arXiv subjects

Yuri S. Kivshar

Publications and source records attributed to Yuri S. Kivshar.

At least 19 recordsLinked to original sources

arXiv2024

Enhanced biochemical sensing with high-Q transmission resonances in free-standing membrane metasurfaces

Optical metasurfaces provide novel solutions to label-free biochemical sensing by localizing light resonantly beyond the diffraction limit, thereby selectively enhancing light-matter interactions for improved analytical performance. However, high-Q resonances in metasurfaces are usually achieved in the reflection mode, which impedes metasurface integration into compact imaging systems. Here, we demonstrate a novel metasurface platform for advanced biochemical sensing based on the physics of the bound states in the continuum (BIC) and electromagnetically induced transparency (EIT) modes, which arise when two interfering resonances from a periodic pattern of tilted elliptic holes overlap both spectrally and spatially, creating a narrow transparency window in the mid-infrared spectrum. We experimentally measure these resonant peaks observed in transmission mode (Q~734 at ~8.8 um) in free-standing silicon membranes and confirm their tunability through geometric scaling. We also demonstrate the strong coupling of the BIC-EIT modes with a thinly coated PMMA film on the metasurface, characterized by a large Rabi splitting (32 cm-1) and biosensing of protein monolayers in transmission mode. Our new photonic platform can facilitate the integration of metasurface biochemical sensors into compact and monolithic optical systems while being compatible with scalable manufacturing, thereby clearing the way for on-site biochemical sensing in everyday applications.

physics.optics↗

arXiv2024

Interaction-induced multiparticle bound states in the continuum

Bound states in the continuum (BICs) are localized modes residing in the radiation continuum. They were first predicted for single-particle states, and became a general feature of many wave systems. In many-body quantum physics, it is still unclear what would be a close analog of BICs, and whether interparticle interaction may induce BICs. Here, we predict a novel type of multiparticle states in the interaction-modulated Bose-Hubbard model that can be associated with the BIC concept. Under periodic boundary conditions, a so-called quasi-BIC appears as a bound pair residing in a standing wave formed by the third particle. Under open boundary conditions, such a hybrid state becomes an eigenstate of the system. We demonstrate that the Thouless pumping of the quasi-BICs can be realized by modulating the onsite interactions in space and time. Surprisingly, while the center-of-mass of the quasi-BIC is shifted by a unit cell in one cycle, the bound pair moves in the opposite direction with the standing wave.

quant-ph↗

arXiv2024

Substrate-induced maximum optical chirality of planar dielectric structures

Resonant dielectric planar structures can interact selectively with light of particular helicity thus providing an attractive platform for chiral flat optics. The absence of mirror-symmetry planes defines geometric chirality, and it remains the main condition for achieving strong circular dichroism. For planar optical structures such as photonic-crystal membranes and metasurfaces, breaking of out-of-plane mirror symmetry is especially challenging, as it requires to fabricate meta-atoms with a tilt, variable height, or vertically shifted positions. Although transparent substrates formally break out-of-plane mirror symmetries, their optical effect is typically subtle being rarely considered for enhancing optical chirality. Here we reveal that low-refractive-index substrates can induce up to maximum optical chirality in otherwise achiral metastructures so that the transparency to waves of one helicity is combined with resonant blocking of waves of the opposite helicity. This effect originates from engineering twisted photonic eigenstates of different parities. Our perturbation analysis developed in terms of the resonant-state expansion reveals how the eigenstate coupling induced by a substrate gives rise to a pair of chiral resonances of opposite handedness. Our general theory is confirmed by the specific examples of light transmission in the normal and oblique directions by a rotation-symmetric photonic-crystal membrane placed on different transparent substrates.

