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Yao-Lun Yang

Publications and source records attributed to Yao-Lun Yang.

At least 37 records · Page 2Linked to original sources

EPISODE III: The Nested Jet/Outflow Morphology of EC 53 Revealed by JWST and ALMA

We present an extensive study of the structure and kinematics of the jet and outflow of EC 53, a Class I protostar with a quasi-periodic variability, using combined James Webb Space Telescope (JWST) and Atacama Large Millimeter/submillimeter Array (ALMA) observations. ALMA continuum observations resolve a compact disk with a radius of $\sim$0.14\arcsec\ (60\,au). Scattered light from the outflow cavity is prominent in the short-wavelength NIRCam and NIRSpec observations, revealing only the southeast nearside lobe. We detected 27 H$_2$ emission lines tracing a narrow, cone-shaped structure within the outflow cavity. A high-velocity ionized jet is detected in several forbidden atomic lines, characterized by a position angle of 142\degree, an opening angle of 1.4\degree, and an estimated geometric launching radius of at most $\sim$40\,au. Mid-infrared CO ro-vibrational emission lines, stronger in the P-branch, show a similar distribution to the H$_2$ emission and are likely to originate from hot gas within the outflow cavity. CO and C$_2$H emission lines detected by ALMA trace slower, colder outflow components and cavity walls. The spatial and kinematic stratification between the hot atomic and molecular components and the colder molecular gas is consistent with predictions from MHD disk wind models, although envelope material entrained by a wide-angle wind or jet may also contribute. Our analysis highlights the powerful synergy between JWST and ALMA in advancing the understanding of protostellar jets and outflows across multiple spatial and physical scales.

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The Structure and Kinematics of Three Class 0 Protostellar Jets from JWST

We present observations of jets within 2000 au of three deeply embedded protostars using 2.9-27 micron observations with JWST. These observations show the morphologies and kinematics of the collimated jets from three protostars, the low-mass Class 0 protostars B335 and HOPS 153, and the intermediate-mass protostar HOPS 370. These jets are traced by shock-ionized fine-structure line emission observed with the JWST NIRSpec and MIRI IFUs. We find that [Fe II] emission traces the full extent of the inner 1000 to 2000 au of the jets, depending on distance to the protostar, while other ions mostly trace isolated shocked knots. The jets show evidence of wiggling motion in the plane of the sky as well as asymmetries between blue and red-shifted lobes. The widths of the jets increase non-monotonically with distance from the central protostar, with opening angles ranging from 2.1 degrees to < 10.1 degrees for the three protostars in the sample. The jets have total velocities ranging from 147 to 184 km/s after correcting for disk inclination. For B335, an 8-month gap between NIRSpec and MIRI MRS observations enabled measurement of the tangential velocity of a shocked knot; in combination with the radial velocity, this shows that the jet has a different inclination than the outflow cavity. We find multiple knots before and during a recent outburst in B335, although the knots were more frequent during the burst. The asymmetries between blue- and red-shifted lobes strongly suggest complex interactions between the circumstellar disks and magnetic fields.

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CORINOS IV: Quantifying Baseline-Fitting Uncertainties in SO$_2$ Ice Measurements with JWST/MIRI

Sulfur dioxide (SO$_2$) ice has been tentatively detected in protostellar envelopes, but its reliability as a solid-state sulfur reservoir remains unclear. We present new measurements of SO$_2$ ice from 6.8-8.5 $μ$m toward four Class 0 protostars observed with JWST's Mid-Infrared (MIRI) Medium Resolution Spectrometer, as part of the COMs ORigin Investigated by the Next-generation Observatory in Space (CORINOS) program. The sample spans a luminosity range from 1 $L_\odot$ (B335, IRAS 15398-3359) to 10 $L_\odot$ (L483, Ser-emb~7). To assess continuum placement uncertainty in absorption spectra, we apply randomized polynomial fits over the restricted region. We fit laboratory spectra from the Leiden Ice Database for Astrochemistry (LIDA) using the open-source Python library Omnifit. We detect the 7.7 $μ$m CH$_4$ band in all sources and find its column density robust to baseline choice, providing a reference for evaluating the weaker SO$_2$ feature on its blue shoulder and quantifying baseline-related uncertainty. Three SO$_2$ laboratory ices were tested: pure SO$_2$ ice yields 0.3-1.2% of volatile sulfur may be locked in SO$_2$ ice (lower and upper limits); CH$_3$OH:SO$_2$ ice gives 0.02-0.18%, but with lower quality fitting. The best-fitting H$_2$O:SO$_2$ ice yields 0.2-0.9%, which we consider the most realistic. These ranges define plausible bounds on SO$_2$ ice abundances in our sample. We find evidence for SO$_2$ in Ser-emb 7, L483, and IRAS 15398-3359, but emphasize the noisy spectrum of B335 prevents a definitive detection. Comparing SO$_2$ ice abundances across the different environments, we assess how conditions influence role of SO$_2$ as a potential sulfur reservoir and implications for the longstanding ``missing sulfur'' problem.

