arXiv subjects

Yuri Aikawa

Publications and source records attributed to Yuri Aikawa.

At least 73 records · Page 4Linked to original sources

arXiv2023

Early Planet Formation in Embedded Disks (eDisk). IV. The Ringed and Warped Structure of the Disk around the Class I Protostar L1489 IRS

Constraining the physical and chemical structure of young embedded disks is crucial to understanding the earliest stages of planet formation. As part of the Early Planet Formation in Embedded Disks Atacama Large Millimeter/submillimeter Array Large Program, we present high spatial resolution ($\sim$0$.\!\!^{\prime\prime}$1 or $\sim$15 au) observations of the 1.3 mm continuum and $^{13}$CO $J=$ 2-1, C$^{18}$O $J=$ 2-1, and SO $J_N=$ $6_5$-$5_4$ molecular lines toward the disk around the Class I protostar L1489 IRS. The continuum emission shows a ring-like structure at 56 au from the central protostar and a tenuous, optically thin emission extending beyond $\sim$300 au. The $^{13}$CO emission traces the warm disk surface, while the C$^{18}$O emission originates from near the disk midplane. The coincidence of the radial emission peak of C$^{18}$O with the dust ring may indicate a gap-ring structure in the gaseous disk as well. The SO emission shows a highly complex distribution, including a compact, prominent component at $\lesssim$30 au, which is likely to originate from thermally sublimated SO molecules. The compact SO emission also shows a velocity gradient along a slightly ($\sim15^\circ$) tilted direction with respect to the major axis of the dust disk, which we interpret as an inner warped disk in addition to the warp around $\sim$200 au suggested by previous work. These warped structures may be formed by a planet or companion with an inclined orbit, or by a gradual change in the angular momentum axis during gas infall.

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arXiv2023

Early Planet Formation in Embedded Disks (eDisk) III: A first high-resolution view of sub-mm continuum and molecular line emission toward the Class 0 protostar L1527 IRS

Studying the physical and chemical conditions of young embedded disks is crucial to constrain the initial conditions for planet formation. Here, we present Atacama Large Millimeter/submillimeter Array (ALMA) observations of dust continuum at $\sim$0.06" (8 au) resolution and molecular line emission at $\sim$0.17" (24 au) resolution toward the Class 0 protostar L1527 IRS from the Large Program eDisk (Early Planet Formation in Embedded Disks). The continuum emission is smooth without substructures, but asymmetric along both the major and minor axes of the disk as previously observed. The detected lines of $^{12}$CO, $^{13}$CO, C$^{18}$O, H$_2$CO, c-C$_3$H$_2$, SO, SiO, and DCN trace different components of the protostellar system, with a disk wind potentially visible in $^{12}$CO. The $^{13}$CO brightness temperature and the H$_2$CO line ratio confirm that the disk is too warm for CO freeze out, with the snowline located at $\sim$350 au in the envelope. Both molecules show potential evidence of a temperature increase around the disk-envelope interface. SO seems to originate predominantly in UV-irradiated regions such as the disk surface and the outflow cavity walls rather than at the disk-envelope interface as previously suggested. Finally, the continuum asymmetry along the minor axis is consistent with the inclination derived from the large-scale (100" or 14,000 au) outflow, but opposite to that based on the molecular jet and envelope emission, suggesting a misalignment in the system. Overall, these results highlight the importance of observing multiple molecular species in multiple transitions to characterize the physical and chemical environment of young disks.

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arXiv2023

Early Planet Formation in Embedded Disks (eDisk). I. Overview of the Program and First Results

We present an overview of the Large Program, ``Early Planet Formation in Embedded Disks (eDisk)'', conducted with the Atacama Large Millimeter/submillimeter Array (ALMA). The ubiquitous detections of substructures, particularly rings and gaps, in protoplanetary disks around T Tauri stars raise the possibility that at least some planet formation may have already started during the embedded stages of star formation. In order to address exactly how and when planet formation is initiated, the program focuses on searching for substructures in disks around 12 Class 0 and 7 Class I protostars in nearby ($< $200 pc) star-forming regions through 1.3 mm continuum observations at a resolution of $\sim7$ au (0.04"). The initial results show that the continuum emission, mostly arising from dust disks around the sample protostars, has relatively few distinctive substructures, such as rings and spirals, in marked contrast to Class II disks. The dramatic difference may suggest that substructures quickly develop in disks when the systems evolve from protostars to Class II sources or alternatively that high optical depth of the continuum emission could obscure internal structures. Kinematic information obtained through CO isotopologue lines and other lines reveals the presence of Keplerian disks around protostars, providing us with crucial physical parameters, in particular, the dynamical mass of the central protostars. We describe the background of the eDisk program, the sample selection and their ALMA observations, the data reduction, and also highlight representative first-look results.

