Nonequilibrium Bounds for Canonical Nonlinearity Under Single-Shot Work
For classical discrete systems under constant composition (specifically substitutional alloys), canonical average acts as a map from a set of many-body interatomic interactions to a set of configuration in thermodynamic equilibrium, which is generally nonlinear. In terms of the configurational geometry (i.e., information about configurational density of states), the nonlinearity has been measured as special vector on configuration space, which is extended to Kullback-Leibler (KL) divergence on statistical manifold. Although they successfully provide new insight into how the geometry of lattice characterizes the nonlinearity, their application is essentially restricted to thermodynamic equilibrium. Based on the resource theory (especially, thermo-majorization), we here extend the applicability of the nonlinearity to nonequilibrium states obtained through single-shot work on Gibbs state. We reveal that the extended nonlinearity for nonequilibrium state is bounded from upper and lower by the information about one of the optimal Renyi divergences for equilibrium states in between practical and linear systems, and temperature and work.