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Xiaoyi Zhou

Publications and source records attributed to Xiaoyi Zhou.

10 recordsLinked to original sources

Graphitic-C3N4/TiO2(B) S-scheme Heterojunctions for Efficient Photocatalytic H2 Production and Organic Pollution Degradation

Achieving both broad solar-spectrum absorption and strong redox capability is critical for semiconductor photocatalysts in environmental remediation and energy conversion. Herein, an S-scheme heterojunction photocatalyst is constructed by coupling TiO2(B) nanorods with g-C3N4 nanosheets. Its well-matched band structure extends light absorption from the UV to the visible region and enables efficient charge separation. Under simulated sunlight irradiation, the 40 wt% g-C3N4/TiO2(B) heterojunction delivers a H2 evolution rate of 1.98 mmol g-1 h-1 for water reduction with methanol as the sacrificial agent, which is 1.5 and 2.0 times higher than those of pure g-C3N4 and TiO2(B), respectively. When exposed to amoxicillin wastewater instead of methanol solution, the heterojunction degrades 98.2% of amoxicillin and produces 20.70 umol g-1 of H2 within 90 min. Moreover, the heterojunction shows excellent photodegradation activity toward various organic antibiotics and dyes, owing to the S-scheme charge separation mechanism. This work highlights the promising potential of S-scheme heterojunctions for photocatalytic H2 production coupled with organic wastewater treatment.

cond-mat.mtrl-sci

Ultrafast photo-thermoelectric currents in graphene junctions in the mid-infrared

Graphene is widely recognized for its ultrafast and broadband photocurrent response, but whether the broadband ultrafast characteristics are preserved at mid-infrared wavelengths with photon energies below the optical phonon energy remains an open question. Here, we investigate the carrier dynamics in graphene junctions under mid-infrared excitation using an ultrafast pump-probe photocurrent spectroscopy. We utilize dual split gate devices to demonstrate that the photo-thermoelectric effect can dominate the photoresponse of graphene also for a mid-infrared femtosecond excitation. We observe that graphene retains its broadband photocurrent response in this spectral region, but the photocurrent relaxation time increases from ca. 2 ps below 8-9 micrometer up to 3 ps at longer mid-infrared wavelengths. The absence of a pronounced phonon bottleneck in the decay dynamics at room temperature suggests an efficient interplay of electron-electron and electron-phonon scattering even for photon energies below the optical phonon energy in graphene. The observed wavelength dependence of the photocurrent relaxation times is consistent with energy-dependent theoretical relaxation times as derived from a microscopic transport theory of graphene that includes electron-phonon coupling within a Holstein-Peierls Hamiltonian.

cond-mat.mes-hall

Generating Adversarial Point Clouds Using Diffusion Model

Adversarial attack methods for 3D point cloud classification reveal the vulnerabilities of point cloud recognition models. This vulnerability could lead to safety risks in critical applications that use deep learning models, such as autonomous vehicles. To uncover the deficiencies of these models, researchers can evaluate their security through adversarial attacks. However, most existing adversarial attack methods are based on white-box attacks. While these methods achieve high attack success rates and imperceptibility, their applicability in real-world scenarios is limited. Black-box attacks, which are more meaningful in real-world scenarios, often yield poor results. This paper proposes a novel black-box adversarial example generation method that utilizes a diffusion model to improve the attack success rate and imperceptibility in the black-box setting, without relying on the internal information of the point cloud classification model to generate adversarial samples. We use a 3D diffusion model to use the compressed features of the point cloud as prior knowledge to guide the reverse diffusion process to add adversarial points to clean examples. Subsequently, its reverse process is employed to transform the distribution of other categories into adversarial points, which are then added to the point cloud.

cs.CR

PCPT and ACPT: Copyright Protection and Traceability Scheme for DNN Models

Deep neural networks (DNNs) have achieved tremendous success in artificial intelligence (AI) fields. However, DNN models can be easily illegally copied, redistributed, or abused by criminals, seriously damaging the interests of model inventors. The copyright protection of DNN models by neural network watermarking has been studied, but the establishment of a traceability mechanism for determining the authorized users of a leaked model is a new problem driven by the demand for AI services. Because the existing traceability mechanisms are used for models without watermarks, a small number of false-positives are generated. Existing black-box active protection schemes have loose authorization control and are vulnerable to forgery attacks. Therefore, based on the idea of black-box neural network watermarking with the video framing and image perceptual hash algorithm, a passive copyright protection and traceability framework PCPT is proposed that uses an additional class of DNN models, improving the existing traceability mechanism that yields a small number of false-positives. Based on an authorization control strategy and image perceptual hash algorithm, a DNN model active copyright protection and traceability framework ACPT is proposed. This framework uses the authorization control center constructed by the detector and verifier. This approach realizes stricter authorization control, which establishes a strong connection between users and model owners, improves the framework security, and supports traceability verification.

cs.CR

RAEDiff: Denoising Diffusion Probabilistic Models Based Reversible Adversarial Examples Self-Generation and Self-Recovery