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arXiv2023

Early Planet Formation in Embedded Disks (eDisk). II. Limited Dust Settling and Prominent Snow Surfaces in the Edge-on Class I Disk IRAS 04302+2247

While dust disks around optically visible, Class II protostars are found to be vertically thin, when and how dust settles to the midplane are unclear. As part of the Atacama Large Millimeter/submillimeter Array (ALMA) large program, Early Planet Formation in Embedded Disks, we analyze the edge-on, embedded, Class I protostar IRAS 04302+2247, also nicknamed the ``Butterfly Star." With a resolution of 0.05" (8~au), the 1.3 mm continuum shows an asymmetry along the minor axis which is evidence of an optically thick and geometrically thick disk viewed nearly edge-on. There is no evidence of rings and gaps, which could be due to the lack of radial substructure or the highly inclined and optically thick view. With 0.1" (16~au) resolution, we resolve the 2D snow surfaces, i.e., the boundary region between freeze-out and sublimation, for $^{12}$CO $J$=2--1, $^{13}$CO $J$=2--1, C$^{18}$O $J$=2--1, $H_{2}$CO $J$=$3_{0,3}$--$2_{0,2}$, and SO $J$=$6_{5}$--$5_{4}$, and constrain the CO midplane snow line to $\sim 130$ au. We find Keplerian rotation around a protostar of $1.6 \pm 0.4 M_{\odot}$ using C$^{18}$O. Through forward ray-tracing using RADMC-3D, we find that the dust scale height is $\sim 6$ au at a radius of 100~au from the central star and is comparable to the gas pressure scale height. The results suggest that the dust of this Class~I source has yet to vertically settle significantly.

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arXiv2023

Primordial or Secondary? Testing models of debris disk gas with ALMA

The origin and evolution of gas in debris disks is still not well understood. Secondary gas production from cometary material or a primordial origin have been proposed. So far, observations have mostly concentrated on CO, with only few C observations available. We create an overview of the C and CO content of debris disk gas and use it test state-of-the-art models. We use new and archival ALMA observations of CO and CI emission, complemented by CII data from Herschel, for a sample of 14 debris disks. This expands the number of disks with ALMA measurements of both CO and CI by ten disks. We present new detections of CI emission towards three disks: HD 21997, HD 121191 and HD 121617. We use a simple disk model to derive gas masses and column densities. We find that current state-of-the-art models of secondary gas production overpredict the neutral carbon content of debris disk gas. This does not rule out a secondary origin, but might indicate that the models require an additional C removal process. Alternatively, the gas might be produced in transient events rather than a steady-state collisional cascade. We also test a primordial gas origin by comparing our results to a simplified thermo-chemical model. This yields promising results, but more detailed work is required before a conclusion can be reached. Our work demonstrates that the combination of C and CO data is a powerful tool to advance our understanding of debris disk gas.

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arXiv2023

Molecules with ALMA at Planet-forming Scales (MAPS). Complex Kinematics in the AS 209 Disk Induced by a Forming Planet and Disk Winds

We study the kinematics of the AS 209 disk using the J=2-1 transitions of $^{12}$CO, $^{13}$CO, and C$^{18}$O. We derive the radial, azimuthal, and vertical velocity of the gas, taking into account the lowered emission surface near the annular gap at ~1.7 (200 au) within which a candidate circumplanetary disk-hosting planet has been reported previously. In $^{12}$CO and $^{13}$CO, we find a coherent upward flow arising from the gap. The upward gas flow is as fast as $150~{\rm m~s}^{-1}$ in the regions traced by $^{12}$CO emission, which corresponds to about 50% of the local sound speed or $6\%$ of the local Keplerian speed. Such an upward gas flow is difficult to reconcile with an embedded planet alone. Instead, we propose that magnetically driven winds via ambipolar diffusion are triggered by the low gas density within the planet-carved gap, dominating the kinematics of the gap region. We estimate the ambipolar Elsasser number, Am, using the HCO$^+$ column density as a proxy for ion density and find that Am is ~0.1 at the radial location of the upward flow. This value is broadly consistent with the value at which numerical simulations find ambipolar diffusion drives strong winds. We hypothesize the activation of magnetically-driven winds in a planet-carved gap can control the growth of the embedded planet. We provide a scaling relationship which describes the wind-regulated terminal mass: adopting parameters relevant to 100 au from a solar-mass star, we find the wind-regulated terminal mass is about one Jupiter mass, which may help explain the dearth of directly imaged super-Jovian-mass planets.

