arXiv subjects

Yves Marrocchi

Publications and source records attributed to Yves Marrocchi.

16 recordsLinked to original sources

arXiv2026

Non-equilibrium condensation of the first Solar System solids

Primitive meteorites (chondrites) consist of an out-of-equilibrium assemblage of minerals formed during the assembling of our Solar Nebula. The conditions under which their precursors condensed remain unclear as a result of subsequent re-processing in the protoplanetary disk or in asteroidal parent bodies. Chondrites are classified into three main classes enstatite (EC), ordinary (OC), and carbonaceous (CC) distinguished by different bulk composition and oxidation state. While equilibrium condensation models explain the composition of some of their refractory components they do not explain the emergence of three mineralogical classes. Moreover, the low pressures, steep temperature gradients, and short dynamical transport timescales in forming protoplanetary disks likely hindered equilibrium. Here we test the hypothesis that chondrite precursors formed via kinetic non-equilibrium condensation. Using a new time-dependent condensation model, we show that varying the cooling rate and pressure produce only three types of mineralogies. Departure from equilibrium yields increasingly oxidized and hydrous mineralogies. When projected into a Urey-Craig diagram, the predicted mineralogical types fall close to the redox states of EC, OC, and CC chondrites. These results suggest that the mineralogical diversity of chondrites may reflect, in part, local condensation kinetics, offering an alternative to large-scale variations of oxidation conditions.

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arXiv2026

A Collective Trigger for Widespread Planetesimal Formation Revealed by Accretion Ages

The formation of planetesimals was an integral part of the cascading series of processes that built the terrestrial planets. To illuminate planetesimal formation, here we develop a refined thermal evolution model to calculate the formation ages of meteorite parent planetesimals. This model includes chemical reactions and phase changes during heating, as well as natural variations in the proportions of the constituent phases of these planetesimals. We find that the parent bodies of non-carbonaceous (NC) and carbonaceous (CC) iron meteorites start forming at very similar times (~0.95 Myr after calcium-aluminium-rich inclusion [CAI] formation) and occupy overlapping time windows. NC and CC chondrite parent bodies formed later during non-overlapping periods. We combine these ages with proportions of isotopic end-members we recover from mixing models to construct records of motion throughout the protoplanetary disk. These records argue that NC and CC material traversed the barrier in the disk after ~0.95 Myr after CAI formation. The onset of this motion coincided with planetesimal formation, indicating that the phenomenon that drove motion also triggered planetesimal formation. We argue that this feature also served as the semi-permeable barrier in the disk. Although its identity is uncertain, the effects this phenomenon had on the timing of planetesimal formation and motion through the disk can now serve as constraints on models of disk evolution. Models that reproduce these effects would elucidate the nature and implications of this phenomenon, which is key to unlocking a holistic model of terrestrial planet building.

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arXiv2026

Alkali recondensation into chondrules

While sub-mm melt droplets should rapidly lose alkali elements in a vacuum at liquidus temperatures, chondrules are only modestly depleted in them (by less than one order of magnitude). The detection of sodium in olivine cores has previously suggested very high saturating partial pressures of gaseous sodium, but we show that alkalis were lost during heating and recondensed at lower temperatures, essentially in the present-day chondrule mesostases. This recondensation was accompanied by mass-dependent enrichment in light isotopes (for multi-isotope alkalis such as K and Rb), but its limited extent indicates a cooling acceleration (or "quenching"). The isotopic fractionation also constrains the ratio of the chondrule density and the cooling rate prior to the quench around $10^{-6}\:\mathrm{kg.m^{-3}.K^{-1}.h}$ suggesting densities above $\sim 10^{-6}\:\mathrm{kg/m^3}$. In a nebular context, this is achievable by radial and vertical concentrations near pressure bumps.

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arXiv2025

The refractory-to-ice ratio in comet 67P: implications on the composition of the comet-forming region of the protoplanetary disk

