arXiv subjects

Wouter Vlemmings

Publications and source records attributed to Wouter Vlemmings.

At least 19 recordsLinked to original sources

arXiv2026

Efficient Interstellar Grain Growth from High Sticking Coefficients on Amorphous Carbon Dust

Cosmic dust is the solid phase of the interstellar medium (ISM), classically assumed to be composed of carbonaceous and silicate grains with size distributions spanning $\sim 5~\AA$ to $\sim 1~\mu$m (Weingartner & Draine 2001, Draine & Li 2007, Hensley & Draine 2023). While it constitutes at most order-of-magnitude $\mathbf{1\%}$ of the ISM mass, dust is second only to stars in importance for the observable properties of galaxies (Zavala et al. 2021). Large uncertainties in the efficiency of grain growth obfuscate the relative contribution of the two dominant sources of dust in the Universe: direct production from evolved stars versus gas-phase accretion in the ambient ISM (Feldmann 2015, Esmerian & Gnedin 2022, Esmerian & Gnedin 2024). Advances in supercomputers have only recently allowed us to move beyond simple, idealized predictions of dust grain growth efficiencies (Leitch-Devlin & Williams 1985) with atomistic dynamical calculations (Bossion et al. 2024). We show that small carbon dust grains can grow significantly on timescales much shorter than the age of the universe and, in some ISM phases, comparable to the lifetimes of giant molecular clouds. Specifically, we perform molecular dynamics simulations of an amorphous carbon (a-C) grain surface impacted by gas-phase atoms of cosmologically abundant elements with realistic interstellar conditions, finding high ($\gtrsim 0.2$) sticking coefficients for all non-inert elements at all relevant gas and grain temperatures. We present the results of experiments conducted on similar dust candidate materials that support our theoretical calculations. Our results therefore confirm that the process of gas-phase accretion onto grains is likely an efficient mechanism for the growth of interstellar dust mass on astrophysical timescales, and plausibly central to the evolutionary life-cycle of interstellar grains at all cosmic epochs. (abridged)

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arXiv2026

HST observations of chromospheric UV lines in the AGB star R Leo

The role of stellar chromospheres in the chemistry, mass loss, and evolution of cool evolved stars remains poorly understood. We present high-resolution ultraviolet spectra of the nearby Mira-type AGB star R~Leo obtained with STIS on board the \textit{Hubble Space Telescope}. We focus on two strong chromospheric diagnostics, the Mg\,\textsc{ii} h \& k resonance lines and the C\,\textsc{ii}] 2325\,\AA\ multiplet, and model their formation with the NLTE radiative-transfer code RH using phase-dependent hydrodynamic atmospheric structures that include pulsation-driven shocks. The observed C\,\textsc{ii}] multiplet ratios imply an electron density of order $10^9\,\mathrm{cm^{-3}}$. The RH contribution functions show that the C\,\textsc{ii}] emission is strongly localized in a compact shock-heated shell at the first temperature peak of the model atmosphere, near $R\simeq1.8~R_{\rm phot}$, where $T\sim10^4$\,K and the local electron density is a few $10^8\,\mathrm{cm^{-3}}$. In contrast, the Mg\,\textsc{ii} h \& k lines probe a more extended region ($R< 16~R_{\rm phot}$), with the line cores forming at greater radial distances than the wings. The Mg\,\textsc{ii} h line is reproduced more reliably than the k line, which is more strongly affected by circumstellar and interstellar absorption. As an additional low-opacity kinematic check, the semi-forbidden Al\,\textsc{ii}] $\lambda2669$ line shows a projected stellar-rest-frame blueshift of $\sim6~{\rm km~s^{-1}}$, consistent with shock-related motions expected in Mira atmospheres. Overall, the compact C\,\textsc{ii}] formation region, the extended Mg\,\textsc{ii} contribution functions, and the strong phase dependence of the synthetic Mg\,\textsc{ii} profiles support a picture in which pulsation-driven shocks shape the ultraviolet chromospheric emission lines in Mira variable stars.

