arXiv subjects

Yevgeny Raitses

Publications and source records attributed to Yevgeny Raitses.

29 records · Page 2Linked to original sources

arXiv2020

Characterization of plasma and gas-phase chemistry during boron-nitride nanomaterial synthesis by laser-ablation of boron-rich targets

In this work, solid targets made from boron and boron nitride (BN) materials are ablated by a nanosecond pulsed laser at sub-atmospheric pressures of nitrogen and helium gases. Excited species in the ablation plume from the target are probed with spatiotemporally resolved optical emission spectroscopy (OES). Evaluation of chemical composition in the plasma plume revealed that for both boron-rich targets, emission from BN molecules is always observed in nitrogen-rich environments. In addition, BN molecules also present when ablating a boron nitride target in helium gas -- an indication that BN molecules in the plume may originate from the solid target. Furthermore, the ablation of BN target features emission of B2N molecules, regardless of the pressure and surrounding gas. These results suggest that the ablation of the BN target is more favorable for the generation of complex molecules containing boron and nitrogen species and possibly hint that BN is also more favorable feedstock for high-yield BN nanomaterial synthesis. Plasma parameters such as electron temperature (peak value of 1.3 eV) and density (peak value of 2x10^18 cm^-3) were also investigated in this work in order to discuss the chemical dynamics in the plume.

physics.plasm-ph↗

arXiv2020

Performance of Oscillating Plasma Thrusters

Traditional expressions and definitions describing performance of plasma thrusters, including the thrust, specific impulse, and the thruster efficiency, assume a steady state plasma flow with a constant flow velocity. However, it is very common for these thrusters that the plasma exhibits unstable behavior resulting in time-variations of the thrust and the exhaust velocity. For example, in Hall thrusters, the ionization instability leads to strong oscillations of the discharge current (so-called breathing oscillations), plasma density, ion energy, and as a result the ion flow. In this paper, we revisit the formulation of the thrust and the thrust efficiency to account for time variations of the ion parameters including the phase shift between the ion energy and the ion flow. For sinusoidal oscillations it was found thrust can potentially change more than 20%. It is shown that by modulating ion energy at specific amplitudes, thrust can be maximized in such regimes. Finally, an expression for the thruster efficiency of the modulating thruster is derived to show a mechanism for inefficiencies in such thrusters.

physics.plasm-ph↗

arXiv2019

Determining Gas Composition for Growth of BNNTs Using Thermodynamic Approach

A high-yield production of high-quality boron-nitride nanotubes (BNNTs) was reported recently in several publications. A boron-rich material is evaporated by a laser or plasma in a nitrogen-rich atmosphere to supply precursor gaseous species for nucleation and growth of BNNTs. Either hydrogen was added or pressure was increased in the system to achieve high yield and high purity of the synthesized nanotubes. According to the widely-accepted "root grow" mechanism, upon the gas cooling, boron droplets form first, then they adsorb nitrogen from surrounding gas species, and BNNTs grow on their surfaces. However, what are these precursor species that provide nitrogen for the growth is still an open question. To answer this question, we performed thermodynamic calculations of B-N mixture composition considering broad set of gas species. In enhancement of previous studies, the condensation of boron is now taken into account and is shown to have drastic effect on the gas chemical composition. B2N molecules were identified to be a major source of nitrogen for growth of BNNTs. Presence of B2N molecules in a B-N gas mixture was verified by our spectroscopic measurements during a laser ablation of boron-rich targets in nitrogen. It was shown that the increase of pressure has a quantitative effect on the mixture composition yielding increase of the precursor density. The hydrogen addition might open an additional channel of nitrogen supply to support growth of BNNTs. Nitrogen atoms react with abundant H2 molecules to form NH2 and then NH3 precursor species, instead of just recombining back to inert N2 molecules, as in the no-hydrogen case. In addition, thermodynamics was applied in conjunction with agglomeration theory to predict the size of boron droplets upon growth of BNNTs. Analytical relations for identification of crucial species densities were derived.

physics.chem-ph↗

arXiv2019

Boundary-induced effect on the spoke-like activity in ExB plasma

The spoke instability in an $E\times B$ Penning discharge is shown to be strongly affected by the boundary that is perpendicular to $B$ field lines. The instability is the strongest when bounded by dielectric walls. With a conducting wall, biased to collect electron current from the plasma, the spoke becomes faster, less coherent and localised closer to the axis. The corresponding anomalous cross-field transport is assessed via simultaneous time-resolved measurements of plasma potential and density. This shows a dominant large-scale $E\times B$ anomalous character of the electron cross-field current for dielectric walls reaching $40-100$% of the discharge current, with an effective Hall parameter $β_\mathrm{eff}\sim10$. The anomalous current is greatly reduced with the conducting boundary (characterised by $β_\mathrm{eff}\sim10^2$). These experimental measurements are shown to be qualitatively consistent with the decrease of the $E$ field that triggers the collisionless Simon-Hoh instability.

physics.plasm-ph↗

arXiv2019

Validated Modeling of Atmospheric-Pressure Anodic Arc

We performed self-consistent modeling of the atmospheric-pressure plasmas produced by arc discharges. Special numerical procedure for coupling of the plasma current, emission current, ion current, sheath voltage drop, heat fluxes at plasma-electrode interfaces was developed and implemented into the ANSYS CFX code. Validation of the simulation results is performed through comparison of simulation results with the previously available experimental data obtained by a range of various plasma diagnostics.