Comets, asteroids, and other small bodies are thought to be remnants of the original planetesimal population of the Solar System. As such, their physical, chemical, and isotopic properties hold crucial details on how and where they formed and how they evolved. Yet, placing precise constraints on the formation region of these bodies has been challenging. Data from spacecraft missions have a particularly high potential of addressing the question of the origin of the visited bodies. ESA's Rosetta mission to comet 67P/Churyumov-Gerasimenko returned data from the comet for two years on its journey around the Sun. This extensive data set has revolutionised our view on comets and still holds unsolved problems. We use the Rosetta/ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) measurement of the volatile/ice composition and the Rosetta/COSIMA (COmetary Secondary Ion Mass Analyzer) measurements of the refractory composition of comet 67P. These measurements are combined using a Monte Carlo method. The refractory-to-ice ratio is a free parameter that is constrained a posteriori. Using only the composition, we constrain the refractory-to-ice ratio to $0.5<\chi<1.7$, and derive the bulk elemental abundances for 67P of H, C, N, O, Na, Mg, Al, S, K, Ar, Ca, Cr, Mn, Fe, Kr, and Xe. We find the noble gas xenon in near solar elemental abundance in comet 67P. Krypton is slightly depleted, while argon is heavily depleted. Comet 67P is enriched in all three noble gases by up to 2.5 orders of magnitude compared to CI chondrites. We show this is consistent with a formation region between 25 and 35 au in a protoplanetary disk region with temperatures between 30 and 40 K and with the trapping of dust for a long time in rings of the protoplanetary disk.

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arXiv2024

Formation and evolution of a protoplanetary disk: combining observations, simulations and cosmochemical constraints

We present a plausible and coherent view of the evolution of the protosolar disk that is consistent with the cosmochemical constraints and compatible with observations of other protoplanetary disks and sophisticated numerical simulations. The evidence that high-temperature condensates, CAIs and AOAs, formed near the protosun before being transported to the outer disk can be explained by either an early phase of vigorous radial spreading of the disk, or fast transport of these condensates from the vicinity of the protosun towards large disk radii via the protostellar outflow. The assumption that the material accreted towards the end of the infall phase was isotopically distinct allows us to explain the observed dichotomy in nucleosynthetic isotopic anomalies of meteorites and leads to intriguing predictions on the isotopic composition of refractory elements in comets. When the infall of material waned, the disk started to evolve as an accretion disk. Initially, dust drifted inwards, shrinking the radius of the dust component to ~ 45 au, probably about 1/2 of the width of the gas component. Then structures must have emerged, producing a series of pressure maxima in the disk which trapped the dust on My timescales. This allowed planetesimals to form at radically distinct times without changing significantly of isotopic properties. There was no late accretion of material onto the disk via streamers. The disk disappeared in ~5 Myr, as indicated by paleomagnetic data in meteorites. In conclusion, the evolution of the protosolar disk seems to have been quite typical in terms of size, lifetime, and dust behavior, suggesting that the peculiarities of the Solar system with respect to extrasolar planetary system probably originate from the chaotic nature of planet formation and not at the level of the parental disk.

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arXiv2024

Condensate evolution in the solar nebula inferred from combined Cr, Ti, and O isotope analyses of amoeboid olivine aggregates

Refractory inclusions in chondritic meteorites, namely amoeboid olivine aggregates (AOAs) and Ca-Al-rich inclusions (CAIs), are among the first solids to have formed in the solar system. The isotopic composition of CAIs is distinct from bulk meteorites, which either results from extreme processing of presolar carriers in the CAI-forming region, or reflects an inherited heterogeneity from the Sun's parental molecular cloud. Amoeboid olivine aggregates are less refractory than CAIs and provide a record of how the isotopic composition of solid material in the disk may have changed in time and space. However, the isotopic composition of AOAs and how this composition relates to that of CAIs and later-formed solids is unknown. Here, using new O, Ti, and Cr isotopic data for eight AOAs from the Allende CV3 chondrite, we show that CAIs and AOAs share a common isotopic composition, indicating a close genetic link and formation from the same isotopic reservoir. Because AOAs are less refractory than CAIs, this observation is difficult to reconcile with a thermal processing origin of the isotope anomalies. Instead, the common isotopic composition of CAIs and AOAs is readily accounted for in a model in which the isotopic composition of infalling material from the Sun's parental molecular cloud changed over time. In this model, CAIs and AOAs record the isotopic composition of the early infall, while later-formed solids contain a larger fraction of the later, isotopically distinct infall. This model implies that CAIs and AOAs record the isotopic composition of the Sun and suggests that the nucleosynthetic isotope heterogeneity of the solar system is predominantly produced by mixing of solar nebula condensates, which acquired their distinct isotopic compositions as a result of time-varied infall from the protosolar cloud.