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arXiv2023

Processing of hydroxylamine, NH2OH, an important prebiotic precursor, on interstellar ices

Hydroxylamine, NH2OH, is one of the already detected interstellar molecules with the highest prebiotic potential. Yet, the abundance of this molecule found by astronomical observations is rather low for a relatively simple molecule, $\sim$ 10$^{-10}$ relative to H2. This seemingly low abundance can be rationalized by destruction routes operating on interstellar dust grains. In this work, we tested the viability of this hypothesis under several prisms, finding that the origin of a lower abundance of \ce{NH2OH} can be explained by two chemical processes, one operating at low temperature (10 K) and the other at intermediate temperature (20 K). At low temperatures, enabling the hydrogen abstraction reaction HNO + H -> NO + H2, even in small amounts, partially inhibits the formation of NH2OH through successive hydrogenation of NO, and reduces its abundance on the grains. We found that enabling a 15--30 % of binding sites for this reaction results in reductions of \ce{NH2OH} abundance of $\sim$ 1-2 orders of magnitude. At warmer temperatures (20 K, in our study), the reaction NH2OH + H -> HNOH + H2, which was found to be fast (k$\sim$10$^{6}$ s$^{-1}$) in this work, followed by further abstractions by adsorbates that are immobile at 10 K (O, N) are the main route of \ce{NH2OH} destruction. Our results shed light on the abundance of hydroxylamine in space and pave the way to constraining the subsequent chemistry experienced by this molecule and its derivatives in the interstellar prebiotic chemistry canvas.

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arXiv2023

A Constraint on the Amount of Hydrogen from the CO Chemistry in Debris Disks

The faint CO gases in debris disks are easily dissolved into C by UV irradiation, while CO can be reformed via reactions with hydrogen. The abundance ratio of C/CO could thus be a probe of the amount of hydrogen in the debris disks. We conduct radiative transfer calculations with chemical reactions for debris disks. For a typical dust-to-gas mass ratio of debris disks, CO formation proceeds without the involvement of H$_2$ because a small amount of dust grains makes H$_2$ formation inefficient. We find that the CO to C number density ratio depends on a combination of $n_\mathrm{H}Z^{0.4}χ^{-1.1}$, where $n_\mathrm{H}$ is the hydrogen nucleus number density, $Z$ is the metallicity, and $χ$ is the FUV flux normalized by the Habing flux. Using an analytic formula for the CO number density, we give constraints on the amount of hydrogen and metallicity for debris disks. CO formation is accelerated by excited H$_2$ either when the dust-to-gas mass ratio is increased or the energy barrier of chemisorption of hydrogen on the dust surface is decreased. This acceleration of CO formation occurs only when the shielding effects of CO are insignificant. In shielded regions, the CO fractions are almost independent of the parameters of dust grains.

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arXiv2023

FAUST VII. Detection of A Hot Corino in the Prototypical Warm Carbon-Chain Chemistry Source IRAS 15398-3359

We have observed the low-mass protostellar source, IRAS 15398$-$3359, at a resolution of 0.$''$2-0.$''$3, as part of the Atacama Large Millimeter/Submillimeter Array Large Program FAUST, to examine the presence of a hot corino in the vicinity of the protostar. We detect nine CH$_3$OH lines including the high excitation lines with upper state energies up to 500 K. The CH$_3$OH rotational temperature and the column density are derived to be 119$^{+20}_{-26}$ K and 3.2$^{+2.5}_{-1.0}\times$10$^{18}$ cm$^{-2}$, respectively. The beam filling factor is derived to be 0.018$^{+0.005}_{-0.003}$, indicating that the emitting region of CH$_3$OH is much smaller than the synthesized beam size and is not resolved. The emitting region of three high excitation lines, 18$_{3,15}-18_{2,16}$, A ($E_u=$447 K), 19$_{3,16}-19_{2,17}$, A ($E_u=$491 K), and 20$_{3,17}-20_{2,18}$, A ($E_u=$537 K), is located within the 50 au area around the protostar, and seems to have a slight extension toward the northwest. Toward the continuum peak, we also detect one emission line from CH$_2$DOH and two features of multiple CH$_3$OCHO lines. These results, in combination with previous reports, indicate that IRAS 15398$-$3359 is a source with hybrid properties showing both hot corino chemistry rich in complex organic molecules on small scales $\sim$10 au) and warm carbon-chain chemistry (WCCC) rich in carbon-chain species on large scales ($\sim$100-1000 au). A possible implication of the small emitting region is further discussed in relation to the origin of the hot corino activity.

