arXiv subjects

Y. Xie

Publications and source records attributed to Y. Xie.

28 records · Page 2Linked to original sources

arXiv2014

Phase transitions and thermal-stress-induced structural changes in a ferroelectric Pb(Zr0.80Ti0.20)O3 single crystal

A single crystal of lead-zirconate-titanate (PZT), composition Pb(Zr0.80Ti0.20)O3, was studied by polarized-Raman scattering as a function of temperature. Raman spectra reveal that the local structure deviates from the average structure in both ferroelectric and paraelectric phases. We show that the crystal possesses several, inequivalent complex domain boundaries which show no sign of instability even 200 K above the ferroelectric-to-paraelectric phase transition temperature TC. Two types of boundaries are addressed. The first boundary was formed between ferroelectric domains below TC. This boundary remained stable up to the highest measurement temperatures, and stabilized the domains so that they had the same orientation after repeated heating and cooling cycles. These domains transformed normally to the cubic paraelectric phase. Another type of boundary was formed at 673 K and exhibited no signs of instability up to 923 K. The boundary formation was reversible: it formed and vanished between 573 and 673 K during heating and cooling, respectively. A model in which the crystal is divided into thin slices with different Zr/Ti ratios is proposed. The physical mechanism behind the thermal-stress-induced structural changes is related to the different thermal expansion of the slices, which forces the domain to grow similarly after each heating and cooling cycle. The results are interesting for non-volatile memory development, as it implies that the original ferroelectric state can be restored after the material has been transformed to the paraelectric phase. It also suggests that a low-symmetry structure, stable up to high-temperatures, can be prepared through controlled deposition of layers with desired compositions.

cond-mat.mtrl-sci↗

arXiv2014

The role of random electric fields in relaxors

PbZr_{1-x}Ti_xO_3 (PZT) and Pb(Mg_{1/3}Nb_{2/3})_{1-x}Ti_xO_3 (PMN-$x$PT) are complex lead-oxide perovskites that display exceptional piezoelectric properties for pseudorhombohedral compositions near a tetragonal phase boundary. In PZT these compositions are ferroelectrics, but in PMN-xPT they are relaxors because the dielectric permittivity is frequency dependent and exhibits non-Arrhenius behavior. We show that the nanoscale structure unique to PMN-xPT and other lead-oxide perovskite relaxors is absent in PZT and correlates with a greater than 100% enhancement of the longitudinal piezoelectric coefficient in PMN-xPT relative to that in PZT. By comparing dielectric, structural, lattice dynamical, and piezoelectric measurements on PZT and PMN-xPT, two nearly identical compounds that represent weak and strong random electric field limits, we show that quenched (static) random fields establish the relaxor phase and identify the order parameter.

cond-mat.mtrl-sci↗

arXiv2013

A statistical model approximation for perovskite solid-solutions: a Raman study of lead-zirconate-titanate single crystal

Lead titanate (PbTiO3) is a classical example of a ferroelectric perovskite oxide illustrating a displacive phase transition accompanied by a softening of a symmetry-breaking mode. The underlying assumption justifying the soft-mode theory is that the crystal is macroscopically sufficiently uniform so that a meaningful free energy function can be formed. In contrast to PbTiO3, experimental studies show that the phase transition behaviour of lead-zirconate-titanate solid solution (PZT) is far more subtle. Most of the studies on the PZT system have been dedicated to ceramic or powder samples, in which case an unambiguous soft-mode study is not possible, as modes with different symmetries appear together. Our Raman scattering study on titanium-rich PZT single crystal shows that the phase transitions in PZT cannot be described by a simple soft-mode theory. In strong contrast to PbTiO3, splitting of transverse E-symmetry modes reveals that there are different locally-ordered regions. The role of crystal defects, random distribution of Ti and Zr at the B-cation site and Pb ions shifted away from their ideal positions, dictates the phase transition mechanism. A statistical model explaining the observed peak splitting and phase transformation to a complex state with spatially varying local order in the vicinity of the morphotropic phase boundary is given.

cond-mat.mtrl-sci↗

arXiv2010

Single Crystal Study of Competing Rhombohedral and Monoclinic Order in Lead Zirconate Titanate

Neutron diffraction data obtained on single crystals of PbZr1-xTixO3 with x = 0.325 and x = 0.460, which lie on the pseudorhombohedral side of the morphotropic phase boundary, suggest a coexistence of rhombohedral (R3m/R3c) and monoclinic (Cm) domains and that monoclinic order is enhanced by Ti substitution. A monoclinic phase with a doubled unit cell (Cc) is ruled out as the ground state.

cond-mat.mtrl-sci↗

arXiv2010

Search for neutral Higgs bosons decaying into four taus at LEP2

A search for the production and non-standard decay of a Higgs boson, h, into four taus through intermediate pseudoscalars, a, is conducted on 683 pb-1 of data collected by the ALEPH experiment at centre-of-mass energies from 183 to 209 GeV. No excess of events above background is observed, and exclusion limits are placed on the combined production cross section times branching ratio, ξ^2 = σ(e+e- --> Zh)/σ_{SM}(e+e- --> Zh) x B(h --> aa)x B(a --> τ^+τ^-)^2. For mh < 107 GeV/c2 and 4 < ma < 10 GeV/c2, ξ^2 > 1 is excluded at the 95% confidence level.

