arXiv subjects

Yunlong Xiao

Publications and source records attributed to Yunlong Xiao.

At least 37 records · Page 2Linked to original sources

arXiv2024

Communication with Quantum Catalysts

Communication is essential for advancing science and technology. Quantum communication, in particular, benefits from the use of catalysts. During the communication process, these catalysts enhance performance while remaining unchanged. Although chemical catalysts that undergo deactivation typically perform worse than those that remain unaffected, quantum catalysts, referred to as embezzling catalysts, can surprisingly outperform their non-deactivating counterparts despite experiencing slight alterations. In this work, we employ embezzling quantum catalysts to enhance the transmission of both quantum and classical information. Our results reveal that using embezzling catalysts augments the efficiency of information transmission across noisy quantum channels, ensuring a non-zero catalytic channel capacity. Furthermore, we introduce catalytic superdense coding, demonstrating how embezzling catalysts can enhance the transmission of classical information. Finally, we explore methods to reduce the dimensionality of catalysts, a step toward making quantum catalysis a practical reality.

quant-ph↗

arXiv2024

Room temperature Si:S barrier infrared detector with broadband response up to 4.4μm

Mid-infrared spectrum is a critical tool for chemical analysis, industrial inspection, environment, and other fields due to its rich chemical bond information. However, the complicated growth or fabrication procedures of existing mid-infrared sensitive materials hinder the large-scale production and utilization of mid-infrared detectors. To address this issue, we developed Si:S barrier detectors employing sulfur doped silicon and a sophisticated band barrier design. Since the transport of dark current and photo current is separated, the barrier design effectively suppresses the dark current while allowing the photo current to leverage gain mechanisms, thereby substantially improving signal-to-noise ratio. As a result, the detector exhibits an infrared response range covering from 1.12 to 4.4μm with a peak at 3.3μm, excluding its intrinsic response in visible range. Its peak quantum efficiency surpasses that of the best mid-infrared silicon-based detector reported to date by an order of magnitude, reaching 2% at room temperature. The peak detectivity at 90K is 1.4E11 Jones @1.4V and decreases to 4.4E9 Jones @1.4V, 210K, comparable to the typical III-V and IV-VI photodetectors at one thousandth fabrication cost. Leveraging the well-established silicon-based manufacturing process, this device holds promise for large-scale production at a reduced price, offering a cost-effective solution for future mid-infrared detection.

physics.app-ph↗

arXiv2024

Generating High-Precision Force Fields for Molecular Dynamics Simulations to Study Chemical Reaction Mechanisms using Molecular Configuration Transformer

Theoretical studies on chemical reaction mechanisms have been crucial in organic chemistry. Traditionally, calculating the manually constructed molecular conformations of transition states for chemical reactions using quantum chemical calculations is the most commonly used method. However, this way is heavily dependent on individual experience and chemical intuition. In our previous study, we proposed a research paradigm that uses enhanced sampling in molecular dynamics simulations to study chemical reactions. This approach can directly simulate the entire process of a chemical reaction. However, the computational speed limits the use of high-precision potential energy functions for simulations. To address this issue, we present a scheme for training high-precision force fields for molecular modeling using a previously developed graph-neural-network-based molecular model, molecular configuration transformer. This potential energy function allows for highly accurate simulations at a low computational cost, leading to more precise calculations of the mechanism of chemical reactions. We applied this approach to study a Claisen rearrangement reaction and a Carbonyl insertion reaction catalyzed by Manganese.

physics.chem-ph↗

arXiv2023

Fundamental Limitations on Communication over a Quantum Network

Entanglement, a fundamental feature of quantum mechanics, has long been recognized as a valuable resource in enabling secure communications and surpassing classical limits. However, previous research has primarily concentrated on static entangled states generated at a single point in time, overlooking the crucial role of the quantum dynamics responsible for creating such states. Here, we propose a framework for investigating entanglement across multiple time points, termed temporal entanglement, and demonstrate that the performance of a quantum network in transmitting information is inherently dependent on its temporal entanglement. Through case studies, we showcase the capabilities of our framework in enhancing conventional quantum teleportation and achieving exponential performance growth in the protocol of quantum repeaters. Additionally, our framework effectively doubles the communication distance in certain noise models. Our results address the longstanding question surrounding temporal entanglement within non-Markovian processes and its impact on quantum communication, thereby pushing the frontiers of quantum information science.

