arXiv subjects

Yu Chai

Publications and source records attributed to Yu Chai.

4 recordsLinked to original sources

arXiv2025

Surface mobility of a glass-forming polymer in an ionic liquid

The free surface of glassy polymers exhibits enhanced segmental dynamics compared to the bulk, forming a liquid-like layer that lowers the glass transition temperature (Tg) in nanometersized polymer samples. Recent studies have shown that immersing polymers in ionic liquids can suppress this enhanced surface dynamics. To investigate how ionic liquids influence polymer dynamics near the ionic-liquid-polymer interface, we measure the surface leveling of nanometersized stepped polystyrene films immersed in ionic liquids, and compared the results to the case of films in vacuum. Our results reveal that ionic liquids significantly slow the leveling process both above and below Tg. However, our results indicate that the liquid-like surface layer below Tg does exist in ionic liquids. Numerical solutions of the thin-film equation, incorporating appropriate boundary conditions, show that the surface mobility of PS films in ionic liquids can match that of PS films in vacuum. Thus, while ionic liquids alter the polymer flow process, they do not eliminate the dynamical heterogeneity inherent to glassy polymers.

cond-mat.soft↗

arXiv2025

Identifying Root Cause of bugs by Capturing Changed Code Lines with Relational Graph Neural Networks

The Just-In-Time defect prediction model helps development teams improve software quality and efficiency by assessing whether code changes submitted by developers are likely to introduce defects in real-time, allowing timely identification of potential issues during the commit stage. However, two main challenges exist in current work due to the reality that all deleted and added lines in bug-fixing commits may be related to the root cause of the introduced bug: 1) lack of effective integration of heterogeneous graph information, and 2) lack of semantic relationships between changed code lines. To address these challenges, we propose a method called RC-Detection, which utilizes relational graph convolutional network to capture the semantic relationships between changed code lines. RC-Detection is used to detect root-cause deletion lines in changed code lines, thereby identifying the root cause of introduced bugs in bug-fixing commits. To evaluate the effectiveness of RC-Detection, we used three datasets that contain high-quality bug-fixing and bug-introducing commits. Extensive experiments were conducted to evaluate the performance of our model by collecting data from 87 open-source projects, including 675 bug-fix commits. The experimental results show that, compared to the most advanced root cause detection methods, RC-Detection improved Recall@1, Recall@2, Recall@3, and MFR by at 4.107%, 5.113%, 4.289%, and 24.536%, respectively.

cs.SE↗

arXiv2019

Using Mw dependence of surface dynamics of glassy polymers to probe the length scale of free surface mobility

We describe a series of surface levelling experiments in glassy polystyrene (PS) of varying molecular weight. The evolution through a mobile surface layer is described by the glassy thin film equation that was introduced and used in a previous work. Excellent agreement with the data is achieved, with surface mobility as the single free parameter. Different molecular-weight dependencies in mobility are then observed above and below the glass transition. The results are discussed in terms of surface-chain anchoring in the bulk matrix, and the length scale for surface mobility.

cond-mat.soft↗

arXiv2015

A direct quantitative measure of surface mobility in a glassy polymer

Thin polymer films have striking dynamical properties that differ from their bulk counterparts. With the simple geometry of a stepped polymer film on a substrate, we probe mobility above and below the glass transition temperature $T_{\textrm{g}}$. Above $T_{\textrm{g}}$ the entire film flows, while below $T_{\textrm{g}}$ only the near surface region responds to the excess interfacial energy. An analytical thin film model for flow limited to the free surface region shows excellent agreement with sub-$T_{\textrm{g}}$ data. The system transitions from whole film flow to surface localized flow over a narrow temperature region near the bulk $T_{\textrm{g}}$. The experiments and model provide a measure of surface mobility in a sample geometry where confinement and substrate effects are negligible. This fine control of the glassy rheology is of key interest to nanolithography among numerous other applications.

cond-mat.soft↗