Wolfgang Gaderbauer | Searcharxiv

arXiv2020

Effects of Alloying Elements on Surface Oxides of Hot-Dip Galvanized Press Hardened Steel

Effects of steel alloying elements on the formation of the surface oxide layer of hot-dip galvanized press hardened steel after austenitization annealing were examined with various advanced microscopy and spectroscopy techniques. The main oxides on top of the original thin Al2O3 layer, originating from the primary galvanizing process, are identified as ZnO and (Mn,Zn)Mn2O4 spinel. For some of the investigated steel alloys, a non-uniform, several nanometer thick Cr enriched, additional film was found at the Al2O3 layer. At a sufficiently high concentration, Cr can act as a substitute for Al during annealing, strengthening and regenerating the original Al2O3 layer with Cr2O3. Further analysis with secondary ion mass spectrometry allowed a reliable distinction between ZnO and Zn(OH)2.

physics.app-ph↗

arXiv2020

Influence of structure and cation distribution on magnetic anisotropy and damping in Zn/Al doped nickel ferrites

An in-depth analysis of Zn/Al doped nickel ferrites grown by reactive magnetron sputtering is relevant due to their promising characteristics for applications in spintronics. The material is insulating and ferromagnetic at room temperature with an additional low magnetic damping. By studying the complex interplay between strain and cation distribution their impact on the magnetic properties, i.e. anisotropy, damping and g-factor is unravelled. In particular, a strong influence of the lattice site occupation of Ni$^{2+}_{\text{Td}}$ and cation coordination of Fe$^{2+}_{\text{Oh}}$ on the intrinsic damping is found. Furthermore, the critical role of the incorporation of Zn$^{2+}$ and Al$^{3+}$ is evidenced by comparison with a sample of altered composition. Especially, the dopant Zn$^{2+}$ is evidenced as a tuning factor for Ni$^{2+}_{\text{Td}}$ and therefore unquenched orbital moments directly controlling the g-factor. A strain-independent reduction of the magnetic anisotropy and damping by adapting the cation distribution is demonstrated.

cond-mat.mtrl-sci↗