Xavier Moya — Page 2

arXiv2006

Lattice dynamics and phonon softening in Ni-Mn-Al Heusler alloys

Inelastic and elastic neutron scattering have been used to study a single crystal of the Ni$_{54}$Mn$_{23}$Al$_{23}$ Heusler alloy over a broad temperature range. The paper reports the first experimental determination of the low-lying phonon dispersion curves for this alloy system. We find that the frequencies of the TA$_2$ modes are relatively low. This branch exhibits an anomaly (dip) at a wave number $ξ_{0} ={1/3}\approx 0.33$, which softens with decreasing temperature. Associated with this anomalous dip at $ξ_{0}$, an elastic central peak scattering is also present. We have also observed satellites due to the magnetic ordering.

cond-mat.mtrl-sci↗

arXiv2005

Inverse magnetocaloric effect in ferromagnetic Ni-Mn-Sn alloys

The magnetocaloric effect (MCE) in paramagnetic materials has been widely used for attaining very low temperatures by applying a magnetic field isothermally and removing it adiabatically. The effect can be exploited also for room temperature refrigeration by using recently discovered giant MCE materials. In this letter, we report on an inverse situation in Ni-Mn-Sn alloys, whereby applying a magnetic field adiabatically, rather than removing it, causes the sample to cool. This has been known to occur in some intermetallic compounds, for which a moderate entropy increase can be induced when a field is applied, thus giving rise to an inverse magnetocaloric effect. However, the entropy change found for some ferromagnetic Ni-Mn-Sn alloys is just as large as that reported for giant MCE materials, but with opposite sign. The giant inverse MCE has its origin in a martensitic phase transformation that modifies the magnetic exchange interactions due to the change in the lattice parameters.

cond-mat.mtrl-sci↗