arXiv subjects

Weiwei Zhao

Publications and source records attributed to Weiwei Zhao.

At least 19 recordsLinked to original sources

arXiv2026

Nitrogen doping induced metal-insulator transition with iso-symmetric character in rutile VO2

Metal-insulator transitions (MITs) in correlated oxides offer immense potential for next-generation Mottronic devices. However, their integration into practical applications is often hindered by the coupling of MITs with symmetry-lowering structural phase transitions, which limits switching speed and endurance. In this study, we engineered an iso-symmetric MIT on average in epitaxial rutile VO2 thin films via an in-situ nitrogen doping strategy. Nitrogen incorporation effectively suppresses V-V dimerization, enabling an iso-symmetric MIT, while preserving the original crystal symmetry. Furthermore, in-operando time-resolved optical reflectivity measurements revealed a shortened switching time in nitrogen-doped films, highlighting their enhanced performance. Our findings provide critical insights into the underlying mechanisms of MITs and introduce anion doping as a powerful tool for tailoring phase transitions in strongly correlated electron systems. This approach opens new avenues for the development of high-performance electronic and photonic devices.

cond-mat.mtrl-sci↗

arXiv2026

Joint Optimization of Flexible Antenna Array Shape and Beamforming for Secure Communication

Flexible antenna arrays (FAAs) can physically reshape their geometry to add new spatial degrees of freedom, whereas transmit beamforming adjusts the complex element weights to electronically steer and shape the array's radiation pattern, thereby significantly improving communication performance. This paper is the first to explore the integration of FAA geometry control and beamforming for physical layer security enhancement, where a base station equipped with an FAA communicates with a legitimate user in the presence of passive eavesdroppers. To safeguard confidential transmissions, we formulate a new secrecy rate maximization problem that jointly optimizes the transmit beamforming vector and a continuous FAA shape control parameter. Due to the non convex nature of the problem, an alternating optimization algorithm is developed to decompose the joint design into tractable subproblems, which are solved iteratively to refine both the FAA geometry and beamforming strategy. Simulation results confirm that the proposed joint optimization framework significantly outperforms conventional fixed shape or beamforming only schemes, demonstrating the potential of FAA enabled reconfigurability for secure wireless communications.

eess.SP↗

arXiv2026

Vulnerabilities of Audio-Based Biometric Authentication Systems Against Deepfake Speech Synthesis

As audio deepfakes transition from research artifacts to widely available commercial tools, robust biometric authentication faces pressing security threats in high-stakes industries. This paper presents a systematic empirical evaluation of state-of-the-art speaker authentication systems based on a large-scale speech synthesis dataset, revealing two major security vulnerabilities: 1) modern voice cloning models trained on very small samples can easily bypass commercial speaker verification systems; and 2) anti-spoofing detectors struggle to generalize across different methods of audio synthesis, leading to a significant gap between in-domain performance and real-world robustness. These findings call for a reconsideration of security measures and stress the need for architectural innovations, adaptive defenses, and the transition towards multi-factor authentication.

cs.SD↗

arXiv2025

Multimodal Peer Review Simulation with Actionable To-Do Recommendations for Community-Aware Manuscript Revisions

While large language models (LLMs) offer promising capabilities for automating academic workflows, existing systems for academic peer review remain constrained by text-only inputs, limited contextual grounding, and a lack of actionable feedback. In this work, we present an interactive web-based system for multimodal, community-aware peer review simulation to enable effective manuscript revisions before paper submission. Our framework integrates textual and visual information through multimodal LLMs, enhances review quality via retrieval-augmented generation (RAG) grounded in web-scale OpenReview data, and converts generated reviews into actionable to-do lists using the proposed Action:Objective[\#] format, providing structured and traceable guidance. The system integrates seamlessly into existing academic writing platforms, providing interactive interfaces for real-time feedback and revision tracking. Experimental results highlight the effectiveness of the proposed system in generating more comprehensive and useful reviews aligned with expert standards, surpassing ablated baselines and advancing transparent, human-centered scholarly assistance.

cs.CL↗

arXiv2025

Quality over Quantity: Boosting Data Efficiency Through Ensembled Multimodal Data Curation

