arXiv subjects

Wolfgang Wernsdorfer

Publications and source records attributed to Wolfgang Wernsdorfer.

At least 37 records · Page 2Linked to original sources

arXiv2025

Granular Aluminum Parametric Amplifier for Low-Noise Measurements in Tesla Fields

Josephson junction parametric amplifiers have become essential tools for microwave quantum circuit readout with minimal added noise. Even after improving at an impressive rate in the last decade, they remain vulnerable to magnetic field, which limits their use in many applications such as spin qubits, Andreev and molecular magnet devices, dark matter searches, etc. Kinetic inductance materials, such as granular aluminum (grAl), offer an alternative source of non-linearity with innate magnetic field resilience. We present a non-degenerate amplifier made of two coupled grAl resonators resilient to in-plane magnetic field up to 1 T. It offers 20 dB of gain close to the quantum limit of added noise, with a gain-bandwidth product of 28 MHz and -110 dBm input saturation power.

quant-ph↗

arXiv2025

Probing Magnetism in Self-Assembled Organometallic Complexes using Kondo Spectroscopy

Control of individual spins at the atomic level holds great promise for miniaturized spintronics, quantum sensing, and quantum information processing. Both single atomic and molecular spin centers are prime candidates for these applications and are often individually addressed and manipulated using scanning tunneling microscopy (STM). In this work, we present a hybrid approach and demonstrate a robust method for self-assembly of magnetic organometallic complexes consisting of individual iron (Fe) atoms and molecules on a silver substrate using STM. We employ two types of molecules, bis(dibenzoylmethane) copper(II) [Cu(dbm)2] and iron phthalocyanine (FePc). We show that in both cases the Fe atoms preferentially attach underneath the benzene ring ligand of the molecules, effectively forming an organometallic half-sandwich arene complex, Fe(C6H6), that is akin to the properties of metallocenes. In both situations, a molecule can be combined with up to two Fe atoms. In addition, we observe a change in the magnetic properties of the attached Fe atoms in scanning tunneling spectroscopy, revealing a distinct Kondo signature at the Fe sites. We explain the latter using density functional theory calculations, and find that the bond formation between the Fe 3d-orbitals and the benzene π-molecular orbitals creates a favorable situation for Kondo screening of the d_xz- and d_yz-like orbitals. Thus, this work establishes a reliable design principle for forming hybrid organometallic complexes and simultaneous tuning of their atomic spin states.

cond-mat.mes-hall↗

arXiv2024

Observation of Josephson Harmonics in Tunnel Junctions

Approaches to developing large-scale superconducting quantum processors must cope with the numerous microscopic degrees of freedom that are ubiquitous in solid-state devices. State-of-the-art superconducting qubits employ aluminum oxide (AlO$_x$) tunnel Josephson junctions as the sources of nonlinearity necessary to perform quantum operations. Analyses of these junctions typically assume an idealized, purely sinusoidal current-phase relation. However, this relation is only expected to hold in the limit of vanishingly low-transparency channels in the AlO$_x$ barrier. Here we show that the standard current-phase relation fails to accurately describe the energy spectra of transmon artificial atoms across various samples and laboratories. Instead, a mesoscopic model of tunneling through an inhomogeneous AlO$_x$ barrier predicts percent-level contributions from higher Josephson harmonics. By including these in the transmon Hamiltonian, we obtain orders of magnitude better agreement between the computed and measured energy spectra. The presence and impact of Josephson harmonics has important implications for developing AlO$_x$-based quantum technologies including quantum computers and parametric amplifiers. As an example, we show that engineered Josephson harmonics can reduce the charge dispersion and the associated errors in transmon qubits by an order of magnitude, while preserving their anharmonicity.

quant-ph↗

arXiv2024

Quantum Spin-Engineering in On-Surface Molecular Ferrimagnets

The design and control of atomic-scale spin structures constitute major challenges for spin-based quantum technology platforms, including quantum dots, color centers, and molecular spins. Here, we showcase a strategy for designing the quantum properties of molecular spin qubits by combining tip-assisted on-surface assembly with electron spin resonance scanning tunneling microscopy (ESR-STM): We fabricate magnetic dimer complexes that consist of an iron phthalocyanine (FePc) molecule and an organometallic half-sandwich complex formed by the FePc ligand and an attached iron atom, Fe(C6H6). The total complex forms a mixed-spin (1/2,1) quantum ferrimagnet with a well-separated correlated ground state doublet, which we utilize for coherent control. As a result of the correlation, the quantum ferrimagnet shows an improved spin lifetime (>1.5 $μ$s) as it is partially protected against inelastic electron scattering. Lastly, the ferrimagnet units also enable intermolecular coupling, that can be used to realize both ferromagnetic or antiferromagnetic structures. Thus, quantum ferrimagnets provide a versatile platform to improve coherent control in general and to study complex magnetic interactions.