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arXiv2026

The unique capabilities of HST for stellar physics: Probing Atmospheric Structure, Chromospheres, and Mass Loss of Evolved Stars

Evolved stars are among the primary sources of chemical enrichment and dust production in galaxies. During the giant phases, stars return a substantial fraction of their mass to the interstellar medium (ISM) through stellar winds, enriching galaxies with newly synthesized elements and dust. However, the atmospheric structure and physical processes that initiate mass loss remain poorly constrained observationally. Understanding the origin, structure, and evolution of stellar chromospheres remains a long-standing problem in stellar astrophysics. While the mechanisms responsible for chromospheric heating and atmospheric dynamics are not fully understood even in the Sun, they become more complex in evolved stars due to pulsation, shocks, convection, extended atmospheres, and possible magnetic activity. Determining the thermal, density, and velocity structure of these extended atmospheres is therefore essential for understanding atmospheric heating, the onset of mass loss, and the late stages of stellar evolution. High-resolution NUV and FUV spectroscopy (R ~ 30,000-100,000) provided by HST/STIS occupies a unique observational parameter space that cannot be replaced by existing facilities. HST/STIS therefore remains essential for understanding the atmospheric physics and mass-loss processes of evolved stars. We highlight the need to preserve and prioritize high-resolution NUV and FUV spectroscopic capabilities with HST. Such programs would provide essential benchmarks for stellar atmosphere modeling, complement ongoing ALMA and optical observations, and help define future UV-optical capabilities for the Habitable Worlds Observatory (HWO).

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arXiv2025

Towards ALMA2040: An update from the European community and invitation to contribute

Over the last 15 years, the Atacama Large Millimeter/submillimeter Array (ALMA) has revolutionized astrophysics by providing unprecedented resolution and sensitivity in observing the cold universe, including the formation of stars, planets, and galaxies. With groundbreaking discoveries ranging from the first detailed images of protoplanetary disks to the kinematics of galaxies in the Epoch of Reionization, ALMA has showcased the vast discovery potential of the (sub-)mm wavelength regime. However, in another 15 years from now--in the 2040s--the science landscape will have changed dramatically as new major observational facilities will have started their operations or have come towards advanced maturity in their scientific outcome (e.g., JWST, Rubin Observatory, ELT, Euclid, Gaia, Plato, Ariel, Roman Space Telescope, SPHEREx, LiteBIRD, LISA, SKA and others). At the same time, ALMA's current Wideband Sensitivity Upgrade will have been in place for ~10 years, and ALMA itself will have been operational for 30 years. To fully exploit this era, the community needs a next-generation facility operating at (sub-)mm wavelengths with capabilities far beyond those possible within ALMA's current infrastructure. To this end, ALMA2040 is a community-driven initiative to define the key scientific questions of the 2040s and translate them into a technical vision for a next-generation transformational (sub-)millimeter facility. Our goal with this document is to summarize the current status of the effort, synthesize outcomes from the 2025 workshops, outline next steps toward a reference design concept, and invite broad participation from the global mm/sub-mm community to help shape this future facility. In the following we provide details on the process and scope. We invite everyone who wishes to join the effort and/or contribute to the dedicated White Papers planned for 2026.

astro-ph.IM↗

arXiv2025

Probing Infrared eXcess to Investigate Early-Universe Dust (PIXIEDust)

Despite the implied presence of dust through reddened UV emission in high-redshift galaxies, no dust emission has been detected in the (sub)millimetre regime beyond $z > 8.3$. This study combines around two hundred hours of Atacama Large Millimeter/submillimeter Array (ALMA) and Northern Extended Millimeter Array (NOEMA) observations on ten $z > 8$ galaxies, revealing no significant dust emission down to a $1 \sigma$ depth of $2.0$, $2.0$, and $1.5 \,\mu$Jy at rest-frame 158, 88 $\mu$m, and across all the data, respectively. This constrains average dust masses to be below $< 10^{5}$ M$_{\odot}$ at $3 \sigma$ and dust-to-stellar mass ratios to be below $3.7 \times{} 10^{-4}$ (assuming $T_{\rm dust} = 50$ K and $\beta_{\rm dust} = 2.0$). Binning by redshift ($8 < z < 9.5$ and $9.5 < z < 15$), UV-continuum slope ($\beta_{\rm UV} \lessgtr -2$) and stellar mass ($\log_{10} M_{\ast}/{\rm M_{\odot}} \lessgtr 9$) yields similarly stringent constraints. Combined with other studies, these results are consistent with inefficient dust build-up in the $z > 8$ Universe, likely due to inefficient supernova production, limited interstellar grain growth and/or ejection by outflows. We provide data and tools online to facilitate community-wide high-redshift dust searches.