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IPA. Accretion rate of a low-mass Class 0 protostar, measured via mid-infrared fluorescent OH emission

The earliest stages of star formation are highlighted by complex interactions between accretion, outflow, and radiative processes, which shape the chemical and physical environment of the emerging protostar. James Webb Space Telescope observations of the low-mass, low-luminosity Class 0 protostar IRAS 16253-2429 reveal a central compact source. This object exhibits a rich mid-infrared emission spectrum of OH pure rotational lines and $\rm CO_2$ ro-vibrational lines. Unusually for a young stellar object, it has no mid-infrared line emission from $\rm H_2O$ to match the other molecules. We demonstrate that the emitting OH molecules arise from UV photodissociation of $\rm H_2O$ in its second absorption band at $λ= 114-145$ nm, and that the OH emission is a fluorescent cascade starting with highest-excitation rotational states. This situation offers the opportunity of using the infrared OH spectrum to measure the UV flux from the central protostar. Thereby we determine the disk-star accretion rate to be $3 \times 10^{-10} \ M_\sun \ {\rm year^{-1}}$, and demonstrate that the system luminosity arises mostly from the protostar's photosphere rather than from accretion luminosity. The result is in accord with the measured outflow rate of IRAS 16253-2429 and lies within the outflow/accretion-flow rate trend often inferred for protostars; and with episodic accretion as the dominant mechanism by which this protostar has grown.

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The Flying Saucer edge-on disc's Near Infrared silhouette revealed by the JWST JEDIce program

Edge-on discs offer a unique opportunity to probe radial and vertical dust and gas distributions in the protoplanetary phase. This study aims to investigate the distribution of micron-sized dust particles in the Flying Saucer (BKLT J162813-243139) in Rho Ophiuchi, leveraging the unique observational conditions of a bright infrared background that enables the edge-on disc to be seen in both silhouette and scattered light at certain, specific wavelengths. As part of the JWST Edge-on Disc Ice program ('JEDIce'), we use NIRSpec IFU observations of the Flying Saucer, serendipitously observed against a PAH-emitting background, to constrain the dust distribution and grain sizes through radiative transfer modelling. Observation of the Flying Saucer in silhouette at 3.29 microns reveals that the midplane radial extent of small dust grains is ~235 au, larger than the large-grain disc extent previously determined to be 190 au from millimetre data. The scattered light observed in emission probes micron sized icy grains at large vertical distances above the midplane. The vertical extent of the disc silhouette is similar at visible, near-IR, and mid-IR wavelengths, corroborating the conclusion that dust settling is inefficient for grains as large as tens of microns, vertically and radially.

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Early Planet Formation in Embedded Disks (eDisk). XX. Constraining the Chemical Tracers of Young Protostellar Sources