In an era overwhelmed by vast amounts of data, the effective curation of web-crawl datasets is essential for optimizing model performance. This paper tackles the challenges associated with the unstructured and heterogeneous nature of such datasets. Traditional heuristic curation methods often inadequately capture complex features, resulting in biases and the exclusion of relevant data. We introduce an advanced, learning-driven approach, Ensemble Curation Of DAta ThroUgh Multimodal Operators (EcoDatum), incorporating a novel quality-guided deduplication method to ensure balanced feature distributions. EcoDatum strategically integrates various unimodal and multimodal data curation operators within a weak supervision ensemble framework, utilizing automated optimization to score each data point effectively. EcoDatum, which significantly improves the data curation quality and efficiency, outperforms existing state-of-the-art (SOTA) techniques, ranked 1st on the DataComp leaderboard, with an average performance score of 0.182 across 38 diverse evaluation datasets. This represents a 28% improvement over the DataComp baseline method, demonstrating its effectiveness in improving dataset curation and model training efficiency.

cs.LG↗

arXiv2024

Spontaneous Motion of Liquid Droplets on Soft Gradient Surfaces

We report an experimental investigation of the spontaneous motion of liquid droplets on soft gels with a crosslinking gradient. By systematically adjusting the spatial difference in crosslinking density, we observed that millimeter-sized liquid droplets moved along the gradient of elastic modulus and even climbed tilted slopes against gravity. Unlike the wetting dynamics of micro-droplets, which are governed by elastocapillary effects, we demonstrated that the observed spontaneous movements of millimeter-sized droplets were attributed to the surface energy difference resulting from the variation in crosslinking density. Using {\em in-situ} confocal microscopy imaging, we analyzed the viscoelastic dissipation induced by the moving wetting ridges near dynamic contact lines. Based on the relationship between the crosslinking density and surface energy of soft gels, our findings reveal a new method for controlling droplet dynamics at soft and dissipative interfaces.

cond-mat.soft↗

arXiv2023

Emergence and Growth Dynamics of Wetting-induced Phase Separation on Soft Solids

Liquid droplets on soft solids, such as soft polymeric gels, can induce substantial surface deformations, leading to the formation of wetting ridges at contact points. While these contact ridges have been shown to govern the rich surface mechanics on compliant substrates, the inherently divergent characteristics of contact points and the multiphase nature of soft reticulated gels pose great challenges for continuum mechanical theories in modeling soft wetting phenomena. In this study, we report in-situ experimental characterizations of the emergence and growth dynamics of the wetting-induced phase separation. The measurements demonstrate how the migration of free chains prevents the stress singularities at contact points. Based on the Onsager variational principle, we present a phenomenological model that effectively captures the extraction process of free chains, including a crossover from a short-term diffusive state to a long-term equilibrium state. By comparing model predictions with experimental results for varied crosslinking densities, we reveal how the intrinsic material parameters of soft gels dictate phase separation dynamics.

cond-mat.soft↗

arXiv2023

Gd-Based Solvated Shells for Defect Passivation of CsPbBr$_3$ Nanoplatelets Enabling Efficient Color-Saturated Blue Electroluminescence

Reduced-dimensional CsPbBr$_3$ nanoplatelets (NPLs) are promising candidates for color-saturated blue emitters, yet their electroluminescence performance is hampered by non-radiative recombination, which is associated with bromine vacancies. Here, we show that a post-synthetic treatment of CsPbBr$_3$ NPLs with GdBr$_3$-dimethylformamide (DMF) can effectively eliminate defects while preserving the color. According to a combined experimental and theoretical study, Gd$^{3+}$ ions are less reactive with NPLs as a result of compact interaction between them and DMF, and this stable Gd$^{3+}$-DMF solvation structure makes Brions more available and allows them to move more freely. Consequently, defects are rapidly passivated and photoluminescence quantum yield increases dramatically (from 35 to ~100%), while the surface ligand density and emission color remain unchanged. The result is a remarkable electroluminescence efficiency of 2.4% (at 464 nm), one of the highest in pure blue perovskite NPL light-emitting diodes. It is noteworthy that the conductive NPL film shows a high photoluminescence quantum yield of 80%, demonstrating NPLs' significant electroluminescence potential with further device structure design.

physics.app-ph↗

arXiv2023

Tunable positions of Weyl nodes via magnetism and pressure in the ferromagnetic Weyl semimetal CeAlSi