quant-ph↗

arXiv2023

Quantum Uncertainty Principles for Measurements with Interventions

Heisenberg's uncertainty principle implies fundamental constraints on what properties of a quantum system can we simultaneously learn. However, it typically assumes that we probe these properties via measurements at a single point in time. In contrast, inferring causal dependencies in complex processes often requires interactive experimentation - multiple rounds of interventions where we adaptively probe the process with different inputs to observe how they affect outputs. Here we demonstrate universal uncertainty principles for general interactive measurements involving arbitrary rounds of interventions. As a case study, we show that they imply an uncertainty trade-off between measurements compatible with different causal dependencies.

quant-ph↗

arXiv2023

Non-collinear density functional theory

An approach to generalize any kind of collinear functionals in density functional theory to non-collinear functionals is proposed. This approach, for the very first time, satisfies the correct collinear limit for any kind of functionals, guaranteeing that the exact collinear functional after generalized is still exact for collinear spins. Besides, it has well-defined and numerically stable functional derivatives, a desired feature for non-collinear and spin-flip time-dependent density functional theory. Furthermore, it provides local torque, hinting at its applications in spin dynamics.

quant-ph↗

arXiv2022

Near-Optimal Variance-Based Uncertainty Relations

Learning physical properties of a quantum system is essential for the developments of quantum technologies. However, Heisenberg's uncertainty principle constrains the potential knowledge one can simultaneously have about a system in quantum theory. Aside from its fundamental significance, the mathematical characterization of this restriction, known as `uncertainty relation', plays important roles in a wide range of applications, stimulating the formation of tighter uncertainty relations. In this work, we investigate the fundamental limitations of variance-based uncertainty relations, and introduce several `near optimal' bounds for incompatible observables. Our results consist of two morphologically distinct phases: lower bounds that illustrate the uncertainties about measurement outcomes, and the upper bound that indicates the potential knowledge we can gain. Combining them together leads to an \emph{uncertainty interval}, which captures the essence of uncertainties in quantum theory. Finally, we have detailed how to formulate lower bounds for product-form variance-based uncertainty relations by employing entropic uncertainty relations, and hence built a link between different forms of uncertainty relations.

quant-ph↗

arXiv2022

SOiCI and iCISO: Combining iterative configuration interaction with spin-orbit coupling in two ways

The near-exact iCIPT2 approach for strongly correlated systems of electrons, which stems from the combination of iterative configuration interaction (iCI, an exact solver of full CI) with configuration selection for static correlation and second-order perturbation theory (PT2) for dynamic correlation, is extended to the relativistic domain. In the spirit of spin separation, relativistic effects are treated in two steps: scalar relativity is treated by the infinite-order, spin-free part of the exact two-component (X2C) relativistic Hamiltonian, whereas spin-orbit coupling (SOC) is treated by the first-order, Douglas-Kroll-Hess-like SOC operator derived from the same X2C Hamiltonian. Two possible combinations of iCIPT2 with SOC are considered, i.e., SOiCI and iCISO. The former treats SOC and electron correlation on an equal footing, whereas the latter treats SOC in the spirit of state interaction, by constructing and diagonalizing an effective spin-orbit Hamiltonian matrix in a small number of correlated scalar states. Both double group and time reversal symmetries are incorporated to simplify the computation. Pilot applications reveal that SOiCI is very accurate for the spin-orbit splitting (SOS) of heavy atoms, whereas the computationally very cheap iCISO can safely be applied to the SOS of light atoms and even of systems containing heavy atoms when SOC is largely quenched by ligand fields.

physics.chem-ph↗

arXiv2020

Multiple uncertainty relation for accelerated quantum information

The uncertainty principle, first introduced by Heisenberg in inertial frames, clearly distinguishes quantum theories from classical mechanics. In non-inertial frames, its information-theoretic expressions, namely entropic uncertainty relations, have been extensively studied through delocalized quantum fields, and localization of the quantum fields were discussed as well. However, infeasibility of measurements applied on a delocalized quantum field due to the finite size of measurement apparatuses is left unexplained. Therefore, physical clarification of a quantum protocol revealing entropic uncertainty relations still needs investigation. Building on advances in quantum field theories and theoretical developments in entropic uncertainty relations, we demonstrate a relativistic protocol of an uncertainty game in the presence of localized fermionic quantum fields inside cavities. Moreover, a novel lower bound for entropic uncertainty relations with multiple quantum memories is given in terms of the Holevo quantity, which implies how acceleration affects uncertainty relations.