Recent studies indicate that the formation of planets in protoplanetary disks begins early in the embedded Class 0/I phases of protostellar evolution. The physical and chemical makeup of the embedded phase can provide valuable insights into the process of star and planet formation. This study aims to provide a thorough overview of the various morphologies for molecular emissions observed on disk scales toward nearby embedded sources. We present high angular resolution (0.1", 15 au) molecular line emissions for $^{12}$CO, $^{13}$CO, C$^{18}$O, SO, SiO, DCN, CH$_3$OH, H$_2$CO, and c-C$_3$H$_2$ towards 19 nearby protostellar sources in the context of the Atacama Large Millimeter/submillimeter Array (ALMA) Large Program "Early Planet Formation in Embedded Disks (eDisk)". Emissions in $^{12}$CO are seen towards all sources and primarily trace outflowing materials. A few sources also show high-velocity jets in SiO emission and high-velocity channel maps of $^{12}$CO. The $^{13}$CO and C$^{18}$O emissions are well-known tracers of high-density regions and trace the inner envelope and disk regions with clear signs of rotation seen at continuum scales. The large-scale emissions of $^{13}$CO also delineate the outflow cavity walls where the outflowing and infalling materials interact with each other, and exposure to UV radiation leads to the formation of hydrocarbons such as c-C$_3$H$_2$. Both DCN and CH$_3$OH, when detected, show compact emissions from the inner envelope and disk regions that peak at the position of the protostar. The CH$_3$OH emissions are contained within the region of DCN emissions, which suggests that CH$_3$OH traces the hot core regions. Likewise, a few sources also display emissions in CH$_3$OH towards the outflow. Both SO and H$_2$CO show complex morphology among the sources, suggesting that they are formed through multiple processes in protostellar systems.

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Measuring metal sulfides in interstellar dust with PRIMA

Sulfur is known to undergo severe depletion when moving from diffuse clouds to the denser regimes of the interstellar medium in molecular clouds. The form in which sulfur gets depleted onto dust grains, however, remains a mystery. One possibility is that sulfur gets locked in interstellar dust in the form of sulfide minerals. Recently, metal sulfides such as NaS and MgS have been detected in a shocked molecular cloud in the Galactic Center, suggesting that these molecules could represent an important reservoir of sulfur in dust grains. In this contribution, we discuss the prospect of observing metal sulfides such as MgS and FeS in absorption experiments carried out with the FIRESS instrument onboard PRIMA using its low resolution observing mode. Our estimates show that the molecular bands of MgS and FeS found between 20 and 50 $μ$m could be detected in absorption with S/N ${\geq}$ 5 for sources brighter than 200 mJy in just 1 h of observing time against low-mass protostellar objects. This science case, therefore, has the potential to unveil the main reservoir of sulfur in interstellar dust, constraining in what form sulfur is incorporated into minor bodies of our solar system.

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PEACHES IV: Tracing the Formation & Evolution of C$_2$H in Perseus Low-Mass Protostars

The radical hydrocarbon molecule C$_2$H is widely detected in various stages of star and planet formation, and has emerged as a useful tracer of high-C/O gas within the photochemically active surface layers of mature (Class II) protoplanetary disks. However, the chemistry and evolution of C$_2$H within younger (Class 0/I) protostars remains much more poorly understood. Here, using data observed as part of the PEACHES survey along with new ALMA ACA observations, we investigate the C$_2$H emission towards an unbiased sample of 35 Class 0/I low-mass protostars in Perseus. With this large sample, we identify a clear association between C$_2$H emission and the protostellar outflow cavity walls, and a consistent spatial anti-correlation between C$_2$H and SO emission. Together, these trends confirm that C$_2$H is tracing photochemically active, O-poor gas in these younger sources. We fitted the C$_2$H spectra with a simple LTE model to yield column density maps, and find values ranging from 10$^{14}$ -- 10$^{15}$ cm$^{-2}$ in these sources. We also looked for trends in the C$_2$H emission morphology as a function of various protostellar evolutionary metrics, but find no clear patterns: the C$_2$H emission remains spatially extended in most sources, independent of age. This indicates that the transition to the compact C$_2$H emission observed on the surface of Class II disks must happen rapidly, sometime just after the embedded stage.

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ALMASOP. A Rotating Feature Rich in Complex Organic Molecules in a Protostellar Core

Interstellar complex organic molecules (COMs) in solar-like young stellar objects (YSOs), particularly within protostellar disks, are of significant interest due to their potential connection to prebiotic chemistry in emerging planetary systems. We report the discovery of a rotating feature enriched in COMs, including CH3OH, CH3CHO, and NH2CHO, in the protostellar core G192.12-11.10. By constructing a YSO model, we find that the COM-rich feature is likely located within or near the boundary of the Keplerian disk. The image synthesis results suggest that additional heating mechanisms leading to a warm ring or a warm inner disk are required to reproduce the observed emission. We discuss possible origins of the COM-rich feature, particularly accretion shocks as a plausible cause for a warm ring. Additionally, molecules such as C18O, H2CO, DCS, H2S, and OCS exhibit distinct behavior compared to CH3OH, indicating a range of physical and chemical conditions within the region. The observed kinematics of H2S and OCS suggest that OCS resides in regions closer to the central protostar than H2S, consistent with previous experimental studies.