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arXiv2023

Reaction dynamics on amorphous solid water surfaces using interatomic machine learned potentials. Microscopic energy partition revealed from the P + H -> PH reaction

Energy redistribution after a chemical reaction is one of the few mechanisms to explain the diffusion and desorption of molecules which require more energy than the thermal energy available in quiescent molecular clouds (10 K). This energy distribution can be important in phosphorous hydrides, elusive yet fundamental molecules for interstellar prebiotic chemistry. We studied the reaction dynamics of the \ce{P + H -> PH} reaction on amorphous solid water, a reaction of astrophysical interest, using \emph{ab-initio} molecular dynamics with atomic forces evaluated by a neural network interatomic potential. We found that the exact nature of the initial phosphorous binding sites is less relevant for the energy dissipation process because the nascent PH molecule rapidly migrates to sites with higher binding energy after the reaction. Non-thermal diffusion and desorption-after-reaction were observed and occurred early in the dynamics, essentially decoupled from the dissipation of the chemical reaction energy. From an extensive sampling of reactions on sites, we constrained the average dissipated reaction energy within the simulation time (50 ps) to be between 50 and 70 %. Most importantly, the fraction of translational energy acquired by the formed molecule was found to be mostly between 1 and 5 %. Including these values, specifically for the test cases of 2% and 5% of translational energy conversion, in astrochemical models, reveals very low gas-phase abundances of PH$_{x}$ molecules and reflects that considering binding energy distributions is paramount for correctly merging microscopic and macroscopic modelling of non-thermal surface astrochemical processes. Finally, we found that PD molecules dissipate more of the reaction energy. This effect can be relevant for the deuterium fractionation and preferential distillation of molecules in the interstellar medium.

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arXiv2023

Cold Deuterium Fractionation in the Nearest Planet-Forming Disk

Deuterium fractionation provides a window to the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed towards a handful of disks, it remains unclear whether this chemistry affects the composition of forming planetesimals due to limited observational constraints on the radial and vertical distribution of deuterated molecules. To shed light on this question, we introduce new ALMA observations of DCO$^+$ and DCN $J=2-1$ at an angular resolution of $0.5"$ (30 au) and combine them with archival data of higher energy transitions towards the protoplanetary disk around TW Hya. We carry out a radial excitation analysis assuming both LTE and non-LTE to localize the physical conditions traced by DCO$^+$ and DCN emission in the disk, thus assessing deuterium fractionation efficiencies and pathways at different disk locations. We find similar disk-averaged column densities of $1.9\times10^{12}$ and $9.8\times10^{11}$ cm$^{-2}$ for DCO$^{+}$ and DCN, with typical kinetic temperatures for both molecules of 20-30K, indicating a common origin near the comet- and planet-forming midplane. The observed DCO$^+$/DCN abundance ratio, combined with recent modeling results, provide tentative evidence of a gas phase C/O enhancement within $<40$ au. Observations of DCO$^+$ and DCN in other disks, as well as HCN and HCO$^+$, will be necessary to place the trends exhibited by TW Hya in context, and fully constrain the main deuteration mechanisms in disks.

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arXiv2022

The first interferometric measurements of NH$_2$D/NH$_3$ ratio in hot corinos

The nitrogen chemical evolution during star and planet formation is still not fully understood. Ammonia (NH$_3$) is a key specie in the understanding of the molecular evolution in star-forming clouds and nitrogen isotope fractionation. In this paper, we present high spatial resolution observations of multiple emission lines of NH$_3$ toward the protobinary system NGC1333 IRAS4A with Karl G. Jansky Very Large Array (VLA). We spatially resolved the binary (hereafter 4A1 and 4A2) and detected compact emission of NH$_3$ transitions with high excitation energies ($\gtrsim$100 K) from the vicinity of the protostars, indicating the NH$_3$ ice has sublimated at the inner hot region. The NH$_3$ column density is estimated to be $\sim 10^{17}-10^{18}$ cm$^{-2}$. We also detected two NH$_2$D transitions, allowing us to constrain the deuterium fractionation of ammonia. The NH$_2$D/NH$_3$ ratios are as high as $\sim 0.3-1$ in both 4A1 and 4A2. From the comparisons with the astrochemical models in the literature, the high NH$_2$D/NH$_3$ ratios suggest that the formation of NH$_3$ ices mainly started in the prestellar phase after the formation of bulk water ice finished, and that the primary nitrogen reservoir in the star-forming cloud could be atomic nitrogen (or N atoms) rather than nitrogen-bearing species such as N$_2$ and NH$_3$. The implications on the physical properties of IRAS4A cores are discussed as well.

