arXiv subjects

Y. T. Yan

Publications and source records attributed to Y. T. Yan.

At least 19 recordsLinked to original sources

arXiv2025

Ammonia in the hot core W51-IRS2: Maser line profiles, variability, and saturation

W51-IRS2 is known to be one of the most prolific sources of interstellar ammonia (NH$_3$) maser lines. So far, however, many of these inversion lines have rarely been studied. Here we report spectrally resolved line profiles for the majority of detected features and provide information on the variability of these maser components between 2012 and 2023. This includes the first tentative detection of a ($J$,$K$) = (5,2) maser in the interstellar medium and the first tentative detection of a (6,4) maser in W51-IRS2. Furthermore, we report for the first time NH$_3$ (9,6) maser emission below Local Standard of Rest velocities of 50 km s$^{-1}$ in this source as well as double maser features occasionally seen in other transitions. The detected maser lines strongly indicate vibrational pumping by $\approx$10 $μ$m photons, which must be abundant due to the high kinetic temperature ($\approx$300 K) of the ammonia emitting gas. The detection of vibrationally excited NH$_3$, suggesting a vibrational excitation temperature consistent with the kinetic one, and a comparison with measured SiO line profiles is also presented. For the (10,7) line, we find a tentative correlation between flux density and line width compatible with unsaturated maser emission. The velocity drift of the so-called 45 km s$^{-1}$ maser features, reported to be +0.2 km s$^{-1}$ yr$^{-1}$ between 1996 and 2012, has either slowed down to values $<$0.1 km s$^{-1}$ or has entirely disappeared. In 2023, the component is only seen in ammonia inversion lines that are located at least 800 K above the ground state. The other features have faded. Possible scenarios explaining this phenomenon are discussed.

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arXiv2025

The Chemical Clock of High-mass Star-forming Regions: N2H+/CCS

Using the IRAM 30 m telescope, we presented observations of N2H+ J = 1-0, CCS JN = 87-76 and 77-66 lines toward a large sample of ultracompact HII regions (UC HIIs). Among our 88 UC HIIs, 87 and 33 sources were detected in the N2H+ J = 1-0 and CCS JN = 87-76 lines, respectively. For the CCS 77-66 transition, we detected emission in 10 out of 82 targeted sources, all of which also exhibited emission in the CCS JN = 87-76 line. Physical parameters are derived for our detections, including the optical depth and excitation temperature of N2H+, the rotational temperature of CCS and the column density. Combining our results and previous observation results in different stages of high-mass star-forming regions (HMSFRs), we found that the column density ratio N(N2H+)/N(CCS) increases from high-mass starless cores (HMSCs) through high-mass protostellar cores (HMPOs) to UC HIIs. This implies that N(N2H+)/N(CCS) can trace the evolution process of HMSFRs. It was supported by our gas-grain chemical model, which shows that N(N2H+)/N(CCS) increases with the evolution age of HMSFRs. The temperature, density and chemical age were also constrained from our best-fit model at each stage. Thus, we propose N(N2H+)/N(CCS) as a reliable chemical clock of HMSFRs.

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arXiv2025

Shock-induced HCNH+ abundance enhancement in the heart of the starburst galaxy NGC 253 unveiled by ALCHEMI

Understanding the chemistry of molecular clouds is pivotal to elucidate star formation and galaxy evolution. As one of the important molecular ions, HCNH+ plays an important role in this chemistry. Yet, its behavior and significance under extreme conditions, such as in the CMZs of external galaxies, are still largely unexplored. We aim to reveal the physical and chemical properties of the CMZ in the starburst galaxy NGC253 with multiple HCNH+ transitions to shed light on the molecule's behavior under the extreme physical conditions of a starburst. We employ molecular line data including results for four rotational transitions of HCNH+ from the ALCHEMI large program to investigate underlying physical and chemical processes. Despite weak intensities, HCNH+ emission is widespread throughout NGC253's CMZ, which suggests that this molecular ion can effectively trace large-scale structures within molecular clouds. Using the quantum mechanical coupled states approximation, we computed rate coefficients for collisions of HCNH+ with para-H2 and ortho-H2 at kinetic temperatures up to 500 K. Using these coefficients in a non-LTE modeling framework and employing a Monte Carlo Markov chain analysis, we find that HCNH+ emission originates from regions with H2 number densities of $\sim10^{2.80}-10^{3.55}$~cm$^{-3}$, establishing HCNH+ as a tracer of low-density environments. Our analysis reveals that most of the HCNH+ abundances in the CMZ of NGC253 are higher than all reported values in the Milky Way. We performed static, PDR, and shock modeling, and found that recurrent shocks could potentially account for the elevated HCNH+ abundances observed in this CMZ. We propose that the unexpectedly high HCNH+ abundances may result from chemical enhancement, primarily driven by the elevated gas temperatures and cosmic ray ionization rates of shocked, low-density gas in the nuclear starburst regions of NGC253.

