Xiaomei Zeng | Searcharxiv

arXiv2024

Enhancement of piezoelectric response in V doped LiNbO3 films deposited by RF magnetron sputtering

LiNbO3 films doped with vanadium (V) were deposited using RF magnetron sputtering technique. To realize doping with a wider range of V concentration, a 30 mm V metal inlaid target asymmetrically embedded in the 150 mm lithium niobate target was used. The V concentration in the deposited films was a decreasing function of the distance from the V target. The V/Nb ratio in the film decreased from 0.155 to 0.024. Surface and inner morphology and structure, phase and element composition, microstructure, and ferroelectric properties of the undoped and V doped LiNbO3 films were studied. The measured maximal d33 constant of the LiNbVO film with V/Nb ratio of 0.07 was about three times higher than that of the undoped LiNbO3 film, 13.5 pC/N and 4.76 pC/N, respectively. The optimal composition in the deposition geometry used was within the V/Nb ratio range of 0.05 to 0.13. Undoped and V doped LiNbO3 thin films were used as bulk acoustic wave ultrasonic transducers deposited on stainless steel plates to generate longitudinal waves and compare their ultrasonic performance.

cond-mat.mtrl-sci↗

arXiv2021

AlCrO protected textured stainless steel surface for high temperature solar selective absorber applications

The diffusion of substrate material into absorbing layer and oxidation of metal substrate or cermet metal nanoparticles at high temperatures are known as inevitable problems of the solar selective absorbers. In this study, we consider the use of textured stainless steel (SS) surface coated with a protective AlCr oxide layer as a high temperature solar selective absorber. The textured SS surface was prepared by ion etching techniques and AlCr oxide protective layer was deposited by RF magnetron sputtering. The absorptivity and emissivity of the as-prepared absorbers were 0.86-0.92 and 0.151-0.168, respectively. In order to evaluate the thermal stability, the absorbers were annealed at 600-800 C for different time in ambient atmosphere. Absorbers demonstrated a red shift of the onset of the reflectivity at all annealing temperatures. The high activation energy of 315 kJ/mol was calculated. The service lifetime of the absorbers at 500 C was estimated to be about 100 years and at 700 and 800 C the absorbers were stable about 50 and 1 hours, respectively. A detailed examination of the annealed absorber surface revealed growth of surface Mn3O4 nanocrystals, which resulted in observed change of the reflectance spectra, while the textured surface morphology had no significant change. The results show that the protective textured surface has much higher thermal stability in air than iron based cermet absorbers.

physics.chem-ph↗