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X. Haubois

Publications and source records attributed to X. Haubois.

At least 19 recordsLinked to original sources

Status and performance of the Asgard/NOTT cold nulling camera

Long-baseline nulling interferometry suppresses the on-axis light of a star, enabling high-contrast observations of faint circumstellar emission and exoplanets at high angular resolution. The Nulling Observations of dusT and PlaneTs (NOTT) instrument is the L'-band nulling interferometer of the Asgard instrument suite and will be the first nuller installed at the Very Large Telescope Interferometer (VLTI). Its main scientific goals are to characterise hot/warm exozodiacal dust and young Jupiter-like exoplanets at close (<10 AU) orbital separations, where indirect detection methods are most sensitive. NOTT uses a four-telescope integrated-optics photonic beam combiner operating over 3.5-4.0 micrometres. The photonic chip produces photometric, bright, and nulled outputs that are polarization-split, spectrally dispersed, and imaged onto a 5-micrometre-cutoff HAWAII-2RG detector by the NOTT cold nulling camera. The cold optical assembly includes the photonic-chip interface, injection optics, collimator, Wollaston prism, dispersive element, imager, and cryogenic detector stage. The mechanical implementation is designed for operation near 90 K using aluminium support structures, spring-loaded optical mounts, and cryogenic-compatible mechanisms to preserve alignment during cooldown. We present the current status and performance of the NOTT cold nulling camera and cryostat assembly. The system is undergoing assembly, integration, and verification to validate thermal stability, detector operation, vacuum performance, and opto-mechanical repeatability. Initial cryogenic tests have demonstrated operation near 100 K for the cold optics and 30 K for the detector, cryogenic validation of the filter wheel, and a vacuum pressure of 8 x 10^-8 mbar. These activities represent a key step toward deploying NOTT as the first nulling interferometer at the VLTI.

astro-ph.IM

Improving constraints on the Yukawa correction at the Galactic Center with multiple stellar orbits

We investigate the presence of a Yukawa-like correction ($\propto \, αe^{- r/λ}$) to Newtonian gravity at the Galactic Center, using a multi-star fitting code, including the newly discovered star S$301$, to improve the constraints obtained using S$2$ orbit alone. We perform a Markov Chain Monte Carlo analysis using the astrometric and spectroscopic data of stars S$2$, S$55$, S$29$, S$38$ and S$301$ collected by GRAVITY, GRAVITY$^+$, NACO and SINFONI instruments, covering the period from $1992$ to $2025$. Compared to GRAVITY Collaboration 2025 (Paper I), in which only S$2$ was fitted, the tightest bound on the Yukawa coupling is again reached at $λ= 3\cdot10^{13}\,\rm m\ (\sim 200\,AU)$, where we find $|α| < 6 \cdot10^{-4}$, an improvement of roughly a factor five. The addition of S$301$ extends the constraint to short ranges that were inaccessible to S$2$, yielding $|α| < 0.004$ at $λ=10^{12}\,\rm m$ and $|α| < 0.006$ at $λ=5\cdot 10^{11}\,\rm m$, while S$29$, with its larger apoapsis, gives $|α| < 0.1$ at $λ\sim 2\cdot10^{15}\,\rm m$. The latter two represent the tightest limits at these scale lengths on a Yukawa correction obtained to date around a supermassive black hole.

astro-ph.GA

Asgard/NOTT: Status of laboratory nulling performance

Nulling interferometry enables the direct detection of faint companions and circumstellar structures at angular separations unresolvable by classical, diffraction-limited imagers, whilst dramatically improving the measurable contrast. The Asgard/NOTT nulling instrument aims to achieve a contrast performance of 10^-5 in the L' wavelength band (3.5 - 4.0 μm), enabling observation and characterization of young giant exoplanets near the snowline and hot exozodiacal dust. Previous studies have verified the nulling capabilities, of the chip in ambient conditions and of the test bench in cryogenic conditions. This work aims to add the first ambient performance assessment of the test bench with spectrally dispersed light. Necessary revisions are made to the data acquisition and calibration pipeline and fringe scans are carried out, modeled and fitted. The splitting ratios of the 4-telescope nulling beam combiner, a photonic Gallium Lanthanum Sulfide (GLS) chip, are moreover characterized on the bench, showing tentative agreement with previous chip characterization. The null performance has worsened, the achieved contrast of ~ 10^-1 being one order of magnitude higher than what earlier characterized performance showed. Multiple future changes to the test bed and to the approach taken promise an improved characterization of performance. In particular, the input beam intensities will be deliberately mismatched to account for the imbalanced splitting ratios of the directional couplers. With the installation of the final cryostat and camera, the developed tools will be leveraged to re-assess the performance in ambient and cryogenic conditions.

