arXiv subjects

Yixiao Wang

Publications and source records attributed to Yixiao Wang.

56 records · Page 4Linked to original sources

arXiv2021

A Priori Calibration of Transient Kinetics Data via Machine Learning

The temporal analysis of products reactor provides a vast amount of transient kinetic information that may be used to describe a variety of chemical features including the residence time distribution, kinetic coefficients, number of active sites, and the reaction mechanism. However, as with any measurement device, the TAP reactor signal is convoluted with noise. To reduce the uncertainty of the kinetic measurement and any derived parameters or mechanisms, proper preprocessing must be performed prior to any advanced analysis. This preprocessing consists of baseline correction, i.e., a shift in the voltage response, and calibration, i.e., a scaling of the flux response based on prior experiments. The current methodology of preprocessing requires significant user discretion and reliance on previous experiments that may drift over time. Herein we use machine learning techniques combined with physical constraints to convert the raw instrument signal to chemical information. As such, the proposed methodology demonstrates clear benefits over the traditional preprocessing in the calibration of the inert and feed mixture products without need of prior calibration experiments or heuristic input from the user.

cs.LG↗

arXiv2021

Deriving Word Vectors from Contextualized Language Models using Topic-Aware Mention Selection

One of the long-standing challenges in lexical semantics consists in learning representations of words which reflect their semantic properties. The remarkable success of word embeddings for this purpose suggests that high-quality representations can be obtained by summarizing the sentence contexts of word mentions. In this paper, we propose a method for learning word representations that follows this basic strategy, but differs from standard word embeddings in two important ways. First, we take advantage of contextualized language models (CLMs) rather than bags of word vectors to encode contexts. Second, rather than learning a word vector directly, we use a topic model to partition the contexts in which words appear, and then learn different topic-specific vectors for each word. Finally, we use a task-specific supervision signal to make a soft selection of the resulting vectors. We show that this simple strategy leads to high-quality word vectors, which are more predictive of semantic properties than word embeddings and existing CLM-based strategies.

cs.CL↗