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arXiv2023

Gaia search for early-formed andesitic asteroidal crusts

Context. Andesitic meteorites are among the oldest achondrites known to date. They record volcanic events and crust formation episodes in primordial planetesimals that took place about 4.565 Myr ago. However, no analogue for these meteorites has been found in the asteroid population to date. Aims. We searched for spectroscopic analogues of the andesitic meteorite Erg Chech 002 in the asteroid population using the Gaia DR3 spectral dataset. Methods. In order to identify which asteroids have the most similar spectrum to Erg Chech 002, we first determined the spectral parameters of Gaia DR3 asteroids (spectral slope and Band I depth) and compared them to the spectral parameters of different samples of the meteorite. In addition, we performed a spectral curve matching between Erg Chech 002 and Gaia DR3 asteroid data, and we compared the results of both methods. Results. We found that 51 main-belt asteroids have a visible spectrum similar to the one of Erg Chech 002, and 91 have a spectrum similar to the space-weathered spectra of the meteorite, corresponding to 0.08 and 0.15% of the whole Gaia DR3 dataset of asteroids with spectra, respectively. The asteroids that best match the laboratory samples of the meteorite are mostly located in the inner main belt, while the objects matching the space-weathered meteorite models show slightly more scattering across the belt. Conclusions. Despite the fact that we find asteroids that potentially match Erg Chech 002, these asteroids are extremely rare. Moreover, a visible spectrum alone is not completely diagnostic of an Erg Chech 002-like composition. Near-infrared spectra will be important to confirm (or rule out) the spectral matches between Erg Chech 002 and the candidate asteroid population.

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arXiv2021

Constraints on planetesimal accretion inferred from particle-size distribution in CO chondrites

The formation of planetesimals was a key step in the assemblage of planetary bodies, yet many aspects of their formation remain poorly constrained. Notably, the mechanism by which chondrules -- sub-millimetric spheroids that dominate primitive meteorites -- were incorporated into planetesimals remains poorly understood. Here we classify and analyze particle-size distributions in various CO carbonaceous chondrites found in the Atacama Desert. Our results show that the average circle-equivalent diameters of chondrules define a positive trend with the petrographic grade, which reflects the progressive role of thermal metamorphism within the CO parent body. We show that this relationship could not have been established by thermal metamorphism alone but rather by aerodynamic sorting during accretion. By modeling the self-gravitational contraction of clumps of chondrules, we show that (i) the accretion of the CO parent body(ies) would have generated a gradual change of chondrule size with depth in the parent body, with larger chondrules being more centrally concentrated than smaller ones, and (ii) any subsequent growth by pebble accretion would have been insignificant. These findings give substantial support to the view that planetesimals formed via gravitational collapse.

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arXiv2021

Origin of hydrogen isotopic variations in chondritic water and organics

Chondrites are rocky fragments of asteroids that formed at different times and heliocentric distances in the early solar system. Most chondrite groups contain water-bearing minerals, attesting that both water-ice and dust were accreted on their parent asteroids. Nonetheless, the hydrogen isotopic composition (D/H) of water in the different chondrite groups remains poorly constrained, due to the intimate mixture of hydrated minerals and organic compounds, the other main H-bearing phase in chondrites. Building on our recent works using in situ secondary ion mass spectrometry analyses, we determined the H isotopic composition of water in a large set of chondritic samples (CI, CM, CO, CR, and C-ungrouped carbonaceous chondrites) and report that water in each group shows a distinct and unique D/H signature. Based on a comparison with literature data on bulk chondrites and their water and organics, our data do not support a preponderant role of parent-body processes in controlling the D/H variations among chondrites. Instead, we propose that the water and organic D/H signatures were mostly shaped by interactions between the protoplanetary disk and the molecular cloud that episodically fed the disk over several million years. Because the preservation of D-rich interstellar water and/or organics in chondritic materials is only possible below their respective sublimation temperatures (160 and 350-450 K), the H isotopic signatures of chondritic materials depend on both the timing and location at which their parent body formed.

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arXiv2021

Origin of isolated olivine grains in carbonaceous chondrites

We report microscopic, cathodoluminescence, chemical and O isotopic measurements of FeO-poor isolated olivine grains (IOG) in the carbonaceous chondrites Allende (CV3), Northwest Africa 5958 (C2-ung), Northwest Africa 11086 (CM2-an), Allan Hills 77307 (CO3.0). The general petrographic, chemical and isotopic similarity with bona fide type I chondrules confirms that the IOG derived from them. The concentric CL zoning, reflecting a decrease in refractory elements toward the margins, and frequent rimming by enstatite are taken as evidence of interaction of the IOG with the gas as stand-alone objects. This indicates that they were splashed out of chondrules when these were still partially molten. CaO-rich refractory forsterites, which are restricted to $Δ^{17}O < -4\permil$ likely escaped equilibration at lower temperatures because of their large size and possibly quicker quenching. The IOG thus bear witness to frequent collisions in the chondrule-forming regions.