physics.plasm-ph↗

arXiv2018

Root-Growth of Boron Nitride Nanotubes: Experiments and \textit{Ab Initio} Simulations

We have synthesized boron nitride nanotubes (BNNTs) in an arc in presence of boron and nitrogen species only, without transition metals. We find that BNNTs are often attached to pure boron nanoparticles, suggesting that root-growth is a likely mechanism for their formation. To gain further insight into this process we have studied key mechanisms for root growth of BNNTs on the surface of a liquid boron droplet by ab initio molecular dynamics simulations. We find that nitrogen atoms reside predominantly on the droplet surface where they organize to form boron nitride islands below 2400 K. To minimize contact with the liquid particle underneath, the islands assume non-planar configurations that are likely precursors for the thermal nucleation of cap structures. Once formed, the caps are stable and can easily incorporate nitrogen and boron atoms at their base, resulting in further growth. Our simulations support the root-growth mechanism of BNNTs and provide comprehensive evidence of the active role played by liquid boron.

physics.chem-ph↗

arXiv2018

Controlling azimuthal spoke modes in cylindrical Hall thruster using a segmented anode

Azimuthal spoke-like modes commonly occur in ExB discharges. The natural occurrence of the spoke mode is correlated with changes of plasma parameters. Here, instead of allowing these changes to occur naturally, we report a technique for actively controlling the spoke by adjusting the boundary condition at the anode. The technique is demonstrated using a cylindrical Hall thruster equipped with a segmented anode. By varying the voltage and the relative phases of the anode segments, properties of the azimuthal mode can be altered substantially, as shown by fast camera images and probe diagnostics. This technique may be extended to other Hall discharges in order to either induce or suppress azimuthal activities, and thereby controlling the operation and the performance of the devices.

physics.plasm-ph↗

arXiv2018

Scaling of Spoke Rotation Frequency within a Penning Discharge

A rotating plasma spoke is shown to develop in two-dimensional full-sized kinetic simulations of a Penning discharge cross-section. Electron cross-field transport within the discharge is highly anomalous and correlates strongly with the spoke phase. Similarity between collisional and collisionless simulations demonstrates that ionization is not necessary for spoke formation. Parameter scans with discharge current $I_d$, applied magnetic field strength $B$ and ion mass $m_i$ show that spoke frequency scales with $\sqrt{e E_r L_n / m_i}$, where $E_r$ is the radial electric field, $L_n$ is the gradient length scale and $e$ is the fundamental charge. This scaling suggests that the spoke may develop as a non-linear phase of the collisionless Simon-Hoh instability.

physics.plasm-ph↗

arXiv2018

Synthesis of nanoparticles in carbon arc: measurements and modeling

This work studies the region of nanoparticle growth in atmospheric pressure carbon arc. Detection of the nanoparticles is realized via the planar laser induced incandescence (PLII) approach. Measurements revealed large clouds of nanoparticles in the arc periphery, bordering the region with high density of diatomic carbon molecules. Two-dimensional computational fluid dynamic simulations of the arc combined with thermodynamic modeling explain these results due to interplay of the condensation of carbon molecular species and the convection flow pattern. The results have shown that the nanoparticles are formed in the colder, outside regions of the arc and described the parameters necessary for coagulation.

physics.plasm-ph↗

arXiv2018

Floating potential of emitting surfaces in plasmas with respect to the space potential

The potential difference between a floating emitting surface and the plasma surrounding it has been described by several sheath models, including the space-charge-limited sheath, the electron sheath with high emission current, and the inverse sheath produced by charge-exchange ion trapping. Our measurements reveal that each of these models has its own regime of validity. We determine the potential of an emissive filament relative to the plasma potential, emphasizing variations in emitted current density and neutral particle density. The potential of a filament in a diffuse plasma is first shown to vanish, consistent with the electron sheath model and increasing electron emission. In a denser plasma with ample neutral pressure, the floating filament potential is positive, as predicted by a derived ion trapping condition. Lastly, the filament floated negatively in a third plasma, where flowing ions and electrons and nonnegligible electric fields may have disrupted ion trapping. Depending on the regime chosen, emitting surfaces can float positively or negatively with respect to the plasma potential.

physics.plasm-ph↗

arXiv2018

Particle-in-cell simulations of anomalous transport in a Penning discharge

Electrostatic particle-in-cell simulations of a Penning discharge are performed in order to investigate azimuthally asymmetric, spoke-like structures previously observed in experiments. Two-dimensional simulations show that for Penning-discharge conditions, a persistent nonlinear spoke-like structure forms readily and rotates in the direction of ExB and electron diamagnetic drifts. The azimuthal velocity is within about a factor of two of the ion acoustic speed. The spoke frequency follows the experimentally observed scaling with ion mass, which indicates the importance of ion inertia in spoke formation. The spoke provides enhanced (anomalous) radial electron transport, and the effective cross-field conductivity is several times larger than the classical (collisional) value. The level of anomalous current obtained in the simulations is in good agreement with the experimental data. The rotating spoke channels most of the radial current, observable by an edge probe as short pulses.

physics.plasm-ph↗