hep-ex↗

arXiv2009

Transparent dense sodium

Under pressure, metals exhibit increasingly shorter interatomic distances. Intuitively, this response is expected to be accompanied by an increase in the widths of the valence and conduction bands and hence a more pronounced free-electron-like behaviour. But at the densities that can now be achieved experimentally, compression can be so substantial that core electrons overlap. This effect dramatically alters electronic properties from those typically associated with simple free-electron metals such as lithium and sodium, leading in turn to structurally complex phases and superconductivity with a high critical temperature. But the most intriguing prediction - that the seemingly simple metals Li and Na will transform under pressure into insulating states, owing to pairing of alkali atoms - has yet to be experimentally confirmed. Here we report experimental observations of a pressure-induced transformation of Na into an optically transparent phase at 200 GPa (corresponding to 5.0-fold compression). Experimental and computational data identify the new phase as a wide bandgap dielectric with a six-coordinated, highly distorted double-hexagonal close-packed structure. We attribute the emergence of this dense insulating state not to atom pairing, but to p-d hybridizations of valence electrons and their repulsion by core electrons into the lattice interstices. We expect that such insulating states may also form in other elements and compounds when compression is sufficiently strong that atomic cores start to overlap strongly.

cond-mat.mtrl-sci↗

arXiv2009

Magnetically Torqued Neutrino-Dominated Accretion Flows for Gamma-ray Bursts

Recent observations and theoretical work on gamma-ray bursts (GRBs) favor the central engine model of a Kerr black hole (BH) surrounded by a magnetized neutrino-dominated accretion flow (NDAF). The magnetic coupling between the BH and disk through a large-scale closed magnetic field exerts a torque on the disk, and transports the rotational energy from the BH to the disk. We investigate the properties of the NDAF with this magnetic torque. For a rapid spinning BH, the magnetic torque transfers enormous rotational energy from BH into the inner disk. There are two consequences: (i) the luminosity of neutrino annihilation is greatly augmented; (ii) the disk becomes thermally and viscously unstable in the inner region, and behaves S-Shape of the surface density versus accretion rate. It turns out that magnetically torqued NDAF can be invoked to interpret the variability of gamma-ray luminosity. In addition, we discuss the possibility of restarting the central engine to produce the X-ray flares with required energy.

astro-ph.HE↗

arXiv2009

Surface structure and solidification morphology of aluminum nanoclusters

Classical molecular dynamics simulation with embedded atom method potential had been performed to investigate the surface structure and solidification morphology of aluminum nanoclusters Aln (n = 256, 604, 1220 and 2048). It is found that Al cluster surfaces are comprised of (111) and (001) crystal planes. (110) crystal plane is not found on Al cluster surfaces in our simulation. On the surfaces of smaller Al clusters (n = 256 and 604), (111) crystal planes are dominant. On larger Al clusters (n = 1220 and 2048), (111) planes are still dominant but (001) planes can not be neglected. Atomic density on cluster (111)/(001) surface is smaller/larger than the corresponding value on bulk surface. Computational analysis on total surface area and surface energies indicates that the total surface energy of an ideal Al nanocluster has the minimum value when (001) planes occupy 25% of the total surface area. We predict that a melted Al cluster will be a truncated octahedron after equilibrium solidification.

cond-mat.mtrl-sci↗

arXiv2007

Thermal-Aware Task Allocation and Scheduling for Embedded Systems

Temperature affects not only the reliability but also the performance, power, and cost of the embedded system. This paper proposes a thermal-aware task allocation and scheduling algorithm for embedded systems. The algorithm is used as a sub-routine for hardware/software co-synthesis to reduce the peak temperature and achieve a thermally even distribution while meeting real time constraints. The paper investigates both power-aware and thermal-aware approaches to task allocation and scheduling. The experimental results show that the thermal-aware approach outperforms the power-aware schemes in terms of maximal and average temperature reductions. To the best of our knowledge, this is the first task allocation and scheduling algorithm that takes temperature into consideration.

cs.AR↗

arXiv2006

Surface-wave interferometry on single subwavelength slit-groove structures fabricated on gold films

We apply the technique of far-field interferometry to measure the properties of surface waves generated by two-dimensional (2D) single subwavelength slit-groove structures on gold films. The effective surface index of refraction measured for the surface wave propagating over a distance of more than 12 microns is determined to be 1.016 with a measurement uncertainty of 0.004, to within experimental uncertainty of the expected bound surface plasmon-polariton (SPP) value for a Au/Air interface of 1.018. We compare these measurements to finite-difference-time-domain (FDTD) numerical simulations of the optical field transmission through these devices. We find excellent agreement between the measurements and the simulations for the surface index of refraction. The measurements also show that the surface wave propagation parameter exhibits transient behavior close to the slit, evolving smoothly from greater values asymptotically toward the value expected for the SPP over the first 2-3 microns of slit-groove distance. This behavior is confirmed by the FDTD simulations.

physics.optics↗