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arXiv2024

Interstellar Nitrogen Isotope Ratios: Measurements on tracers of C$^{14}$N and C$^{15}$N

The nitrogen isotope ratio 14N/15N is a powerful tool to trace Galactic stellar nucleosynthesis and constraining Galactic chemical evolution. Previous observations have found lower 14N/15N ratios in the Galactic center and higher values in the Galactic disk. This is consistent with the inside-out formation scenario of our Milky Way. However, previous studies mostly utilized double isotope ratios also including 12C/13C, which introduces additional uncertainties. Here we therefore present observations of C14N and its rare isotopologue, C15N, toward a sample of star forming regions, measured by the IRAM 30 m and/or the ARO 12 m telescope at $λ$ ~3 mm wavelength. For those 35 sources detected in both isotopologues, physical parameters are determined. Furthermore we have obtained nitrogen isotope ratios using the strongest hyperfine components of CN and C15N. For those sources showing small deviations from Local Thermodynamical Equilibrium and/or self-absorption, the weakest hyperfine component, likely free of the latter effect, was used to obtain reliable 14N/15N values. Our measured 14N/15N isotope ratios from C14N and C15N measurements are compatible with those from our earlier measurements of NH3 and 15NH3 (Paper I), i.e., increasing ratios to a Galacticentric distance of ~9 kpc. The unweighted second order polynomial fit yields $\frac{{\rm C^{14}N}}{{\rm C^{15}N}} = (-4.85 \pm 1.89)\;{\rm kpc^{-2}} \times R_{\rm GC}^{2} + (82.11 \pm 31.93) \;{\rm kpc^{-1}} \times R_{\rm GC} - (28.12 \pm 126.62)$. Toward the outer galaxy, the isotope ratio tends to decrease, supporting an earlier finding by H13CN/HC15N. Galactic chemical evolution models are consistent with our measurements of the 14N/15N isotope ratio, i.e. a rising trend from the Galactic center region to approximately 9 kpc, followed by a decreasing trend with increasing $R_{\rm GC}$ toward the outer Galaxy.

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arXiv2024

An ALCHEMI inspection of sulphur-bearing species towards the central molecular zone of NGC 253

Sulphur-bearing species are detected in various environments within Galactic star-forming regions and are particularly abundant in the gas phase of outflows and shocks, and photo-dissociation regions. In this work, we aim to investigate the nature of the emission from the most common sulphur-bearing species observable at millimetre wavelengths towards the nuclear starburst of the galaxy NGC 253. We intend to understand which type of regions are probed by sulphur-bearing species and which process(es) dominate(s) the release of sulphur into the gas phase. We used the high-angular resolution (1.6" or 27 pc) observations from the ALCHEMI ALMA Large Program to image several sulphur-bearing species towards the central molecular zone (CMZ) of NGC 253. We performed local thermodynamic equilibrium (LTE) and non-LTE large velocity gradient (LVG) analyses to derive the physical conditions of the gas in which S-bearing species are emitted, and their abundance ratios across the CMZ. Finally, we compared our results with previous ALCHEMI studies and a few selected Galactic environments. We found that not all sulphur-bearing species trace the same type of gas: strong evidence indicates that H2S and part of the emission of OCS, H2CS, and SO, are tracing shocks whilst part of SO and CS emission rather trace the dense molecular gas. For some species, such as CCS and SO2, we could not firmly conclude on their origin of emission. The present analysis indicates that the emission from most sulphur-bearing species throughout the CMZ is likely dominated by shocks associated with ongoing star formation. In the inner part of the CMZ where the presence of super star clusters was previously indicated, we could not distinguish between shocks or thermal evaporation as the main process releasing the S-bearing species.

