arXiv subjects

Xuetao Zhu

Publications and source records attributed to Xuetao Zhu.

30 records · Page 2Linked to original sources

arXiv2018

Probing lattice vibration at surface and interface of SiO$_2$/Si with nanometer resolution

Recent advances in monochromatic aberration corrected electron microscopy make it possible to detect the lattice vibration with both high-energy resolution and high spatial resolution. Here, we use sub-10 meV electron energy loss spectroscopy to investigate the local vibrational properties at surface and interface of an amorphous SiO$_2$ (a-SiO$_2$) thin film on Si substrate. We find that each optical mode splits into three sub-modes, i.e., surface mode, bulk mode and interface mode, which can be measured from different locations. The pure surface modes can be measured in the vacuum near the surface, and the pure interface modes are expected to be obtained either at the interface location or in the Si, while inside the SiO$_2$ the measured signal is a mixture of bulk, surface, and interface modes. The bulk mode has the largest vibration energy and surface mode has the lowest. The energy of surface mode is thickness dependent, showing a blue-shift as z-thickness (parallel to fast electron beam) of SiO$_2$ film increases, while the bulk and interface modes have constant vibration energy. The intensity of bulk mode linearly increases with thickness being increased, and it drops steeply to zero near the surface and interface (within a few nanometers). The surface modes decay slowly in the vacuum following a Bessel function. The mechanism of the observed spatially dependent vibration behavior is discussed and quantitatively compared with dielectric response theory analysis. Our nanometer scale measurements of vibrations properties provide useful information about the bonding conditions at the surface and interface and thus may help to design better silicon-based electronic devices via surface and interface treatments

cond-mat.mtrl-sci↗

arXiv2018

Lattice Dynamics of Ultrathin FeSe Films on SrTiO3

Charge transfer and electron-phonon coupling (EPC) are proposed to be two important constituents associated with enhanced superconductivity in the single unit cell FeSe films on oxide surfaces. Using high-resolution electron energy loss spectroscopy combined with first-principles calculations, we have explored the lattice dynamics of ultrathin FeSe films grown on SrTiO3. We show that, despite the significant effect from the substrate on the electronic structure and superconductivity of the system, the FeSe phonons in the films are unaffected. The energy dispersion and linewidth associated with the Fe- and Se-derived vibrational modes are thickness- and temperature-independent. Theoretical calculations indicate the crucial role of antiferromagnetic correlation in FeSe to reproduce the experimental phonon dispersion. Importantly, the only detectable change due to the growth of FeSe films is the broadening of the Fuchs-Kliewer (F-K) phonons associated with the lattice vibrations of SrTiO$_3$(001) substrate. If EPC plays any role in the enhancement of film superconductivity, it must be the interfacial coupling between the electrons in FeSe film and the F-K phonons from substrate rather than the phonons of FeSe.

cond-mat.supr-con↗

arXiv2017

Anomalous Acoustic Plasmon Mode from Topologically Protected States

Plasmons, the collective excitations of electrons in the bulk or at the surface, play an important role in the properties of materials, and have generated the field of Plasmonics. We report the observation of a highly unusual acoustic plasmon mode on the surface of a three-dimensional topological insulator (TI), Bi2Se3, using momentum resolved inelastic electron scattering. In sharp contrast to ordinary plasmon modes, this mode exhibits almost linear dispersion into the second Brillouin zone and remains prominent with remarkably weak damping not seen in any other systems. This behavior must be associated with the inherent robustness of the electrons in the TI surface state, so that not only the surface Dirac states but also their collective excitations are topologically protected. On the other hand, this mode has much smaller energy dispersion than expected from a continuous media excitation picture, which can be attributed to the strong coupling with surface phonons.

cond-mat.mtrl-sci↗

arXiv2017

Superstructure evolution of tellurium atoms on Au(111) surface at different coverages

