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Will R. M. Rocha

Publications and source records attributed to Will R. M. Rocha.

15 recordsLinked to original sources

A fast machine learning tool to predict the composition of astronomical ices from infrared absorption spectra

Current observations taken by James Webb Space Telescope (JWST) allow us to observe the absorption features of icy mantles that cover interstellar dust grains, which are mainly composed of $\mathrm{H_2O}$, $\mathrm{CO}$, and $\mathrm{CO_2}$, along with other minor species. Thanks to its sensitivity and spectral resolution, JWST has the potential to observe ice features towards hundreds of sources at different stages along the process of star formation. However, identifying the spectral features of the different species and quantifying the ice composition is not trivial and requires complex spectroscopic analysis. We present Automatic Ice Composition Estimator (AICE), a new tool based on artificial neural networks. Based on the infrared (IR) ice absorption spectrum between 2.5 and 10 microns, AICE predicts the ice fractional composition in terms of $\mathrm{H_2O}$, $\mathrm{CO}$, $\mathrm{CO_2}$, $\mathrm{CH_3OH}$, $\mathrm{NH_3}$, and $\mathrm{CH_4}$. To train the model, we used hundreds of laboratory experiments of ice mixtures from different databases, which were reprocessed with baseline subtraction and normalisation. Once trained, AICE takes less than one second on a conventional computer to predict the ice composition associated with the observed IR absorption spectrum, with typical errors of $\sim$3 $\%$ in the species fraction. We tested its performance on two spectra reported towards the NIR38 and J110621 background stars observed within the JWST Ice Age program, demonstrating a good agreement with previous estimations of the ice composition. The fast and accurate performance of AICE enables the systematic analysis of hundreds of different ice spectra with a modest time investment. In addition, this model can be enhanced and re-trained with more laboratory data, improving the precision of the predictions and expanding the list of predicted species.

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Investigating the Nested Structure of the Outflow from the Low Luminosity Protostar IRAS 16253-2429 using JWST and ALMA

Understanding the earliest stage of star and planet formation requires detailed observations to address the connection and interplay between the accretion, outflow and disk evolution. We present results from the observations of the low luminosity ($L_\mathrm{bol}\sim~0.2~L_\odot$) and mass (M$_*\sim$\,0.15~M$_\odot$) Class~0 protostar IRAS 16253$-$2429, conducted as part of the \textit{eDisk} ALMA large program and the JWST cycle-1 GO program \textit{IPA}. Observations reveal a wide hourglass-shaped continuum cavity traced in scattered light (at $\leq$~5~$μ$m), with a brighter, extended northern side. We detect 15 pure rotational H$_2$ transitions (E$_\mathrm{up}$:~1015--21411~K), revealing a wide-angle molecular outflow. {The outflow width (as traced in H$_2$~0-0~S(11)) at the protostellar location measures $\leq$35 au, slightly larger than the dust and Keplerian disk diameters ($\sim$30 au) but wider than the 20--23~au jet width in [Fe II].} {The opening angle narrows from 40--35\arcdeg{} for the low-J H$_2$ lines (up to S(5)) and the cold gas component (ALMA $^{12}$CO) to $\sim$28--19\arcdeg{} for the high-J H$_2$ lines (S(7)--S(11)).} Position-velocity diagrams of H$_2$ reveal higher velocities for higher E$_{up}$, ranging from ~12.5 km~s$^{-1}$ for H$_2$~0-0~S(1) and S(2) to ~28.5 km~s$^{-1}$ for H$_2$~0-0~S(5)~and~S(7) with respect to the mean flow velocity. The nested excitation and velocity structure of the collimated jet and wide angle wind suggest a magnetohydrodynamic wind as a likely launching mechanism, similar to the findings in other protostars and Class II sources. The lower velocity mm CO may be gas from the infalling envelope accelerated outwards by the wide angle wind along the cavity walls.