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Performance Analysis of the Asgard/NOTT Nulling Interferometer: Optimizing Observing Modes for High-contrast Detection

We evaluate the performance of three beam-combination schemes, single-Bracewell, asymmetric dual-Bracewell, and symmetric dual-Bracewell, for the forthcoming Asgard/NOTT nulling interferometer at the Very Large Telescope Interferometer. Utilizing the SCIFYsim end-to-end simulator, we assess the instrument's performance by deriving the precision of calibrated null measurements as a function of stellar magnitude and simulating observations of varying hot exozodiacal dust (HEZD) distributions and a hot Jupiter. The study reveals distinct trade-offs for each observing mode. The single-Bracewell mode provides high throughput and preserves spatial information but suffers from poor error suppression. The asymmetric dual-Bracewell mode offers the strongest error suppression for detecting point-like sources, but it inherently suppresses symmetric astrophysical signals such as expected from HEZD. The symmetric dual-Bracewell mode provides a middle ground with modest error suppression while being sensitive to symmetric emission. We conclude that utilizing a combination of all three observing modes provides a robust strategy for detecting HEZD, constraining the structure of its distribution, and identifying false positives from stellar companions.

astro-ph.IM

Asgard/NOTT: Cryogenic characterization of the mid-infrared chip

NOTT is part of the new visitor instrument suite Asgard for the Very Large Telescope Interferometer (VLTI), and the first long-baseline nulling interferometer that will be operational in the southern hemisphere. It is an L'-band (3.5-4$\,μ$m) instrument optimized for imaging hot exozodiacal dust and young giant planets orbiting around the snowline of nearby main-sequence stars. For planet imaging, the L' band has the advantage of relaxing the requirements on the star-planet contrast to $\sim 10^{-5}$ while limiting the level of background noise compared with longer wavelengths. Nulling interferometry in the L'-band was made possible by the development of mid-infrared integrated optics with high throughput. NOTT uses a photonic beam combiner made of Gallium Lanthanum Sulfide (GLS), manufactured at Macquarie University and characterized at ambient temperatures at Universität zu Köln. This first characterization showed that the chip could achieve the broadband contrast requirement for exoplanet imaging. Using the test bench of the NOTT instrument assembled at KU Leuven, and its test cryostat, we successfully cooled the chip down to $\sim 138\,$K and performed its first characterization at cryogenic temperatures. The results show a raw broadband contrast of $\sim1\,\%$, similar to the previous measurements done at ambient temperatures. The splitting ratios of the different couplers are also shown to remain stable at cryogenic temperatures, with less than $\sim 2\,\%$ uncertainty compared to ambient measurements. These results thus show that the beam-combining properties and splitting ratios are behaving as expected at 138$\,$K. The current maximum throughput of the chip is estimated at $\sim37\,\%$. Future work will investigate an anti-reflection coating to reduce its Fresnel losses and increase its throughput to $\sim50\,\%$.

astro-ph.IM

ESO User Support and Observation Preparation for VLTI Science Operations

We present recent enhancements to VLTI observing capabilities from a user-oriented perspective, together with new developments in ESO's Observation Handling Tools and end-to-end operations model for VLTI. Key upgrades include GRAVITY+ Coudé guiding with laser guide stars at the UTs, improved limiting magnitudes for GRAVITY and MATISSE, and a new MATISSE narrow-field off-axis mode, all supported by a streamlined, uniform template structure. Phase 2 tools now enable finding-chart generation and the selection of Coudé guide stars and fringe-tracker targets, and will soon offer expanded preparation features and uv-coverage visualisation. We summarise usage statistics for snapshot, astrometric, imaging, and time-series observations, outline VLTI scheduling considerations, and present new video tutorials. Starting in 2026, an archive data stream of reduced GRAVITY dispersed visibilities has become available. Complementary community engagement in VLTI operations continues to grow. We close by identifying operational lessons for future interferometric facilities, including the importance of an end-to-end data-flow and user-support model, flexible scheduling, high-level observation-preparation tools, and coordinated community support to keep complex interferometric facilities usable by a broad community.

