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Yongle Li

Publications and source records attributed to Yongle Li.

10 recordsLinked to original sources

Communication-Efficient and Personalized Federated Foundation Model Fine-Tuning via Tri-Matrix Adaptation

In federated learning, fine-tuning pre-trained foundation models poses significant challenges, particularly regarding high communication cost and suboptimal model performance due to data heterogeneity between the clients. To address these issues, this paper introduces communication-efficient federated LoRA adaption (CE-LoRA), a method that employs a tri-factorization low-rank adaptation approach with personalized model parameter aggregation. We first presents a novel LoRA parameter factorization by introducing a small-size dense matrix, which can significantly reduce the communication cost and achieve comparable empirical performance than transferring the low-rank parameter matrix used by existing methods. Without violating data privacy, the server considers the client similarity in both training dataset and model parameter space, and learns personalized weights for model aggregation. Our experiments on various LLM and VLM fine-tuning tasks demonstrate that CE-LoRA not only significantly reduces communication overhead but also improves performance under not independently and identically distributed data conditions. In addition, CE-LoRA improves data privacy protection, effectively mitigating gradient-based data reconstruction attacks.

cs.LG

First Principles Reactive Flux Theory for Surface Reactions: Multiple Channels and Recrossing Dynamics

Heterogenous reactions typically consist of multiple elementary steps and their rate coefficients are of fundamental importance in elucidating the mechanisms and micro-kinetics of these processes. Transition-state theory (TST) for calculating surface reaction rate coefficients often relies solely on the harmonic approximation of adsorbent vibrations and neglects recrossing dynamics. Here, we combine, for the first time, an efficient metadynamics enhanced sampling method with a more general reactive flux approach to calculate rate coefficients of surface reactions of any order and/or with multiple reaction coordinates, overcoming these limitations of TST. We apply this approach to a textbook surface reaction, CO oxidation on Pt(111), for which rate constants have been precisely measured, using a full-dimensional neural network potential energy surface constructed from first-principles data. An accurate multi-dimensional free-energy surface is obtained by incorporating three collective variables, yielding rate coefficients for both CO oxidation and the competing CO desorption that are in good agreement with experimental data. Interestingly, our results reveal significant dynamic recrossing in both channels, which however arises from distinct physical mechanisms. This approach represents an accurate and general framework for calculating rate coefficients of elementary surface processes from first-principles, which is vital for developing predictive kinetic models for heterogenous catalysis.

physics.chem-ph

Dual-Phase Accelerated Prompt Optimization

Gradient-free prompt optimization methods have made significant strides in enhancing the performance of closed-source Large Language Models (LLMs) across a wide range of tasks. However, existing approaches make light of the importance of high-quality prompt initialization and the identification of effective optimization directions, thus resulting in substantial optimization steps to obtain satisfactory performance. In this light, we aim to accelerate prompt optimization process to tackle the challenge of low convergence rate. We propose a dual-phase approach which starts with generating high-quality initial prompts by adopting a well-designed meta-instruction to delve into task-specific information, and iteratively optimize the prompts at the sentence level, leveraging previous tuning experience to expand prompt candidates and accept effective ones. Extensive experiments on eight datasets demonstrate the effectiveness of our proposed method, achieving a consistent accuracy gain over baselines with less than five optimization steps.

cs.CL

Reactions dynamics for X + H2 insertion reactions(X=C(1D), N(2D), O(1D), S(1D)) with Cayley Propagator ring-polymer molecular dynamics

In this work, rate coefficients of four prototypical insertion reactions, X + H2 -- H + XH (X=C(1D), N(2D), O(1D), S(1D)) and associated isotope reactions are calculated based on ring polymer molecular dynamics (RPMD) with Cayley propagator (Cayley-RPMD). The associated kinetic isotope effects (KIEs) are systematically studied too. The Cayley propagator used in this work increases the stability of numerical integration in RPMD calculations, and also supports a larger evolution time interval, allowing us to reach both high accuracy and efficiency. So, our results do not only provide chemical kinetic data for the title reactions in an extended temperature range, but also consist of experimental results, standard RPMD, and other theoretical methods. The results in this work also reflect that Cayley-RPMD has strong consistency and high reliability in the investigations of chemical dynamics for insertion reactions.

physics.chem-ph

Reaction dynamics for the Cl($^2$P) + XCl $\to$ XCl + Cl($^2$P) (X = H, D, Mu) reaction on a high-fidelity ground state potential energy surface

Globally accurate full-dimensional ground state potential energy surface (PES) for the Cl($^2$P) + XCl $\to$ HCl + Cl($^2$P) reaction, a prototypical heavy-light-heavy abstract reaction, is developed using permutation invariant polynomial neural network (PIP-NN) method and embedded atom neural network (EANN) method, with the corresponding total root mean square error (RMSE) being only 0.043 and 0.056 kcal/mol, respectively. The saddle point of this reaction system is found to be nonlinear. A full-dimensional approximate quantum mechanical method, ring-polymer molecular dynamics (RPMD) with Cayley propagator, is employed to calculate the thermal rate coefficients and kinetic isotopic effects of title reactions Cl($^2$P) + XCl $\to$ XCl + Cl($^2$P) (X = H, D, Mu) on both new PESs. The results reproduce the experimental results at high temperatures perfectly, but with moderate accuracy at lower temperatures. The similar kinetic behavior is supported by quantum dynamics using wave packet calculations as well.

