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Zhihao Gao

Publications and source records attributed to Zhihao Gao.

10 recordsLinked to original sources

Library Reachability in LSR-Synth: How Anti-Memorization Design Changes the Measurement of Symbolic Discovery

Existing benchmarks for scientific equation discovery are largely composed of well-known equations available in the public domain, making it difficult to determine whether a model is discovering laws from data or merely recalling answers from its training corpus. LSR-Synth mitigates this problem by introducing novel synthetic terms into established scientific mechanisms and filtering the resulting tasks for novelty, solvability, and scientific plausibility. This paper examines a narrower measurement question: can these tasks further distinguish scientific priors supplied by language models from conventional operator search that does not access task semantics? We construct a semantics-free baseline using a fixed vocabulary with publicly documented provenance, and assess the role of candidate coverage through semantic blinding, library weakening, and matched operator-family knockouts. Under the current task snapshot, search budget, and scoring protocol, the fixed vocabulary already covers most tasks, while language-model-generated candidates rarely expand the set of solvable instances. Their marginal contribution becomes substantial only when vocabulary coverage is selectively disrupted. Strict out-of-distribution evaluation lowers the absolute success rates of all methods but does not alter this relationship. These findings neither invalidate LSR-Synth's controls against memorization of complete formulas nor imply that language-model priors are generally unhelpful. Rather, they support a more limited conclusion: most current tasks remain suitable for evaluating the fitting and recombination of previously unseen expressions, but are insufficient on their own to identify contributions from priors beyond a fixed search space.

cs.AI

ChemMat-AgentSafetyBench: Evaluating Long-Horizon Attacks and Defenses in Chemistry and Materials Agents

Chemistry and materials agents integrate literature retrieval, candidate generation, property prediction, and protocol planning into continuous discovery workflows. Consequently, the relevant safety question is shifting from whether a model answers a hazardous question to whether an agent releases a hazardous protocol through a tool-mediated workflow. We introduce \bench, a benchmark that evaluates whether chemistry and materials agents can be steered toward hazardous endpoints through user input, tool observations, or persistent memory. The benchmark contains 432 fixed harmful case specifications spanning eight hazard classes, three scenario shells, four tool-and-memory environments, a single-turn direct-attack baseline, and five online long-horizon attacks: intent hijacking, tool chaining, objective drifting, task injection, and memory poisoning. The concrete language of each online attack is generated from the evolving trajectory at runtime and is therefore not counted in the static benchmark size. In the four-model main experiment with a fixed attacker, agents release complete hazardous synthesis or preparation procedures in 25.6\% of runs. Replacing the attacker model yields mean success rates from 18.4\% to 26.5\%, indicating that the risk is not an artifact of a single attacker. Input- and state-level defenses adapted from general-purpose agent safety, as well as candidate checks designed for chemistry and materials, reduce some failures but still leave complete-path release rates between 9.2\% and 22.5\%. Existing defenses therefore do not simultaneously cover multi-entry contamination, tool state, and the final artifact boundary. These results highlight a widening gap between the rapid development of scientific agents and the safety evaluation and defenses available to the chemistry and materials community.

cs.CR

Isomeric yield ratios and mass spectrometry of Y and Nb isotopes in the neutron-rich N=60 region: the unusual case of $^{98}$Y