physics.optics↗

arXiv2024

Non-Hermitian Singularities in Scattering Spectra of Mie Resonators

Non-Hermitian systems are known to possess unique singularities in the scattering spectra such as exceptional points, bound states in the continuum, Diabolic points, and anapole states, which are usually considered to be independent. Here, we demonstrate the fundamental relationships between non-Hermitian singularities and observe them experimentally in the scattering spectra. We reveal that exceptional points appear in the anapole regime, and diabolic points are associated with superscattering. We confirm our findings with microwave experiments by measuring the scattering spectra of subwavelength Mie-resonant ceramic rings. Our study underpins the generic behavior of non-Hermitian singularities in the scattering spectra of subwavelength resonators, uncovering their novel applications in non-Hermitian nonlinear optics and topological photonics.

physics.class-ph↗

arXiv2024

Collective nature of high-Q resonances in finite-size photonic metastructures

We study high quality-factor (high Q) resonances supported by periodic arrays of Mie resonators from the perspectives of both Bloch wave theory and multiple scattering theory. We reveal that, unlike a common belief, the bound states in the continuum (BICs) derived by the Bloch-wave theory do not directly determine the resonance with the highest Q value in large but finite arrays. Higher Q factors appear to be associated with collective resonances formed by nominally guided modes below the light line associated with strong effect of both electric and magnetic multipoles. Our findings offer valuable insights into accessing the modes with higher Q resonances via bonding modes within finite metastructures. Our results underpin the pivotal significance of magnetic and electric multipoles in the design of resonant metadevices and nonlocal flat-band optics. Moreover, our demonstrations reveal that coupled arrays of high-Q microcavities do not inherently result in a stronger light-matter interaction when compared to coupled low-Q nanoresonators. This result emphasizes the critical importance of the study of multiple light-scattering effects in cavity-based systems.

physics.optics↗

arXiv2024

Stabilization of molecular hydrogen-bonded chains by carbon nanotubes

We study numerically nonlinear dynamics of several types of molecular systems composed of hydrogen-bonded chains placed inside carbon nanotubes with open edges. We demonstrate that carbon nanotubes provide a stabilization mechanism for quasi-one-dimensional molecular chains via the formation of their secondary structures. In particular, a polypeptide chain (Gly)$_N$ placed inside a carbon nanotube can form of a stable helical chain ($3_{10}$, $α$, $π$ and $β$-helix) with parallel chains of hydrogen-bonded peptide groups. A chain of hydrogen fluoride molecules can form hydrogen-bonded zigzag chain. We reveal that in such geometries the hydrogen-bonded chains may remain stable even at $T=500$~K. Thus, our results suggest that the use of carbon nanotubes with encapsulated hydrogen fluoride molecules may support high proton conductivity operating at high temperatures.

cond-mat.mes-hall↗

arXiv2023

Chiral electroluminescence from thin-film perovskite metacavities

Chiral light sources realized in ultracompact device platforms are highly desirable for various applications. Among active media employed for thin-film emission devices, lead-halide perovskites have been extensively studied for photoluminescence due to their exceptional properties. However, up to date, there have been no demonstrations of chiral electroluminescence with a substantial degree of circular polarization (DCP), being critical for the development of practical devices. Here, we propose a new concept of chiral light sources based on a thin-film perovskite metacavity and experimentally demonstrate chiral electroluminescence with DCP approaching 0.38. We design a metacavity created by a metal and a dielectric metasurface supporting photonic eigenstates with close-to-maximum chiral response. Chiral cavity modes facilitate asymmetric electroluminescence of pairs of left and right circularly polarized waves propagating in the opposite oblique directions. The proposed ultracompact light sources are especially advantageous for many applications requiring chiral light beams of both helicities.