cond-mat.mes-hall↗

arXiv2024

Thermalization of a flexible microwave stripline measured by a superconducting qubit

With the demand for scalable cryogenic microwave circuitry continuously rising, recently developed flexible microwave striplines offer the tantalyzing perspective of increasing the cabling density by an order of magnitude without thermally overloading the cryostat. We use a superconducting quantum circuit to test the thermalization of input flex cables with integrated $60\,$dB of attenuation distributed at various temperature stages. From the measured decoherence rate of a superconducting fluxonium qubit, we estimate a residual population of the readout resonator below $3.5\cdot10^{-3}$ photons and we measure a $0.28\,$ms thermalization time for the flexible stripline attenuators. Furthermore, we confirm that the qubit reaches an effective temperature of $26.4\,$mK, close to the base temperature of the cryostat, practically the same as when using a conventional semi-rigid coaxial cable setup.

quant-ph↗

arXiv2024

Industrial 300$\,$mm wafer processed spin qubits in natural silicon/silicon-germanium

The realisation of an universal quantum computer will require the operation of thousands to millions of qubits. The possibility of using existing industrial semiconductor fabrication techniques and infrastructure for up-scaling and reproducibility makes silicon based spin qubits one of the most promising platforms to achieve this goal. The implementation of the up to now largest semiconductor based quantum processor was realized in a silicon/silicon-germanium heterostructure known for its low charge noise, long qubit coherence times and fast driving speeds, but the high structural complexity creates challenges for industrial implementations. Here we demonstrate quantum dots hosted in a natural Si/SiGe heterostructure fully fabricated by an industrial 300$\,$mm semiconductor wafer process line from heterostructure growth to Co micromagnet monolithic integration. We report charge noise values below 2$\,\mathrm{μeV/\sqrt{Hz}}$, spin relaxation times of over 1$\,$s and coherence times $T_2^*$ and $T_2^H$ of 1$\,\mathrm{μs}$ and 50$\,\mathrm{μs}$ respectively, for quantum wells grown using natural silicon. Further, we achieve Rabi frequencies up to 5$\,$MHz and single qubit gate fidelities above 99$\,\%$. In addition to scalability, the high reproducibility of the 300$\,$mm processes enables the deterministic study of qubit metric dependencies on process parameters, which is essential for optimising qubit quality.

cond-mat.mes-hall↗

arXiv2024

Pure kinetic inductance coupling for cQED with flux qubits

We demonstrate a qubit-readout architecture where the dispersive coupling is entirely mediated by a kinetic inductance. This allows us to engineer the dispersive shift of the readout resonator independent of the qubit and resonator capacitances. We validate the pure kinetic coupling concept and demonstrate various generalized flux qubit regimes from plasmon to fluxon, with dispersive shifts ranging from 60 kHz to 2 MHz at the half-flux quantum sweet spot. We achieve readout performances comparable to conventional architectures with quantum state preparation fidelities of 99.7 % and 92.7 % for the ground and excited states, respectively, and below 0.1 % leakage to non-computational states.

quant-ph↗

arXiv2024

Two-level system hyperpolarization using a quantum Szilard engine

The innate complexity of solid state physics exposes superconducting quantum circuits to interactions with uncontrolled degrees of freedom degrading their coherence. By using a simple stabilization sequence we show that a superconducting fluxonium qubit is coupled to a two-level system (TLS) environment of unknown origin, with a relatively long energy relaxation time exceeding $50\,\text{ms}$. Implementing a quantum Szilard engine with an active feedback control loop allows us to decide whether the qubit heats or cools its TLS environment. The TLSs can be cooled down resulting in a four times lower qubit population, or they can be heated to manifest themselves as a negative temperature environment corresponding to a qubit population of $\sim 80\,\%$. We show that the TLSs and the qubit are each other's dominant loss mechanism and that the qubit relaxation is independent of the TLS populations. Understanding and mitigating TLS environments is therefore not only crucial to improve qubit lifetimes but also to avoid non-Markovian qubit dynamics.

quant-ph↗

arXiv2024

Noise reduction by bias cooling in gated Si/SixGe1-x quantum dots

Silicon-Germanium heterostructures are a promising quantum circuit platform, but crucial aspects as the long-term charge dynamics and cooldown-to-cooldown variations are still widely unexplored quantitatively. In this letter we present the results of an extensive bias cooling study performed on gated silicon-germanium quantum dots with an Al2O3-dielectric. Over 80 cooldowns were performed in the course of our investigations. The performance of the devices is assessed by low-frequency charge noise measurements in the band of 200 micro Hertz to 10 milli Hertz. We measure the total noise power as a function of the applied voltage during cooldown in four different devices and find a minimum in noise at 0.7V bias cooling voltage for all observed samples. We manage to decrease the total noise power median by a factor of 6 and compute a reduced tunneling current density using Schrödinger-Poisson simulations. Furthermore, we show the variation in noise from the same device in the course of eleven different cooldowns performed under the nominally same conditions.

