arXiv subjects

Yun-Yi Pai

Publications and source records attributed to Yun-Yi Pai.

At least 19 recordsLinked to original sources

arXiv2023

Emergent magnetism with continuous control in the ultrahigh conductivity layered oxide PdCoO2

The current challenge to realizing continuously tunable magnetism lies in our inability to systematically change properties such as valence, spin, and orbital degrees of freedom as well as crystallographic geometry. Here, we demonstrate that ferromagnetism can be externally turned on with the application of low-energy helium implantation and subsequently erased and returned to the pristine state via annealing. This high level of continuous control is made possible by targeting magnetic metastability in the ultra-high conductivity, non-magnetic layered oxide PdCoO2 where local lattice distortions generated by helium implantation induce emergence of a net moment on the surrounding transition metal octahedral sites. These highly-localized moments communicate through the itinerant metal states which triggers the onset of percolated long-range ferromagnetism. The ability to continuously tune competing interactions enables tailoring precise magnetic and magnetotransport responses in an ultra-high conductivity film and will be critical to applications across spintronics.

cond-mat.mtrl-sci↗

arXiv2023

Quantum Enhanced Probes of Magnetic Circular Dichroism

Magneto-optical microscopies, including optical measurements of magnetic circular dichroism, are increasingly ubiquitous tools for probing spin-orbit coupling, charge-carrier g-factors, and chiral excitations in matter, but the minimum detectable signal in classical magnetic circular dichroism measurements is fundamentally limited by the shot-noise limit of the optical readout field. Here, we use a two-mode squeezed light source to improve the minimum detectable signal in magnetic circular dichroism measurements by 3 dB compared with state-of-the-art classical measurements, even with relatively lossy samples like terbium gallium garnet. We also identify additional opportunities for improvement in quantum-enhanced magneto-optical microscopies, and we demonstrate the importance of these approaches for environmentally sensitive materials and for low temperature measurements where increased optical power can introduce unacceptable thermal perturbations.

quant-ph↗

arXiv2023

Surface acoustic wave generation and detection in quantum paraelectric regime of SrTiO$_3$-based heterostructure

Strontium titanate (STO), apart from being a ubiquitous substrate for complex-oxide heterostructures, possesses a multitude of strongly-coupled electronic and mechanical properties. Surface acoustic wave (SAW) generation and detection offers insight into electromechanical couplings that are sensitive to quantum paraelectricity and other structural phase transitions. Propagating SAWs can interact with STO-based electronic nanostructures, in particular LaAlO$_3$/SrTiO$_3$ (LAO/STO). Here we report generation and detection of SAW within LAO/STO heterointerfaces at cryogenic temperatures ($T\ge$~2 K) using superconducting interdigitated transducers (IDTs). The temperature dependence shows an increase in the SAWs quality factor that saturates at $T\approx 8 $ K. The effect of backgate tuning on the SAW resonance frequency shows the possible acoustic coupling with the ferroelastic domain wall evolution. This method of generating SAWs provides a pathway towards dynamic tuning of ferroelastic domain structures, which are expected to influence electronic properties of complex-oxide nanostructures. Devices which incorporate SAWs may in turn help to elucidate the role of ferroelastic domain structures in mediating electronic behavior.

cond-mat.str-el↗

arXiv2022

Electron Pairing and Nematicity in LaAlO$_3$/SrTiO$_3$ Nanostructures

Strongly correlated electronic systems exhibit a wealth of unconventional behavior stemming from strong electron-electron interactions. The LaAlO$_3$/SrTiO$_3$ (LAO/STO) heterostructure supports rich and varied low-temperature transport characteristics including low-density superconductivity, and electron pairing without superconductivity for which the microscopic origins is still not understood. LAO/STO also exhibits inexplicable signatures of electronic nematicity via nonlinear and anomalous Hall effects. Nanoscale control over the conductivity of the LAO/STO interface enables mesoscopic experiments that can probe these effects and address their microscopic origins. Here we report a direct correlation between electron pairing without superconductivity, anomalous Hall effect and electronic nematicity in quasi-1D ballistic nanoscale LAO/STO Hall crosses. The characteristic magnetic field at which the Hall coefficient changes directly coincides with the depairing of non-superconducting pairs showing a strong correlation between the two distinct phenomena. Angle-dependent Hall measurements further reveal an onset of electronic nematicity that again coincides with the electron pairing transition, unveiling a rotational symmetry breaking due to the transition from paired to unpaired phases at the interface. The results presented here highlights the influence of preformed electron pairs on the transport properties of LAO/STO and provide evidence of the elusive pairing ''glue'' that gives rise to electron pairing in SrTiO$_3$-based systems.

cond-mat.mes-hall↗

arXiv2022

Monolayer superconductivity and tunable topological electronic structure at the Fe(Te,Se)/Bi2Te3 interface