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CORINOS IV: Quantifying Baseline-Fitting Uncertainties in SO$_2$ Ice Measurements with JWST/MIRI

Sulfur dioxide (SO$_2$) ice has been tentatively detected in protostellar envelopes, but its reliability as a solid-state sulfur reservoir remains unclear. We present new measurements of SO$_2$ ice from 6.8-8.5 $μ$m toward four Class 0 protostars observed with JWST's Mid-Infrared (MIRI) Medium Resolution Spectrometer, as part of the COMs ORigin Investigated by the Next-generation Observatory in Space (CORINOS) program. The sample spans a luminosity range from 1 $L_\odot$ (B335, IRAS 15398-3359) to 10 $L_\odot$ (L483, Ser-emb~7). To assess continuum placement uncertainty in absorption spectra, we apply randomized polynomial fits over the restricted region. We fit laboratory spectra from the Leiden Ice Database for Astrochemistry (LIDA) using the open-source Python library Omnifit. We detect the 7.7 $μ$m CH$_4$ band in all sources and find its column density robust to baseline choice, providing a reference for evaluating the weaker SO$_2$ feature on its blue shoulder and quantifying baseline-related uncertainty. Three SO$_2$ laboratory ices were tested: pure SO$_2$ ice yields 0.3-1.2% of volatile sulfur may be locked in SO$_2$ ice (lower and upper limits); CH$_3$OH:SO$_2$ ice gives 0.02-0.18%, but with lower quality fitting. The best-fitting H$_2$O:SO$_2$ ice yields 0.2-0.9%, which we consider the most realistic. These ranges define plausible bounds on SO$_2$ ice abundances in our sample. We find evidence for SO$_2$ in Ser-emb 7, L483, and IRAS 15398-3359, but emphasize the noisy spectrum of B335 prevents a definitive detection. Comparing SO$_2$ ice abundances across the different environments, we assess how conditions influence role of SO$_2$ as a potential sulfur reservoir and implications for the longstanding ``missing sulfur'' problem.

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IPA. Accretion rate of a low-mass Class 0 protostar, measured via mid-infrared fluorescent OH emission

The earliest stages of star formation are highlighted by complex interactions between accretion, outflow, and radiative processes, which shape the chemical and physical environment of the emerging protostar. James Webb Space Telescope observations of the low-mass, low-luminosity Class 0 protostar IRAS 16253-2429 reveal a central compact source. This object exhibits a rich mid-infrared emission spectrum of OH pure rotational lines and $\rm CO_2$ ro-vibrational lines. Unusually for a young stellar object, it has no mid-infrared line emission from $\rm H_2O$ to match the other molecules. We demonstrate that the emitting OH molecules arise from UV photodissociation of $\rm H_2O$ in its second absorption band at $λ= 114-145$ nm, and that the OH emission is a fluorescent cascade starting with highest-excitation rotational states. This situation offers the opportunity of using the infrared OH spectrum to measure the UV flux from the central protostar. Thereby we determine the disk-star accretion rate to be $3 \times 10^{-10} \ M_\sun \ {\rm year^{-1}}$, and demonstrate that the system luminosity arises mostly from the protostar's photosphere rather than from accretion luminosity. The result is in accord with the measured outflow rate of IRAS 16253-2429 and lies within the outflow/accretion-flow rate trend often inferred for protostars; and with episodic accretion as the dominant mechanism by which this protostar has grown.

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Protostars at Subsolar Metallicity: First Detection of Large Solid-state Complex Organic Molecules in the Large Magellanic Cloud

We present the results of James Webb Space Telescope observations of the protostar ST6 in the Large Magellanic Cloud (LMC) with the Medium Resolution Spectrograph of the Mid-Infrared Instrument (4.9-27.9 $μ$m). Characterized by one-third to half-solar metallicity and strong UV radiation fields, the environment of the LMC allows us to study the physics and chemistry of star-forming regions under the conditions similar to those at earlier cosmological epochs. We detected five icy complex organic molecules (COMs): methanol (CH$_3$OH), acetaldehyde (CH$_3$CHO), ethanol (CH$_3$CH$_2$OH), methyl formate (HCOOCH$_3$), and acetic acid (CH$_3$COOH). This is the first conclusive detection of CH$_3$COOH ice in an astrophysical context, and CH$_3$CHO, CH$_3$CH$_2$OH, and HCOOCH$_3$ ices are the first secure detections outside the Galaxy and in a low-metallicity environment. We address the presence of glycolaldehyde (HOCH$_2$CHO, a precursor of biomolecules), an isomer of HCOOCH$_3$ and CH$_3$COOH, but its detection is inconclusive. ST6's spectrum is also rich in simple ices: H$_2$O, CO$_2$, CH$_4$, SO$_2$, H$_2$CO, HCOOH, OCN$^{-}$, HCOO$^{-}$, NH$_3$, and NH$_4^{+}$. We obtain the composition and molecular abundances in the icy dust mantles by fitting the spectrum in the 6.8-8.4 $μ$m range with a large sample of laboratory ice spectra using the ENIIGMA fitting tool or the local continuum method. We found differences in the simple and COM ice abundances with respect to H$_2$O ice between ST6 and Galactic protostars that likely reflect differences in metallicity and UV flux. More laboratory ice spectra of COMs are needed to better reconstruct the observed infrared spectra of protostars.