cond-mat.mes-hall↗

arXiv2024

Anomalous Nernst effect in the noncollinear antiferromagnet Mn$_5$Si$_3$

Investigating the off-diagonal components of the conductivity and thermoelectric tensor of materials hosting complex antiferromagnetic structures has become a viable method to reveal the effects of topology and chirality on the electronic transport in these systems. In this respect, Mn$_5$Si$_3$ is an interesting metallic compound that exhibits several antiferromagnetic phases below 100 K with different collinear and noncollinear arrangements of Mn magnetic moments. Previous investigations have shown that the transitions between the various phases give rise to large changes of the anomalous Hall effect. Here, we report measurements of the anomalous Nernst effect of Mn$_5$Si$_3$ single crystals. Below 25 K we observe a sign change of the zero-field Nernst signal with a concomitant decrease of the Hall signal and a gradual reduction of the remanent magnetization which we attribute to a subtle rearrangement of the magnetic moment configuration at low temperatures.

cond-mat.mtrl-sci↗

arXiv2024

Superconducting nitridized-aluminum thin films

We report the direct observation of superconductivity in nitridized-aluminum thin films. The films are produced by sputtering deposition of aluminum in a controlled mixture of nitrogen diluted in argon. The concentration of applied nitrogen directly determines the properties of the superconducting thin films. We observe samples displaying critical temperatures up to 3.38$\pm$0.01K and resilience to in-plane magnetic fields well above 1T, with good reproducibility of the results. This work represents an unambiguous demonstration of tunable superconductivity in aluminum-based nitridized thin films. Our results put forward nitridized aluminum as a promising material to be employed in superconducting quantum circuits for quantum technology applications.

cond-mat.supr-con↗

arXiv2024

Microwave Control of the Tin-Vacancy Spin Qubit in Diamond with a Superconducting Waveguide

Group-IV color centers in diamond are promising candidates for quantum networks due to their dominant zero-phonon line and symmetry-protected optical transitions that connect to coherent spin levels. The negatively charged tin-vacancy (SnV) center possesses long electron spin lifetimes due to its large spin-orbit splitting. However, the magnetic dipole transitions required for microwave spin control are suppressed, and strain is necessary to enable these transitions. Recent work has shown spin control of strained emitters using microwave lines that suffer from Ohmic losses, restricting coherence through heating. We utilize a superconducting coplanar waveguide to measure SnV centers subjected to strain, observing substantial improvement. A detailed analysis of the SnV center electron spin Hamiltonian based on the angle-dependent splitting of the ground and excited states is performed. We demonstrate coherent spin manipulation and obtain a Hahn echo coherence time of up to $T_2 = 430\,μ$s. With dynamical decoupling, we can prolong coherence to $T_2 = 10\,$ms, about six-fold improved compared to earlier works. We also observe a nearby coupling $^{13}\mathrm{C}$ spin which may serve as a quantum memory. This substantiates the potential of SnV centers in diamond and demonstrates the benefit of superconducting microwave structures.

quant-ph↗

arXiv2024

Nano-assembled open quantum dot nanotube devices

A pristine suspended carbon nanotube is a near ideal environment to host long-lived quantum states. For this reason, they have been used as the core element of qubits and to explore numerous condensed matter physics phenomena. One of the most advanced technique to realize complex carbon nanotube based quantum circuits relies on a mechanical integration of the nanotube into the circuit. Despite the high-quality and complexity of the fabricated circuits, the range of possible experiments was limited to the closed quantum dot regime. Here, by engineering a transparent metal-nanotube interface, we developed a technique that overcomes this limitation. We reliably reach the open quantum dot regime as demonstrated by measurements of Fabry-Perot interferences and Kondo physics in multiple devices. A circuit-nanotube alignment precision of +/-200nm is demonstrated. Our technique allows to envision experiments requiring the combination of complex circuits and strongly coupled carbon nanotubes such as the realization of carbon nanotube superconducting qubits or flux-mediated optomechanics experiments.

physics.app-ph↗

arXiv2023

Non-degenerate parametric amplifiers based on dispersion engineered Josephson junction arrays

Determining the state of a qubit on a timescale much shorter than its relaxation time is an essential requirement for quantum information processing. With the aid of a new type of non-degenerate parametric amplifier, we demonstrate the continuous detection of quantum jumps of a transmon qubit with 90% fidelity in state discrimination. Entirely fabricated with standard two-step optical lithography techniques, this type of parametric amplifier consists of a dispersion engineered Josephson junction (JJ) array. By using long arrays, containing $10^3$ JJs, we can obtain amplification at multiple eigenmodes with frequencies below $10~\mathrm{GHz}$, which is the typical range for qubit readout. Moreover, by introducing a moderate flux tunability of each mode, employing superconducting quantum interference device (SQUID) junctions, a single amplifier device could potentially cover the entire frequency band between 1 and $10~\mathrm{GHz}$.

