arXiv subjects

Zhifu Shi

Publications and source records attributed to Zhifu Shi.

4 recordsLinked to original sources

arXiv2026

Tunable spin-phonon polarons in a chiral molecular qubit framework

Chiral structures that produce asymmetric spin-phonon coupling can theoretically generate spin-phonon polarons -- quasiparticles exhibiting non-degenerate spin states with phonon displacements. These quasiparticles are speculated to be the origin of chirality-induced spin selectivity and presumably can display exotic dynamic behaviors. However, direct experimental evidence of spin-phonon polarons has been lacking. Using a chiral molecular qubit framework embedding stable semiquinone-like radicals, we report spin dynamic signatures that indicate the formation of spin-phonon polarons for the first time. Our non-adiabatic model reveals that these quasiparticles introduce an active spin relaxation channel when polaron reorganization energy approaches Zeeman splitting. This new channel manifests itself as anomalous, temperature-independent spin relaxation, which can be suppressed by high magnetic fields or pore-filling solvents (e.g. CH2Cl2, CS2). Such field- and guest-tunable relaxation is unattainable in conventional spin systems. Harnessing this mechanism could boost repetition rates in spin-based quantum information technologies without compromising coherence or quantum sensing performance.

cond-mat.mes-hall↗

arXiv2021

A New Design of Resonant Cavity for the W-band EPR spectrometer

We report a new design of resonant cavity for W-band EPR spectrometer. It suits with both solenoid-type and split-pair magnets. The cavity operates on the TE$_{011}$ mode, where the microwave magnetic field is along the cylindrical axis. Its cylindrical axis is horizontal, so the magnetic field of the microwave is always perpendicular to the vertical external magnetic field provided by a solenoid-type magnet. By rotating the cavity, the microwave magnetic field can also be perpendicular to a horizontal external field when a split-pair magnet is used. Furthermore, a tiny metal cylinder allows for the adjustment of coupling. This enables both continuous-wave (CW) and pulsed EPR experiments. The coupling-varying ability has been demonstrated by reflection coefficient (S11) measurement, and CW and pulsed EPR experiments have been conducted. The performance data indicates a prospect of wide applications of the cavity in the fields of physics, chemistry and biology.

physics.ins-det↗

arXiv2019

Observation of dynamical phase transitions in a topological nanomechanical system

Dynamical phase transitions (DPTs), characterized by non-analytic behaviors in time domain, extend the equilibrium phase transitions to far-from-equilibrium situations. It has been predicted that DPTs can be precisely identified by the discontinuities of the Pancharatnam geometric phase (PGP) during the time evolution. However, PGP always mixes with dynamical phase and the experimental observation of DPTs by PGP is still absent. Here, we theoretically present a novel scheme for eliminating the dynamical phase by taking advantage of chiral symmetry in the Su-Schrieffer-Heeger (SSH) model, and experimentally observe DPTs by directly measuring PGP in a quenched topological nanomechanical lattice. Time-dependent topological structures of the SSH model are configured by eight strong-coupled high-quality-factor nanomechanical oscillators. By measuring the vibration phase and the normalized amplitude of the edge oscillator, we show a direct classical analog of DPTs. Furthermore, we experimentally demonstrate the robustness of DPTs against weak structure disorders, and numerically explore the relation between DPTs and the equilibrium phase boundary. This work not only establishes the quantitative method to identify DPTs, but also opens the door for studying non-equilibrium topological dynamics with a well-controlled nanomechanical system.

quant-ph↗

arXiv2017

Experimental protection of the coherence of a molecular qubit exceeding a millisecond

There are several important solid-state systems, such as defects in solids, superconducting circuits and molecular qubits, for attractive candidates of quantum computations. Molecular qubits, which benefit from the power of chemistry for the tailored and inexpensive synthesis of new systems, face the challenge from decoherence effect. The decoherence effect is due to the molecular qubits' inevitable interactions to their environment. Strategies to overcome decoherence effect have been developed, such as designing a nuclear spin free environment and working at atomic clock transitions. These chemical approaches, however, have some fundamental limitations. For example, chemical approach restricts the ligand selection and design to ligands with zero nuclear magnetic dipole moment, such as carbon, oxygen, and sulfur. Herein, a physical approach, named Dynamical decoupling (DD), is utilized to combat decoherence, while the limitations of the chemical approaches can be avoided. The phase memory time $T_2$ for a transition metal complex has been prolonged to exceed one millisecond ($1.4~$ms) by employing DD. The single qubit figure of merit $Q_M $ reaches $ 1.4\times 10^5$, which is $40$ times better than that previously reported value for such system. Our results show that molecular qubits, with milliseconds $T_2$, are promising candidates for quantum information processing.

quant-ph↗