astro-ph.IM

Discovery of a star sensitive to the spin of Sgr A*

Residing in the center of the Milky Way, Sgr A* is the closest massive black hole (MBH). Its vicinity has allowed measuring individual stellar orbits around it. The stars act as test particles and probe the gravitational potential around the $4.3 \times 10^6 M_\odot$ MBH. These observations have determined the central mass to sub-percent precision, and the mildly relativistic motions of stars have given access to the dominant relativistic corrections, the gravitational redshift, the transverse Doppler effect, and the prograde precession imposed by the Schwarzschild metric nature of the potential. These effects are of order $β^2 = (v/c)^2$ (for velocity $v$ and speed of light $c$). The Kerr metric for a rotating black hole leads to corrections of order $β^3$. Here, we report the discovery of a faint main-sequence star ($m_K = 19.3$), S301, on a 8.7-year orbit and with small enough a pericenter distance, such that the star's peak velocity reaches $25000\,$km/s. Within the measurement capabilities of current near-infrared interferometry and future spectroscopy on an extremely large telescope, S301's motion is directly sensitive to the spin of Sgr A*. The high eccentricity of S301 suggests that it is the captured component of a binary that was torn apart via the Hills mechanism.

astro-ph.GA

Exploring the presence of a fifth force at the Galactic Center

Aims: The presence of a Yukawa-like correction to Newtonian gravity is investigated at the Galactic Center, leading to a new upper limit for the intensity of such a correction. Methods: We perform a Markov Chain Monte Carlo analysis using the astrometric and spectroscopic data of star S$2$ collected at the Very Large Telescope by GRAVITY, NACO and SINFONI instruments, covering the period from $1992$ to $2022$. Results: The precision of the GRAVITY instrument allows us to derive the most stringent upper limit at the Galactic Center for the intensity of the Yukawa contribution ($\propto \, αe^{- λr}$) to be $|α| < 0.003$ for a scale length $λ= 3 \cdot 10^{13}\, \rm m\, (\sim 200 \, \rm AU)$. This improves by roughly one order of magnitude all estimates obtained in previous works.

astro-ph.GA

The ExoGRAVITY survey: A K-band spectral library of giant exoplanet and brown dwarf companions

Direct observations of exoplanet and brown dwarf companions with near-infrared interferometry, first enabled by the dual-field mode of VLTI/GRAVITY, provide unique measurements of the objects' orbital motions and atmospheric compositions. Here, we compile a homogeneous library of all exoplanet and brown dwarf K-band spectra observed by GRAVITY thus far. We re-reduced all the available GRAVITY dual-field high-contrast data and, where companions are detected, extract their ~2.0-2.4 $μ$m K-band contrast spectra. We then derived stellar model atmospheres for all employed flux references, which we used to convert the companion contrast into companion flux spectra. Solely from the resulting GRAVITY spectra, we extracted spectral types, spectral indices, and bulk physical properties for all companions. Finally, and with the help of age constraints from the literature, we also derived isochronal masses for most companions using evolutionary models. The resulting library contains R ~ 500 GRAVITY spectra of 39 substellar companions from late M to late T spectral types, including the entire L-T transition. Throughout this transition, a shift from CO-dominated late M- and L-type dwarfs to CH4-dominated T-type dwarfs can be observed in the K-band. The GRAVITY spectra alone constrain the objects' bolometric luminosity to typically within $\pm$0.15 dex. The derived isochronal masses agree with dynamical masses from the literature where available, except for HD 4113 c for which we confirm its previously reported potential underluminosity. Medium-resolution spectroscopy of substellar companions with GRAVITY provides insight into the carbon chemistry and the cloudiness of these objects' atmospheres. It also constrains these objects' bolometric luminosities which can yield measurements of their formation entropy if combined with dynamical masses, for instance from Gaia and GRAVITY astrometry.

astro-ph.EP

Spatially resolved broad line region in a quasar at z=4: Dynamical black hole mass and prominent outflow

We present the first near-infrared interferometric data of a QSO at z=4. The K-band observations were performed with GRAVITY+ on the VLTI using all four UTs, detecting a differential phase signal that traces the spatially resolved kinematics for both the \hb\ and \hg\ lines in the broad line region. We fit the two lines simultaneously with an updated model that includes distinct rotating and conical outflowing components. For the best fit model, more than 80\% of the \hi\ line emission from the BLR originates in an outflow with a velocity up to $10^4$ km s$^{-1}$. This is oriented so that our line of sight is along an edge of the conical structure, which produces the prominent blue wing on the line profile. A combination of anisotropic line emission and mid-plane opacity lead to the single-sided phase signal. The model is able to qualitatively match both the outflowing \civ\ line profile and the systemic \oi\ fluorescent emission. The derived black hole mass of $8\times10^8$ M$_\odot$ is the highest redshift black hole mass measurement to date obtained directly from BLR dynamics. It is an order of magnitude lower than that inferred from various single epoch scaling relations, and implies that the accretion is highly super-Eddington. With reference to recent simulations, the data suggest that this QSO is emitting close to its radiative limit in a regime where strong outflows are expected around a polar conical region.