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arXiv2025

An empirical view of the extended atmosphere and inner envelope of the asymptotic giant branch star R Doradus. II. Constraining the dust properties with radiative transfer modelling

Mass loss in oxygen-rich asymptotic giant branch (AGB) stars remains poorly understood, as the dust detected around them appears too transparent to drive winds through absorption alone. The current paradigm invokes outflows driven by photon scattering on relatively large grains ($\sim0.3\,\mu$m), but whether such grains exist in sufficient quantities remains uncertain. We test whether the dust around the oxygen-rich AGB star R~Doradus can drive its wind by combining polarimetric constraints, elemental abundance limits, and force-balance calculations. We examine Fe-free silicates (MgSiO$_3$), alumina (Al$_2$O$_3$), and Fe-bearing silicates (MgFeSiO$_4$) to evaluate whether any species can produce enough radiative pressure under realistic conditions. Using high-angular-resolution polarimetric observations from SPHERE/ZIMPOL at the VLT, we model the circumstellar dust with RADMC-3D and explore a broad parameter space in grain size, density structure, and wavelength-dependent stellar radius. For models consistent with the observations, we assess wind feasibility using updated gas-density profiles, elemental depletion constraints, and radiation-pressure thresholds. Although several dust configurations reproduce the observed scattering patterns, none generate sufficient radiative force at realistic gas-to-dust ratios, even under maximal elemental depletion. Our results for R~Doradus indicate that photon scattering on dust cannot by itself launch the wind, implying that additional mechanisms must contribute.

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arXiv2025

A warm ultra-luminous infrared galaxy just 600 million years after the Big Bang

We present an Atacama Large Millimeter/submillimeter Array (ALMA) Band 9 continuum detection ($3.3 \sigma$) of MACS0416_Y1 that confirms the suspected warm dust (91$^{+62}_{-35}$ K) of this Lyman-Break Galaxy (LBG) at $z = 8.3$ with $\log_{10} M_{\ast}/$M$_{\odot} = 9.0 \pm 0.1$. A modified black-body fit to the ALMA Bands 3 through 9 data of MACS0416_Y1 finds an intrinsic infrared luminosity of 1.0$^{+1.8}_{-0.6} \times{} 10^{12}\ \mathrm{L_{\odot}}$, placing this UV-selected LBG in the regime of Ultra Luminous Infrared Galaxies (ULIRGs). Its luminous but modest dust reservoir (1.4$^{+1.3}_{-0.5} \times{} 10^{6}\ \mathrm{M_{\odot}}$) is co-spatial to regions with a UV-continuum slope $\beta_{\rm UV} \approx -1.5$ as seen by James Webb Space Telescope (JWST) imaging. Although this implies some dust obscuration, the JWST photometry implies less obscured star formation than seen in the complete characterization by ALMA, implying some spatial separation of dust and stars on scales below 200 pc, i.e., smaller than those probed by JWST and ALMA. This source is an extreme example of dust-obscured star formation contributing strongly to the cosmic build-up of stellar mass, which can only be revealed through direct and comprehensive observations in the (sub)mm regime.

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arXiv2025

The Binding Energies of Atoms on Amorphous Silicate Dust: A Computational Study

Context. We investigate the binding energies of atoms to interstellar dust particles, which play a key role in their growth and evolution, as well as for the chemical reactions on their surfaces. Aims. We aim to compute the binding energies of abundant atoms in the interstellar medium (C, N, O, Mg, Al, Si, S, Ca, Fe, and Ni) to silicate dust. Methods. We used the Geometries, Frequencies, and Non-covalent Interactions Tight Binding (GFN1-xTB) method to compute the binding energies. An FeMgSiO$_4$ periodic surface model, containing 81 local minima on the surface, was used. Results. A range of binding energies was found for each element. The median of the binding energies follows the order Si (14.8 eV) > Al (12.8 eV) > Ca (12.7 eV) > C (9.5 eV) > O (8.1 eV) > N (6.2 eV) > Fe (6.0 eV) > S (5.2 eV) > Mg (2.4 eV). The probability distribution of binding energies for each element except Ca is statistically consistent with a log-normal distribution. Conclusions. In general, Si, Ca, and Al atoms have large binding energies. Thus, these atoms can stay on the silicate dust particles at high temperatures. The binding energies of the other atoms, C, N, O, Mg, S, Fe and Ni, are relatively weak. However, the computed binding energies for these elements are still far stronger than the energies associated with dust temperatures typical of the ambient interstellar medium (ISM), suggesting that silicate grains are generally stable against sublimation. We estimate sublimation temperatures for silicate grains to range from 1600 K to 3000K depending on assumed grain size and lifetime. These binding energies on silicate dust grains, estimated from first principles for the first time, provide invaluable input to models of dust evolution and dust-catalyzed chemical reactions in the interstellar medium.