The isomeric yield ratio (IYR) of fission products is an observable that carries relevant information about the fragments emerging from the scission of a fissioning nucleus. We report on IYR of $^{96,98,100}$Y and $^{100,102}$Nb, together with the previously reported values for $^{97}$Y and $^{99}$Nb, produced in the 28 MeV $α$-induced fission of $^{232}$Th at the Ion Guide Isotope Separation On-Line (IGISOL) facility of the University of Jyv{ä}skyl{ä}. We measured the IYR using two different techniques, the phase-imaging ion-cyclotron-resonance (PI-ICR) and the multiple-reflection time-of-flight mass spectrometry (MR-TOF-MS) methods. Moreover, we measured the masses of the long-lived states in $^{98,100}$Y and $^{100,102}$Nb populated via in-trap $β$-decay of their precursors. Since the $β$-decay selectively populates states with a favourable spin-parity, we could identify the measured state and show that the ground state is the low-spin state in the cases of $^{98}$Y and $^{100}$Nb, while it is the high-spin state in the cases of $^{100}$Y and $^{102}$Nb. This measurement confirms the spin-parity assignments of all the nuclei as they are reported in the NUBASE2020 evaluations, disagreeing with the assignment for $^{100}$Y reported in the ENSDF evaluation. Making also use of previously reported data, we observe an anomalously low IYR for the $N=59$ isotope $^{98}$Y as compared to other yttrium or neighboring niobium isotopes. This behavior is very rare across the nuclear chart and is posited to be connected to the characteristic shape coexistence of $^{98}$Y, and to the change in the charge radii of the ground and excited states in the $N=58-60$ region.

nucl-ex

Disentangling the influence of excitation energy and compound nucleus angular momentum on fission fragment angular momentum

The origin of the large angular momenta observed for fission fragments is still a question under discussion. To address this, we study isomeric yield ratios (IYR), i.e. the relative population of two or more long-lived metastable states with different spins, of fission products. We report on IYR of 17 isotopes produced in the 28 MeV $α$-induced fission of $^{232}$Th at the IGISOL facility of the University of Jyväskylä. The fissioning nuclei in this reaction are $^{233,234,235}$U*. We compare our data to IYR from thermal neutron-induced fission of $^{233}$U and $^{235}$U, and we observe statistically significant larger IYR in the $^{232}$Th($α$,f) reaction, where the average compound nucleus (CN) spin is 7.5 $\hbar$, than in $^{233,235}$U(n$_{th}$,f), with average spins 2.5 and 3.5 $\hbar$, respectively. To assess the influence of the excitation energy, we study literature data of IYR from photon-induced fission reactions, and find that the IYR are independent of the CN excitation energy. We conclude that the different IYR must be explained by the different CN spin alone. This implies that the FF angular momentum only partly comes from the fission process itself, and is in addition influenced by the angular momentum present in the CN.

nucl-ex

Estimating angular momenta of fission fragments from isomeric yield ratios

Purpose: To deduce the angular momenta of fission fragments based on the observed isomeric yield ratios (IYR) in 25-MeV proton-induced fission of 238U and to compare these using Wilson's model. Method: A surrogate model of GEF has been developed to generate properties of primary fission fragments. Based on the excitation energy and angular momentum of fission fragments from GEF, an energy versus angular momentum matrix is reconstructed using a set of parameters. With such matrices as input, TALYS is used to calculate the de-excitation of the fission fragments, from which the IYRs are obtained. By varying one of the parameters, the root-mean-square angular momentum (Jrms), which determines the angular momentum distribution of the matrix, Jrms-dependent IYRs are obtained. Considering all primary fission fragments contributing to the IYR for a given fission product, the average angular momentum of those fragments is estimated. Results: Data of 31 IYRs in proton-induced fission of 238U were analysed. As a result, the average Jrms, equivalent to average angular momentum Jav, with uncertainties of 24 fission products, are presented. Considering the neutron emissions of the primary fission fragments, the Jav as a function of the primary fission fragment is presented. A mass dependency of Jav is observed in the proton-induced fission of 238U. Moreover, the Jav for A larger than 131 could be described by the parameterisation proposed by J. Wilson. In general, higher Jav are observed in the present work compared to those from Wilson et al. This is likely due to the higher excitation energy of the fissioning nuclei in this work compared to Wilson's. Furthermore, systematic measurements of the Jav of fission products in the symmetric mass region are presented for the first time. A decreasing trend with mass numbers is observed, which can not be explained by the proposal in Wilson's paper.