The interface between two-dimensional topological Dirac states and an s-wave superconductor is expected to support Majorana bound states that can be used for quantum computing applications. Realizing these novel states of matter and their applications requires control over superconductivity and spin-orbit coupling to achieve spin-momentum locked topological surface states which are simultaneously superconducting. While signatures of Majorana bound states have been observed in the magnetic vortex cores of bulk FeTe0.55Se0.45, inhomogeneity and disorder from doping makes these signatures unclear and inconsistent between vortices. Here we report superconductivity in monolayer FeTe1-ySey (Fe(Te,Se)) grown on Bi2Te3 by molecular beam epitaxy. Spin and angle resolved photoemission spectroscopy directly resolve the interfacial spin and electronic structure of Fe(Te,Se)/Bi2Te3 heterostructures. We find that for y = 0.25 the Fe(Te,Se) electronic structure overlaps with the topological Bi2Te3 interfacial states which disrupts the desired spin-momentum locking. In contrast, for y = 0.1 a smaller Fe(Te,Se) Fermi surface allows for clear spin-momentum locking observed in the topological states. Hence, we demonstrate the Fe(Te,Se)/Bi2Te3 system is a highly tunable platform for realizing Majorana bound states where reduced doping can improve characteristics important for Majorana interrogation and potential applications.

cond-mat.supr-con↗

arXiv2022

Surface-Driven Evolution of the Anomalous Hall Effect in Magnetic Topological Insulator MnBi2Te4 Thin Films

Understanding the effects of interfacial modification to the functional properties of magnetic topological insulator thin films is crucial for developing novel technological applications from spintronics to quantum computing. Here, we report that a large electronic and magnetic response is induced in the intrinsic magnetic topological insulator MnBi2Te4 by controlling the propagation of surface oxidation. We show that the formation of the surface oxide layer is confined to the top 1-2 unit cells but drives large changes in the overall magnetic response. Specifically, we observe a dramatic reversal of the sign of the anomalous Hall effect driven by finite thickness magnetism, which indicates that the film splits into distinct magnetic layers each with a unique electronic signature. These data reveal a delicate dependence of the overall magnetic and electronic response of MnBi2Te4 on the stoichiometry of the top layers. Our study suggests that perturbations resulting from surface oxidation may play a non-trivial role in the stabilization of the quantum anomalous Hall effect in this system and that understanding targeted modifications to the surface may open new routes for engineering novel topological and magnetic responses in this fascinating material.

cond-mat.mtrl-sci↗

arXiv2022

Phonon Chirality Induced by Vibronic-Orbital Coupling

The notion that phonons can carry pseudo-angular momentum has become popular in the last decade, with recent research efforts highlighting phonon chirality, Berry curvature of phonon band structure, and the phonon Hall effect. When a phonon is resonantly coupled to a crystal electric field excitation, a so-called vibronic bound state forms. Here, we observe angular momentum transfer of $δ$Jz = $\pm$1$\hbar$ between phonons and an orbital state in a vibronic bound state of a candidate quantum spin liquid. This observation has profound implications for the engineering of phonon band structure topology through chiral quasiparticle interactions.

cond-mat.mes-hall↗

arXiv2022

Correlative nanoscale imaging of strained hBN spin defects

Spin defects like the negatively charged boron vacancy color center ($V_B^-$) in hexagonal boron nitride (hBN) may enable new forms of quantum sensing with near-surface defects in layered van der Waals heterostructures. Here, we reveal the effect of strain associated with creases in hBN flakes on $V_B^-$ and $V_B$ color centers in hBN with correlative cathodoluminescence and photoluminescence microscopies. We observe strong localized enhancement and redshifting of the $V_B^-$ luminescence at creases, consistent with density functional theory calculations showing $V_B^-$ migration toward regions with moderate uniaxial compressive strain. The ability to manipulate these spin defects with highly localized strain offers intriguing possibilities for future 2D quantum sensors.

cond-mat.mes-hall↗

arXiv2022

Snowmass 2021 White Paper: The Windchime Project

The absence of clear signals from particle dark matter in direct detection experiments motivates new approaches in disparate regions of viable parameter space. In this Snowmass white paper, we outline the Windchime project, a program to build a large array of quantum-enhanced mechanical sensors. The ultimate aim is to build a detector capable of searching for Planck mass-scale dark matter purely through its gravitational coupling to ordinary matter. In the shorter term, we aim to search for a number of other physics targets, especially some ultralight dark matter candidates. Here, we discuss the basic design, open R&D challenges and opportunities, current experimental efforts, and both short- and long-term physics targets of the Windchime project.

hep-ex↗

arXiv2022

Electronic and topological properties of the van der Waals layered superconductor PtTe