astro-ph.GA↗

arXiv2025

Stephenson 2 DFK 52: Discovery of an exotic red supergiant in the massive stellar cluster RSGC2

Atacama Large Millimeter/submillimeter Array (ALMA) observations at 1.3mm have recently revealed surprising complexity in the circumstellar environment of DFK 52, a red supergiant (RSG) located in the Stephenson 2 massive open cluster. We provide an initial characterisation of the star's mass-loss properties by studying its circumstellar emission in continuum, $^{12}$CO, $^{13}$CO, and SiO rotational lines. We find that DFK 52 is surrounded by an extremely large outflow (up to 50,000 au in radius) that shows complex morphologies in both its molecular and dust emission. The size of the circumstellar medium is unprecedented, even when compared with other known extreme RSGs, and its lower luminosity indicates that its mass ejection mechanism may be unique among this population. The molecular emission can be partially reproduced by a two-component model consisting of a fast (27 km/s) detached equatorial component with $M{\sim}0.05$ $M_{\odot}$ and a slow (10 km/s) spherical envelope with $\dot{M}\sim3\times10^{-6}$ $M_{\odot}$ yr$^{-1}$. This suggests that DFK 52 underwent a dramatic mass-loss event $\sim$4000 years ago, but has since transitioned into having a slower more symmetric mass loss. We conservatively estimate a total mass of $0.1-1$ $M_{\odot}$ in the complex extended regions of the outflow. The uncertain nature of the dramatic mass loss warrants extensive follow-up of this likely supernova progenitor.

astro-ph.GA↗

arXiv2024

Accurate sticking coefficient calculation for carbonaceous dust growth through accretion and desorption in astrophysical environments

Context. Cosmic dust is ubiquitous in astrophysical environments, where it significantly influences the chemistry and the spectra. Dust grains are likely to grow through the accretion of atoms and molecules from the gas-phase onto them. Despite their importance, only a few studies compute sticking coefficients for relevant temperatures and species, and their direct impact on grain growth. Overall, the formation of dust and its growth are processes not well understood. Aims. To calculate sticking coefficients, binding energies, and grain growth rates over a wide range of temperatures, for various gas species interacting with carbonaceous dust grains. Methods. We perform molecular dynamics simulations with a reactive force field algorithm to compute accurate sticking coefficients and obtain binding energies. The results are included in an astrophysical model of nucleation regions to study dust growth. Results. We present, for the first time, sticking coefficients of H, H2, C, O, and CO on amorphous carbon structures for temperatures ranging from 50 K to 2250 K. In addition, we estimate the binding energies of H, C, and O in carbonaceous dust to calculate the thermal desorption rates. Combining accretion and desorption allows us to determine an effective accretion rate and sublimation temperature for carbonaceous dust. Conclusions. We find that sticking coefficients can differ substantially from what is commonly used in astrophysical models and this gives new insight on carbonaceous dust grain growth via accretion in dust-forming regions.

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arXiv2024

Probing the Extended Atmospheres of AGB Stars: I. Synthetic imaging of 1D hydrodynamical models at radio and (sub-)millimeter wavelengths

We investigate the observable characteristics of the extended atmospheres of AGB stars across a wide range of radio and (sub-)mm wavelengths using state-of-the-art 1D dynamical atmosphere and wind models over one pulsation period. We also study the relationships between the observable features and model properties. We further study practical distance ranges for observable sources assuming the capabilities of current and upcoming observatories. We present time-variable, frequency-dependent profiles of pulsating AGB stars' atmospheres, illustrating observable features in resolved and unresolved observations, including disc brightness temperature, photosphere radius, and resolved and unresolved spectral indices. Notably, temporal variations in disc brightness temperature closely mirror the temperature variability of the stellar atmosphere. We find that while the photospheric radius decreases due to gas dilution in the layers between consecutive shocks, the increase in the observed stellar radius reflects shock propagation through the atmosphere during the expansion phase, providing a direct measurement method for the shock velocity. Furthermore, our models indicate that enhanced gas temperatures after the passage of a strong shock might be observable in the high-frequency ALMA bands as a decrease in the brightness temperature with increasing frequency. We demonstrate that synthetic observations based on state-of-the-art dynamical atmosphere and wind models are necessary for proper interpretations of current (ALMA and VLA) and future (SKA and ngVLA) observations and that multi-wavelength observations of AGB stars are crucial for empirical studies of their extended atmospheres.