astro-ph.GA

First Light for the GRAVITY+ Adaptive Optics: Extreme Adaptive Optics for the Very Large Telescope Interferometer

GRAVITY+ improves by orders of magnitude the sensitivity, sky-coverage and contrast of the Very Large Telescope Interferometer (VLTI). A central part of this project is the development of Gravity Plus Adaptive Optics (GPAO), a dedicated high-order and laser-guide star Adaptive Optics (AO) system for VLTI. GPAO consists of four state-of-the-art AO systems equipping all 8m-class Unit Telescopes (UTs) for the wavefront correction of the VLTI instruments. It offers both visible and infrared Natural Guide Star (NGS) and Laser Guide Star (LGS) operations. The paper presents the design, operations and performances of GPAO. We illustrate the improvement brought by GPAO with interferometric observations obtained during the commissioning of the NGS mode end-2024. These science results include the first optical interferometry observations of a redshift $z\sim4$ quasar, the spectroscopy of a cool brown-dwarf with magnitude $K\sim 21.0$, the first observations of a Class I young star with GRAVITY, and the first sub-micro arcsecond differential astrometry in the optical. Together with the entire GRAVITY+ project, the implementation of GPAO is a true paradigm shift for observing the optical Universe at very high angular resolution.

astro-ph.IM

The mid-infrared spectrum of $β$ Pictoris b. First VLTI/MATISSE interferometric observations of an exoplanet

Few spectra of directly-imaged exoplanets have been obtained in the mid-infrared (> 3 $μ$m). This region is particularly rich in molecular spectral signatures, whose measurements can help recover atmospheric parameters and provide a better understanding of giant planet formation and atmospheric dynamics. In the past years, exoplanet interferometry with the VLTI/GRAVITY instrument has provided medium-resolution spectra of a dozen substellar companions in the near infrared. The 100-meter interferometric baselines allow for the stellar and planetary signals to be efficiently disentangled at close angular separations (< 0.3''). We aim to extend this technique to the mid-infrared using MATISSE, the VLTI's mid-infrared spectro-interferometer. We take advantage of the fringe tracking and off-axis pointing capabilities recently brought by the GRA4MAT upgrade. Using this new mode, we observed the giant planet $β$ Pictoris b in L and M bands (2.75-5 $μ$m) at a spectral resolution of 500. We developed a method to correct chromatic dispersion and non-common paths effects in the fringe phase and modelled the planet astrometry and stellar contamination. We obtained a high-signal-to-noise spectrum of $β$ Pictoris b, showing the planet continuum in L (for the first time) and M bands, which contains broad absorption features of H$_2$O and CO. In conjunction with a new GRAVITY spectrum, we modelled it with the ForMoSA nested sampling tool and the Exo-REM grid of atmospheric models, and found a solar carbon-to-oxygen ratio in the planet atmosphere. This study opens the way to the characterization of fainter and closer-in planets with MATISSE, which could complement the JWST at angular separations too close for it to obtain exoplanet spectra. Starting in 2025, the new adaptive optics system brought by the GRAVITY+ upgrade will further extend the detection limits of MATISSE.

astro-ph.EP

Interferometric view into RT Pav's long secondary period. binary vs oscillatory convective modes