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arXiv2022

Molecules with ALMA at Planet-forming Scales (MAPS). A Circumplanetary Disk Candidate in Molecular Line Emission in the AS 209 Disk

We report the discovery of a circumplanetary disk (CPD) candidate embedded in the circumstellar disk of the T Tauri star AS 209 at a radial distance of about 200 au (on-sky separation of 1."4 from the star at a position angle of $161^\circ$), isolated via $^{13}$CO $J=2-1$ emission. This is the first instance of CPD detection via gaseous emission capable of tracing the overall CPD mass. The CPD is spatially unresolved with a $117\times82$ mas beam and manifests as a point source in $^{13}$CO, indicating that its diameter is $\lesssim14$ au. The CPD is embedded within an annular gap in the circumstellar disk previously identified using $^{12}$CO and near-infrared scattered light observations, and is associated with localized velocity perturbations in $^{12}$CO. The coincidence of these features suggests that they have a common origin: an embedded giant planet. We use the $^{13}$CO intensity to constrain the CPD gas temperature and mass. We find that the CPD temperature is $\gtrsim35$ K, higher than the circumstellar disk temperature at the radial location of the CPD, 22 K, suggesting that heating sources localized to the CPD must be present. The CPD gas mass is $\gtrsim 0.095 M_{\rm Jup} \simeq 30 M_{\rm Earth}$ adopting a standard $^{13}$CO abundance. From the non-detection of millimeter continuum emission at the location of the CPD ($3σ$ flux density $\lesssim26.4~μ$Jy), we infer that the CPD dust mass is $\lesssim 0.027 M_{\rm Earth} \simeq 2.2$ lunar masses, indicating a low dust-to-gas mass ratio of $\lesssim9\times10^{-4}$. We discuss the formation mechanism of the CPD-hosting giant planet on a wide orbit in the framework of gravitational instability and pebble accretion.

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arXiv2022

Ice features of low-luminosity protostars in near-infrared spectra of AKARI/IRC

We present near-infrared spectra of three low-luminosity protostars and one background star in the Perseus molecular cloud, acquired using the Infrared Camera (IRC) onboard the \textit{AKARI} space telescope. For the comparison with different star-forming environments, we also present spectra of the massive protostar AFGL 7009S, where the protostellar envelope is heated significantly, and the low-mass protostar RNO 91, which is suspected to be undergoing an episodic burst. We detected ice absorption features of \ch{H2O}, \ch{CO2}, and \ch{CO} at all spectra around the wavelengths of 3.05, 4.27, and 4.67 $μ$m, respectively. At least two low-luminosity protostars, we also detected the \ch{XCN} ice feature at 4.62 $μ$m. The presence of the crystalline \ch{H2O} ice and \ch{XCN} ice components indicates that the low-luminosity protostars experienced a hot phase via accretion bursts during the past mass accretion process. We compared the ice abundances of low-luminosity protostars with those of the embedded low-mass protostars and the dense molecular clouds and cores, suggesting that their ice abundances reflect the strength of prior bursts and the timescale after the last burst.

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arXiv2022

A VLA View of the Flared, Asymmetric Disk Around the Class 0 Protostar L1527 IRS

We present high resolution Karl G. Jansky Very Large Array (VLA) observations of the protostar L1527 IRS at 7 mm, 1.3 cm, and 2 cm wavelengths. We detect the edge-on dust disk at all three wavelengths and find that it is asymmetric, with the southern side of the disk brighter than the northern side. We confirm this asymmetry through analytic modeling and also find that the disk is flared at 7 mm. We test the data against models including gap features in the intensity profile, and though we cannot rule such models out, they do not provide a statistically significant improvement in the quality of fit to the data. From these fits, we can however place constraints on allowed properties of any gaps that could be present in the true, underlying intensity profile. The physical nature of the asymmetry is difficult to associate with physical features due to the edge-on nature of the disk, but could be related to spiral arms or asymmetries seen in other imaging of more face-on disks.