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arXiv2020

Early evolution of the solar accretion disk inferred from Cr-Ti-O isotopes in individual chondrules

Isotopic anomalies in chondrules hold important clues about the dynamics of mixing and transport processes in the solar accretion disk. These anomalies have been interpreted to indicate either disk-wide transport of chondrules or local heterogeneities of chondrule precursors. However, all previous studies relied on isotopic data for a single element (either Cr, Ti, or O), which does not allow distinguishing between source and precursor signatures as the cause of the chondrules isotope anomalies. Here we obtained the first combined O, Ti, and Cr isotope data for individual chondrules from enstatite, ordinary, and carbonaceous chondrites. We find that chondrules from non-carbonaceous (NC) chondrites have relatively homogeneous Δ17O, ε50Ti, and ε54Cr, which are similar to the compositions of their host chondrites. By contrast, chondrules from carbonaceous chondrites (CC) have more variable compositions. Although the compositions of the analyzed CC and NC chondrules may overlap for either ε50Ti, ε54Cr, or Δ17O, in multi-isotope space none of the CC chondrules plot in the compositional field of NC chondrites, and no NC chondrule plots within the field of CC chondrites. As such, our data reveal a fundamental isotopic difference between NC and CC chondrules, which is inconsistent with a disk-wide transport of chondrules across and between the NC and CC reservoirs. Instead, the isotopic variations among CC chondrules reflect local precursor heterogeneities, which most likely result from mixing between NC-like dust and a chemically diverse dust component that was isotopically similar to CAIs and AOAs.The same mixing processes, but on a larger, disk-wide scale, were likely responsible for establishing the distinct isotopic compositions of the NC and CC reservoirs, which represent in inner and outer disk, respectively.

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arXiv2018

Chondrule heritage and thermal histories from trace element and oxygen isotope analyses of chondrules and amoeboid olivine aggregates

We report combined oxygen isotope and mineral-scale trace element analyses of amoeboid olivine aggregates (AOA) and chondrules in ungrouped carbonaceous chondrite Northwest Africa 5958. The trace element geochemistry of olivine in AOA, for the first time measured by LA-ICP-MS, is consistent with a condensation origin although the shallow slope of its rare earth element (REE) pattern has yet to be physically explained. Ferromagnesian silicates in type I chondrules resemble those in other carbonaceous chondrites both geochemically and isotopically, and we find a correlation between 16O enrichment and many incompatible elements in olivine. The variation in incompatible element concentrations may relate to varying amounts of olivine crystallization during a sub-isothermal stage of chondrule-forming events, the duration of which may be anticorrelated with the local solid/gas ratio if this was the determinant of oxygen isotopic ratios as recently proposed. While aqueous alteration has depleted many chondrule mesostases in REE, some chondrules show recognizable subdued group II-like patterns supporting the idea that the immediate precursors of chondrules were nebular condensates.

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arXiv2016

Magmatic sulfides in the porphyritic chondrules of EH enstatite chondrites

The nature and distribution of sulfides within 17 porphyritic chondrules of the Sahara 97096 EH3 enstatite chondrite have been studied by backscattered electron microscopy and electron microprobe in order to investigate the role of gas-melt interactions in the chondrule sulfide formation. Troilite (FeS) is systematically present and is the most abundant sulfide within the EH3 chondrite chondrules. It is found either poikilitically enclosed in low-Ca pyroxenes or scattered within the glassy mesostasis. Oldhamite (CaS) and niningerite [(Mg,Fe,Mn)S] are present in about 60% of the chondrules studied. While oldhamite is preferentially present in the mesostasis, niningerite associated with silica is generally observed in contact with troilite and low-Ca pyroxene. The chondrule mesostases contain high abundances of alkali and volatile elements as well as silica. Our data suggest that most of the sulfides found in EH3 chondrite chondrules are magmatic minerals that formed after the dissolution of S from a volatile-rich gaseous environment into the molten chondrules. Troilite formation occurred via sulfur solubility within Fe-poor chondrule melts followed by sulfide saturation, which causes an immiscible iron sulfide liquid to separate from the silicate melt. The FeS saturation started at the same time as or prior to the crystallization of low-Ca pyroxene during the high temperature chondrule forming event(s). Protracted gas-melt interactions under high partial pressures of S and SiO led to the formation of niningerite-silica associations via destabilization of the previously formed FeS and low-Ca pyroxene. We also propose that formation of the oldhamite occurred via the sulfide saturation of Fe-poor chondrule melts at moderate S concentration due to the high degree of polymerization and the high Na-content of the chondrule melts, which allowed the activity of CaO in the melt to be enhanced.