astro-ph.SR↗

arXiv2024

High-Speed Outflows and Dusty Disks during the AGB to PN Transition: The PANORAMA survey

As mass-losing asymptotic giant branch (AGB) stars evolve to planetary nebulae (PNe), the mass outflow geometries transform from nearly spherical to extreme aspherical. The physical mechanisms governing this transformation are widely believed to be linked to binarity and the associated production of disks and fast jets during transitional (post-AGB) evolutionary stages. We are carrying out a systematic ALMA survey ($P$re-planet$A$ry $N$ebulae high-angular-res$O$lution su$R$vey with $A$L$MA$ or PANORAMA) of a representative sample of bipolar and multipolar post-AGB objects. We have obtained high angular-resolution (0".1-0".4) observations of the CO(3--2) and/or 6--5 emission in order to probe the spatio-kinematic structure of the collimated outflows and the central disk/torii. The results are remarkable, generally showing the presence of bipolar or multipolar high-velocity outflows, dense toroidal waists, and in one case, a geometrically-thin circular ring around the central bipolar nebula. A high degree of point-symmetry characterizes the morphology of the mass ejecta. In this contribution, we present these and other highlights from our survey. We aim to use 2D/3D radiative transfer modeling in order to derive accurate outflow momenta, masses and mass-loss rates for our sample, and build hydrodynamical models that can explain the observed spatio-kinematic structures. These results will then be used to distinguish between different classes of PN-shaping binary interaction models.

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arXiv2024

Resolved ALMA observations of water in the inner astronomical units of the HL Tau disk

The water molecule is a key ingredient in the formation of planetary systems, with the water snowline being a favourable location for the growth of massive planetary cores. Here we present Atacama Large Millimeter/ submillimeter Array data of the ringed protoplanetary disk orbiting the young star HL Tauri that show centrally peaked, bright emission arising from three distinct transitions of the main water isotopologue. The spatially and spectrally resolved water content probes gas in a thermal range down to the water sublimation temperature. Our analysis implies a stringent lower limit of 3.7 Earth oceans of water vapour available within the inner 17 astronomical units of the system. We show that our observations are limited to probing the water content in the atmosphere of the disk, due to the high dust column density and absorption, and indicate that the main water isotopologue is the best tracer to spatially resolve water vapour in protoplanetary disks.

astro-ph.EP↗

arXiv2024

Maser polarization through anisotropic pumping

(Abridged) Polarized emission from masers is an excellent tool to study magnetic fields in maser sources. The linear polarization of most masers is understood as an interplay of maser saturation and anisotropic pumping. However, for the latter mechanism, no quantitative modeling has been presented yet. We present a comprehensive model of maser polarization, including quantitative modeling of both anisotropic pumping and the effects of maser saturation on the polarization of masers. We extend regular maser excitation modeling with a dimension that describes the molecular population alignments, as well as including the linear polarization dimension to the radiative transfer. The results of the excitation analysis yield the anisotropic pumping and decay parameters, that are subsequently used in one-dimensional proper maser polarization radiative transfer modeling. We present the anisotropic pumping parameters for a variety of transitions from class I CH$_3$OH masers, H$_2$O masers and SiO masers. SiO masers are highly anisotropically pumped due to them occurring in the vicinity of a late-type star, that irradiates the maser region with a strong directional radiation field. Class I CH$_3$OH masers and H$_2$O masers occur in association with shocks, and they are modestly anisotropically pumped due to the anisotropy of the excitation region. Our modeling constitutes the first quantitative constraints on the anisotropic pumping of masers. We find that anisotropic pumping can explain the high polarization yields of SiO masers, as well as the modest polarization of unsaturated class I CH$_3$OH masers. We predict that the $183$ GHz H$_2$O maser is strongly anisotropically pumped. Finally, we outline a mechanism through which non-Zeeman circular polarization is produced, when the magnetic field changes direction along the propagation through an anisotropically pumped maser.