We report the crystal growth and structural and electronic properties of superconducting, van der Waals layered PtTe. Easily cleavable crystals with a plate-like morphology consistent with the layered structure were grown from a platinum rich flux. A consistent determination of $T_c = 0.57$ K is made from the onset of diamagnetism, the zero of resistivity, and the midpoint of the heat capacity jump. The observed behavior is consistent with type-II superconductivity, with upper critical field at $T=0$ estimated using the Werthamer-Helfand-Hohenberg theory to be 143 and 65 Oe for fields out of and in the plane, respectively. The heat capacity discontinuity is close to the weak coupling BCS value. Density functional theory calculations and analysis of the electronic structure finds that PtTe is a topological semimetal with numerous surface states, but suggests the superconducting state itself may be topologically trivial. Angle resolved photoemission spectroscopy reveals a normal-state Fermi surface in remarkable agreement with theory, and confirms the overall topological nature of the material by experimental identification of the surface bands. Together, these findings identify PtTe as an interesting example of a cleavable, topological, and superconducting material.

cond-mat.supr-con↗

arXiv2021

Advanced Architectures for High-Performance Quantum Networking

As practical quantum networks prepare to serve an ever-expanding number of nodes, there has grown a need for advanced auxiliary classical systems that support the quantum protocols and maintain compatibility with the existing fiber-optic infrastructure. We propose and demonstrate a quantum local area network design that addresses current deployment limitations in timing and security in a scalable fashion using commercial off-the-shelf components. We employ White Rabbit switches to synchronize three remote nodes with ultra-low timing jitter, significantly increasing the fidelities of the distributed entangled states over previous work with Global Positioning System clocks. Second, using a parallel quantum key distribution channel, we secure the classical communications needed for instrument control and data management. In this way, the conventional network which manages our entanglement network is secured using keys generated via an underlying quantum key distribution layer, preserving the integrity of the supporting systems and the relevant data in a future-proof fashion.

quant-ph↗

arXiv2021

Nearly-Resonant Crystalline-Phononic Coupling in Quantum Spin Liquid Candidate CsYbSe$_2$

CsYbSe$_2$, a recently identified quantum spin liquid (QSL) candidate, exhibits strong crystal electric field (CEF) excitations. Here, we identify phonon and CEF modes with Raman spectroscopy and observe strong CEF-phonon mixing resulting in a vibronic bound state. Complex, mesoscale interplay between phonon modes and CEF modes is observed in real space, and an unexpected nearly resonant condition is satisfied, yielding up to fifth-order combination modes, with a total of 17 modes identified in the spectra. This study paves the way to coherent control of possible QSL ground states with optically accessible CEF-phonon manifolds and mesoscale engineering of CEF-phonon interactions.

cond-mat.str-el↗

arXiv2021

Self-regulated growth of candidate topological superconducting parkerite by molecular beam epitaxy

Ternary chalcogenides such as the parkerites and shandites are a broad class of materials exhibiting rich diversity of transport and magnetic behavior as well as an array of topological phases including Weyl and Dirac nodes. However, they remain largely unexplored as high-quality epitaxial thin films. Here, we report the self-regulated growth of thin films of the strong spin-orbit coupled superconductor Pd3Bi2Se2 on SrTiO3 by molecular beam epitaxy. Films are found to grow in a self-regulated fashion, where, in excess Se, the temperature and relative flux ratio of Pd to Bi controls the formation of Pd3Bi2Se2 due to the combined volatility of Bi, Se, and Bi-Se bonded phases. The resulting films are shown to be of high structural quality, the stoichiometry is independent of the Pd:Bi and Se flux ratio and exhibit a superconducting transition temperature of 800 mK and critical field of 17.7 +/- 0.5 mT, as probed by transport as well as magnetometry. Understanding and navigating the growth of the chemically and structurally diverse classes of ternary chalcogenides opens a vast space for discovering new phenomena as well as enabling new applications.

cond-mat.mtrl-sci↗

arXiv2021

Design and realization of Ohmic and Schottky interfaces for oxide electronics

Understanding band alignment and charge transfer at complex oxide interfaces is critical to tailoring and utilizing their diverse functionality. Towards this goal, we design and experimentally validate both Ohmic- and Schottky-like charge transfers at oxide/oxide semiconductor/metal interfaces. We utilize a method for predicting band alignment and charge transfer in ABO3 perovskites, where previously established rules for simple semiconductors fail. The prototypical systems chosen are the rare class of oxide metals, SrBO3 with B=V-Ta, when interfaced with the multifaceted semiconducting oxide, SrTiO3. For B=Nb and Ta, we confirm that a large accumulation of charge occurs in SrTiO3 due to higher energy Nb and Ta d-states relative to Ti; this gives rise to a high mobility metallic interface, which is an ideal epitaxial oxide/oxide Ohmic contact. On the other hand, for B=V, there is no charge transfer into the SrTiO3 interface, which serves as a highly conductive epitaxial gate metal. Going beyond these specific cases, this work opens the door to integrating the vast phenomena of ABO3 perovskites into a wide range of practical devices.