The noncentrosymmetric ferromagnetic Weyl semimetal CeAlSi with simultaneous space-inversion (SI) and time-reversal (TR) symmetry breaking provides a unique platform for the exploration of novel topological states. Here, by employing electrical and thermoelectrical transport, angle-resolved photoemission spectroscopy (ARPES), high-pressure techniques, and band calculations, we demonstrate that magnetism and pressure can serve as efficient parameters to tune the positions of Weyl nodes in CeAlSi. At ambient pressure, an anomalous Hall effect (AHE) and an anomalous Nernst effect (ANE) arise in the paramagnetic state, and then are enhanced when temperature approaches the ferromagnetic ordering temperature, evidencing magnetism facilitates the AHE/ANE. Such an enhancement of AHE/ANE can be ascribed to the tuning of the positions of Weyl nodes via magnetism. The ARPES measurements reveal that the ferromagnetism serves as a pivotal knob to tune the band structure of CeAlSi both in the bulk and on the surface. Such magnetism-tunable electronic structure has hitherto not been reported in other magnetic $R$Al$Pn$ ($R$ = rare earth elements, $Pn$ = Si, Ge) siblings, suggesting the great potential of controlling Weyl node positions in CeAlSi. Under pressure, an enhancement and a sign change of AHE are discovered. Based on band calculations, the evolution of AHE may root in the tuning of Weyl nodes via pressure. Moreover, multiple pressure-induced phase transitions are uncovered. These findings indicate that CeAlSi provides a unique and tunable platform for exploring exotic topological physics and electron correlations, as well as catering to an array of potential applications, such as spintronics and thermoelectrics.

cond-mat.mtrl-sci↗

arXiv2022

Semimetal Contacts to Monolayer Semiconductor: Weak Metalization as an Effective Mechanism to Schottky Barrier Lowering

Recent experiment has uncovered semimetal bismuth (Bi) as an excellent electrical contact to monolayer MoS$_2$ with ultralow contact resistance. The contact physics of the broader semimetal/monolayer-semiconductor family beyond Bi/MoS$_2$, however, remains largely unexplored thus far. Here we perform a comprehensive first-principle density functional theory investigation on the electrical contact properties between six archetypal two-dimensional (2D) transition metal dichalcogenide (TMDC) semiconductors, i.e. MoS$_2$, WS$_2$, MoSe$_2$, WSe$_2$, MoTe$_2$ and WTe$_2$, and two representative types of semimetals, Bi and antimony (Sb). As Bi and Sb work functions energetically aligns well with the TMDC conduction band edge, Ohmic or nearly-Ohmic $n$-type contacts are prevalent. The interlayer distance of semimetal/TMDC contacts are significantly larger than that of the metal/TMDC counterparts, which results in only weak metalization of TMDC upon contact formation. Intriguingly, such weak metalization generates semimetal-induced gap states (MIGS) that extends below the conduction band minimum, thus offering an effective mechanism to reduce or eliminate the $n$-type Schottky barrier height (SBH) while still preserving the electronic structures of 2D TMDC. A modified Schottky-Mott rule that takes into account SMIGS, interface dipole potential, and Fermi level shifting is proposed, which provides an improved agreement with the DFT-simulated SBH. We further show that the tunneling-specific resistivity of Sb/TMDC contacts are generally lower than the Bi counterparts, thus indicating a better charge injection efficiency can be achieved through Sb contacts. Our findings reveal the promising potential of Bi and Sb as excellent companion electrode materials for advancing 2D semiconductor device technology.

cond-mat.mtrl-sci↗

arXiv2022

Non-monotonic Rheology and Stress Heterogeneity in confined Granular suspensions

We systematically investigated the impact of boundary confinement on the shear-thickening rheology of dense granular suspensions. Under highly confined conditions, dense suspensions were found to exhibit size-dependent or even rarely reported non-monotonic ($S$-shaped) flow curves in steady states. By performing in-situ boundary stress microscopy measurements, we observed enhanced flow heterogeneities in confined suspensions, where concentrated high-stress domains propagated stably either along or against the shear direction. By comparing the boundary stress microscopy results with macroscopic flow responses, we revealed the connection between non-monotonic rheology and stress heterogeneity in confined suspensions. These findings suggest the possibility of controlling suspension rheology by imposing different boundary confinements.

cond-mat.soft↗

arXiv2022

2D Janus Niobium Oxydihalide NbO$XY$: Multifunctional High-Mobility Piezoelectric Semiconductor for Electronics, Photonics and Sustainable Energy Applications