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arXiv2015

Multiple carriers of Q noble gases in primitive meteorites

The main carrier of primordial heavy noble gases in chondrites is thought to be an organic phase, known as phase Q, whose precise characterization has resisted decades of investigation. Indirect techniques have revealed that phase Q might be composed of two subphases, one of them associated with sulfide. Here we provide experimental evidence that noble gases trapped within meteoritic sulfides present chemically- and thermally-driven behavior patterns that are similar to Q-gases. We therefore suggest that phase Q is likely composed of two subcomponents: carbonaceous phases and sulfides. In situ decay of iodine at concentrations levels consistent with those reported for meteoritic sulfides can reproduce the 129Xe excess observed for Q-gases relative to fractionated Solar Wind. We suggest that the Q-bearing sulfides formed at high temperature and could have recorded the conditions that prevailed in the chondrule-forming region(s).

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arXiv2015

Structure, composition, and location of organic matter in the enstatite chondrite Sahara 97096 (EH3)

The insoluble organic matter (IOM) of an unequilibrated enstatite chondrite Sahara (SAH) 97096 has been investigated using a battery of analytical techniques. As the enstatite chondrites are thought to have formed in a reduced environment at higher temperatures than carbonaceous chondrites, they constitute an interesting comparative material to test the heterogeneities of the IOM in the solar system and to constrain the processes that could affect IOM during solar system evolution. The SAH 97096 IOM is found in situ: as submicrometer grains in the network of fine-grained matrix occurring mostly around chondrules and as inclusions in metallic nodules, where the carbonaceous matter appears to be more graphitized. IOM in these two settings has very similar $δ^{15}N$ and $δ^{13}C$; this supports the idea that graphitized inclusions in metal could be formed by metal catalytic graphitization of matrix IOM. A detailed comparison between the IOM extracted from a fresh part and a terrestrially weathered part of SAH 97096 shows the similarity between both IOM samples in spite of the high degree of mineral alteration in the latter. The isolated IOM exhibits a heterogeneous polyaromatic macromolecular structure, sometimes highly graphitized, without any detectable free radicals and deuterium-heterogeneity and having mean H- and N-isotopic compositions in the range of values observed for carbonaceous chondrites. It contains some submicrometer-sized areas highly enriched in $^{15}N$ ($δ^{15}N$ up to 1600 permil). These observations reinforce the idea that the IOM found in carbonaceous chondrites is a common component widespread in the solar system. Most of the features of SAH 97096 IOM could be explained by the thermal modification of this main component.

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arXiv2014

Nitrogen isotopic fractionation during abiotic synthesis of organic solid particles

The formation of organic compounds is generally assumed to result from abiotic processes in the Solar System, with the exception of biogenic organics on Earth. Nitrogen-bearing organics are of particular interest, notably for prebiotic perspectives but also for overall comprehension of organic formation in the young solar system and in planetary atmospheres. We have investigated abiotic synthesis of organics upon plasma discharge, with special attention to N isotope fractionation. Organic aerosols were synthesized from N2-CH4 and N2-CO gaseous mixtures using low-pressure plasma discharge experiments, aimed at simulating chemistry occurring in Titan s atmosphere and in the protosolar nebula, respectively. Nitrogen is efficiently incorporated into the synthesized solids, independently of the oxidation degree, of the N2 content of the starting gas mixture, and of the nitrogen speciation in the aerosols. The aerosols are depleted in 15N by 15-25 permil relative to the initial N2 gas, whatever the experimental setup is. Such an isotopic fractionation is attributed to mass-dependent kinetic effect(s). Nitrogen isotope fractionation upon electric discharge cannot account for the large N isotope variations observed among solar system objects and reservoirs. Extreme N isotope signatures in the solar system are more likely the result of self-shielding during N2 photodissociation, exotic effect during photodissociation of N2 and/or low temperature ion-molecule isotope exchange. Kinetic N isotope fractionation may play a significant role in the Titan s atmosphere. We also suggest that the low delta15N values of Archaean organic matter are partly the result of abiotic synthesis of organics that occurred at that time.

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