nucl-th

Variation of Tensor Force due to Nuclear Medium Effect

The enhancement of $J^π(T)$=3$^{+}$(0) state with isospin $T=0$ excited by the tensor force in the free $^{6}$Li nucleus has been observed, for the first time, relative to a shrinkable excitation in the $^{6}$Li cluster component inside its host nucleus. Comparatively, the excitation of $J^π(T)$=0$^{+}$(1) state with isospin $T=1$ for these two $^{6}$Li formations take on an approximately equal excitation strength. The mechanism of such tensor force effect was proposed due to the intensive nuclear medium role on isospin $T$=0 state.

nucl-ex

Aspect of Clusters Correlation at Light Nuclei Excited State

The correlation of $αα$ was probed via measuring the transverse momentum $p_{T}$ and width $δp_{T}$ of one $α$, for the first time, which represents the spatial and dynamical essentialities of the initial coupling state in $^{8}$Be nucleus. The weighted interaction vertex of 3$α$ reflected by the magnitudes of their relative momentums and relative emission angles proves the isosceles triangle configuration for 3$α$ at the high excited energy analogous Hoyle states.

nucl-ex

Multi-alpha Boson Gas state in Fusion Evaporation Reaction and Three-body Force

The experimental evidence for the $α$ Boson gas state in the $^{11}$C+$^{12}$C$\rightarrow$$^{23}$Mg$^{\ast}$ fusion evaporation reaction is presented. By measuring the $α$ emission spectrum with multiplicity 2 and 3, we provide insight into the existence of a three-body force among $α$ particles. The observed spectrum exhibited distinct tails corresponding to $α$ particles emitted in pairs and triplets consistent well with the model-calculations of AV18-UX and chiral effective field theory of NV2-3-la*, indicating the formation of $α$ clusters with three-body force in the Boson gas state.

nucl-ex

The Emission Order of Hydrogen Isotopes via Correlation Functions in 30 MeV/u Ar+Au Reactions

The intensity interferometry is applied as a chronometer of the particle emission of hydrogen isotopes from the intermediate velocity source formed in $^{40}$Ar+$^{197}$Au reactions at 30 MeV/u. The dynamic emission order of $τ_{\rm p}>τ_{\rm d}>τ_{\rm t}$ is evidenced via the correlation functions of nonidentical particle pairs. Assuming the similar source size, the same emission order is inferred from the correlation functions of identical particle pairs, where $τ_{\rm p} \approx 100 {\rm ~fm/c}$ is extracted by the fit of Koonin-Pratt equation to p-p correlation function. Transport model simulations demonstrate that the dynamic emission order of light charged particles depends on the stiffness of the nuclear symmetry energy.

nucl-ex

Properties of the fast fission and the coincident emissions of light charged particles in $^{40}$Ar + $^{197}$Au reactions at 30 MeV/u

The experiment of Ar+Au reactions at 30 MeV/u have been performed using the Compact Spectrometer for Heavy IoN Experiments (CSHINE) in phase I. The light-charged particles are measured by the silicon stripe telescopes in coincidence with the fission fragments recorded by the parallel plate avalanche counters. The distribution properties of the azimuth difference $Δϕ$ and the time-of-flight difference $ΔTOF$ of the fission fragments are presented varying the folding angles which represents the linear momentum transfer from the projectile to the reaction system. The relative abundance of the light charged particles in the fission events to the inclusive events is compared as a function of the laboratory angle $θ_{\rm lab}$ ranging from $18^\circ$ to $60^\circ$ in various folding angle windows. The angular evolution of the yield ratios of p/d and t/d in coincidence with fission fragments is investigated. In a relative comparison, tritons are more abundantly emitted at small angles, while protons are more abundant at large angles. The angular evolution of the neutron richness of the light-charged particles is consistent with the results obtained in previous inclusive experiments.

nucl-ex