We systematically investigated the superstructure evolution of Te atoms on Au(111) substrate at different coverages. As revealed by low temperature scanning tunneling microscopy and spectroscopy, Te atoms form one-dimensional root3 R30° chains near 0.10 monolayer (ML). Two two-dimensional chiral structures, (root111*root111)R4.7° and (3root21*3root21)R10.9°, can be formed and their stability can be tuned by slightly adjusting the Te coverge near 1/3 ML. A honeycomb-like superstructure is observed by further increasing the coverage to 4/9 ML. An interfacial state emerges at ~-0.65 eV due to Te adsorption on Au(111). The formation of these Te-induced high-order superstructures is accompanied by relaxation of gold atoms in the surface layer, indicating the strong Te-Au interaction.

cond-mat.mes-hall↗

arXiv2017

Superconducting transition of FeSe/SrTiO3 induced by adsorption of semiconducting organic molecules

We prepared superconducting and non-superconducting FeSe films on SrTiO3(001) substrates (FeSe/STO) and investigated the superconducting transition induced by charge transfer between organic molecules and FeSe layers by low temperature scanning tunneling microscopy and spectroscopy. At low coverage, donor- and acceptor-type molecules adsorbed preferentially on the non-superconducting and superconducting FeSe layers, respectively. Superconductivity was induced by donor molecules on non-superconducting FeSe layer, while the superconductivity was suppressed near acceptor molecules. The corresponding evolutions of electronic states and work function were also resolved by scanning tunneling microscopy. These results illustrate the important role played by local electron concentration in the superconducting transition of FeSe/STO.

cond-mat.supr-con↗

arXiv2016

The Role of SrTiO3 Phonon Penetrating into thin FeSe Films in the Enhancement of Superconductivity

The significant role of interfacial coupling on the superconductivity enhancement in FeSe films on SrTiO3 has been widely recognized. But the explicit origination of this coupling is yet to be identified. Here by surface phonon measurements using high resolution electron energy loss spectroscopy, we found electric field generated by Fuchs-Kliewer (F-K) phonon modes of SrTiO3 can penetrate into FeSe films and strongly interact with electrons therein. The mode-specific electron-phonon coupling (EPC) constant for the ~92 meV F-K phonon is ~0.25 in the single-layer FeSe on SrTiO3. With increasing FeSe thickness, the penetrating field intensity decays exponentially, which matches well the observed exponential decay of the superconducting gap. It is unambiguously shown that the SrTiO3 F-K phonon penetrating into FeSe is essential in the interfacial superconductivity enhancement.

cond-mat.supr-con↗

arXiv2015

Classification of Charge Density Waves Based on Their Nature

The concept of a Charge Density Wave (CDW) permeates much of condensed matter physics and chemistry. Conceptually, CDWs have their origin rooted in the instability of a one-dimensional system described by Peierls. The extension of this concept to reduced dimensional systems has led to the concept of Fermi surface nesting (FSN), which dictates the wave vector q_cdw of the CDW and the corresponding lattice distortion. The idea is that segments of the Fermi contours are connected by q_cdw, resulting in the effective screening of phonons inducing Kohn Anomalies in their dispersion at q_cdw, driving a lattice restructuring at low temperatures. There is growing theoretical and experimental evidence that this picture fails in many real systems and in fact it is the momentum dependence of the electron-phonon coupling (EPC) matrix element that determines the characteristic of CDW phase (q_cdw). Here, based on the published results for the prototypical CDW system 2H-NbSe2, we show how well the q-dependent EPC matrix element, but not the FSN, can describe the origin of CDW. We further demonstrate a procedure of combing electronic band and phonon (dispersion and linewidth) measurements to extract the EPC matrix element, allowing the electronic states involved in the EPC to be identified. Thus we show that a large EPC does not necessarily induce the CDW phase, with Bi2Sr2CaCu2O8 (Bi2212) as the example, and the charge ordered phenomena observed in various cuprates are not driven by FSN or EPC. To experimentally resolve the microscopic picture of EPC will lead to a fundamental change in the way we think about, write about, and classify Charge Density Waves.