Long secondary periods (LSPs) occur in about one-third of evolved stars, yet their origin remains unclear. The leading explanations are oscillatory convective modes and a binary companion embedded in dust. We investigate the LSP of the red giant RT Pav using multi-wavelength VLTI interferometry (PIONIER, GRAVITY, MATISSE; 1.5-5.0 microns), obtained near the phase where a companion would appear most separated. These data, combined with photometry and Gaia DR3 astrometry, constrain possible companion masses, orbits, and photometric effects. We model the interferometric observables using uniform-disk, limb-darkened, ellipse, binary, and oscillatory convective dipole representations, supported by Monte Carlo simulations. Gaia limits any companion to a mass whose Roche-lobe volume is too small to hold the obscuring or scattering material required to reproduce the observed LSP modulation. While binary fits can yield low chi-squared values, the inferred positions are inconsistent across wavelength, closure phases do not increase with wavelength as dusty companions predict, and significant detections occur in only two of four bands. Theoretical estimates show that a roughly 1 percent flux companion at LSP-like separations should be consistently detectable for typical O-rich AGB dust, but is not consistently observed. In contrast, an oscillatory convective dipole with a temperature contrast of about 200 K reproduces the H-band morphology and visible-light amplitude without violating Gaia or photometric constraints, and binary-like residuals vanish when dipole models are fitted. Our results therefore favor oscillatory convective modes over a binary origin for the LSP in RT Pav. Time-resolved spectro-interferometry across the LSP cycle is a natural next step.

astro-ph.SR

Exomoon search with VLTI/GRAVITY around the substellar companion HD 206893 B

Direct astrometric detection of exomoons remains unexplored. This study presents the first application of high-precision astrometry to search for exomoons around substellar companions. We investigate whether the orbital motion of the companion HD 206893 B exhibits astrometric residuals consistent with the gravitational influence of an exomoon or binary planet. Using the VLTI/GRAVITY instrument, we monitored the astrometric positions of HD 206893 B and c across both short (days to months) and long (yearly) timescales. This enabled us to isolate potential residual wobbles in the motion of component B attributable to an orbiting moon. Our analysis reveals tentative astrometric residuals in the HD 206893 B orbit. If interpreted as an exomoon signature, these residuals correspond to a candidate (HD 206893 B I) with an orbital period of approximately 0.76 years and a mass of $\sim$0.4 Jupiter masses. However, the origin of these residuals remains ambiguous and could be due to systematics. Complementing the astrometry, our analysis of GRAVITY $R=4000$ spectroscopy for HD 206893 B confirms a clear detection of water, but no CO is found using cross-correlation. We also find that AF Lep b, and $β$ Pic b are the best short-term candidates to look for moons with GRAVITY+. Our observations demonstrate the transformative potential of high-precision astrometry in the search for exomoons, and proves the feasibility of the technique to detect moons with masses lower than Jupiter and potentially down to less than Neptune in optimistic cases. Crucially, further high-precision astrometric observations with VLTI/GRAVITY are essential to verify the reality and nature of this signal and attempt this technique on a variety of planetary systems.

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Constraints on the Orbit of the Young Substellar Companion GQ Lup B from High-Resolution Spectroscopy and VLTI/GRAVITY Astrometry

Understanding the orbits of giant planets is critical for testing planet formation models, particularly at wide separations greater than 10 au where traditional core accretion becomes inefficient. However, constraining orbits at these separations has been challenging because of sparse orbital coverage and degeneracies in the orbital parameters. We use existing high-resolution spectroscopic measurements from CRIRES+ (R ~ 100000), astrometric data from SPHERE, NACO, and ALMA, and new high-precision GRAVITY astrometry to refine the orbit of GQ Lup B, a ~30 M_J companion at ~100 au, in a system that also hosts a circumstellar disk and a wide companion, GQ Lup C. Including radial velocity data significantly improves orbital constraints by breaking the degeneracy between inclination and eccentricity that affects astrometry-only fits for long-period companions. This work is among the first to combine high-precision astrometry with the companion's relative radial velocity to achieve improved orbital constraints. The eccentricity is refined from e = 0.47 (+0.14, -0.16) with GRAVITY alone to e = 0.35 (+0.10, -0.09) when RVs and GRAVITY data are combined. The orbit is misaligned by 63 (+6, -14) deg relative to the circumstellar disk and 52 (+19, -24) deg relative to the host star spin axis, and is more consistent (34 (+6, -13) deg) with the inclination of the wide tertiary companion GQ Lup C disk. These results support a formation scenario for GQ Lup B consistent with cloud fragmentation and highlight the power of combining companion RV constraints with interferometric astrometry to probe the dynamics and formation of wide-orbit substellar companions.

