machine learning frameworks, including differentiable programming and derivative-free optimization, to efficiently optimize the tunability of both excitonic reciprocal and linear-anisotropy-induced nonreciprocal circular dichroism (CD) responses. We experimentally implement designed heterostructures with wafer-scale self-assembled aligned CNTs and deposited PCMs. We dynamically program reciprocal and nonreciprocal CD responses by inducing phase transitions of PCMs, and nonreciprocal responses display polarity reversal of CD upon sample flipping in broadband spectral ranges. All experimental results agree with simulations. Further, we demonstrate that the vertical dimension of heterostructure is scalable with the number of stacking layers and aligned CNTs play dual roles - the layer to produce CD responses and the Joule heating electrode to electrically program PCMs. This heterostructure platform is versatile and expandable to a library of 1D nanomaterials and electro-optic materials for exploring novel chiral phenomena and photonic and optoelectronic devices.

physics.optics↗

arXiv2024

A critical review on recent progress of solution-processed monolayer assembly of nanomaterials and applications

The rapid development in nanotechnology has necessitated accurate and efficient assembly strategies for nanomaterials. Monolayer assembly of nanomaterials (MAN) represents an extreme challenge in manufacturing and is critical in understanding interactions among nanomaterials, solvents, and substrates. MAN enables highly tunable performance in electronic and photonic devices. This review summarizes the recent progress on the methods to achieve MAN and discusses important control factors. Moreover, the importance of MAN is elaborated by a broad range of applications in electronics and photonics. In the end, we outlook the opportunities as well as challenges in manufacturing and new applications.

physics.app-ph↗

arXiv2023

LightRidge: An End-to-end Agile Design Framework for Diffractive Optical Neural Networks

To lower the barrier to diffractive optical neural networks (DONNs) design, exploration, and deployment, we propose LightRidge, the first end-to-end optical ML compilation framework, which consists of (1) precise and differentiable optical physics kernels that enable complete explorations of DONNs architectures, (2) optical physics computation kernel acceleration that significantly reduces the runtime cost in training, emulation, and deployment of DONNs, and (3) versatile and flexible optical system modeling and user-friendly domain-specific-language (DSL). As a result, LightRidge framework enables efficient end-to-end design and deployment of DONNs, and significantly reduces the efforts for programming, hardware-software codesign, and chip integration. Our results are experimentally conducted with physical optical systems, where we demonstrate: (1) the optical physics kernels precisely correlated to low-level physics and systems, (2) significant speedups in runtime with physics-aware emulation workloads compared to the state-of-the-art commercial system, (3) effective architectural design space exploration verified by the hardware prototype and on-chip integration case study, and (4) novel DONN design principles including successful demonstrations of advanced image classification and image segmentation task using DONNs architecture and topology.

cs.AR↗

arXiv2023

Transition from Diffusive to Superdiffusive Transport in Carbon Nanotube Networks via Nematic Order Control

The one-dimensional confinement of quasiparticles in individual carbon nanotubes (CNTs) leads to extremely anisotropic electronic and optical properties. In a macroscopic ensemble of randomly oriented CNTs, this anisotropy disappears together with other properties that make them attractive for certain device applications. The question however remains if not only anisotropy, but other types of behaviours are suppressed by disorder. Here, we compare the dynamics of quasiparticles under strong electric fields in aligned and random CNT networks using a combination of terahertz emission and photocurrent experiments and out-of-equilibrium numerical simulations. We find that the degree of alignment strongly influences the excited quasiparticles' dynamics, rerouting the thermalisation pathways. This is, in particular, evidenced in the high-energy, high-momentum electronic population (probed through the formation of low energy excitons via exciton impact ionization) and the transport regime evolving from diffusive to superdiffusive.

cond-mat.mtrl-sci↗

arXiv2023

Rubik's Optical Neural Networks: Multi-task Learning with Physics-aware Rotation Architecture

Recently, there are increasing efforts on advancing optical neural networks (ONNs), which bring significant advantages for machine learning (ML) in terms of power efficiency, parallelism, and computational speed. With the considerable benefits in computation speed and energy efficiency, there are significant interests in leveraging ONNs into medical sensing, security screening, drug detection, and autonomous driving. However, due to the challenge of implementing reconfigurability, deploying multi-task learning (MTL) algorithms on ONNs requires re-building and duplicating the physical diffractive systems, which significantly degrades the energy and cost efficiency in practical application scenarios. This work presents a novel ONNs architecture, namely, \textit{RubikONNs}, which utilizes the physical properties of optical systems to encode multiple feed-forward functions by physically rotating the hardware similarly to rotating a \textit{Rubik's Cube}. To optimize MTL performance on RubikONNs, two domain-specific physics-aware training algorithms \textit{RotAgg} and \textit{RotSeq} are proposed. Our experimental results demonstrate more than 4$\times$ improvements in energy and cost efficiency with marginal accuracy degradation compared to the state-of-the-art approaches.