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arXiv2024

Discovery of widespread non-metastable ammonia masers in the Milky Way

We present the results of a search for ammonia maser emission in 119 Galactic high-mass star-forming regions (HMSFRs) known to host 22 GHz H$_2$O maser emission. Our survey has led to the discovery of non-metastable NH$_3$ inversion line masers toward 14 of these sources. This doubles the number of known non-metastable ammonia masers in our Galaxy, including nine new very high excitation ($J,K$)~=~(9,6) maser sources. These maser lines, including NH$_3$ (5,4), (6,4), (6,5), (7,6), (8,6), (9,6), (9,8), (10,8), and (11,9), arise from energy levels of 342 K, 513 K, 465 K, 606 K, 834 K, 1090 K, 942 K, 1226 K, and 1449 K above the ground state. Additionally, we tentatively report a new metastable NH$_3$ (3,3) maser in G048.49 and an NH$_3$ (7,7) maser in G029.95. Our observations reveal that all of the newly detected NH$_3$ maser lines exhibit either blueshifted or redshifted velocities with respect to the source systemic velocities. Among the non-metastable ammonia maser lines, larger velocity distributions, offset from the source systemic velocities, are found in the ortho-NH$_3$ ($K=3n$) than in the para-NH$_3$ ($K\neq3n$) transitions.

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arXiv2024

Molecular isotopologue measurements toward super star clusters and the relation to their ages in NGC253 with ALCHEMI

Determining the evolution of the CNO isotopes in the interstellar medium (ISM) of starburst galaxies can yield important constraints on the ages of superstar clusters (SSCs), or on other aspects and contributing factors of their evolution. Due to the time-dependent nature of the abundances of isotopes within the ISM as they are supplied from processes such as nucleosynthesis or chemical fractionation, this provides the possible opportunity to probe the ability of isotopes ratios to trace the ages of high star forming regions, such as SSCs. The goal of this study is to investigate whether the isotopic variations in SSC regions within NGC253 are correlated with their different ages as derived from stellar population modelling. We have measured abundance ratios of CO, HCN and HCO$^+$ isotopologues in six regions containing SSCs within NGC253 using high spatial resolution (1.6",$\sim 28$pc) data from the ALCHEMI (ALma Comprehensive High-resolution Extragalactic Molecular Inventory) ALMA Large program. We have then analysed these ratios using RADEX radiative transfer modelling, with the parameter space sampled using the nested sampling Monte Carlo algorithm MLFriends. These abundance ratios were then compared to ages predicted in each region via the fitting of observed star formation tracers (such as Br$γ$) to starburst stellar population evolution models. We do not find any significant trend with age for the CO and HCN isotopologue ratios on the timescales for the ages of the SSC* regions observed. The driving factors of these ratios within SSCs could be the Initial Mass Function as well as possibly fractionation effects. To further probe these effects in SSCs over time a larger sample of SSCs must be observed spanning a larger age range.

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arXiv2023

A Systematic Observational Study on Galactic Interstellar Ratio 18O/17O. II. C18O and C17O J=2-1 Data Analysis

To investigate the relative amount of ejecta from high-mass versus intermediate-mass stars and to trace the chemical evolution of the Galaxy, we have performed with the IRAM 30m and the SMT 10m telescopes a systematic study of Galactic interstellar 18O/17O ratios toward a sample of 421 molecular clouds, covering a galactocentric distance range of 1-22 kpc. The results presented in this paper are based on the J=2-1 transition and encompass 364 sources showing both C18O and C17O detections. The previously suggested 18O/17O gradient is confirmed. For the 41 sources detected with both facilities, good agreement is obtained. A correlation of 18O/17O ratios with heliocentric distance is not found, indicating that beam dilution and linear beam sizes are not relevant. For the subsample of IRAM 30 m high-mass star-forming regions with accurate parallax distances, an unweighted fit gives 18O/17O = (0.12+-0.02)R_GC+(2.38+-0.13) with a correlation coefficient of R = 0.67. While the slope is consistent with our J=1-0 measurement, ratios are systematically lower. This should be caused by larger optical depths of C18O 2-1 lines, w.r.t the corresponding 1-0 transitions, which is supported by RADEX calculations and the fact that C18O/C17O is positively correlated with 13CO/C18O. After considering optical depth effects with C18O J=2-1 reaching typically an optical depth of 0.5, corrected 18O/17O ratios from the J=1-0 and J=2-1 lines become consistent. A good numerical fit to the data is provided by the MWG-12 model, including both rotating stars and novae.