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Direct imaging discovery of a young giant planet orbiting on Solar System scales

HD 135344 AB is a young visual binary system that is best known for the protoplanetary disk around the secondary star. The circumstellar environment of the A0-type primary star, on the other hand, is already depleted. HD 135344 A is therefore an ideal target for the exploration of recently formed giant planets because it is not obscured by dust. We searched for and characterized substellar companions to HD 135344 A down to separations of about 10 au. We observed HD 135344 A with VLT/SPHERE in the $H23$ and $K12$ bands and obtained $YJ$ and $YJH$ spectroscopy. In addition, we carried out VLTI/GRAVITY observations for the further astrometric and spectroscopic confirmation of a detected companion. We discovered a close-in young giant planet, HD 135344 Ab, with a mass of about 10 $M_\mathrm{J}$. The multi-epoch astrometry confirms the bound nature based on common parallax and common proper motion. This firmly rules out the scenario of a non-stationary background star. The semi-major axis of the planetary orbit is approximately 15-20 au, and the photometry is consistent with that of a mid L-type object. The inferred atmospheric and bulk parameters further confirm the young and planetary nature of the companion. HD 135344 Ab is one of the youngest directly imaged planets that has fully formed and orbits on Solar System scales. It is a valuable target for studying the early evolution and atmosphere of a giant planet that could have formed in the vicinity of the snowline.

astro-ph.EP

Orbit and atmosphere of HIP 99770 b through the eyes of VLTI/GRAVITY

Context: Inferring the likely formation channel of giant exoplanets and brown dwarf companions from orbital and atmospheric observables remains a formidable challenge. Further and more precise directly measured dynamical masses of these companions are required to inform and gauge formation, evolutionary, and atmospheric models. We present an updated study of HIP 99770 b based on observations conducted with VLTI/GRAVITY. Aims: Combining the new data with previous observations from the literature, we characterise HIP 99770 b to better constrain its orbit, dynamical mass, and atmospheric properties, as well as to shed light on its likely formation channel. Methods: We ran a renewed orbit fit to further constrain the dynamical mass of the companion and the orbit solution. We also analysed the GRAVITY K-band spectrum, placing it into context with literature data, and extracting magnitude, age, spectral type, bulk properties and atmospheric characteristics of HIP 99770 b. Results: We detected the companion at a radial separation of $417\,\mathrm{mas}$ from its host. The new orbit fit yields a dynamical mass of $17_{-5}^{+6}\,\mathrm{M}_\mathrm{Jup}$ and an eccentricity of $0.31_{-0.12}^{+0.06}$. We also find that additional relative astrometry epochs in the future will not enable further constraints on the dynamical mass due to the dominating relative uncertainty on the Hipparcos-Gaia proper motion anomaly. The publication of Gaia DR4 will likely ease this predicament. We find that the companion is consistent with spectral type L8 and exhibits a potential metal enrichment in its atmosphere. Conclusions: These results do not yet allow for a definite inference of the companion's formation channel. Nevertheless, the new constraints on its bulk properties and the additional GRAVITY spectrum presented here will aid future efforts to determine the formation history of HIP 99770 b.

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Four-of-a-kind? Comprehensive atmospheric characterisation of the HR 8799 planets with VLTI/GRAVITY

With four companions at separations from 16 to 71 au, HR 8799 is a unique target for direct imaging, presenting an opportunity for the comparative study of exoplanets with a shared formation history. Combining new VLTI/GRAVITY observations obtained within the ExoGRAVITY program with archival data, we perform a systematic atmospheric characterisation of all four planets. We explore different levels of model flexibility to understand the temperature structure, chemistry and clouds of each planet using both petitRADTRANS atmospheric retrievals and fits to self-consistent radiative-convective equilibrium models. Using Bayesian Model Averaging to combine multiple retrievals, we find that the HR 8799 planets are highly enriched in metals, with [M/H] $\gtrsim$1, and have stellar to super-stellar C/O ratios. The C/O ratio increases with increasing separation from $0.55^{+0.12}_{-0.10}$ for d to $0.78^{+0.03}_{-0.04}$ for b, with the exception of the innermost planet which has a C/O ratio of $0.87\pm0.03$. By retrieving a quench pressure and using a disequilibrium chemistry model we derive vertical mixing strengths compatible with predictions for high-metallicity, self-luminous atmospheres. Bayesian evidence comparisons strongly favour the presence of HCN in HR 8799 c and e, as well as CH$_{4}$ in HR 8799 c, with detections at $>5σ$ confidence. All of the planets are cloudy, with no evidence for patchiness. The clouds of c, d and e are best fit by silicate clouds lying above a deep iron cloud layer, while the clouds of the cooler HR 8799 b are more likely composed of Na$_{2}$S. With well defined atmospheric properties, future exploration of this system is well positioned to unveil further detail in these planets, extending our understanding of the composition, structure, and formation history of these siblings.

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