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IPA: Class 0 Protostars Viewed in CO Emission Using JWST

We investigate the bright CO fundamental emission in the central regions of five protostars in their primary mass assembly phase using new observations from JWST's Near-Infrared Spectrograph (NIRSpec) and Mid-Infrared Instrument (MIRI). CO line emission images and fluxes are extracted for a forest of $\sim$150 ro-vibrational transitions from two vibrational bands, $v=1-0$ and $v=2-1$. However, ${}^{13}$CO is undetected, indicating that ${}^{12}$CO emission is optically thin. We use H$_2$ emission lines to correct fluxes for extinction and then construct rotation diagrams for the CO lines with the highest spectral resolution and sensitivity to estimate rotational temperatures and numbers of CO molecules. Two distinct rotational temperature components are required for $v=1$ ($\sim600$ to 1000 K and 2000 to $\sim 10^4$ K), while one hotter component is required for $v=2$ ($\gtrsim 3500$ K). ${}^{13}$CO is depleted compared to the abundances found in the ISM, indicating selective UV photodissociation of ${}^{13}$CO; therefore, UV radiative pumping may explain the higher rotational temperatures in $v=2$. The average vibrational temperature is $\sim 1000$ K for our sources and is similar to the lowest rotational temperature components. Using the measured rotational and vibrational temperatures to infer a total number of CO molecules, we find that the total gas masses range from lower limits of $\sim10^{22}$ g for the lowest mass protostars to $\sim 10^{26}$ g for the highest mass protostars. Our gas mass lower limits are compatible with those in more evolved systems, which suggest the lowest rotational temperature component comes from the inner disk, scattered into our line of sight, but we also cannot exclude the contribution to the CO emission from disk winds for higher mass targets.

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JWST Observations of Young protoStars (JOYS): Linked accretion and ejection in a Class I protobinary system

Accretion and ejection sets the outcome of the star and planet formation process. The mid-infrared wavelength range offers key tracers of those processes that were difficult to detect and spatially resolve in protostars until now. We aim to characterize the interplay between accretion and ejection in the low-mass Class I protobinary system TMC1, comprising two young stellar objects: TMC1-W and TMC1-E with 85 au separation. With the {\it James Webb} Space Telescope (JWST) - Mid-Infrared Instrument (MIRI) observations in 5 - 28 $μ$m range, we measure intensities of emission lines of H$_2$, atoms and ions, e.g., [Fe II] and [Ne II], and HI recombination lines. We detect H$_2$ outflow coming from TMC1-E, with no significant H$_2$ emission from TMC1-W. The H$_2$ emission from TMC1-E outflow appears narrow and extends to wider opening angles with decreasing E$_{up}$ from S(8) to S(1) rotational transitions, indicating a disk wind origin. The outflow from TMC1-E protostar shows spatially extended emission lines of [Ne II], [Ne III], [Ar II], and [Ar III], with their line ratios consistent with UV radiation as a source of ionization. With ALMA, we detect accretion streamer infalling from $>$ 1000 au scales onto the TMC1-E component. TMC1-W protostar powers a collimated jet, detected with [Fe II] and [Ni II] consistent with energetic flow. A much weaker ionized jet is observed from TMC1-E. TMC1-W is associated with strong emission from hydrogen recombination lines, tracing the accretion onto the young star. Observations of a binary Class I protostellar system show that the two processes are clearly intertwined, with accretion from the envelope onto the disk influencing a wide-angle wind ejected on disk scales, while accretion from the protostellar disk onto the protostar is associated with the source launching a collimated high-velocity jet within the innermost regions of the disk.

