arXiv subjects

Zelong Wang

Publications and source records attributed to Zelong Wang.

7 recordsLinked to original sources

arXiv2026

Superconducting Hydride Mg2RhH6 Experimentally Achieved at Lower Pressure

Although tremendous progress has been made in recent years in the field of polyhydride superconductors, the realization of high critical temperature superconductivity still relies on formidable high pressures. Searching for superconducting hydrides at lower pressures is of particular importance. Here we report the first experimental synthesis of the Mg2RhH6, which achieves superconductivity under a significantly reduced pressure of 30 GPa. The synthesis of Mg2RhH6 proceeds via a two step process (1) preparation of the Mg2RhH5 precursor containing hydrogen atoms stabilized by covalent bonds, followed by (2) hydrogen supplementation resulting in the filling of electrons into anti bonding orbitals above 30 GPa, which was accompanied by the structural transition from RhH5 square pyramid to RhH6 octahedron. Superconductivity is achieved at 30 GPa with a Tc of 24 K, which is further enhanced to 29 K at 53 GPa, evidenced by a sharp drop of resistivity to zero and characteristic suppression of Tc under applied magnetic fields. Our experiments prove the Mg2RhH6 superconductor to be thermodynamically stable above 30 GPa, making it the first case exhibiting a Tc of approximately 30 K at a readily accessible pressure. This study pioneers a highly promising pathway for the rational design and discovery of high temperature superconductors within phonon mediated BCS framework.

cond-mat.supr-con↗

arXiv2026

Breaking the Tokenizer Barrier: On-Policy Distillation across Model Families

On-Policy Distillation (OPD) has become a core technique in the post-training of Large Language Models (LLMs) for transferring knowledge from domain experts to student models. However, existing OPD distillation methods require teacher and student models to share the same tokenizer, restricting the applicability of OPD within the model series. Current mainstream practice typically employs Supervised Fine-Tuning (SFT) on teacher-generated responses for cross-tokenizer distillation, which fails to capture the rich knowledge embedded in the teacher's probability distribution. In this work, we enable the standard on-policy distillation method to operate across model families, ensuring that high-fidelity token-level signals can propagate across different tokenizers with a precise token-mapping algorithm. Extensive experiments show that cross-tokenizer OPD is significantly more compute-efficient than baselines on various benchmarks. Our results unlock a broader range of teacher-student pairs for OPD, opening up new avenues for adapting and enhancing interactions between LLMs.

cs.LG↗

arXiv2025

Read Before You Think: Mitigating LLM Comprehension Failures with Step-by-Step Reading

Large Language Models (LLMs) often fail on complex reasoning tasks due to flawed question comprehension, not just flawed logic. This paper presents a systematic investigation into these comprehension failures. Our work yields three key insights: (1) the step-by-step principle, effective for calculation, can be migrated to the reading process to enhance comprehension; (2) increasing the proportion of question-related tokens (e.g., via repetition) succeeds by refocusing attention, a mechanism that can be explicitly controlled; and (3) backward dependencies represent a core bottleneck for decoder-only models that persists even with strong methods like Chain-of-Thought. Based on these findings, we introduce the Step-by-Step Reading (SSR) family of prompts. This multi-stage approach culminates in SSR++, a method specifically engineered to deepen model comprehension by guiding it to parse questions with finer granularity, focus attention on critical tokens, and resolve backward dependencies through iterative re-contextualization. SSR++ sets a new state-of-the-art on multiple reasoning benchmarks, and our analysis confirms it works by directly mitigating semantic misunderstanding. These results demonstrate that guiding how a model reads is a powerful and efficient method for improving its reasoning ability.

cs.CL↗

arXiv2024

One Pot Synthesis of Cubic Gauche Polymeric Nitrogen

The long sought cubic gauche polymeric nitrogen (cg-N) consisting of N-N single bonds has been synthesized by a simple route using sodium azide as a precursor at ambient conditions. The recrystallization process was designed to expose crystal faces with low activation energy that facilitates initiating the polymeric reaction at ambient conditions. The azide was considered as a precursor due to the low energy barrier in transforming double bonded N=N to single bonded cg-N. Raman spectrum measurements detected the emerging vibron peaks at 635 cm-1 for the polymerized sodium azide samples, demonstrating the formation of cg-N with N-N single bonds. Different from traditional high pressure technique and recently developed plasma enhanced chemical vapor deposition method, the route achieves the quantitative synthesis of cg-N at ambient conditions. The simple method to synthesize cg-N offers potential for further scale up production as well as practical applications of polymeric nitrogen based materials as high energy density materials.

cond-mat.mtrl-sci↗

arXiv2024

Training Agents with Weakly Supervised Feedback from Large Language Models

Large Language Models (LLMs) offer a promising basis for creating agents that can tackle complex tasks through iterative environmental interaction. Existing methods either require these agents to mimic expert-provided trajectories or rely on definitive environmental feedback for reinforcement learning which limits their application to specific scenarios like gaming or code generation. This paper introduces a novel training method for LLM-based agents using weakly supervised signals from a critic LLM, bypassing the need for expert trajectories or definitive feedback. Our agents are trained in iterative manner, where they initially generate trajectories through environmental interaction. Subsequently, a critic LLM selects a subset of good trajectories, which are then used to update the agents, enabling them to generate improved trajectories in the next iteration. Extensive tests on the API-bank dataset show consistent improvement in our agents' capabilities and comparable performance to GPT-4, despite using open-source models with much fewer parameters.

cs.CL↗

arXiv2024

A facile route to synthesize cubic gauche polymeric nitrogen

In this work, the long-sought cg-N with N-N single bond has been synthesized for the first time by a thermal-driven-only chemical route at ambient conditions. The successful synthesis of cg-N was achieved by first creating a solution of azides, which was then pretreated under vacuum conditions. Following the pretreatment, the resultant concentrated azide was heated at temperatures ranging from 260°C to 330°C for a reaction time of 3 hours, ultimately leading to the formation of cg-N. The emergent intense Raman peak characterized of cg-N provides solid evidence that the double bonded nitrogen-nitrogen transforms into a single bond form, which agrees well with cg-N structure. To date, this is the only work achieving the quantity of cg-N synthesized at ambient conditions by a facile route that can be further developed for the scalable synthesis and applications of polymerized nitrogen-based materials as high energy density materials.

cond-mat.mtrl-sci↗

arXiv2019

Deep CNN frameworks comparison for malaria diagnosis

We compare Deep Convolutional Neural Networks (DCNN) frameworks, namely AlexNet and VGGNet, for the classification of healthy and malaria-infected cells in large, grayscale, low quality and low resolution microscopic images, in the case only a small training set is available. Experimental results deliver promising results on the path to quick, automatic and precise classification in unstained images.

eess.IV↗