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Won-Geun Kim

Publications and source records attributed to Won-Geun Kim.

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Bioinspired Microactuators Fabricated via One-step Meniscus-guided 3D Nanoprinting

We introduce a bioinspired microactuator fabricated via a one-step meniscus guided 3D nanoprinting technique. This technique directly produces a freestanding three dimensional composite architecture by integrating a rigid nanoparticle framework with a hygroscopic polymer matrix in a single, assembly free process. Inspired by the functional integration of rigid and compliant components in insect exoskeletal joint, our design synergistically combines load-bearing strength and humidity-driven swelling in a single microscale pillar. Comprehensive experiments, including comparative control structures and microscopic analysis, elucidated the actuation mechanism: the nanoparticle scaffold provides mechanical support while the polymeric phase provides volumetric expansion, yielding large reversible elongation under humidity with preserved structural integrity. The resulting AuNP PVP microactuator shows humidity responsive actuation at the microscale, with representative demonstrations of repeated humidity cycling and load lifting up to approximately 800 times its estimated own weight under the tested conditions. Variant geometries such as hinged pillars demonstrate how axial swelling can be converted into bending motion, and an optical configuration shows how actuation can modulate reflected light signals. This nanoprinting approach provides a simple strategy for constructing bioinspired soft microactuators with humidity-responsive deformation and potential applicability in microscale sensing, optical modulation, and adaptive microdevices.

physics.optics

Spatially Uniform and Defect-Tolerant Plasmonic Responses in 3D printed Gold Nanoparticle Assemblies

Three-dimensional (3D) assemblies of gold nanoparticles (AuNPs) offer a rich platform for plasmonic coupling and near-field engineering, yet their optical behavior is often complex due to structural disorder and fabrication-induced variability. Here, we present a systematic optical investigation of large-scale 3D AuNP assemblies fabricated via meniscus-guided assembly, focusing on the reproducibility and spatial uniformity. Spatially-resolved dark-field scattering measurements reveal that high-aspect-ratio AuNP pillars exhibit uniform scattering spectra along their height and across different pillars, despite variations in geometry and structure. Electromagnetic simulations suggest that this robustness arises from an ensemble-averaged plasmonic response governed by many local coupling regions within a finite plasmon delocalization length. Simulated near-field and surface charge distributions suggest that the broad ensemble response remains spatially distributed under representative structural perturbations, consistent with volumetric averaging. Building on this robust platform, we introduce compositional modulation through a core-satellite architecture by incorporating smaller AuNPs. This yields a composition-dependent spectral redistribution, including an additional long-wavelength spectral feature in the core-satellite assemblies. Wavelength-dependent surface-enhanced Raman scattering measurements reveal contrasting responses under 633 and 785 nm excitation, reflecting redistribution of local plasmonic coupling pathways. These results establish design principles for robust 3D plasmonic nanoparticle assemblies with ensemble-averaged and composition-tunable optical responses.

physics.optics