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Investigating Protostellar Accretion-Driven Outflows Across the Mass Spectrum: JWST NIRSpec IFU 3-5~$μ$m Spectral Mapping of Five Young Protostars

Investigating Protostellar Accretion is a Cycle 1 JWST program using the NIRSpec+MIRI integral field units to obtain 2.9--28 $μ$m spectral cubes of five young protostars with luminosities of 0.2-10,000 L$_{\odot}$ in their primary accretion phase. This paper introduces the NIRSpec 2.9--5.3 $μ$m data of the inner 840-9000 au with spatial resolutions from 28-300 au. The spectra show rising continuum emission; deep ice absorption; emission from H$_{2}$, H~I, and [Fe~II]; and the CO fundamental series in emission and absorption. Maps of the continuum emission show scattered light cavities for all five protostars. In the cavities, collimated jets are detected in [Fe~II] for the four $< 320$~L$_{\odot}$ protostars, two of which are additionally traced in Br-$α$. Knots of [Fe~II] emission are detected toward the most luminous protostar, and knots of [FeII] emission with dynamical times of $< 30$~yrs are found in the jets of the others. While only one jet is traced in H$_2$, knots of H$_2$ and CO are detected in the jets of four protostars. H$_2$ is seen extending through the cavities, showing that they are filled by warm molecular gas. Bright H$_2$ emission is seen along the walls of a single cavity, while in three cavities narrow shells of H$_2$ emission are found, one of which has an [Fe~II] knot at its apex. These data show cavities containing collimated jets traced in atomic/ionic gas surrounded by warm molecular gas in a wide-angle wind and/or gas accelerated by bow shocks in the jets.

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JWST detections of amorphous and crystalline HDO ice toward massive protostars

This work aims to utilize the increased sensitivity and resolution of the JWST to quantify the HDO/H$_{2}$O ratio in ices toward young stellar objects (YSOs) and to determine if the HDO/H$_{2}$O ratios measured in the gas phase toward massive YSOs (MYSOs) are representative of the ratios in their ice envelopes. Two protostars observed in the Investigating Protostellar Accretion (IPA) program using JWST NIRSpec were analyzed: HOPS 370, an intermediate-mass YSO (IMYSO), and IRAS 20126+4104, a MYSO. The HDO ice toward these sources was detected above the 3$σ$ level and quantified via its 4.1 $μ$m band. The contributions from the CH$_{3}$OH combination modes to the observed optical depth in this spectral region were constrained via the CH$_{3}$OH 3.53 $μ$m band to ensure that the integrated optical depth of the HDO feature was not overestimated. H$_{2}$O ice was quantified via its 3 $μ$m band. From these fits, ice HDO/H$_{2}$O abundance ratios of 4.6$\pm$1.8$\times$10$^{-3}$ and 2.6$\pm$1.2$\times$10$^{-3}$ are obtained for HOPS 370 and IRAS 20126+4104, respectively. The simultaneous detections of both crystalline HDO and crystalline H$_{2}$O corroborate the assignment of the observed feature at 4.1 $μ$m to HDO ice. The ice HDO/H$_{2}$O ratios are similar to the highest reported gas HDO/H$_{2}$O ratios measured toward MYSOs as well as the hot inner regions of isolated low-mass protostars, suggesting that at least some of the gas HDO/H$_{2}$O ratios measured toward massive hot cores are representative of the HDO/H$_{2}$O ratios in ices. The need for an H$_{2}$O-rich CH$_{3}$OH component in the CH$_{3}$OH ice analysis supports recent experimental and observational results that indicate that some CH$_{3}$OH ice may form prior to the CO freeze-out stage in H$_{2}$O-rich ice layers.

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JWST observations of $^{13}$CO$_{2}$ ice: Tracing the chemical environment and thermal history of ices in protostellar envelopes