physics.optics↗

arXiv2023

Chiral organic molecular structures supported by multilayer surfaces

We study numerically the dynamics of acetanilide (ACN) molecules placed on a flat surface of a multilayer hexagonal boron nitride structure. We demonstrate that the ACN molecules, being achiral in three dimensions, become chiral after being placed on the substrate. Homochirality of the ACN molecules leads to stable secondary structures stabilized by hydrogen bonds between peptide groups of the molecules. Numerical simulations of systems of such molecules reveal that the structure of the resulting hydrogen-bond chains depends on the isomeric composition of the molecules. If all molecules are homochiral (i.e. only one isomer is present), they form secondary structures (chains of hydrogen bonds in the shapes of arcs, circles, and spirals). If the molecules at the substrate form a racemic mixture, then no regular secondary structures appear, and only curvilinear chains of hydrogen bonds of random shapes can emerge. A hydrogen-bond chain can form a straight zigzag only if it has an alternation of isomers. Such chains can create two-dimensional (2D) regular lattices, or 2D crystals. The melting scenarios of such 2D crystals depend on density of its coverage of the substrate. At 25% coverage, melting occurs continuously in a certain temperature interval. For a complete coverage, melting occurs at 415-470 K due to a shift of 11% of all molecules into the second layer of the substrate.

cond-mat.mes-hall↗

arXiv2022

Permittivity-asymmetric quasi-bound states in the continuum

Broken symmetries lie at the heart of nontrivial physical phenomena. Breaking the in-plane geometrical symmetry of optical systems allows to access a set of electromagnetic states termed symmetry-protected quasi-bound states in the continuum (qBICs). Here we demonstrate, theoretically, numerically and experimentally, that such optical states can also be accessed in metasurfaces by breaking the in-plane symmetry in the permittivity of the comprising materials, showing a remarkable equivalence to their geometrically-asymmetric counterparts. However, while the physical size of atoms imposes a limit on the lowest achievable geometrical asymmetry, weak permittivity modulations due to carrier doping and electro-optical Pockels and Kerr effects, usually considered insignificant, open up the possibility of infinitesimal permittivity asymmetries for on-demand, and dynamically tuneable optical resonances of extremely high quality factors. We probe the excitation of permittivity-asymmetric qBICs (${\varepsilon}$-qBICs) using a prototype Si/TiO$_{2}$ metasurface, in which the asymmetry in the unit cell is provided by the refractive index contrast of the dissimilar materials, surpassing any unwanted asymmetries from nanofabrication defects or angular deviations of light from normal incidence. ${\varepsilon}$-qBICs can also be excited in 1D gratings, where quality-factor enhancement and tailored interference phenomena via the interplay of geometrical and permittivity asymmetries are numerically demonstrated. The emergence of ${\varepsilon}$-qBICs in systems with broken symmetries in their permittivity may enable to test time-energy uncertainties in quantum mechanics, and lead to a whole new class of low-footprint optical and optoelectronic devices, from arbitrarily narrow filters and topological sources, biosensing and ultrastrong light-matter interaction platforms, to tuneable optical switches.

physics.optics↗

arXiv2022

Observation of intrinsic chiral bound states in the continuum

Photons with spin angular momentum possess intrinsic chirality which underpins many phenomena including nonlinear optics1, quantum optics2, topological photonics3 and chiroptics4. Intrinsic chirality is weak in natural materials, and recent theoretical proposals5-7 aimed to enlarge circular dichroism by resonant metasurfaces supporting bound states in the continuum that enhance substantially chiral light-matter interaction. Those insightful works resort to three-dimensional sophisticated geometries, which are too challenging to be realized for optical frequencies8. Therefore, most of the experimental attempts9-11 showing strong circular dichroism rely on false/extrinsic chirality by employing either oblique incidence9, 10 or structural anisotropy11. Here, we report on the experimental realization of true/intrinsic chiral response with resonant metasurfaces where the engineered slant geometry breaks both in-plane and out-of-plane symmetries. Our result marks the first observation of intrinsic chiral bound states in the continuum with near-unity chiral dichroism of 0.93 and record-high quality factor exceeding 2663 for visible frequencies. Our chiral metasurfaces promise a plethora of applications in chiral light sources and detectors, chiral sensing, valleytronics and asymmetric photocatalysis.