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arXiv2023

The messy death of a multiple star system and the resulting planetary nebula as observed by JWST

Planetary nebulae (PNe), the ejected envelopes of red giant stars, provide us with a history of the last, mass-losing phases of 90 percent of stars initially more massive than the Sun. Here, we analyse James Webb Space Telescope (JWST) Early Release Observation (ERO) images of the PN NGC3132. A structured, extended H2 halo surrounding an ionised central bubble is imprinted with spiral structures, likely shaped by a low-mass companion orbiting the central star at 40-60 AU. The images also reveal a mid-IR excess at the central star interpreted as a dusty disk, indicative of an interaction with another, closer companion. Including the previously known, A-type visual companion, the progenitor of the NGC3132 PN must have been at least a stellar quartet. The JWST images allow us to generate a model of the illumination, ionisation and hydrodynamics of the molecular halo, demonstrating the power of JWST to investigate complex stellar outflows. Further, new measurements of the A-type visual companion allow us to derive the value for the mass of the progenitor of a central star to date with excellent precision: 2.86+/-0.06 Mo. These results serve as path finders for future JWST observations of PNe providing unique insight into fundamental astrophysical processes including colliding winds, and binary star interactions, with implications for supernovae and gravitational wave systems.

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arXiv2021

Observational identification of a sample of likely recent Common-Envelope Events

One of the most poorly understood stellar evolutionary paths is that of binary systems undergoing common-envelope evolution, when the envelope of a giant star engulfs the orbit of a companion. Although this interaction leads to a great variety of astrophysical systems, direct empirical studies are difficult because few objects experiencing common-envelope evolution are known. We present ALMA observations towards sources known as water fountains that reveal they had low initial masses ($<4~{\rm M}_\odot$) and ejected a significant fraction of it over less than a few hundred years. The only mechanism able to explain such rapid mass ejection is common-envelope evolution. Our calculations show that the water-fountain sample accounts for a large fraction of the systems in our Galaxy which have just experienced the common-envelope phase. Since water-fountain sources show characteristic fast bipolar outflows, outflows and jets likely play an important role right before, during or immediately after the common-envelope phase.

astro-ph.SR↗

arXiv2021

Tracing the large-scale magnetic field morphology in protoplanetary disks using molecular line polarization

(abridged) Magnetic fields are fundamental to the accretion dynamics of protoplanetary disks and they likely affect planet formation. Typical methods to study the magnetic field morphology observe the polarization of dust or spectral lines. However, it has recently become clear that dust-polarization in ALMA's spectral regime does not always faithfully trace the magnetic field structure of protoplanetary disks, which leaves spectral line polarization as a promising method for mapping the magnetic field morphologies of such sources. We aim to model the emergent polarization of different molecular lines in the ALMA wavelength regime that are excited in protoplanetary disks. We explore a variety of disk models and molecules to identify those properties that are conducive to the emergence of polarization in spectral lines and may therefore be viably used for magnetic field measurements in protoplanetary disks. We used PORTAL in conjunction with LIME. Together, they allowed us to treat the polarized line radiative transfer of complex three-dimensional physical and magnetic field structures. We present simulations of the emergence of spectral line polarization of different molecules and molecular transitions in the ALMA wavelength regime. We find that molecules that thermalize at high densities, such as HCN, are also the most susceptible to polarization. We find that such molecules are expected to be significantly polarized in protoplanetary disks, while molecules that thermalize at low densities, such as CO, are only significantly polarized in the outer disk regions. We present the simulated polarization maps at a range of inclinations and magnetic field morphologies, and we comment on the observational feasibility of ALMA linear polarization observations of protoplanetary disks.

astro-ph.SR↗

arXiv2020

Polarization properties of methanol masers

(Abridged) Astronomical masers have been effective tools to study magnetic fields for many years. In particular, methanol can be used to probe different parts of protostars such as accretion discs and outflows, since it produces one of the strongest and the most commonly observed masers in massive star-forming regions. We investigate the polarization properties of selected methanol maser transitions in light of newly calculated methanol Landé g-factors and considering hyperfine components. We compare our results with previous observations and we evaluate the effect of preferred hyperfine pumping and non-Zeeman effects. We run simulations using the radiative transfer code CHAMP. We find a dependence of linear and circular polarization fractions on the hyperfine transitions. Preferred hyperfine pumping can explain some high levels of linear and circular polarization and some of the peculiar features seen in the S-shape of observed V-profiles. Methanol masers are not significantly affected by non-Zeeman effects. Our models show that for methanol maser emission, both the linear and circular polarization percentages depend on which hyperfine transition is masing and the degree to which it is being pumped. Since non-Zeeman effects become more relevant at high values of brightness temperatures, it is important to obtain good estimates of these quantities and on maser beaming angles. Better constraints on the brightness temperature will help in understand about the extent to which non-Zeeman effects contribute to the observed polarization percentages. In order to detect separate hyperfine components, an intrinsic thermal line width significantly smaller than the hyperfine separation is required.

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