arXiv subjects

Xiunan Yang

Publications and source records attributed to Xiunan Yang.

4 recordsLinked to original sources

arXiv2019

Emergence and percolation of rigid domains during colloidal glass transition

Using video microscopy, we measure local spatial constraints in disordered binary colloidal samples, ranging from dilute fluids to jammed glasses, and probe their spatial and temporal correlations to local dynamics during the glass transition. We observe the emergence of significant correlations between constraints and local dynamics within the Lindemann criterion, which coincides with the onset of glassy dynamics in supercooled liquids. Rigid domains in fluids are identified based on local constraints, and demonstrate a percolation transition near glass transition, accompanied by the emergence of dynamical heterogeneities. Our results show that the spatial constraints instead of the geometry of amorphous structures is the key that connects the complex spatial-temporal correlations in disordered materials.

cond-mat.soft↗

arXiv2018

Decoupling between thermodynamics and dynamics during rejuvenation in colloidal glasses

We rejuvenate well-aged quasi-2D binary colloidal glasses by thermal cycling, and systematically measure both the statistical responses and particle-level structural evolutions during rejuvenation. While the moduli and boson peak are continuously rejuvenated with increasing number of cycles, the mean square displacement (MSD) fluctuates significantly between different groups of thermal cycles. The decoupling between the thermodynamical and dynamical evolutions suggests different microscopic origins for different bulk properties of glasses. We find that a small fraction of structural rearrangements triggered by thermal cycling could alter the whole elastic continuum and lead to the significant thermodynamic rejuvenation, while localized defects could be activated and deactivated at the positions close to the rearrangements with significantly high mobility change and hence result in the fluctuated dynamics even with only about 10% of particles as fast regions. Our results offer a comprehensive picture for the microscopic mechanisms underlying bulk glass rejuvenation, which could be readily used to refine glass properties or to formulate further statistical theories in glassy systems.

cond-mat.soft↗

arXiv2018

Orientational Order in Disordered Colloidal Suspensions

Exploring structural order in disordered systems including liquids and glasses is an intriguing but challenging issue in condensed matter physics. Here we construct a new parameter based on the angular distribution function of particles and show that this new orientational order has significantly higher correlation with dynamic heterogeneity compared to a translational parameter based on the radial distribution functions in colloidal glasses. The gradual development of orientational and translational order in supercooled liquids shows that the higher correlation between orientational order and dynamics comes from the onset of glass transition and the orientational order would dominate the glassy dynamics after a simple liquid is considerably supercooled. Our results suggest that orientational order reflects the formation of amorphous order during glass transition while translational order is mainly a result of density increase.

cond-mat.soft↗

arXiv2016

Structures of local rearrangements in soft colloidal glasses

We image local structural rearrangements in soft colloidal glasses under small periodic perturbations induced by thermal cycling. Local structural entropy $S_{2}$ positively correlates with observed rearrangements in colloidal glasses. The high $S_{2}$ values of the rearranging clusters in glasses indicate that fragile regions in glasses are structurally less correlated, similar to structural defects in crystalline solids. Slow-evolving high $S_{2}$ spots are capable of predicting local rearrangements long before the relaxations occur, while fluctuation-created high $S_{2}$ spots best correlate with local deformations right before the rearrangement events. Local free volumes are also found to correlate with particle rearrangements at extreme values, although the ability to identify relaxation sites is substantially lower than $S_{2}$. Our experiments provide an efficient structural identifier for the fragile regions in glasses, and highlight the important role of structural correlations in the physics of glasses.

cond-mat.soft↗