Collected and annotated datasets, which are obtained through extensive efforts, are effective for training Deep Neural Network (DNN) models. However, these datasets are susceptible to be misused by unauthorized users, resulting in infringement of Intellectual Property (IP) rights owned by the dataset creators. Reversible Adversarial Exsamples (RAE) can help to solve the issues of IP protection for datasets. RAEs are adversarial perturbed images that can be restored to the original. As a cutting-edge approach, RAE scheme can serve the purposes of preventing unauthorized users from engaging in malicious model training, as well as ensuring the legitimate usage of authorized users. Nevertheless, in the existing work, RAEs still rely on the embedded auxiliary information for restoration, which may compromise their adversarial abilities. In this paper, a novel self-generation and self-recovery method, named as RAEDiff, is introduced for generating RAEs based on a Denoising Diffusion Probabilistic Models (DDPM). It diffuses datasets into a Biased Gaussian Distribution (BGD) and utilizes the prior knowledge of the DDPM for generating and recovering RAEs. The experimental results demonstrate that RAEDiff effectively self-generates adversarial perturbations for DNN models, including Artificial Intelligence Generated Content (AIGC) models, while also exhibiting significant self-recovery capabilities.

cs.CR

DeepHider: A Covert NLP Watermarking Framework Based on Multi-task Learning

Natural language processing (NLP) technology has shown great commercial value in applications such as sentiment analysis. But NLP models are vulnerable to the threat of pirated redistribution, damaging the economic interests of model owners. Digital watermarking technology is an effective means to protect the intellectual property rights of NLP model. The existing NLP model protection mainly designs watermarking schemes by improving both security and robustness purposes, however, the security and robustness of these schemes have the following problems, respectively: (1) Watermarks are difficult to defend against fraudulent declaration by adversary and are easily detected and blocked from verification by human or anomaly detector during the verification process. (2) The watermarking model cannot meet multiple robustness requirements at the same time. To solve the above problems, this paper proposes a novel watermarking framework for NLP model based on the over-parameterization of depth model and the multi-task learning theory. Specifically, a covert trigger set is established to realize the perception-free verification of the watermarking model, and a novel auxiliary network is designed to improve the robustness and security of the watermarking model. The proposed framework was evaluated on two benchmark datasets and three mainstream NLP models, and the results show that the framework can successfully validate model ownership with 100% validation accuracy and advanced robustness and security without compromising the host model performance.

cs.CR

Computation Rate Maximum for Mobile Terminals in UAV-assisted Wireless Powered MEC Networks with Fairness Constraint

This paper investigates an unmanned aerial vehicle (UAV)-assisted wireless powered mobile-edge computing (MEC) system, where the UAV powers the mobile terminals by wireless power transfer (WPT) and provides computation service for them. We aim to maximize the computation rate of terminals while ensuring fairness among them. Considering the random trajectories of mobile terminals, we propose a soft actor-critic (SAC)-based UAV trajectory planning and resource allocation (SAC-TR) algorithm, which combines off-policy and maximum entropy reinforcement learning to promote the convergence of the algorithm. We design the reward as a heterogeneous function of computation rate, fairness, and reaching of destination. Simulation results show that SAC-TR can quickly adapt to varying network environments and outperform representative benchmarks in a variety of situations.

cs.NI

Designing and Analysis of A Wi-Fi Data Offloading Strategy Catering for the Preference of Mobile Users

In recent years, offloading mobile traffic through Wi-Fi has emerged as a potential solution to lower down the communication cost for mobile users. Users hope to reduce the cost while keeping the delay in an acceptable range through Wi-Fi offloading. Also, different users have different sensitivities to the cost and the delay performance. How to make a proper cost-delay tradeoff according to the user's preference is the key issue in the design of the offloading strategy. To address this issue, we propose a preference-oriented offloading strategy for current commercial terminals, which transmit traffic only via one channel simultaneously. We model the strategy as a three-state M/MMSP/1 queueing system, of which the service process is a Markov modulated service process (MMSP), and obtain the structured solutions by establishing a hybrid embedded Markov chain. Our analysis shows that, given the user's preference, there exists an optimal deadline to maximize the utility, which is defined as the linear combination of the cost and the delay. We also provide a method to select the optimal deadline. Our simulation demonstrates that this strategy with the optimal deadline can achieve a good performance.

cs.NI

A deep Convolutional Neural Network for topology optimization with strong generalization ability

This paper proposes a deep Convolutional Neural Network(CNN) with strong generalization ability for structural topology optimization. The architecture of the neural network is made up of encoding and decoding parts, which provide down- and up-sampling operations. In addition, a popular technique, namely U-Net, was adopted to improve the performance of the proposed neural network. The input of the neural network is a well-designed tensor with each channel includes different information for the problem, and the output is the layout of the optimal structure. To train the neural network, a large dataset is generated by a conventional topology optimization approach, i.e. SIMP. The performance of the proposed method was evaluated by comparing its efficiency and accuracy with SIMP on a series of typical optimization problems. Results show that a significant reduction in computation cost was achieved with little sacrifice on the optimality of design solutions. Furthermore, the proposed method can intelligently solve problems under boundary conditions not being included in the training dataset.

cs.LG

The Effect of Mobility on Delayed Data Offloading

Delayed offloading is a widely accepted solution for mobile users to offload their traffic through Wi-Fi when they are moving in urban areas. However, delayed offloading enhances offloading efficiency at the expense of delay performance. Previous works mainly focus on the improvement of offloading efficiency while keeping delay performance in an acceptable region. In this paper, we study the impact of the user mobility on delayed data offloading in respect to the tradeoff between offloading efficiency and delay performance. We model a mobile terminal with delayed data offloading as an M/MMSP/1 queuing system with three service states. To be practical, we consider the feature of currently commercial mobile terminals in our analysis. Our analytical result shows that the mobility of the users can reduce the queueing delay incurred by the delayed offloading, and suggests that delayed offloading strategies can be optimized according to the mobility of the terminals once the delay requirement is given.

cs.NI