cond-mat.mtrl-sci↗

arXiv2013

Electron-Phonon Coupling on the Surface of Topological Insulators

Topological insulators (TIs) are materials that have a bulk electronic band gap like an ordinary insulator but have protected conducting states on their surface. One of the most interesting properties of TIs is their spin helicity, whereby the spin is locked normal to the wave vector of the surface electronic state. The topological surface states should be very stable in TIs, since these spin-textured surface states are robust against spin-independent backscattering. Scattering from defects and other lattice imperfections is possible provided the spin is not completely flipped. However, the quality of TI crystals can be controlled by careful growth, whereas phonons will exist in even the most perfect crystals. Consequently, electron-phonon coupling (EPC) should be the dominant scattering mechanism for surface electronic states at finite temperatures. Hence, the study of EPC in TIs is of exceptional importance in assessing any potential applications. In this article both experimental and theoretical studies of the EPC on the surface of TIs are reviewed, with the contents mainly focused on the typical strong three dimensional TIs, such as Bi2Se3 and Bi2Te3.

cond-mat.mes-hall↗

arXiv2012

Electron-phonon Coupling on the Surface of the Topological Insulator Bi2Se3: Determined from Surface Phonon Dispersion Measurements

In this letter we report measurements of the coupling between Dirac fermion quasiparticles (DFQs) and phonons on the (001) surface of the strong topological insulator Bi2Se3. While most contemporary investigations of this coupling have involved examining the temperature dependence of the DFQ self-energy via angle-resolved photoemission spectroscopy (ARPES) measurements, we employ inelastic helium atom scattering to explore, for the first time, this coupling from the phonon perspective. Using a Hilbert transform, we are able to obtain the imaginary part of the phonon self-energy associated with a dispersive surface phonon branch identified in our previous work [1] as having strong interactions with the DFQs. From this imaginary part of the self-energy we obtain a branch-specific electron-phonon coupling constant of 0.43, which is stronger than the values reported form the ARPES measurements.

cond-mat.mtrl-sci↗

arXiv2011

Interaction of Phonons and Dirac Fermions on the Surface of Bi2Se3: A Strong Kohn Anomaly

We report the first measurements of phonon dispersion curves on the (001) surface of the strong three-dimensional topological insulator Bi2Se3. The surface phonon measurements were carried out with the aid of coherent helium beam surface scattering techniques. The results reveal a prominent signature of the exotic metallic Dirac fermion quasi-particles, including a strong Kohn anomaly. The signature is manifest in a low energy isotropic convex dispersive surface phonon branch with a frequency maximum of 1.8 THz, and having a V-shaped minimum at approximately 2kF that defines the Kohn anomaly. Theoretical analysis attributes this dispersive profile to the renormalization of the surface phonon excitations by the surface Dirac fermions. The contribution of the Dirac fermions to this renormalization is derived in terms of a Coulomb-type perturbation model.

cond-mat.mtrl-sci↗

arXiv2010

Temperature-Dependent Anomalies in the Structure of the (001) Surface of LiCu2O2

Surface corrugation functions, derived from elastic helium atom scattering (HAS) diffraction patterns at different temperatures, reveal that the Cu2+ rows in the (001) surface of LiCu2O2 undergo an outward displacement of about 0.15 Å as the surface was cooled down to 140 K. This is probably the first time that isolated one-dimensional magnetic ion arrays were realized, which qualifies the Li1+Cu2+O2-2 surface as a candidate to study one-dimensional magnetism. The rising Cu2+ rows induce a surface incommensurate structural transition along the a-direction. Surface equilibrium analysis showed that the surface Cu2+ ions at bulk-like positions experience a net outward force along the surface normal which is relieved by the displacement. Temperature-dependent changes of the surface phonon dispersions obtained with the aid of inelastic HAS measurements combined with surface lattice dynamical calculations are also reported.

cond-mat.str-el↗

arXiv2009

Investigation of the Structural and Dynamical Properties of the (001) Surface of LiCu2O2

We report on studies of the structure and dynamics of the (001)surface of single crystal LiCu2O2, investigated by He beam scattering at room temperature, and with lattice dynamical models. The best fit surface corrugation to measured diffraction patterns shows that the surface termination is exclusively a Li+1Cu+2O-2 plane. Lattice dynamics fits to inelastic He scattering spectra reveal the presence of two low-lying surface phonon modes, identified with the motion of Cu+2, Li+1 surface ions normal to the surface.

cond-mat.str-el↗