physics.optics↗

arXiv2022

Radial bound states in the continuum for polarization-invariant nanophotonics

All-dielectric nanophotonics underpinned by the physics of bound states in the continuum (BICs) have demonstrated breakthrough applications in nanoscale light manipulation, frequency conversion and optical sensing. Leading BIC implementations range from isolated nanoantennas with localized electromagnetic fields to symmetry-protected metasurfaces with controllable resonance quality (Q) factors. However, they either require structured light illumination with complex beam-shaping optics or large, fabrication-intense arrays of polarization-sensitive unit cells, hindering tailored nanophotonic applications and on-chip integration. Here, we introduce radial quasi bound states in the continuum (radial BICs) as a new class of radially distributed electromagnetic modes controlled by structural asymmetry in a ring of dielectric rod pair resonators. The radial BIC platform provides polarization-invariant and tunable high-Q resonances with strongly enhanced near fields in an ultracompact footprint as low as 2 $μ$m$^2$. We demonstrate radial BIC realizations in the visible for sensitive biomolecular detection and enhanced second-harmonic generation from monolayers of transition metal dichalcogenides, opening new perspectives for compact, spectrally selective, and polarization-invariant metadevices for multi-functional light-matter coupling, multiplexed sensing, and high-density on-chip photonics.

physics.optics↗

arXiv2022

Modeling of second sound in carbon nanostructures

The study of thermal transport in low-dimensional materials has attracted a lot of attention recently after discovery of high thermal conductivity of graphene. Here we study numerically phonon transport in low-dimensional carbon structures being interested in the hydrodynamic regime revealed through the observation of second sound. We demonstrate that correct numerical modeling of such two-dimensional systems requires semi-classical molecular dynamics simulations of temperature waves that take into account quantum statistics of thermalized phonons. We reveal that second sound can be attributed to the maximum group velocity of bending optical oscillations of carbon structures, and the hydrodynamic effects disappear for $T>200$K, being replaced by diffusive dynamics of thermal waves. Our numerical results suggest that the velocity of second sound in such low-dimensional structures is about 6 km/s, and the hydrodynamic effects are manifested stronger in carbon nanotubes rather than in carbon nanoribbons.

cond-mat.mes-hall↗

arXiv2022

Inverse-designed metaphotonics for hypersensitive detection

Controlling the flow of broadband electromagnetic energy at the nanoscale remains a critical challenge in optoelectronics. Surface plasmon polaritons (or plasmons) provide subwavelength localization of light, but are affected by significant losses. On the contrary, dielectrics lack a sufficiently robust response in the visible to trap photons similar to metallic structures. Overcoming these limitations appears elusive, as it implies devising a path to circumvent causality in the quantum-mechanical form of matter. Here we demonstrate that addressing this problem is possible if we employ a novel approach based on suitably deformed reflective metaphotonic structures. The complex geometrical shape engineered in these reflectors emulates nondispersive index responses, which can be inverse-designed following arbitrary form factors. We discuss the realization of essential components such as resonators with an ultra-high refractive index of $n=100$ in diverse profiles. These structures support localization of light in the form of bound states in the continuum (BIC), fully localized in air, in a platform in which all refractive index regions are physically accessible. We discuss our approach to sensing applications, designing a class of sensors where the analyte directly contacts areas of ultra-high refractive index. Leveraging this feature, we report differential sensitivities up to $350$~nm/RIU in structures with footprints of approximately one micron. These performances are two times better than the closest competitor with a similar form factor. Inversely designed reflective metaphotonics offers a flexible technology for controlling broadband light, supporting optoelectronics' integration with large bandwidths in circuitry with miniaturized footprints.

