arXiv subjects

Zhengbo Yang

Publications and source records attributed to Zhengbo Yang.

6 recordsLinked to original sources

arXiv2026

Seasonal Variability of Pluto's Haze Formation Revealed by Laboratory Simulations

Pluto possesses a thin atmosphere primarily composed of N2, with minor constituents including CO and CH4. Photochemical processes generate distinct haze layers as observed by the New Horizons spacecraft. However, the mechanisms governing haze formation, as well as the composition and physical properties of the hazes, remain poorly constrained. Due to Pluto's highly eccentric orbit and obliquity, its surface temperature and atmospheric composition undergo substantial seasonal variations, but it is unclear how such seasonal variations impact the chemical pathways and efficiency of haze formation in Pluto's atmosphere. To address this, we conducted a laboratory simulation of Pluto's atmospheric photochemistry, in which N2/CH4/CO gas mixtures with CH4 concentrations varying from 0.1% to 5% were exposed to a glow discharge to initiate photochemical reactions. Gas-phase composition was monitored in situ using a residual gas analyzer (RGA), while the solid-phase products were characterized by atomic force microscopy (AFM), a gas pycnometer, infrared spectroscopy (IR), and very high-resolution mass spectrometry (VHRMS) to determine particle sizes, density, and composition, respectively. Our results show that increasing the CH4 mixing ratio significantly enhances the yield of gas and solid products. Under low CH4 conditions, nitrogen is primarily incorporated into solids as cyanide groups; whereas CH4-rich conditions favor the formation of amino groups, greatly promoting nitrogen incorporation into organic solids. These findings not only shed light on how seasonal variations into Pluto's atmosphere composition influence haze formation pathways, but also provide critical parameters to interpret observational data and to improve photochemical and microphysical models of planetary hazes.

astro-ph.EP↗

arXiv2026

Influence of CO versus CH$_4$ on organic haze formation in atmospheres of diverse terrestrial exoplanets

Context. Terrestrial exoplanets are expected to host secondary, high-metallicity atmospheres derived from outgassing of volatiles such as N2, CO2, H2O, CH4, and CO. Photochemical organic hazes are likely to form in such environments, significantly affecting atmospheric observations and planetary habitability. Aims. We investigate haze formation in representative terrestrial exoplanet atmospheres and assess how CH4 versus CO as the primary carbon source affects haze production rates, particle properties, and chemical complexity. Methods. We performed six laboratory simulations by exposing gas mixtures at a few mbar to glow discharge at 300 K. Each atmosphere contained 75% N2, CO2, or H2O, 10% of each of the other two gases, and 5% CH4 or CO. Gas-phase products were analyzed with a residual gas analyzer, and solid products were characterized by production rate, particle density, atomic force microscopy, Fourier-transform infrared spectroscopy, and very high-resolution mass spectrometry. Results. CH4 experiments produced more diverse gas-phase species and much higher haze yields than the corresponding CO experiments. CO-derived hazes showed a narrow particle size range of 10-80 nm, whereas CH4-derived hazes were denser and chemically more complex. The identified molecular formulas suggest growth pathways linked to gaseous precursors such as HCN, CH2O, and C2H4. Conclusions. The atmospheric redox state critically controls haze formation in simulated terrestrial exoplanet atmospheres. CH4 is significantly more effective than CO in initiating organic growth, leading to higher haze production rates and greater chemical complexity. These results provide useful constraints for exoplanet atmospheric modeling and spectral interpretation, and further support the possibility that reducing atmospheres may facilitate prebiotic organic chemistry relevant to the emergence of life.

astro-ph.EP↗

arXiv2026

Quantifying Building Blocks of Life in Planetary Analog Materials: Implications for Prebiotic Chemistry and Biosignature Identification

Building blocks of life such as amino acids, nucleobases, and fatty acids are central to prebiotic chemistry and represent key targets in the search for planetary biosignatures. In planetary materials, biomolecules typically occur at trace levels within complex matrices, posing substantial analytical challenges, particularly for quantitative characterization. Here we develop a gas chromatography tandem mass spectrometry method that enables robust qualitative and quantitative analysis of 56 prebiotically relevant molecules. The method is applied to a Titan aerosol analog and, for the first time, to a Martian gypsum analog from the Qaidam Basin, revealing diverse inventories of amino acids, nucleobases, and fatty acids in both samples. In the Titan aerosol analog, the first detection of phenylalanine and an extensive inventory of fatty acids, together with elevated nucleobase abundances, offers new insights into atmospheric photochemical synthesis of prebiotic molecules. In the Martian analog sample, amino acids are detectable and exhibit pronounced biotic abiotic contrasts in abundance patterns relative to those observed in the Titan aerosol analog, whereas fatty acids show more overlapping abiotic and biotic signatures, highlighting the potential of amino acids as robust biosignatures. These results provide quantitative constraints on prebiotic chemical evolution and underscore the utility of GC-MS-MS for biosignature identification in planetary exploration.

