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Yongming Wang

Publications and source records attributed to Yongming Wang.

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MAPCast: A Convection Allowing MPAS Emulator for Ensemble-based Background Error Covariance Estimation Toward Multi-Scale Data Assimilation

Machine learning (ML) emulators offer a cost-efficient alternative to numerical weather prediction models for generating convection-allowing background ensembles in ensemble-based data assimilation (DA). However, few studies have explored ML-based surrogate background ensembles for estimating background-error covariances (BECs). This study develops a convection-allowing emulator, MAPCast, trained on historical convection-allowing simulations from the Model for Prediction Across Scales (MPAS), and evaluates its ability to estimate BECs, paving the way toward multiscale DA. The evaluation uses 10 retrospective convective cases at 15- and 60-min forecast lead times corresponding to subhourly and hourly DA. MAPCast reproduces MPAS forecasts with good fidelity, including realistic storm coverage, temporal evolution, and similar spatial and spectral characteristics of state variables. Discrepancies are primarily confined to small spatial scales near sharp gradients and convective-scale features and variables. For BEC statistics, MAPCast captures ensemble spread magnitude and spatial distribution for most variables, although larger errors occur for storm-related fields that are vertical velocity and reflectivity. Correlation structures are reproduced most faithfully at mesoscale and above, followed by at convective scales, whereas cross-variable correlations are less accurately represented than univariate correlations, indicating that multivariate coupling remains the principal limitation. MAPCast shows weaker replication of full-scale versus decomposed large and small-scale correlations. BEC estimates derived from 15-min forecasts consistently outperform those from 60-min forecasts, suggesting that shorter lead times better preserve flow-dependent error structures.

physics.ao-ph

Observing and modeling the sequential pairwise reactions that drive solid-state ceramic synthesis

Solid-state synthesis from powder precursors is the primary processing route to advanced multicomponent ceramic materials. Designing ceramic synthesis routes is usually a laborious, trial-and-error process, as heterogeneous mixtures of powder precursors often evolve through a complicated series of reaction intermediates. Here, we show that phase evolution from multiple precursors can be modeled as a sequence of pairwise interfacial reactions, with thermodynamic driving forces that can be efficiently calculated using ab initio methods. Using the synthesis of the classic high-temperature superconductor YBa$_2$Cu$_3$O$_{6+x}$ (YBCO) as a representative system, we rationalize how replacing the common BaCO$_3$ precursor with BaO$_2$ redirects phase evolution through a kinetically-facile pathway. Our model is validated from in situ X-ray diffraction and in situ microscopy observations, which show rapid YBCO formation from BaO$_2$ in only 30 minutes. By combining thermodynamic modeling with in situ characterization, we introduce a new computable framework to interpret and ultimately design synthesis pathways to complex ceramic materials.

cond-mat.mtrl-sci

Synthesis, Crystal Structure, and Physical Properties of New Layered Oxychalcogenide La2O2Bi3AgS6

We have synthesized a new layered oxychalcogenide La2O2Bi3AgS6. From synchrotron X-ray diffraction and Rietveld refinement, the crystal structure of La2O2Bi3AgS6 was refined using a model of the P4/nmm space group with a = 4.0644(1) Å and c = 19.412(1) Å, which is similar to the related compound LaOBiPbS3, while the interlayer bonds (M2-S1 bonds) are apparently shorter in La2O2Bi3AgS6. The tunneling electron microscopy (TEM) image confirmed the lattice constant derived from Rietveld refinement (c ~ 20 Å). The electrical resistivity and Seebeck coefficient suggested that the electronic states of La2O2Bi3AgS6 are more metallic than those of LaOBiS2 and LaOBiPbS3. The insertion of a rock-salt-type chalcogenide into the van der Waals gap of BiS2-based layered compounds, such as LaOBiS2, will be a useful strategy for designing new layered functional materials in the layered chalcogenide family.

cond-mat.mtrl-sci