The structure and composition of simple ices can be modified during stellar evolution by protostellar heating. Key to understanding the involved processes are thermal and chemical tracers that can diagnose the history and environment of the ice. The 15.2 $μ$m bending mode of $^{12}$CO$_2$ has proven to be a valuable tracer of ice heating events but suffers from grain shape and size effects. A viable alternative tracer is the weaker $^{13}$CO$_2$ isotopologue band at 4.39 $μ$m which has now become accessible at high S/N with the $\textit{James Webb}$ Space Telescope (JWST). We present JWST NIRSpec observations of $^{13}$CO$_2$ ice in five deeply embedded Class 0 sources spanning a wide range in luminosities (0.2 - 10$^4$ L$_{\odot}$ ) taken as part of the Investigating Protostellar Accretion Across the Mass Spectrum (IPA) program. The band profiles vary significantly, with the most luminous sources showing a distinct narrow peak at 4.38 $μ$m. We first apply a phenomenological approach and show that a minimum of 3-4 Gaussian profiles are needed to fit the $^{13}$CO$_2$ absorption feature. We then combine these findings with laboratory data and show that a 15.2 $μ$m $^{12}$CO$_2$ band inspired five-component decomposition can be applied for the isotopologue band where each component is representative of CO$_2$ ice in a specific molecular environment. The final solution consists of cold mixtures of CO$_2$ with CH$_3$OH, H$_2$O and CO as well as segregated heated pure CO$_2$ ice. Our results are in agreement with previous studies of the $^{12}$CO$_2$ ice band, further confirming that $^{13}$CO$_{2}$ is a useful alternative tracer of protostellar heating events. We also propose an alternative solution consisting only of heated CO$_2$:CH$_3$OH and CO$_2$:H$_2$O ices and warm pure CO$_2$ ice for decomposing the ice profiles of the two most luminous sources in our sample.

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Discovery of a collimated jet from the low luminosity protostar IRAS 16253$-$2429 in a quiescent accretion phase with the JWST

Investigating Protostellar Accretion (IPA) is a JWST Cycle~1 GO program that uses NIRSpec IFU and MIRI MRS to obtain 2.9--28~$μ$m spectral cubes of young, deeply embedded protostars with luminosities of 0.2 to 10,000~L$_{\odot}$ and central masses of 0.15 to 12~M$_{\odot}$. In this Letter, we report the discovery of a highly collimated atomic jet from the Class~0 protostar IRAS~16253$-$2429, the lowest luminosity source ($L_\mathrm{bol}$ = 0.2 $L_\odot$) in the IPA program. The collimated jet is detected in multiple [Fe~II] lines, [Ne~II], [Ni~II], and H~I lines, but not in molecular emission. The atomic jet has a velocity of about 169~$\pm$~15~km\,s$^{-1}$, after correcting for inclination. The width of the jet increases with distance from the central protostar from 23 to~60 au, corresponding to an opening angle of 2.6~$\pm$~0.5\arcdeg. By comparing the measured flux ratios of various fine structure lines to those predicted by simple shock models, we derive a shock {speed} of 54~km\,s$^{-1}$ and a preshock density of 2.0$\times10^{3}$~cm$^{-3}$ at the base of the jet. {From these quantities and using a suite of jet models and extinction laws we compute a mass loss rate between $0.4 -1.1\times10^{-10}~M_{\odot}$~yr~$^{-1}$.} The low mass loss rate is consistent with simultaneous measurements of low mass accretion rate ($2.4~\pm~0.8~\times~10^{-9}~M_{\odot}$~yr$^{-1}$) for IRAS~16253$-$2429 from JWST observations (Watson et al. in prep), indicating that the protostar is in a quiescent accretion phase. Our results demonstrate that very low-mass protostars can drive highly collimated, atomic jets, even during the quiescent phase.

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Investigating the Impact of Metallicity on Star Formation in the Outer Galaxy. I. VLT/KMOS Survey of Young Stellar Objects in Canis Major

The effects of metallicity on the evolution of protoplanetary disks may be studied in the outer Galaxy where the metallicity is lower than in the solar neighbourhood. We present the VLT/KMOS integral field spectroscopy in the near-infrared of $\sim$120 candidate young stellar objects (YSOs) in the CMa-$\ell$224 star-forming region located at a Galactocentric distance of 9.1 kpc. We characterise the YSO accretion luminosities and accretion rates using the hydrogen Br$γ$ emission and find the median accretion luminosity of $\log{(L_{\rm acc})} = -0.82^{+0.80}_{-0.82} L_\odot$. Based on the measured accretion luminosities, we investigate the hypothesis of star formation history in the CMa-$\ell$224. Their median values suggest that Cluster C, where most of YSO candidates have been identified, might be the most evolved part of the region. The accretion luminosities are similar to those observed toward low-mass YSOs in the Perseus and Orion molecular clouds, and do not reveal the impact of lower metallicity. Similar studies in other outer Galaxy clouds covering a wide range of metallicities are critical to gain a complete picture of star formation in the Galaxy.