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arXiv2023

Sulfur isotope ratios in the Large Magellanic Cloud

Sulfur isotope ratios have emerged as a promising tool for tracing stellar nucleosynthesis, quantifying stellar populations, and investigating the chemical evolution of galaxies. While extensively studied in the Milky Way, in extragalactic environments they remain largely unexplored. We focus on investigating the sulfur isotope ratios in the Large Magellanic Cloud (LMC) to gain insights into sulfur enrichment in this nearby system and to establish benchmarks for such ratios in metal-poor galaxies. We conducted pointed observations of CS and its isotopologues toward N113, one of the most prominent star-formation regions in the LMC, utilizing the Atacama Pathfinder EXperiment 12~m telescope. We present the first robust detection of C$^{33}$S in the LMC by successfully identifying two C$^{33}$S transitions on a large scale of $\sim$5 pc. Our measurements result in an accurate determination of the $^{34}$S/$^{33}$S isotope ratio, which is 2.0$\pm$0.2. Our comparative analysis indicates that the $^{32}$S/$^{33}$S and $^{34}$S/$^{33}$S isotope ratios are about a factor of 2 lower in the LMC than in the Milky Way. Our findings suggest that the low $^{34}$S/$^{33}$S isotope ratio in the LMC can be attributed to a combination of the age effect, low metallicity, and star formation history.

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arXiv2023

A Possible Chemical Clock in High-mass Star-forming Regions: N(HC3N)/N(N2H+)?

We conducted observations of multiple HC3N (J = 10-9, 12-11, and 16-15) lines and the N2H+ (J = 1-0) line toward a large sample of 61 ultracompact (UC) H II regions, through the Institutde Radioastronomie Millmetrique 30 m and the Arizona Radio Observatory 12 m telescopes. The N2H+ J = 1-0 line is detected in 60 sources and HC3N is detected in 59 sources, including 40 sources with three lines, 9 sources with two lines, and 10 sources with one line. Using the rotational diagram, the rotational temperature and column density of HC3N were estimated toward sources with at least two HC3N lines. For 10 sources with only one HC3N line, their parameters were estimated, taking one average value of Trot. For N2H+, we estimated the optical depth of the N2H+ J = 1-0 line, based on the line intensity ratio of its hyperfine structure lines. Then the excitation temperature and column density were calculated. When combining our results in UC H II regions and previous observation results on high-mass starless cores and high-mass protostellar cores, the N(HC3N)/N(N2H+) ratio clearly increases from the region stage. This means that the abundance ratio changes with the evolution of high-mass star-forming regions (HMSFRs). Moreover, positive correlations between the ratio and other evolutionary indicators (dust temperature, bolometric luminosity, and luminosity-to-mass ratio) are found. Thus we propose the ratio of N(HC3N)/N(N2H+) as a reliable chemical clock of HMSFRs.

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arXiv2022

Direct measurements of carbon and sulfur isotope ratios in the Milky Way

With the IRAM 30 meter telescope, we performed observations of the $J$ = 2-1 transitions of CS, C$^{33}$S, C$^{34}$S, C$^{36}$S, $^{13}$CS, $^{13}$C$^{33}$S, and $^{13}$C$^{34}$S as well as the $J$ = 3-2 transitions of C$^{33}$S, C$^{34}$S, C$^{36}$S, and $^{13}$CS toward a large sample of 110 HMSFRs. We measured the $^{12}$C/$^{13}$C, $^{32}$S/$^{34}$S, $^{32}$S/$^{33}$S, $^{32}$S/$^{36}$S, $^{34}$S/$^{33}$S, $^{34}$S/$^{36}$S, and $^{33}$S/$^{36}$S abundance ratios with rare isotopologs of CS, thus avoiding significant saturation effects. With accurate distances obtained from parallax data, we confirm previously identified $^{12}$C/$^{13}$C and $^{32}$S/$^{34}$S gradients as a function of galactocentric distance (RGC). In the CMZ, $^{12}$C/$^{13}$C ratios are higher than suggested by a linear fit to the disk values as a function of RGC. While $^{32}$S/$^{34}$S ratios near the Galactic center and in the inner disk are similar, this is not the case for $^{12}$C/$^{13}$C, when comparing central values with those near RGC of 5 kpc. As was already known, there is no $^{34}$S/$^{33}$S gradient but the average ratio of 4.35~$\pm$~0.44 derived from the $J$ = 2-1 transition lines of C$^{34}$S and C$^{33}$S is well below previously reported values. A comparison between solar and local interstellar $^{32}$S/$^{34}$S and $^{34}$S/$^{33}$S ratios suggests that the Solar System may have been formed from gas with a particularly high $^{34}$S abundance. For the first time, we report positive gradients of $^{32}$S/$^{33}$S, $^{34}$S/$^{36}$S, $^{33}$S/$^{36}$S, and $^{32}{\rm S}/^{36}{\rm S}$ in our Galaxy. The predicted $^{12}$C/$^{13}$C ratios from the latest GCE models are in good agreement with our results. While $^{32}$S/$^{34}$S and $^{32}$S/$^{36}$S ratios show larger differences at larger RGC, $^{32}$S/$^{33}$S ratios show an offset across the entire inner 12 kpc of the Milky Way.