quant-ph↗

arXiv2020

Quasi-Fine-Grained Uncertainty Relations

Nonlocality, which is the key feature of quantum theory, has been linked with the uncertainty principle by fine-grained uncertainty relations, by considering combinations of outcomes for different measurements. However, this approach assumes that information about the system to be fine-grained is local, and does not present an explicitly computable bound. Here, we generalize above approach to general quasi-fine-grained uncertainty relations (QFGURs) which applies in the presence of quantum memory and provides conspicuously computable bounds to quantitatively link the uncertainty to entanglement and Einstein-Podolsky-Rosen (EPR) steering, respectively. Moreover, our QFGURs provide a framework to unify three important forms of uncertainty relations, i.e., universal uncertainty relations, uncertainty principle in the presence of quantum memory, and fine-grained uncertainty relation. This result gives a direct significance to the uncertainty principle, and allows us to determine whether a quantum measurement exhibits typical quantum correlations, meanwhile, it reveals a fundamental connection between basic elements of quantum theory, specifically, uncertainty measures, combined outcomes for different measurements, quantum memory, entanglement and EPR steering.

quant-ph↗

arXiv2020

The Uncertainty Principle of Quantum Processes

Heisenberg's uncertainty principle, which imposes intrinsic restrictions on our ability to predict the outcomes of incompatible quantum measurements to arbitrary precision, demonstrates one of the key differences between classical and quantum mechanics. The physical systems considered in the uncertainty principle are static in nature and described mathematically with a quantum state in a Hilbert space. However, many physical systems are dynamic in nature and described with the formalism of a quantum channel. In this paper, we show that the uncertainty principle can be reformulated to include process-measurements that are performed on quantum channels. Since both quantum states and quantum measurements are themselves special cases of quantum channels, our formalism encapsulates the uncertainty principle in its utmost generality. More specifically, we obtain expressions that generalize the Maassen-Uffink uncertainty relation and the universal uncertainty relations from quantum states to quantum channels.

quant-ph↗

arXiv2019

Strong Majorization Uncertainty Relations: Theory and Experiment

In spite of enormous theoretical and experimental progresses in quantum uncertainty relations, the experimental investigation of most current, and universal formalism of uncertainty relations, namely majorization uncertainty relations (MURs), has not been implemented yet. A significant problem is that previous studies on the classification of MURs only focus on their mathematical expressions, while the physical difference between various forms remains unknown. First, we use a guessing game formalism to study the MURs, which helps us disclosing their physical nature, and distinguishing the essential differences of physical features between diverse forms of MURs. Second, we tighter the bounds of MURs in terms of flatness processes, or equivalently, in terms of majorization lattice. Third, to benchmark our theoretical results, we experimentally verify MURs in the photonic systems.

quant-ph↗

arXiv2019

The Complementary Information Principle of Quantum Mechanics

The uncertainty principle bounds the uncertainties about incompatible measurements, clearly setting quantum theory apart from the classical world. Its mathematical formulation via uncertainty relations, plays an irreplaceable role in quantum technologies. However, neither the uncertainty principle nor uncertainty relations can fully describe the complementarity between quantum measurements. As an attempt to advance the efforts of complementarity in quantum theories, we formally propose a complementary information principle, significantly extending the one introduced by Heisenberg. First, we build a framework of black box testing consisting of pre- and post-testing with two incompatible measurements, introducing a rigorous mathematical expression of complementarity with definite information causality. Second, we provide majorization lower and upper bounds for the complementary information by utilizing the tool of semidefinite programming. In particular, we prove that our bounds are optimal under majorization due to the completeness of the majorization lattice. Finally, as applications to our framework, we present a general method to outer-approximating all uncertainty regions and also establish fundamental limits for all qualified joint uncertainties.