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Determining the methanol deuteration in the disk around V883 Orionis with laboratory measured spectroscopy

Deuterium fractionation, as studied through mono-deuterated methanol, is frequently used as a diagnostic tool to trace the physical conditions and chemical evolution of interstellar sources. This study investigates methanol deuteration in the disk around V883 Ori, utilising recent laboratory spectroscopic data for CH$_2$DOH and CH$_3$OD along with ALMA observations. The derived column densities for CH$_2$DOH and CH$_3$OD are (5.14$\pm$0.08) $\times $10$^{16}$ cm$^{-2}$ and (4.22$\pm$0.06) $\times$ 10$^{16}$ cm$^{-2}$, respectively. The analysis demonstrates the influence of spectroscopic data on determining molecular column density, excitation temperature, and, most importantly, the inferred D/H ratio. The D/H ratio for CH$_2$DOH is calculated to be (7.3$\pm$1.5) $\times$ 10$^{-3}$ after applying a statistical correction, whilst the D/H ratio for CH$_3$OD is (1.79$\pm$0.36) $\times$ 10$^{-2}$. The discovery of an unexpectedly low CH$_2$DOH/CH$_3$OD ratio (1.22$\pm$0.02) in V883 Ori, however, raises further questions about the synthesis and chemical processes involved in CH$_3$OD formation. Overall, this study underscores the importance of accurate spectroscopic data for studies of isotopic fractionation and provides new insights into methanol deuteration chemistry in star-forming regions. Future research, combining updated spectroscopy and chemical modelling, will help further constrain these processes across different masses and evolutionary stages.

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Origin of the Shell Structure in the Primary Outflow from IRAS 15398-3359

IRAS 15398-3359, a Class 0 protostar in Lupus I star forming region, is associated with three generations of outflows. The primary outflow, i.e., the most recent one, shows internal structure named ``shell structure'' in the near infrared emission map. The shell structure is also seen in the emission lines of CO, H$_2$CO, and others species. We find a similar structure in an underexpanded jet produced in aerodynamics and other engineering applications. A high pressure gas ejected through a nozzle expands to form a supersonic flow. When the pressure of the ejected gas becomes lower than that of the ambient gas, the jet is compressed to form a shock wave. The shock heated gas expands again to form substructures along the jet. We examine the similarity between the primary outflow of IRAS 15398-3359 and industrial underexpanded jet and the possibility that the shell structure of the former is due to repeated expansion and compression in the direction perpendicular to the jet propagation.

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Near- to mid-infrared spectroscopic study of ice analysis using the AKARI/IRC and Spitzer/IRS spectra

We present the combined 2.5$-$30$μ$m spectra of four protostars acquired with the infrared camera and the infrared spectrograph on board the AKARI and Spitzer space telescopes, respectively. To analyze the ice absorption features in the 8$-$22$μ$m, we first performed a continuum determination process on mid-infrared spectra and applied a method to subtract the silicate absorption. We conducted a global fitting process to the absorption features in the combined infrared spectra using the experimental ice absorbance data to identify the intrinsic absorption of each ice component. We first derived the H$_{2}$O ice column densities of both stretch and libration modes at 3.05$μ$m and 13.6$μ$m simultaneously. We also identified the absorption features containing NH$_{3}$, CH$_{3}$OH, CO$_{2}$, and CO and decomposed their mixed components and compared their ice abundances at different evolutionary stages of the protostars. We explored possible absorptions of the organic ice species such as HCOOH, CH$_{3}$CHO, and CH$_{3}$CH$_{2}$OH in the mid-infrared ranges. The ice analysis method developed in this study can be applied to the ice spectra obtained by the James Webb Space Telescope.