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arXiv2022

Discovery of non-metastable ammonia masers in Sagittarius B2

We report the discovery of widespread maser emission in non-metastable inversion transitions of NH$_3$ toward various parts of the Sagittarius B2 molecular cloud/star forming region complex: We detect masers in the $J,K = $ (6,3), (7,4), (8,5), (9,6), and (10,7) transitions toward Sgr B2(M) and Sgr B2(N), an NH$_3$ (6,3) maser in Sgr B2(NS), and NH$_3$ (7,4), (9,6), and (10,7) masers in Sgr B2(S). With the high angular resolution data of the Karl G. Jansky Very Large Array (JVLA) in A-configuration we identify 18 maser spots. Nine maser spots arise from Sgr B2(N), one from Sgr B2(NS), five from Sgr B2(M), and three in Sgr B2(S). Compared to our Effelsberg single dish data, the JVLA data indicate no missing flux. The detected maser spots are not resolved by our JVLA observations. Lower limits to the brightness temperature are $>$3000~K and reach up to several 10$^5$~K, manifesting the lines' maser nature. In view of the masers' velocity differences with respect to adjacent hot molecular cores and/or UCH{\scriptsize II} regions, it is argued that all the measured ammonia maser lines may be associated with shocks caused either by outflows or by the expansion of UCH{\scriptsize II} regions. Overall, Sgr B2 is unique in that it allows us to measure many NH$_3$ masers simultaneously, which may be essential to elucidate their so far poorly understood origin and excitation.

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arXiv2022

Interstellar Nitrogen Isotope Ratios: New NH3 Data from the Galactic Center out to the Perseus Arm

Our aim is to measure the interstellar 14N/15N ratio across the Galaxy, to establish a standard data set on interstellar ammonia isotope ratios, and to provide new constraints on the Galactic chemical evolution. The (J, K ) = (1, 1), (2, 2), and (3, 3) lines of 14NH3 and 15NH3 were observed with the Shanghai Tianma 65 m radio telescope (TMRT) and the Effelsberg 100 m telescope toward a large sample of 210 sources. One hundred fourty-one of these sources were detected by the TMRT in 14NH3. Eight of them were also detected in 15NH3. For 10 of the 36 sources with strong NH3 emission, the Effelsberg 100 m telescope successfully detected their 15NH3(1, 1) lines, including 3 sources (G081.7522, W51D, and Orion-KL) with detections by the TMRT telescope. Thus, a total of 15 sources are detected in both the 14NH3 and 15NH3 lines. Line and physical parameters for these 15 sources are derived, including optical depths, rotation and kinetic temperatures, and total column densities. 14N/15N isotope ratios were determined from the 14NH3/15NH3 abundance ratios. The isotope ratios obtained from both telescopes agree for a given source within the uncertainties, and no dependence on heliocentric distance and kinetic temperature is seen. 14N/15N ratios tend to increase with galactocentric distance, confirming a radial nitrogen isotope gradient. This is consistent with results from recent Galactic chemical model calculations, including the impact of superasymptotic giant branch stars and novae.

