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William K. Liu

Publications and source records attributed to William K. Liu.

2 recordsLinked to original sources

Charge Transfer Excited State Contributions to Polarity Dependent Ferromagnetism in ZnO Diluted Magnetic Semiconductors

A close link between the charge transfer electronic structures and polarity dependent high-TC ferromagnetism of TM2+:ZnO DMSs (TM2+ = 3d ions) is demonstrated. Trends in ferromagnetism across the 3d series of TM2+:ZnO DMSs predicted from their charge transfer energies reproduce experimental trends well. These results provide a unified basis for understanding both n- and p-type ferromagnetic oxide DMSs.

cond-mat.mtrl-sci

300 K Ferromagnetic Magnetic Circular Dichroism in Co2+-doped ZnO Activated by Shallow Donors

Cobalt-doped ZnO (Co2+:ZnO) films were studied by magnetic circular dichroism (MCD) spectroscopy. A broad 300 K ferromagnetic MCD signal was observed between 1.4 and 4.0 eV after introducing shallow donor states by exposure of paramagnetic Co2+:ZnO films to zinc vapor. The new sub-bandgap ferromagnetic MCD intensity is attributed to low-energy photoionization transitions originating from a spin-split donor impurity band in ferromagnetic Co2+:ZnO.

cond-mat.mtrl-sci