physics.chem-ph

Molecular dynamics simulation of the transformation of Fe-Co alloy by machine learning force field based on atomic cluster expansion

The force field describing the calculated interaction between atoms or molecules is the key to the accuracy of many molecular dynamics (MD) simulation results. Compared with traditional or semi-empirical force fields, machine learning force fields have the advantages of faster speed and higher precision. We have employed the method of atomic cluster expansion (ACE) combined with first-principles density functional theory (DFT) calculations for machine learning, and successfully obtained the force field of the binary Fe-Co alloy. Molecular dynamics simulations of Fe-Co alloy carried out using this ACE force field predicted the correct phase transition range of Fe-Co alloy.

physics.comp-ph

New Stable and Fast Ring-Polymer Molecular Dynamics for Calculating Bimolecular Rate Coefficients with Example of OH + CH_4

The accurate and efficient calculation of the rate coefficients of chemical reactions is a key issue in the research of chemical dynamics. In this work, by applying the dimension-free ultra-stable Cayley propagator, the thermal rate coefficients of a prototypic high dimensional chemical reaction OH + CH4 -> H2O + CH3 in the temperature range of 200 K to 1500 K are investigated with ring polymer molecular dynamics (RPMD), on a highly accurate full-dimensional potential energy surface. Kinetic isotope effects (KIEs) for three isotopologues of the title reaction are also studied. The results demonstrate excellent agreement with experimental data, even in the deep tunneling region. Especially, the Cayley propagator shows high calculation efficiency with little loss of accuracy. The present results confirmed the applicability of the RPMD method, particularly the speed-up by Cayley propagator, in theoretical calculations of bimolecular reaction rates.

physics.chem-ph

Mechanisms of Molecular Ferroelectrics Made Simple

Molecular ferroelectrics have captured immense attention due to their superiority over inorganic oxide ferroelectrics, such as environmentally friendly, low-cost, flexible, foldable. However, the mechanisms of ferroelectric switching and phase transition for the molecular ferroelectrics are still missing, leaving the development of novel molecular ferroelectrics less efficient. In this work, we have provided a methodology combining molecular dynamics (MD) simulation on a polarized force field named polarized crystal charge (PCC) and enhanced sampling technique, replica-exchange molecular dynamics (REMD) to simulate such mechanisms. With this procedure, we have investigated a promising molecular ferroelectric material, (R)/(S)-3-quinuclidinol crystal. We have simulated the ferroelectric hysteresis loops of both enantiomers and obtained spontaneous polarization of 7/8 μC cm-2 and a corresponding coercive electric field of 15 kV cm-1. We also find the Curie temperature as 380/385 K for ferro-/para-electric phase transition of both enantiomers. All of the simulated results are highly compatible with experimental values. Besides of that, we predict a novel Curie temperature of about 600 K. This finding is further validated by principal component analysis (PCA). Our work would significantly promote the future exploration of multifunctional molecular ferroelectrics for the next generation of intelligent devices.

physics.chem-ph

Rate coefficients of a roaming reaction H + MgH using the ring polymer molecular dynamics

The ring-polymer molecular dynamics (RPMD) was used to calculate the thermal rate coefficients of the two-channel roaming reaction H + MgH. Both reaction channels, tight and roaming, are explicitly considered. This is a pioneering attempt of exerting RPMD method to multi-channel reactions. With the help of a newly developed optimization-interpolation protocol for preparing the initial structures and adaptive protocol for choosing the force constants, we have successfully obtained the thermal rate coefficients. The results are consistent with those from other theoretical methods, such as variational transition state theory (VTST) and quantum dynamics (QD). Especially, RPMD results exhibit negative temperature dependence, which is similar to results from VTST but different from ones from ground state QD calculations.

physics.chem-ph

Ring Polymer Molecular Dynamics in Gas-Surface Reactions: Inclusion of Quantum Effects Made Simple

Accurately modeling gas-surface collision dynamics presents a great challenge for theory, especially in the low energy (or temperature) regime where quantum effects are important. Here, a path integral based non-equilibrium ring polymer molecular dynamics (NE-RPMD) approach is adapted to calculate dissociative initial sticking probabilities (S0) of H2 on Cu(111) and D2O on Ni(111), revealing distinct quantum nature in the two benchmark surface reactions. NE-RPMD successfully captures quantum tunneling in H2 dissociation at very low energies, where the quasi-classical trajectory (QCT) method suddenly fails. Additionally, QCT substantially overestimates S0 of D2O due to severe zero point energy (ZPE) leakage, even at collision energies higher than the ZPE-corrected barrier. Immune to such a problem, NE-RPMD predicts S0 values of D2O in much improved agreement with the benchmark results obtained by the accurate but expensive quantum wavepacket method. Our results suggest NE-RPMD as a promising approach to model quantum effects in gas-surface reactions.

physics.chem-ph