astro-ph.EP↗

arXiv2025

The impact of organic hazes and graphite on the observation of CO2-rich sub-Neptune atmospheres

Many sub-Neptune and super-Earth exoplanets are expected to develop metal-enriched atmospheres due to atmospheric loss processes such as photoevaporation or core-powered mass loss. Thermochemical equilibrium calculations predict that at high metallicity and a temperature range of 300-700 K, CO2 becomes the dominant carbon species, and graphite may be the thermodynamically favored condensate under low-pressure conditions. Building on prior laboratory findings that such environments yield organic haze rather than graphite, we measured the transmittance spectra of organic haze analogues and graphite samples, and computed their optical constants across the measured wavelength range from 0.4 to 25 μm. The organic haze exhibits strong vibrational absorption bands, notably at 3.0, 4.5, and 6.0 μm, while graphite shows featureless broadband absorption. The derived optical constants of haze and graphite provide the first dataset for organic haze analogues formed in CO2-rich atmospheres and offer improved applicability over prior graphite data derived from bulk reflectance or ellipsometry. We implemented these optical constants into the Virga and PICASO cloud and radiative transfer models to simulate transit spectra for GJ 1214b. The synthetic spectra with organic hazes reproduce the muted spectral features in the NIR observed by Hubble and general trends observed by JWST for GJ 1214b, while graphite models yield flat spectra across the observed wavelengths. This suggests haze features may serve as observational markers of carbon-rich atmospheres, whereas graphite's opacity could lead to radius overestimation, offering a possible explanation for super-puff exoplanets. Our work supplies essential optical to infrared data for interpreting observations of CO2-rich exoplanet atmospheres.

astro-ph.EP↗

arXiv2025

Formation of organic hazes in CO$_2$-rich sub-Neptune atmospheres within the graphite-stability regime

Super-Earths and sub-Neptunes are the most common exoplanets, with a "radius valley" suggesting that super-Earths may form by shedding sub-Neptunes' gaseous envelopes. Exoplanets that lie closer to the super-Earth side of the valley are more likely to have lost a significant fraction of their original H/He envelopes and become enriched in heavier elements with CO$_2$ gaining in abundance. It remains unclear which types of haze would form in such atmospheres, potentially significantly affecting spectroscopic observations. To investigate this, we performed laboratory simulations of two CO$_2$-rich gas mixtures (with 2000 times solar metallicity at 300 K and 500 K). We found that under plasma irradiation, organic hazes were produced at both temperatures with higher haze production rate at 300 K probably because condensation occurs more readily at lower temperature. Gas-phase analysis demonstrates the formation of various hydrocarbons, oxygen- and nitrogen-containing species, including reactive gas precursors like C$_2$H$_4$, CH$_2$O, and HCN, for haze formation. The compositional analysis of the haze particles reveals various functional groups and molecular formulas in both samples. The 500 K haze sample has larger average molecular sizes, higher degree of unsaturation with more double or triple bonds presence, and higher nitrogen content incorporated as N-H, C=N bonds, indicating different haze formation pathways. These findings not only improve the haze formation theories in CO$_2$-rich exoplanet atmospheres but also offer important implications for the interpretation of future observational data.

astro-ph.EP↗

arXiv2025

How CO Affects the Composition of Titan's Tholins Generated with ECR Plasma

Titan's atmosphere possesses thick haze layers, but their formation mechanisms remain poorly understood, including the influence of oxygen-containing gas components on organic matter synthesis. As the most abundant oxygen-containing gas, the presence of CO has been found to exert a significant impact on the generation of oxygen-containing organic compounds. Therefore, investigating the influence of CO on the production and composition of Tholins through laboratory simulations, holds profound scientific significance in the context of Titan. The work presented here is an experimental simulation designed to evaluate the impact of CO on the atmospheric chemistry of Titan. To this end, CO was introduced into the standard N2/CH4 mixture at varying mixing ratios from 0.2% to 9%, and exposed to Electron Cyclotron Resonance (ECR) plasma to initiate photochemical reactions. Optical emission spectroscopy was employed for gas-phase in situ characterization, while infrared spectroscopy and high-resolution mass spectrometry were used to analyze the resulting solid products (tholins). Our results demonstrate that the addition of CO enriches the complexity of the chemical system. CO not only supplies oxygen to the system, but also enhances nitrogen's reactivity and incorporation, enhancing the number and quantity of the organic products.

physics.chem-ph↗