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Zheng Li

Publications and source records attributed to Zheng Li.

475 records · Page 27Linked to original sources

Spectrum standardization for laser-induced breakdown spectroscopy measurements

This paper presents a spectra normalization method for laser-induced breakdown spectroscopy (LIBS) measurements by converting the recorded characteristic line intensity at varying conditions to the intensity under a standard condition with standard plasma temperature, degree of ionization, and total number density of the interested species to reduce the measurement uncertainty. The characteristic line intensities of the interested species are first converted to the intensity at a fixed temperature and standard degree of ionization but varying total number density for each laser pulse analysis. Under this state, if the influence of the variation of plasma morphology is neglected, the sum of multiple spectral line intensities for the measured element can be regarded proportional to the total number density of the specific element, and the fluctuation of the total number density, or the variation of ablation mass, was compensated for by the application of this relationship. In the experiments with 29 brass alloy samples, the application of this method to determine Cu concentration shows a significant improvement over generally applied normalization method for measurement precision and accuracy. The average RSD value, average value of the error bar, R2, RMSEP, and average value of the maximum relative error were: 5.29%, 0.68%, 0.98, 2.72%, 16.97%, respectively, while the above parameter values for normalization with the whole spectrum area were: 8.61%, 1.37%, 0.95, 3.28%, 29.19%, respectively.

physics.plasm-ph↗

Bed-inventory Overturn Mechanism for Pant-leg Circulating Fluidized Bed Boilers

A numerical model was established to investigate the lateral mass transfer as well as the mechanism of bed-inventory overturn inside a pant-leg circulating fluidized bed (CFB), which are of great importance to maintain safe and efficient operation of the CFB. Results show that the special flow structure in which the solid particle volume fraction along the central line of the pant-leg CFB is relative high enlarges the lateral mass transfer rate and make it more possible for bed inventory overturn. Although the lateral pressure difference generated from lateral mass transfer inhibits continuing lateral mass transfer, providing the pant-leg CFB with self-balancing ability to some extent, the primary flow rate change due to the outlet pressure change often disable the self-balancing ability by continually enhancing the flow rate difference. As the flow rate of the primary air fan is more sensitive to its outlet pressure, it is easier to lead to bed inventory overturn. While when the solid particle is easier to change its flow patter to follow the surrounding air flow,the self-balancing ability is more active.

physics.flu-dyn↗

A Novel Multivariate Model Based on Dominant Factor for Laser-induced Breakdown Spectroscopy Measurements

This paper presents a new approach of applying partial least squares method combined with a physical principle based dominant factor. The characteristic line intensity of the specific element was taken to build up the dominant factor to reflect the major elemental concentration and partial least squares (PLS) approach was then applied to further improve the model accuracy. The deviation evolution of characteristic line intensity from the ideal condition was depicted and according to the deviation understanding, efforts were taken to model the non-linear self-absorption and inter-element interference effects to improve the accuracy of dominant factor model. With a dominant factor to carry the main quantitative information, the novel multivariate model combines advantages of both the conventional univariate and PLS models and partially avoids the overuse of the unrelated noise in the spectrum for PLS application. The dominant factor makes the combination model more robust over a wide concentration range and PLS application improves the model accuracy for samples with matrices within the calibration sample set. Results show that RMSEP of the final dominant factor based PLS model decreased to 2.33% from 5.25% when using the conventional PLS approach with full spectral information. Furthermore, with the development in understanding the physics of the laser-induced plasma, there is potential to easily improve the accuracy of the dominant factor model as well as the proposed novel multivariate model.

physics.optics↗

Optimal effective current operator for flux qubit accounting for inductive effects

An optimal effective current operator for flux qubit has been investigated by taking account of the inductive effects of the circuit loop. The whole system is treated as two interacting subsystems: one is the inductance-free flux qubit consisting of three Josephson junctions and the other a high frequency LC-oscillator. As the composite system hardly affords one excessively high energy LC photon, an effective theory for the inductive flux qubit providing its physical variable operators has been achieved, which can take account of the inductive effects but does not include the additional degree of freedom for the LC-oscillator. Considering the trade-off between simplicity and accuracy, it has been revealed that the optimal effective current operator resulting in an error only on the order of $L^{3/2}$ provides an approximation of high accuracy, which is also verified numerically.

cond-mat.supr-con↗

Magnetic-Field-Dependent Raman Scattering in Multiferroic Bilayer Films: Evidence for Stress-Mediated Magnetoelectric Coupling

We report the first magnetic-field-dependent Raman scattering studies on Pb(Zr,Ti)O3-CoFe2O4 bilayer multiferroic system. The phonon frequencies of the nano-bilayers obviously change with magnetic field, which is absent in the single Pb(Zr,Ti)O3 films. The magnetostriction of the CoFe2O4 layer generates stress mechanically transferred to the Pb(Zr,Ti)O3 layer, resulting in the mode changes. The observed magnetic-field-induced softening of the soft mode in the Pb(Zr,Ti)O3 layer bears a striking resemblance to direct magnetoelectric output in the bilayers, providing evidence for stress-mediated magnetoelectric coupling mechanism in the multiferroic bi-layers.

cond-mat.mtrl-sci↗

Numerical simulation of leakage effect for quantum NOT operation on three-Josephson-junction flux qubit

Superconducting flux qubits with three Josephson junctions are promising candidates for the building blocks of a quantum computer. We have applied the imaginary time evolution method to study the model of this qubit accurately by calculating its wave functions and eigenenergies. Because such qubits are manipulated with magnetic flux microwave pulses they might be irradiated into non-computational states which is called the leakage effect. Through the evolution of the density matrix of the qubit under either hard-shaped pulse or Gaussian-shaped pulse to carry out quantum NOT operation, we show that the leakage effect is not a serious problem for a flux qubit.

cond-mat.supr-con↗

Diagonalizing the Hamiltonian of capacitively coupled superconducting phase qubits

Coupling qubits together towards large-scale integration is a key point for realizing a quantum computer. We study the capacitively coupled superconducting phase qubits using two diagonalization methods, which are very efficient to obtain the wave functions and energies of the bound states of such two-qubit system. The first diagonalization method is based on two-dimensional cubic approximation for the coupled system with wave functions of the eigenstates for harmonic oscillators as the bases of diagonalization, and also reveals the physics underlying it. The other one utilizes the Fast Fourier Transform to perform diagonalization with plane waves as the bases, and it can be easily extended to other problems with even high dimension.

cond-mat.supr-con↗