cs.LG↗

arXiv2023

Physics-aware Roughness Optimization for Diffractive Optical Neural Networks

As a representative next-generation device/circuit technology beyond CMOS, diffractive optical neural networks (DONNs) have shown promising advantages over conventional deep neural networks due to extreme fast computation speed (light speed) and low energy consumption. However, there is a mismatch, i.e., significant prediction accuracy loss, between the DONN numerical modelling and physical optical device deployment, because of the interpixel interaction within the diffractive layers. In this work, we propose a physics-aware diffractive optical neural network training framework to reduce the performance difference between numerical modeling and practical deployment. Specifically, we propose the roughness modeling regularization in the training process and integrate the physics-aware sparsification method to introduce sparsity to the phase masks to reduce sharp phase changes between adjacent pixels in diffractive layers. We further develop $2π$ periodic optimization to reduce the roughness of the phase masks to preserve the performance of DONN. Experiment results demonstrate that, compared to state-of-the-arts, our physics-aware optimization can provide $35.7\%$, $34.2\%$, $28.1\%$, and $27.3\%$ reduction in roughness with only accuracy loss on MNIST, FMNIST, KMNIST, and EMNIST, respectively.

cs.LG↗

arXiv2023

Scientific Computing with Diffractive Optical Neural Networks

Diffractive optical neural networks (DONNs) have been emerging as a high-throughput and energy-efficient hardware platform to perform all-optical machine learning (ML) in machine vision systems. However, the current demonstrated applications of DONNs are largely straightforward image classification tasks, which undermines the prospect of developing and utilizing such hardware for other ML applications. Here, we numerically and experimentally demonstrate the deployment of an all-optical reconfigurable DONNs system for scientific computing, including guiding two-dimensional quantum material synthesis, predicting the properties of nanomaterials and small molecular cancer drugs, predicting the device response of nanopatterned integrated photonic power splitters, and the dynamic stabilization of an inverted pendulum with reinforcement learning. Despite a large variety of input data structures, we develop a universal feature engineering approach to convert categorical input features to the images that can be processed in the DONNs system. Our results open up new opportunities of employing DONNs systems for a broad range of ML applications.

cs.LG↗

arXiv2023

Controlled synthetic chirality in macroscopic assemblies of carbon nanotubes

There is an emerging recognition that successful utilization of chiral degrees of freedom can bring new scientific and technological opportunities to diverse research areas. Hence, methods are being sought for creating artificial matter with controllable chirality in an uncomplicated and reproducible manner. Here, we report the development of two straightforward methods for fabricating wafer-scale chiral architectures of ordered carbon nanotubes (CNTs) with tunable and giant circular dichroism (CD). Both methods employ simple approaches, (i) mechanical rotation and (ii) twist-stacking, based on controlled vacuum filtration and do not involve any sophisticated nanofabrication processes. We used a racemic mixture of CNTs as the starting material, so the intrinsic chirality of chiral CNTs is not responsible for the observed chirality. In particular, by controlling the stacking angle and handedness in (ii), we were able to maximize the CD response and achieve a record-high deep-ultraviolet ellipticity of 40 $\pm$ 1 mdeg/nm. Our theoretical simulations using the transfer matrix method reproduce the salient features of the experimentally observed CD spectra and further predict that a film of twist-stacked CNTs with an optimized thickness will exhibit an ellipticity as high as 150 mdeg/nm. The created wafer-scale objects represent a new class of synthetic chiral matter consisting of ordered quantum wires whose macroscopic properties are governed by nanoscopic electronic signatures such as van Hove singularities. These artificial structures with engineered chirality will not only provide playgrounds for uncovering new chiral phenomena but also open up new opportunities for developing high-performance chiral photonic and optoelectronic devices.

physics.optics↗

arXiv2022

Physics-aware Differentiable Discrete Codesign for Diffractive Optical Neural Networks

Diffractive optical neural networks (DONNs) have attracted lots of attention as they bring significant advantages in terms of power efficiency, parallelism, and computational speed compared with conventional deep neural networks (DNNs), which have intrinsic limitations when implemented on digital platforms. However, inversely mapping algorithm-trained physical model parameters onto real-world optical devices with discrete values is a non-trivial task as existing optical devices have non-unified discrete levels and non-monotonic properties. This work proposes a novel device-to-system hardware-software codesign framework, which enables efficient physics-aware training of DONNs w.r.t arbitrary experimental measured optical devices across layers. Specifically, Gumbel-Softmax is employed to enable differentiable discrete mapping from real-world device parameters into the forward function of DONNs, where the physical parameters in DONNs can be trained by simply minimizing the loss function of the ML task. The results have demonstrated that our proposed framework offers significant advantages over conventional quantization-based methods, especially with low-precision optical devices. Finally, the proposed algorithm is fully verified with physical experimental optical systems in low-precision settings.

cs.AI↗