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arXiv2022

Cyanopolyyne line survey towards high-mass star-forming regions with TMRT

We carried out a cyanopolyyne line survey towards a large sample of HMSFRs using the Shanghai Tian Ma 65m Radio Telescope (TMRT). Our sample consisted of 123 targets taken from the TMRT C band line survey. It included three kinds of sources, namely those with detection of the 6.7 GHz CH3OH maser alone, with detection of the radio recombination line (RRL) alone, and with detection of both (hereafter referred to as Maser-only, RRL-only, and Maser-RRL sources, respectively). We detected HC3N in 38 sources, HC5N in 11 sources, and HC7N in G24.790+0.084, with the highest detection rate being found for Maser-RRL sources and a very low detection rate found for RRL-only sources. Their column densities were derived using the rotational temperature measured from the NH3 lines. And we constructed and fitted the far-infrared (FIR) spectral energy distributions. Based on these, we derive their dust temperatures, H2 column densities, and abundances of cyanopolyynes relative to H2. The detection rate, the column density, and the relative abundance of HC3N increase from Maser-only to Maser-RRL sources and decrease from Maser-RRL to RRL-only sources. This trend is consistent with the proposed evolutionary trend of HC3N under the assumption that our Maser-only, Maser-RRL, and RRL-only sources correspond to massive young stellar objects, ultra-compact HII regions, and normal classical HII regions, respectively. Furthermore, a statistical analysis of the integrated line intensity and column density of HC3N and shock-tracing molecules (SiO, H2CO) enabled us to find positive correlations between them. This suggests that HC3N may be another tracer of shocks, and should therefore be the subject of further observations and corresponding chemical simulations. Our results indirectly support the idea that the neutral--neutral reaction between C2H2 and CN is the dominant formation pathway of HC3N.

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arXiv2022

Discovery of ammonia (9,6) masers in two high-mass star-forming regions

Molecular maser lines are signposts of high-mass star formation, probing excitation and kinematics of very compact regions in the close environment of young stellar objects and providing useful targets for trigonometric parallax measurements. Only a few NH$_{3}$ (9,6) masers were known so far, and their origin is still poorly understood. Here we aim to find new NH$_{3}$ (9,6) masers to provide a better observational basis to study their role in high-mass star-forming regions. We carried out NH$_{3}$ (9,6) observations toward Cepheus A and G34.26$+$0.15 with the Effelsberg-100 m telescope and the Karl G. Janksy Very Large Array. We discovered new NH$_{3}$ (9,6) masers in Cep A and G34.26$+$0.15, which increases the number of high-mass star-forming regions hosting NH$_{3}$ (9,6) masers from five to seven. Long term monitoring (20 months) at Effelsberg shows that the intensity of the (9,6) maser in G34.26$+$0.15 is decreasing, while the Cep A maser remains stable. Compared to the Effelsberg data and assuming linear variations between the epochs of observation, the JVLA data indicate no missing flux. This suggests that the NH$_3$ (9,6) emission arises from single compact emission regions that are not resolved by the interferometric measurements. As JVLA imaging shows, the NH$_{3}$ (9,6) emission in Cep A originates from a sub-arcsecond sized region, slightly to the west of the peak position of the 1.36\,cm continuum object, HW2. In G34.26$+$0.15, three NH$_{3}$ (9,6) maser spots are observed: one is close to the head of the cometary ultracompact \h2 region C and the other two are emitted from a compact region to the west of the hypercompact \h2 region A. The newly found (9,6) masers appear to be related to outflows. Higher angular resolution of JVLA and VLBI observations are needed to provide more accurate positions and constraints for pumping scenarios.

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arXiv2021

ALCHEMI: an ALMA Comprehensive High-resolution Extragalactic Molecular Inventory. Survey presentation and first results from the ACA array

We used the Atacama Large Millimeter/submillimeter Array (ALMA), covering a nearly contiguous 289 GHz frequency range between 84.2 and 373.2 GHz, to image the continuum and spectral line emission at 1.6\arcsec ($\sim 28$ pc) resolution down to a sensitivity of $30-50$ mK. This article describes the ALMA Comprehensive High-resolution Extragalactic Molecular Inventory (ALCHEMI) Large Program. We focus on the analysis of the spectra extracted from the $15''$ ($\sim255$ pc) resolution ALMA Compact Array data. We model the molecular emission assuming local thermodynamic equilibrium with 78 species detected. Additionally, multiple hydrogen and helium recombination lines are identified. Spectral lines contribute 5 to 36\% of the total emission in frequency bins of 50 GHz. We report the first extragalactic detections of C$_2$H$_5$OH, HOCN, HC$_3$HO, and several rare isotopologues. Isotopic ratios of carbon, oxygen, sulfur, nitrogen and silicon were measure with multiple species. Infrared pumped vibrationaly excited HCN, HNC, and HC$_3$N emission, originating in massive star formation locations, is clearly detected at low resolution, while we do not detect it for HCO$^+$. We suggest high temperature conditions in these regions driving a seemingly "carbon-rich" chemistry which may also explain the observed high abundance of organic species close to those in Galactic hot cores. The $L_{vib}/L_{IR}$ ratio is used as a proxy to estimate a $3\%$ contribution from proto super star cluster to the global infrared emission. Measured isotopic ratios with high dipole moment species agree with those within the central kiloparsec of the Galaxy, while those derived from $\rm^{13}C^{18}O$ are a factor of 5 larger, confirming the existence of multiple ISM components within NGC 253 with different degrees of nucleosynthesis enrichment. ALCHEMI provides a template for early Universe galaxies.