Two-dimensional (2D) niobium oxydihalide NbOI$_2$ has been recently demonstrated as an excellent in-plane piezoelectric and nonlinear optical materials. Here we show that Janus niobium oxydihalide, NbO$XY$ (X, Y = Cl, Br, I and X$\neq$Y), is a multifunctional anisotropic semiconductor family with exceptional piezoelectric, electronic, photocatalytic and optical properties. NbO$XY$ are stable and mechancially flexible monolayers with band gap around the visible light regime of $\sim 1.9$ eV. The anisotropic carrier mobility of NbO$XY$ lies in the range of $10^3 \sim 10^4$ cm$^2$V$^{-1}$s$^{-1}$, which represents some of the highest among 2D semiconductors of bandgap $\gtrsim 2$ eV. Inversion symmetry breaking in Janus NbO$XY$ generates sizable out-of-plane $d_{31}$ piezoelectric response while still retaining a strong in-plane piezoelectricity. Remarkably, NbO$XY$ exhibits an additional out-of-plane piezoelectric response, $d_{32}$ as large as 0.55 pm/V. G$_0$W$_0$-BSE calculation further reveals the strong linear optical dichroism of NbO$XY$ in the visible-to-ultraviolet regime. The optical absorption peaks with $14\sim18$ \% in the deep UV regime ($5\sim6$ eV), outperforming the vast majority of other 2D materials. The high carrier mobility, strong optical absorption, sizable built-in electric field and band alignment compatible with overall water splitting further suggest the strengths of NbO$XY$ in energy conversion application. We further propose a directional stress sensing device to demonstrate how the out-of-plane piezoelectricity can be harnessed for functional device applications. Our findings unveil NbO$XY$ as an exceptional multifunctional 2D semiconductor for flexible electronics, optoelectronics, UV photonics, piezoelectric and sustainable energy applications.

cond-mat.mtrl-sci↗

arXiv2022

Cryogenic in-memory computing using magnetic topological insulators

Machine learning algorithms have been proven effective for essential quantum computation tasks such as quantum error correction and quantum control. Efficient hardware implementation of these algorithms at cryogenic temperatures is essential. Here, we utilize magnetic topological insulators as memristors (termed magnetic topological memristors) and introduce a cryogenic in-memory computing scheme based on the coexistence of the chiral edge state and the topological surface state. The memristive switching and reading of the giant anomalous Hall effect exhibit high energy efficiency, high stability, and low stochasticity. We achieve high accuracy in a proof-of-concept classification task using four magnetic topological memristors. Furthermore, our algorithm-level and circuit-level simulations of large-scale neural networks demonstrate software-level accuracy and lower energy consumption for image recognition and quantum state preparation compared with existing magnetic memristor and CMOS technologies. Our results not only showcase a new application of chiral edge states but also may inspire further topological quantum physics-based novel computing schemes.

cond-mat.mes-hall↗

arXiv2022

Evolution of Dopant-Concentration-Induced Magnetic Exchange Interaction in Topological Insulator Thin Films

Two essential ingredients for the quantum anomalous Hall (QAH) effect, i.e. topological and magnetic orders, can be combined by doping magnetic ions into a topological insulator (TI) film. Through this approach, the QAH effect has been realized in chromium (Cr)- and/or vanadium (V)-doped TI (Bi,Sb)2Te3 thin films. In this work, we synthesize both V- and Cr-doped Bi2Te3 thin films with controlled dopant concentration using molecular beam epitaxy (MBE). By performing magneto-transport measurements, we find that both systems show an unusual but yet similar ferromagnetic response with respect to magnetic dopant concentration, specifically the Curie temperature does not increase monotonically but shows a local maximum at a critical dopant concentration. Our angle-resolved photoemission spectroscopy (ARPES) measurements show that the Cr/V doping introduces hole carriers into Bi2Te3, which consequently move the chemical potential toward the charge neutral point. In addition, the Cr/V doping also reduces the spin-orbit coupling of Bi2Te3 which drives it from a nontrivial TI to a trivial semiconductor. The unusual ferromagnetic response observed in Cr/V-doped Bi2Te3 thin films is attributed to the dopant-concentration-induced magnetic exchange interaction, which displays the evolution from the van Vleck-type ferromagnetism in a nontrivial magnetic TI to the Ruderman-Kittel-Kasuya-Yosida (RKKY)-type ferromagnetism in a trivial diluted magnetic semiconductor. Our work provides insights into the ferromagnetic properties of magnetically doped TI thin films and facilitates the pursuit of high-temperature QAH effect.