physics.optics↗

arXiv2022

Asymmetric topological pumping in nonparaxial photonics

Topological photonics was initially inspired by the quantum-optical analogy between the Schrödinger equation for an electron wavefunction and the paraxial equation for a light beam. Here, we reveal an unexpected phenomenon in topological pumping observed in arrays of nonparaxial optical waveguides where the quantum-optical analogy becomes invalid. We predict theoretically and demonstrate experimentally an asymmetric topological pumping when the injected field transfers from one side of the waveguide array to the other side whereas the reverse process is unexpectedly forbidden. Our finding could open an avenue for exploring topological photonics that enables nontrivial topological phenomena and designs in photonics driven by nonparaxiality.

physics.optics↗

arXiv2021

Planar chiral metasurfaces with maximal tunable chiroptical response driven by bound states in the continuum

Optical metasurfaces with high-Q chiral resonances can boost light-matter interaction for various applications of chiral response for ultrathin, active, and nonlinear metadevices. Usually, such metasurfaces require sophisticated depth-resolved nanofabrication to realize subwavelength stereo-nanostructures, posing overwhelming challenges, especially in the short-wavelength range. Here, we suggest a novel planar design for chiral metasurfaces supporting bound states in the continuum (BICs) and demonstrate experimentally chiroptical responses with record-high Q-factors (Q=390) and near-perfect circular dichroism (CD=0.93) at optical frequencies. The symmetry-reduced meta-atoms are highly birefringent and support winding elliptical eigen-polarizations with opposite helicity surrounding the BIC polarization singularity, providing a convenient way for achieving maximal planar chirality tuned by either breaking in-plane symmetry or changing illumination direction. Such sharply resonant chirality realized in planar metasurfaces promises various practical applications in classical and quantum optics including chiral sensing, enantiomer selection, and chiral quantum emitters.

physics.optics↗

arXiv2021

Topological Photonics on a Small Scale

The study of topological phases of light suggests novel opportunities for creating robust optical structures and on-chip photonic devices which are immune against scattering losses and structural disorder. However, many recent demonstrations of topological effects in optics employ structures with relatively large scales. Here we discuss the physics and realisation of topological photonics on small scales, with the dimensions often smaller or comparable with the wavelength of light. We highlight the recent experimental demonstrations of small-scale topological states based on arrays of resonant nanoparticles and discuss a novel photonic platform employing higher-order topological effects for creating subwavelength highly efficient topologically protected optical cavities. We pay a special attention to the recent progress on topological polaritonic structures and summarize with our vision on the future directions of nanoscale topological photonics and its impact on other fields.

physics.optics↗

arXiv2021

Superscattering Empowered by Bound States in the Continuum

We uncover a novel mechanism for superscattering of subwavelength resonators closely associated with the physics of bound states in the continuum. We demonstrate that superscattering occurs as a consequence of constructive interference driven by the Friedrich-Wintgen mechanism, and it may exceed the currently established limits for the cross-section of a single open scattering channel, within the channel itself. We develop a non-Hermitian model to describe interfering resonances of quasi-normal modes to show that this effect can only occur for scatterers violating the spherical symmetry, and therefore it cannot be predicted with the classical Mie solutions. Our results reveal unusual physics of non-Hermitian systems having important implications for functional metadevices.

physics.optics↗

arXiv2021

All-dielectric thermonanophotonics

Nanophotonics is an important branch of modern optics dealing with light-matter interaction at the nanoscale. Nanoparticles can exhibit enhanced light absorption under illumination by light, and they become nanoscale sources of heat that can be precisely controlled and manipulated. For metal nanoparticles, such effects have been studied in the framework of $\textit{thermoplasmonics}$ which, similar to plasmonics itself, has a number of limitations. Recently emerged $\textit{all-dielectric resonant nanophotonics}$ is associated with optically-induced electric and magnetic Mie resonances, and this field is developing very rapidly in the last decade. As a result, thermoplasmonics is being replaced by $\textit{all-dielectric thermonanophotonics}$ with many important applications such as photothermal cancer therapy, drug and gene delivery, nanochemistry, and photothermal imaging. This review paper aims to introduce this new field of non-plasmonic nanophotonics and discuss associated thermally-induced processes at the nanoscale.

physics.optics↗