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Refractive index and extinction coefficient of vapor-deposited water ice in the UV-Vis range

Laboratory results of the optical properties of vapor-deposited water ice, specifically the refractive index and extinction coefficient, are available mainly for a selective set of wavelengths and a limited number of deposition temperatures. Experimental limitations are the main reason for the lack of broadband data, which is unfortunate as these quantities are needed to interpret and predict astronomical and planetary observations. The goal of this work is to address these lacking data, using an experimental broadband method that is capable of rapidly providing reliable water ice data across the entire UV-visible range. This approach combines the simultaneous use of a monochromatic HeNe laser and a broadband Xe-arc lamp to record interference fringes of water ice during deposition at astronomically relevant ice temperatures. The ice thickness is typically more than 20 $μ$m. Analyzing the period and intensity patterns combining both the monochromatic and broadband interference patterns allows the determination of the wavelength-dependent refractive index and extinction coefficient. We present accurate refractive index and extinction coefficient graphs for wavelengths between 250 and 750 nm and ices deposited between 30 and 160 K. From our data, we find a possible structural change in the ice in the 110-130 K region that has not been reported before. We also discuss that the data presented in this paper can be used to interpret astronomical observations of icy surfaces.

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Fitting infrared ice spectra with genetic modelling algorithms. Presenting the ENIIGMA fitting tool

Context. A variety of laboratory ice spectra simulating different chemical environments, ice morphology as well as thermal and energetic processing are demanded to provide an accurate interpretation of the infrared spectra of protostars. To answer which combination of laboratory data best fit the observations, an automated statistically-based computational approach becomes necessary. Aims. To introduce a new approach, based on evolutionary algorithms, to search for molecules in ice mantles via spectral decomposition of infrared observational data with laboratory ice spectra. Methods. A publicly available and open-source fitting tool, called ENIIGMA (dEcompositioN of Infrared Ice features using Genetic Modelling Algorithms), is introduced. The tool has dedicated Python functions to carry out continuum determination of the protostellar spectra, silicate extraction, spectral decomposition and statistical analysis to calculate confidence intervals and quantify degeneracy. As an assessment of the code, several tests were conducted with known ice samples and constructed mixtures. A complete analysis of the Elias 29 spectrum was performed as well. Results. The ENIIGMA fitting tool can identify the correct ice samples and their fractions in all checks with known samples tested in this paper. Concerning the Elias 29 spectrum, the broad spectral range between 2.5-20 $μ$m was successfully decomposed after continuum determination and silicate extraction. This analysis allowed the identification of different molecules in the ice mantle, including a tentative detection of CH$_3$CH$_2$OH. Conclusions. The ENIIGMA is a toolbox for spectroscopy analysis of infrared spectra that is well-timed with the launch of the James Webb Space Telescope. Additionally, it allows for exploring the different chemical environments and irradiation fields in order to correctly interpret astronomical observations.

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The role of external FUV irradiation in the survival of astrophysical ices in Elias 29

The survival of astrophysical ices in the star-forming regions depends on the suitability of temperature, density and radiation conditions. In this paper, the role of Interstellar Radiation Field (ISRF) on ices in Elias 29 is addressed. This object is the most luminous protostar in $ρ$ Oph E molecular cloud, and is surrounded by many Young Stellar Objects distant only a few arcminutes. In addition, other two brightness BV stars (S1 and HD 147889) enhance the external irradiation in Elias 29. This study was carried out by using the Monte Carlo radiative transfer code RADMC-3D assuming an internal and external irradiation. As result, we found that HD 147889 dominates the ISRF, instead of the closest protostars, and contributes to enhance the external irradiation in 44 times the standard value. Furthermore, remarkable effects are observed in FIR spectrum, as well as in near-IR image. Additionally, the snowline positions of volatile compounds, such as CO, O$_2$, N$_2$ and CH$_4$ are redefined to a toroidal-shaped morphology in the envelope, with low FUV flux (10$^{-7}$ ergs cm$^{-2}$ s$^{-1}$). In such scenario, the formation of complex molecules as result of hydrogenation or oxygenation of volatile species are expected to be severely affected.

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