cond-mat.mes-hall↗

arXiv2022

Nontrivial topological states in BaSn5 superconductor probed by de Haas-van Alphen quantum oscillations

We report herein the nontrivial topological states in an intrinsic type-II superconductor BaSn5 (Tc ~ 4.4 K) probed via measuring the magnetizations, specific heat, de Haas-van Alphen (dHvA) effect and performing first principles calculations. The first principles calculations reveal a topological nodal ring structure centering at the H point in the kz = π plane of the Brillouin zone (BZ), which could be gapped by spin-orbit coupling (SOC), yielding rather small gaps below and above the Fermi level about 0.04 eV and 0.14 eV, respectively. The SOC also results in a pair of Dirac points along the Γ-A direction and located ~ 0.2 eV above the Fermi level. The analysis of the dHvA quantum oscillations supports the calculations by revealing nontrivial Berry phase originated from three hole and one electron pockets related to the bands forming the Dirac cones. Our study thus provides an excellent avenue for investigating the interplay between superconductivity and nontrivial topological states.

cond-mat.supr-con↗

arXiv2022

Critical topology and pressure-induced superconductivity in the van der Waals compound AuTe2Br

The study on quantum spin Hall effect and topological insulators formed the prologue to the surge of research activities in topological materials in the past decade. Compared to intricately engineered quantum wells, three-dimensional weak topological insulators provide a natural route to the quantum spin Hall effect, due to the adiabatic connection between them and a stack of quantum spin Hall insulators, and the convenience in exfoliation of samples associated with their van der Waals-type structure. Despite these advantages, both theoretical prediction and experimental identification of weak topological insulators remain scarce. Here, based on first-principles calculations, we show that AuTe2Br locates at the boundary between a strong and a weak topological insulating state. More interestingly, the critical topology of AuTe2Br persists up to an applied pressure of ~ 15.4 GPa before a structural phase transition accompanied by a change of electronic topology and the onset of superconductivity. Our results establish AuTe2Br as a new candidate for weak topological insulators with the potential to realize various other topological phases of matter.

cond-mat.mtrl-sci↗

arXiv2021

Long-Range Superconducting Proximity Effect in Nickel Nanowires

When a ferromagnet is placed in contact with a superconductor, owing to incompatible spin order, the Cooper pairs from the superconductor cannot survive more than one or two nanometers inside the ferromagnet. This is confirmed in the measurements of ferromagnetic nickel (Ni) nanowires contacted by superconducting niobium (Nb) leads. However, when a 3 nm thick copper oxide (CuO) buffer layer made by exposing an evaporated or a sputtered 3 nm Cu film to air, is inserted between the Nb electrodes and the Ni wire, the spatial extent of the superconducting proximity range is dramatically increased from 2 to a few tens of nanometers. Scanning transmission electron microscope study confirms the formation of a 3 nm thick CuO layer when an evaporated Cu film is exposed to air. Magnetization measurements of such a 3 nm CuO film on a SiO2/Si substrate and on Nb/SiO2/Si show clear evidence of ferromagnetism. One way to understand the long-range proximity effect in the Ni nanowire is that the CuO buffer layer with ferromagnetism facilitates the conversion of singlet superconductivity in Nb into triplet supercurrent along the Ni nanowires.

cond-mat.supr-con↗

arXiv2021

The role of crosslinking density in surface stress and surface energy of soft solids

Surface stress and surface energy are two fundamental parameters that determine the surface properties of any materials. While it is commonly believed that the surface stress and surface energy of liquids are identical, the relationship between the two parameters in soft polymeric gels remains debatable. In this work, we measured the surface stress and surface energy of soft silicone gels with varying weight ratios of crosslinkers in soft wetting experiments. Above a critical density, $k_0$, the surface stress was found to increase significantly with crosslinking density while the surface energy remained unchanged. In this regime, we can estimate a non-zero surface elastic modulus that also increases with the ratio of crosslinkers. By comparing the surface mechanics of the soft gels with their bulk rheology, the surface properties near the critical density $k_0$ were found to be closely related to the underlying percolation transition of the polymer networks.

cond-mat.soft↗