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arXiv2020

Galactic interstellar sulfur isotopes: A radial $^{32}$S$/$$^{34}$S gradient?

We present observations of $^{12}$C$^{32}$S, $^{12}$C$^{34}$S, $^{13}$C$^{32}$S and $^{12}$C$^{33}$S J=2$-$1 lines toward a large sample of massive star forming regions by using the Arizona Radio Observatory 12-m telescope and the IRAM\,30-m. Taking new measurements of the carbon $^{12}$C/$^{13}$C ratio, the $^{32}$S$/$$^{34}$S isotope ratio was determined from the integrated $^{13}$C$^{32}$S/$^{12}$C$^{34}$S line intensity ratios for our sample. Our analysis shows a $^{32}$S$/$$^{34}$S gradient from the inner Galaxy out to a galactocentric distance of 12\,kpc. An unweighted least-squares fit to our data yields $^{32}$S$/$$^{34}$S = (1.56 $\pm$ 0.17)$\rm D_{\rm GC}$ + (6.75 $\pm$ 1.22) with a correlation coefficient of 0.77. Errors represent 1$σ$ standard deviations. Testing this result by (a) excluding the Galactic center region, (b) excluding all sources with C$^{34}$S opacities $>$ 0.25, (c) combining our data and old data from previous study, and (d) using different sets of carbon isotope ratios leads to the conclusion that the observed $^{32}$S$/$$^{34}$S gradient is not an artefact but persists irrespective of the choice of the sample and carbon isotope data. A gradient with rising $^{32}$S$/$$^{34}$S values as a function of galactocentric radius implies that the solar system ratio should be larger than that of the local interstellar medium. With the new carbon isotope ratios we obtain indeed a local $^{32}$S$/$$^{34}$S isotope ratio about 10$\%$ below the solar system one, as expected in case of decreasing $^{32}$S$/$$^{34}$S ratios with time and increased amounts of stellar processing. However, taking older carbon isotope ratios based on a lesser amount of data, such a decrease is not seen. No systematic variation of $^{34}$S$/$$^{33}$S ratios along galactocentric distance was found.

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arXiv2020

A systematic observational study on Galactic interstellar ratio 18O/17O: I. C18O and C17O J=1-0 data analysis

The interstellar oxygen isotopic ratio of 18O/17O can reflect the relative amount of the secular enrichment by ejecta from high-mass versus intermediate-mass stars. Previous observations found a Galactic gradient of 18O/17O, i.e., low ratios in the Galactic center and large values in the Galactic disk, which supports the insideout formation scenario of our Galaxy. However, the observed objects are not many and, in particular, not so many at large galactocentric distances. Thus we started a systematic study on Galactic interstellar 18O/17O, through observations of C18O and C17O multi-transition lines toward a large sample of 286 sources (at least one order of magnitude larger than previous ones), from the Galactic center region to the far outer Galaxy (~22 kpc). Here we present our observations of J=1-0 lines of C18O and C17O, with the ARO12m and the IRAM 30m telescope. We detected successfully both C18O and C17O 1-0 lines for 34 sources among our IRAM30m sample of 50 targets and for 166 sources among our ARO12m sample of 260 targets. The C18O optical depth effect on our ratio results, evaluated by fitting results of C17O spectra with hyperfine components and our RADEX non-LTE model calculation for the strongest source, was found to be insignificant. Beam dilution does not seem to be a problem either, which was supported by the fact of no systematic variation between the isotopic ratio and the heliocentric distance, and consistent measured ratios from two telescopes for most of those detected sources. Our results, though there are still very few detections made for sources in the outer Galaxy, confirm the apparent 18O/17O gradient of 18O/17O = (0.10+-0.03)R_GC+(2.95+-0.30), with a Pearson's rank correlation coefficient R = 0.69. This is supported by the newest Galactic chemical evolution model including the impact of massive stellar rotators and novae.

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