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The SOFIA Massive (SOMA) Star Formation Survey. V. Clustered Protostars

We present $\sim8-40\,μ$m SOFIA-FORCAST images of seven regions of ``clustered" star formation as part of the SOFIA Massive (SOMA) Star Formation Survey. We identify a total of 34 protostar candidates and build their spectral energy distributions (SEDs). We fit these SEDs with a grid of radiative transfer models based on the Turbulent Core Accretion (TCA) theory to derive key protostellar properties, including initial core mass, $M_c$, clump environment mass surface density, $Σ_{\rm cl}$, and current protostellar mass, $m_*$. We also carry out empirical graybody (GB) estimation of $Σ_{\rm cl}$, which allows a case of restricted SED fitting within the TCA model grid. We also release version 2.0 of the open-source Python package \emph{sedcreator}, designed to automate the aperture photometry and SED building and fitting process for sources in clustered environments, where flux contamination from close neighbors typically complicates the process. Using these updated methods, SED fitting yields values of $M_c\sim30-200\:M_{\odot}$, $Σ_{\text{cl,SED}}\sim0.1-3\:{\rm{g\:cm}}^{-2}$, and $m_*\sim4-50\:M_{\odot}$. The graybody fitting yields smaller values of $Σ_{\text{cl,GB}}\lesssim1\:{\rm{g\:cm}}^{-2}$. From these results, we do not find evidence for a critical $Σ_{\rm{cl}}$ needed to form massive ($\gtrsim 8\:M_\odot$) stars. However, we do find tentative evidence for a dearth of the most massive ($m_*\gtrsim30\:M_\odot$) protostars in the clustered regions suggesting a potential impact of environment on the stellar initial mass function.

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CORINOS. III. Outflow Shocked Regions of the Low-mass Protostellar Source IRAS 15398-3359 with JWST and ALMA

While molecular outflows have been studied in details with radio interferometry, observations of the hotter gas in protostellar outflows at a comparable physical scale is often challenging. Combined with ALMA, JWST allows us to investigate the cold and hot gas with unprecedented spatial resolution and sensitivity. We present a detailed comparison between the gas distributions probed with ALMA and JWST in the primary outflow of IRAS 15398$-$3359. At 2000 au scale, the southwestern outflow shows four shell structures in 5--10 micron continuum, whereas the submillimeter H$_2$CO emission traces two of the four shells closest to the protostar. Submillimeter emission from CS, CCH, c-C$_3$H$_2$, and CH$_3$OH shows the same two shells, and the $^{12}$CO emission covers most of the outflow region. SO and SiO only trace a condensation at the edge of the shell closest to the protostar. None of these lines observed with ALMA show the outermost shell. At 500 au scale, we find hot H$_2$ gas inside the outflow cavity with JWST. The derived temperature of H$_2$ is 1147$\pm$198 K within a 0\farcs5 aperture at the protostar. The foreground mass column density of dust is (1.4--2.0)$\times$10$^{-3}$ g$\cdot$cm$^{-2}$ (A$_{\rm v}$ = 47--66 mag) in the outflow, using the dust model from Weingartner & Draine (2001). We also find an 8$^{\circ}$ difference between the directions toward the [Fe II] knot and the outermost shell in the MIRI image, which may be interpreted as the precession of the [Fe II] jet. The dynamical timescale of the [Fe II] knot is 10 yrs, suggesting a current event.

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The SOFIA Massive (SOMA) Star Formation Q-band follow-up I. Carbon-chain chemistry of intermediate-mass protostars

Evidence for similar chemical characteristics around low- and high-mass protostars has been found: in particular, a variety of carbon-chain species and complex organic molecules (COMs) are formed around them. On the other hand, the chemical compositions around intermediate-mass (IM; $2 M_{\odot} < m_* <8 M_{\odot}$) protostars have not been studied with large samples. In particular, it is unclear the extent to which carbon-chain species are formed around them. We aim to obtain the chemical compositions, particularly focusing on carbon-chain species, towards a sample of IM protostars. We have conducted Q-band (31.5-50 GHz) line survey observations towards eleven mainly intermediate-mass protostars with the Yebes 40 m radio telescope. The target protostars were selected from a sub-sample of the source list of the SOFIA Massive (SOMA) Star Formation project. Nine carbon-chain species (HC$_3$N, HC$_5$N, C$_3$H, C$_4$H, $linear-$H$_2$CCC, $cyclic-$C$_3$H$_2$, CCS, C$_3$S, and CH$_3$CCH), three COMs (CH$_3$OH, CH$_3$CHO, and CH$_3$CN), H$_2$CCO, HNCO, and four simple sulfur (S)-bearing species ($^{13}$CS, C$^{34}$S, HCS$^+$, H$_2$CS) have been detected. The rotational temperatures of HC$_5$N are derived to be $\sim20-30$ K in three IM protostars and they are very similar compared to those around low- and high-mass protostars. These results indicate that carbon-chain molecules are formed in lukewarm ($\sim20-30$ K) gas around the IM protostars by the Warm Carbon-Chain Chemistry (WCCC) process. Carbon-chain formation occurs ubiquitously in the warm gas around protostars across a wide range of stellar masses. Carbon-chain molecules and COMs coexist around most of the target IM protostars, which is similar to the situation in low- and high-mass protostars. The chemical characteristics around protostars are common in the low-, intermediate- and high-mass regimes.