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arXiv2022

Diffusion activation energy and desorption activation energy for astrochemically relevant species on water ice show no clear relation

The activation energy for desorption (Edes) and that for surface diffusion (Esd) of adsorbed molecules on dust grains are two of the most important parameters for the chemistry in the interstellar medium. Although Edes is often measured by laboratory experiments, the measurement of Esd is sparse. Due to the lack of data, astrochemical models usually assume a simple scaling relation, Esd = fEdes, where f is a constant, irrespective of adsorbed species. Here, we experimentally measure Esd for CH4, H2S, OCS, CH3OH, and CH3CN on water-ice surfaces using an ultra-high-vacuum transmission electron microscope (UHV-TEM). Compiling the measured Esd values and Edes values from the literature, we find that the value of f ranges from ~0.2 to ~0.7, depending on the species. Unless f (or Esd) for the majority of species is available, a natural alternative approach for astrochemical models is running multiple simulations, varying f for each species randomly. In this approach, ranges of molecular abundances predicted by multiple simulations, rather than abundances predicted by each simulation, are important. We here run 10,000 simulations of astrochemical models of molecular clouds and protostellar envelopes, randomly assigning a value of f for each species. In the former case, we identify several key species whose Esd most strongly affects the uncertainties of the model predictions; Esd for those species should be investigated in future laboratory and quantum chemical studies. In the latter case, uncertainties in the Esd of many species contribute to the uncertainties in the model predictions.

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arXiv2022

Molecules with ALMA at Planet-forming Scales (MAPS) III: Characteristics of Radial Chemical Substructures

The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a detailed, high resolution (${\sim}$10-20 au) view of molecular line emission in five protoplanetary disks at spatial scales relevant for planet formation. Here, we present a systematic analysis of chemical substructures in 18 molecular lines toward the MAPS sources: IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. We identify more than 200 chemical substructures, which are found at nearly all radii where line emission is detected. A wide diversity of radial morphologies - including rings, gaps, and plateaus - is observed both within each disk and across the MAPS sample. This diversity in line emission profiles is also present in the innermost 50 au. Overall, this suggests that planets form in varied chemical environments both across disks and at different radii within the same disk. Interior to 150 au, the majority of chemical substructures across the MAPS disks are spatially coincident with substructures in the millimeter continuum, indicative of physical and chemical links between the disk midplane and warm, elevated molecular emission layers. Some chemical substructures in the inner disk and most chemical substructures exterior to 150 au cannot be directly linked to dust substructure, however, which indicates that there are also other causes of chemical substructures, such as snowlines, gradients in UV photon fluxes, ionization, and radially-varying elemental ratios. This implies that chemical substructures could be developed into powerful probes of different disk characteristics, in addition to influencing the environments within which planets assemble. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2022

Thermal desorption of interstellar ices. A review on the controlling parameters and their implications fromsnowlines to chemical complexity

The evolution of star-forming regions and their thermal balance are strongly influenced by their chemical composition, that, in turn, is determined by the physico-chemical processes that govern the transition between the gas phase and the solid state, specifically icy dust grains (e.g., particles adsorption and desorption). Gas-grain and grain-gas transitions as well as formation and sublimation of interstellar ices are thus essential elements of understanding astrophysical observations of cold environments (e.g., pre-stellar cores) where unexpected amounts of a large variety of chemical species have been observed in the gas phase. Adsorbed atoms and molecules also undergo chemical reactions which are not efficient in the gas phase. Therefore, the parameterization of the physical properties of atoms and molecules interacting with dust grain particles is clearly a key aspect to interpret astronomical observations and to build realistic and predictive astrochemical models. In this consensus evaluation, we focus on parameters controlling the thermal desorption of ices and how these determine pathways towards molecular complexity and define the location of snowlines, which ultimately influence the planet formation process. We review different crucial aspects of desorption parameters both from a theoretical and experimental point of view. We critically assess the desorption parameters commonly used in the astrochemical community for astrophysical relevant species and provide tables with recommended values. In addition, we show that a non-trivial determination of the pre-exponential factor nu using the Transition State Theory can affect the binding energy value. Finally, we conclude this work by discussing the limitations of theoretical and experimental approaches currently used to determine the desorption properties with suggestions for future improvements.

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