quant-ph↗

arXiv2023

Implementation of a transmon qubit using superconducting granular aluminum

The high kinetic inductance offered by granular aluminum (grAl) has recently been employed for linear inductors in superconducting high-impedance qubits and kinetic inductance detectors. Due to its large critical current density compared to typical Josephson junctions, its resilience to external magnetic fields, and its low dissipation, grAl may also provide a robust source of non-linearity for strongly driven quantum circuits, topological superconductivity, and hybrid systems. Having said that, can the grAl non-linearity be sufficient to build a qubit? Here we show that a small grAl volume ($10 \times 200 \times 500 \,\mathrm{nm^3}$) shunted by a thin film aluminum capacitor results in a microwave oscillator with anharmonicity $α$ two orders of magnitude larger than its spectral linewidth $Γ_{01}$, effectively forming a transmon qubit. With increasing drive power, we observe several multi-photon transitions starting from the ground state, from which we extract $α= 2 π\times 4.48\,\mathrm{MHz}$. Resonance fluorescence measurements of the $|0> \rightarrow |1>$ transition yield an intrinsic qubit linewidth $γ= 2 π\times 10\,\mathrm{kHz}$, corresponding to a lifetime of $16\,\mathrm{μs}$. This linewidth remains below $2 π\times 150\,\mathrm{kHz}$ for in-plane magnetic fields up to $\sim70\,\mathrm{mT}$.

quant-ph↗

arXiv2023

Phase transitions associated with magnetic-field induced topological orbital momenta in a non-collinear antiferromagnet

Resistivity measurements are widely exploited to uncover electronic excitations and phase transitions in metallic solids. While single crystals are preferably studied to explore crystalline anisotropies, these usually cancel out in polycrystalline materials. Here we show that in polycrystalline Mn3Zn0.5Ge0.5N with non-collinear antiferromagnetic order, changes in the diagonal and, rather unexpected, off-diagonal components of the resistivity tensor occur at low temperatures indicating subtle transitions between magnetic phases of different symmetry. This is supported by neutron scattering and explained within a phenomenological model which suggests that the phase transitions in magnetic field are associated with field induced topological orbital momenta. The fact that we observe transitions between spin phases in a polycrystal, where effects of crystalline anisotropy are cancelled suggests that they are only controlled by exchange interactions. The observation of an off-diagonal resistivity extends the possibilities for realising antiferromagnetic spintronics with polycrystalline materials.

cond-mat.mtrl-sci↗

arXiv2022

Operating in a deep underground facility improves the locking of gradiometric fluxonium qubits at the sweet spots

We demonstrate flux-bias locking and operation of a gradiometric fluxonium artificial atom using two symmetric granular aluminum (grAl) loops to implement the superinductor. The gradiometric fluxonium shows two orders of magnitude suppression of sensitivity to homogeneous magnetic fields, which can be an asset for hybrid quantum systems requiring strong magnetic field biasing. By cooling down the device in an external magnetic field while crossing the metal-to-superconductor transition, the gradiometric fluxonium can be locked either at $0$ or $Φ_0/2$ effective flux bias, corresponding to an even or odd number of trapped fluxons, respectively. At mK temperatures, the fluxon parity prepared during initialization survives to magnetic field bias exceeding $100 \,Φ_0$. However, even for states biased in the vicinity of $1 \,Φ_0$, we observe unexpectedly short fluxon lifetimes of a few hours, which cannot be explained by thermal or quantum phase slips. When operating in a deep-underground cryostat of the Gran Sasso laboratory, the fluxon lifetimes increase to days, indicating that ionizing events activate phase slips in the grAl superinductor.

quant-ph↗

arXiv2021

Thermalization of nuclear spins in lanthanide molecular magnets

Single molecule magnets distinguish themselves in the field of quantum magnetism through the ability to combine fundamental research with promising applications, the evolution of quantum spintronics in the last decade exemplifying the potential held by molecular based quantum devices. Notably, the read-out and manipulation of the embedded nuclear spin states was used in proof of principle studies of quantum computation at the single molecule level. In this paper we study the relaxation dynamics of the $^{159}$Tb nuclear spins in a diluted molecular crystal by using recently acquired understanding of the nonadiabatic dynamics of TbPc$_2$ molecules. We find that phonon modulated hyperfine interaction opens a direct relaxation channel between the nuclear spins and the phonon bath. We highlight the potential importance of the discovered mechanism for the theory of spin bath and the relaxation dynamics of the molecular spins at crossover temperatures.

cond-mat.mes-hall↗