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The JWST-NIRCam View of Sagittarius C. I. Massive Star Formation and Protostellar Outflows

We present James Webb Space Telescope (JWST)-NIRCam observations of the massive star-forming molecular cloud Sagittarius C (Sgr C) in the Central Molecular Zone (CMZ). In conjunction with ancillary mid-IR and far-IR data, we characterize the two most massive protostars in Sgr C via spectral energy distribution (SED) fitting, estimating that they each have current masses of $m_* \sim 20\:M_\odot$ and surrounding envelope masses of $\sim 100\:M_\odot$. We report a census of lower-mass protostars in Sgr C via a search for infrared counterparts to mm continuum dust cores found with ALMA. We identify 88 molecular hydrogen outflow knot candidates originating from outflows from protostars in Sgr C, the first such unambiguous detections in the infrared in the CMZ. About a quarter of these are associated with flows from the two massive protostars in Sgr C; these extend for over 1 pc and are associated with outflows detected in ALMA SiO line data. An additional $\sim 40$ features likely trace shocks in outflows powered by lower-mass protostars throughout the cloud. We report the discovery of a new star-forming region hosting two prominent bow shocks and several other line-emitting features driven by at least two protostars. We infer that one of these is forming a high-mass star given an SED-derived mass of $m_* \sim 9\:M_\odot$ and associated massive ($\sim 90\:M_\odot$) mm core and water maser. Finally, we identify a population of miscellaneous Molecular Hydrogen Objects (MHOs) that do not appear to be associated with protostellar outflows.

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JWST-IPA: Chemical Inventory and Spatial Mapping of Ices in the Protostar HOPS370 -- Evidence for an Opacity Hole and Thermal Processing of Ices

The composition of protoplanetary disks, and hence the initial conditions of planet formation, may be strongly influenced by the infall and thermal processing of material during the protostellar phase. Composition of dust and ice in protostellar envelopes, shaped by energetic processes driven by the protostar, serves as the fundamental building material for planets and complex organic molecules. As part of the JWST GO program, "Investigating Protostellar Accretion" (IPA), we observed an intermediate-mass protostar HOPS 370 (OMC2-FIR3) using NIRSpec/IFU and MIRI/MRS. This study presents the gas and ice phase chemical inventory revealed with the JWST in the spectral range of $\sim$2.9 to 28 $μ$m and explores the spatial variation of volatile ice species in the protostellar envelope. We find evidence for thermal processing of ice species throughout the inner envelope. We present the first high-spatial resolution ($\sim 80$ au) maps of key volatile ice species H$_{2}$O, CO$_{2}$, $^{13}$CO$_2$, CO, and OCN$^-$, which reveal a highly structured and inhomogeneous density distribution of the protostellar envelope, with a deficiency of ice column density that coincides with the jet/outflow shocked knots. Further, we observe high relative crystallinity of H$_{2}$O ice around the shocked knot seen in the H$_2$ and OH wind/outflow, which can be explained by a lack of outer colder material in the envelope along the line of sight due to the irregular structure of the envelope. These observations show clear evidence of thermal processing of the ices in the inner envelope, close to the outflow cavity walls, heated by the luminous protostar.

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A Natural Laboratory for Astrochemistry, a Variable Protostar B335

Emission lines from complex organic molecules in B335 were observed in four epochs, spanning a luminosity burst of about 10 years duration. The emission lines increased dramatically in intensity as the luminosity increased, but they have decreased only slightly as the luminosity has decreased. This behavior agrees with expectations of rapid sublimation as the dust temperature increases, but slower freeze-out after the dust temperature drops. Further monitoring of this source, along with detailed chemical models, will exploit this natural laboratory for astrochemistry.

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