quant-ph↗

arXiv2019

A Mobile Cloud Collaboration Fall Detection System Based on Ensemble Learning

Falls are one of the important causes of accidental or unintentional injury death worldwide. Therefore, this paper presents a reliable fall detection algorithm and a mobile cloud collaboration system for fall detection. The algorithm is an ensemble learning method based on decision tree, named Falldetection Ensemble Decision Tree (FEDT). The mobile cloud collaboration system can be divided into three stages: 1) mobile stage: use a light-weighted threshold method to filter out the activities of daily livings (ADLs), 2) collaboration stage: transmit data to cloud and meanwhile extract features in the cloud, 3) cloud stage: deploy the model trained by FEDT to give the final detection result with the extracted features. Experiments show that the performance of the proposed FEDT outperforms the others' over 1-3% both on sensitivity and specificity, and more importantly, the system can provide reliable fall detection in practical scenario.

eess.SP↗

arXiv2019

Incompatibility of Observables as State-Independent Bound of Uncertainty Relations

For a pair of observables, they are called "incompatible", if and only if the commutator between them does not vanish, which represents one of the key features in quantum mechanics. The question is, how can we characterize the incompatibility among three or more observables? Here we explore one possible route towards this goal through Heisenberg's uncertainty relations, which impose fundamental constraints on the measurement precisions for incompatible observables. Specifically, we quantify the incompatibility by the optimal state-independent bounds of additive variance-based uncertainty relations. In this way, the degree of incompatibility becomes an intrinsic property among the operators, but not on the quantum state. To justify our case, we focus on the incompatibility of spin systems. For an arbitrary setting of two or three linearly-independent Pauli-spin operators, the incompatibility is analytically solved, the spins are maximally incompatible if and only if they are orthogonal to each other. On the other hand, the measure of incompatibility represents a versatile tool for applications such as testing entanglement of bipartite states, and EPR-steering criteria.

quant-ph↗

arXiv2019

Experimental investigation of majorization uncertainty relations in the high-dimensional systems

Uncertainty relation is not only of fundamental importance to quantum mechanics, but also crucial to the quantum information technology. Recently, majorization formulation of uncertainty relations (MURs) have been widely studied, ranging from two measurements to multiple measurements. Here, for the first time, we experimentally investigate MURs for two measurements and multiple measurements in the high-dimensional systems, and study the intrinsic distinction between direct-product MURs and direct-sum MURs. The experimental results reveal that by taking different nonnegative Schur-concave functions as uncertainty measure, the two types of MURs have their own particular advantages, and also verify that there exists certain case where three-measurement majorization uncertainty relation is much stronger than the one obtained by summing pairwise two-measurement uncertainty relations. Our work not only fills the gap of experimental studies of majorization uncertainty relations, but also represents an advance in quantitatively understanding and experimental verification of majorization uncertainty relations which are universal and capture the essence of uncertainty in quantum theory.

quant-ph↗

arXiv2018

Improved quantum entropic uncertainty relations

We study entropic uncertainty relations by using stepwise linear functions and quadratic functions. Two kinds of improved uncertainty lower bounds are constructed: the state-independent one based on the lower bound of Shannon entropy and the tighter state-dependent one based on the majorization techniques. The analytical results for qubit and qutrit systems with two or three measurement settings are explicitly derived, with detailed examples showing that they outperform the existing bounds. The case with the presence of quantum memory is also investigated.

quant-ph↗

arXiv2017

Holevo Bound of Entropic Uncertainty in Schwarzschild Spacetime

For a pair of incompatible quantum measurements, the total uncertainty can be bounded by a state-independent constant. However, such a bound can be violated if the quantum system is entangled with another quantum system (called memory); the quantum correlation between the systems can reduce the measurement uncertainty. On the other hand, in a curved spacetime, the presence of the Hawking radiation can increase the uncertainty in quantum measurement. The interplay of quantum correlation in the curved spacetime has become an interesting arena for studying quantum uncertainty relations. Here we demonstrate that the bounds of the entropic uncertainty relations, in the presence of memory, can be formulated in terms of the Holevo quantity, which limits how much information can be encoded in a quantum system. Specifically, we considered two examples with Dirac fields, near the event horizon of a Schwarzschild black hole, the Holevo bound provides a better bound than the previous bound based on the mutual information. Furthermore, if the memory moves away from the black hole, the difference between the total uncertainty and the Holevo bound remains a constant, not depending on any property of the black hole.

quant-ph↗