cond-mat.mtrl-sci↗

arXiv2021

Correlated Oxide Dirac Semimetal in the Extreme Quantum Limit

Quantum materials (QMs) with strong correlation and non-trivial topology are indispensable to next-generation information and computing technologies. Exploitation of topological band structure is an ideal starting point to realize correlated topological QMs. Herein, we report that strain-induced symmetry modification in correlated oxide SrNbO3 thin films creates an emerging topological band structure. Dirac electrons in strained SrNbO3 films reveal ultra-high mobility (100,000 cm2/Vs), exceptionally small effective mass (0.04me), and non-zero Berry phase. More importantly, strained SrNbO3 films reach the extreme quantum limit, exhibiting a sign of fractional occupation of Landau levels and giant mass enhancement. Our results suggest that symmetry-modified SrNbO3 is a rare example of a correlated topological QM, in which strong correlation of Dirac electrons leads to the realization of fractional occupation of Landau levels.

cond-mat.str-el↗

arXiv2021

Magneto Optical Sensing beyond the Shot Noise Limit

Magneto-optical sensors including spin noise spectroscopies and magneto-optical Kerr effect microscopies are now ubiquitous tools for materials characterization that can provide new understanding of spin dynamics, hyperfine interactions, spin-orbit interactions, and charge-carrier g-factors. Both interferometric and intensity-difference measurements can provide photon shot-noise limited sensitivity, but further improvements in sensitivity with classical resources require either increased laser power that can induce unwanted heating and electronic perturbations or increased measurement times that can obscure out-of-equilibrium dynamics and radically slow experimental throughput. Proof-of-principle measurements have already demonstrated quantum enhanced spin noise measurements with a squeezed readout field that are likely to be critical to the non-perturbative characterization of spin excitations in quantum materials that emerge at low temperatures. Here, we propose a truncated nonlinear interferometric readout for low-temperature magneto-optical Kerr effect measurements that is accessible with today's quantum optical resources. We show that 10 $\text{nrad}/\sqrt{\text{Hz}}$ sensitivity is achievable with optical power as small as 1 $μ$W such that a realistic $T$ = 83 mK can be maintained in commercially available dilution refrigerators. The quantum advantage for the proposed measurements persists even in the limit of large loss and small squeezing parameters.

quant-ph↗

arXiv2021

Magnetostriction of α-RuCl3 flakes in the zigzag phase

Motivated by the possibility of an intermediate U(1) quantum spin liquid phase in out-of-plane magnetic fields and enhanced magnetic fluctuations in exfoliated α-RuCl3 flakes, we study magneto-Raman spectra of exfoliated multilayer α-RuCl3 in out-of-plane magnetic fields of -6 T to 6 T at temperatures of 670 mK - 4 K. While the literature currently suggests that bulk α-RuCl3 is in an antiferromagnetic zigzag phase with R3bar symmetry at low temperature, we do not observe R3bar symmetry in exfoliated α-RuCl3 at low temperatures. While we saw no magnetic field driven transitions, the Raman modes exhibit unexpected stochastic shifts in response to applied magnetic field that are above the uncertainties inferred from Bayesian analysis. These stochastic shifts are consistent with the emergence of magnetostrictive interactions in exfoliated α-RuCl3.

cond-mat.str-el↗

arXiv2021

Multifunctional Superconducting Nanowire Quantum Sensors

Superconducting nanowire single photon detectors (SNSPDs) offer high-quantum-efficiency and low-dark-count-rate single photon detection. In a growing number of cases, large magnetic fields are being incorporated into quantum microscopes, nanophotonic devices, and sensors for nuclear and high-energy physics that rely on SNSPDs, but superconducting devices generally operate poorly in large magnetic fields. Here, we demonstrate robust performance of amorphous SNSPDs in magnetic fields of up to $\pm 6$ T with a negligible dark count rate and unchanged quantum efficiency at typical bias currents. Critically, we also show that in the electrothermal oscillation regime, the SNSPD can be used as a magnetometer with sensitivity of better than 100 $\mathrm{μT/\sqrt{Hz}}$ and as a thermometer with sensitivity of 20 $\mathrm{μK/\sqrt{Hz}}$ at 1 K. Thus, a single photon detector integrated into a quantum device can be used as a multifunctional quantum sensor capable of describing the temperature and magnetic field on-chip simply by varying the bias current to change the operating modality from single photon detection to thermometry or magnetometry.

quant-ph↗