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Zhiyue Lu

Publications and source records attributed to Zhiyue Lu.

25 records · Page 2Linked to original sources

Sloppy Gear Mechanism for Coupled Stochastic Transportation: from anti-equilibrium flow to infinite selectivity

Non-equilibrium transportation of particles through a restricted space (such as porous media or narrow channels) significantly differs from free space. With a simple model of two types of particles competing to transport via a passive single-lane channel connecting two chemical baths, we find two dynamical modes of transportation -- the dud mode and the ratchet mode. At the ratchet mode, the gradient flow of one type of particle forces the other into a transient anti-equilibrium flow against its gradient. At the dud mode, the two types of particles both flow according to their gradients. This counter-intuitive non-equilibrium effect can be explained by a sloppy gear mechanism. In addition to the anti-gradient flow observed in the ratchet mode, we find that the non-equilibrium sloppy gear mechanism suppresses the flow of one particle while allowing the flow for the other. This mechanism provides a general theoretical framework to explain and design the selective transportation of particles via passive channels.

cond-mat.stat-mech↗

Emergence and Breaking of Duality Symmetry in Generalized Fundamental Thermodynamic Relations

Thermodynamics as limiting behaviors of statistics is generalized to arbitrary system with probability {\it a priori} where thermodynamic infinite-size limit is replaced by multiple-measurement limit. A duality symmetry between Massieu's and Gibbs' entropy arises in the limit of infinitely repeated observations, yielding the Gibbs equation and Hill-Gibbs-Duhem equation (HGDE) as dual pair. If a system has thermodynamic limit satisfying Callen's postulate, entropy being an Eulerian function, the symmetry is lost: the HGDE reduces to the Gibbs-Duhem equation. This theory provides a de-mechanized foundation for classical and nanothermodynamics and offers a framework for distilling emergence from large data, free from underlying details.

cond-mat.stat-mech↗

Generalized Boltzmann distributions for systems strongly coupled to large finite bath -- a microcanonical approach

The theory of probability shows that, as the fraction $X_n/Y\to 0$, the conditional probability for $X_n$, given $X_n+Y \in h_δ:=[h, h+δ]$, has a limit law $f_{X_n}(x)e^{-ψ_n(h_δ)x}$, where $ψ_n(h_δ) $ equals to $[\partial \ln P(Y \in y_δ)/\partial y]_{y=h}$ plus an additional term, contributed from the correlation between $X_n$ and bath $Y$. By applying this limit law to an isolated composite system consisting of two strongly coupled parts, a system of interest and a large but finite bath, we derive the generalized Boltzmann distribution law for the system of interest in the exponential form of a redefined Hamiltonian and corrected Boltzmann temperature that reflects the modification due to strong system-bath coupling and the large but finite bath.

math-ph↗

Non-equilibrium statistical mechanics of continuous attractors

Continuous attractors have been used to understand recent neuroscience experiments where persistent activity patterns encode internal representations of external attributes like head direction or spatial location. However, the conditions under which the emergent bump of neural activity in such networks can be manipulated by space and time-dependent external sensory or motor signals are not understood. Here, we find fundamental limits on how rapidly internal representations encoded along continuous attractors can be updated by an external signal. We apply these results to place cell networks to derive a velocity-dependent non-equilibrium memory capacity in neural networks.

cond-mat.dis-nn↗

Continuous attractor-based clocks are unreliable phase estimators

Statistical estimation theory determines the optimal way of estimating parameters of a fluctuating noisy signal. However, if the estimation is performed on unreliable hardware, a sub-optimal estimation procedure can outperform the previously optimal procedure. Here, we compare classes of circadian clocks by viewing them as phase estimators for the periodic day-night light signal. We find that continuous attractor-based free running clocks, such as those found in the cyanobacterium Synechococcus elongatus and humans, are nearly optimal phase estimators since their flat attractor directions efficiently project out light intensity fluctuations due to weather patterns (`external noise'). However, such flat directions also make these continuous limit cycle attractors highly vulnerable to diffusive 'internal noise'. Given such unreliable biochemical hardware, we find that point attractor-based damped clocks, such as those found in a smaller cyanobacterium with low protein copy number, Prochlorococcus marinus, outperform continuous attractor-based clocks. By interpolating between the two types of clocks found in these organisms, we demonstrate a family of biochemical phase estimation strategies that are best suited to different relative strengths of external and internal noise.

cond-mat.stat-mech↗

Anomalous cooling and heating - the Mpemba effect and its inverse

Under certain conditions, it takes a shorter time to cool a hot system than to cool the same system initiated at a lower temperature. This phenomenon - the "Mpemba Effect" - is well known in water, and has recently been observed in other systems as well. However, there is no single generic mechanism that explains this counter-intuitive behavior. Using the theoretical framework of non-equilibrium thermodynamics, we present a widely applicable mechanism for this effect, derive a sufficient condition for its appearance in Markovian dynamics, and predict an inverse Mpemba effect in heating: under proper conditions, a cold system can heat up faster than the same system initiated at a higher temperature. Our results suggest that it should be possible to observe the Mpemba effect and its inverse in a variety of systems, where they have never been demonstrated before.

cond-mat.stat-mech↗

Generalized integral fluctuation relation with feedback control for diffusion processes

We extend a generalized integral fluctuation relation in diffusion processes that we obtained previously to the situation with feedback control. The general relation not only covers existing results but also predicts other unnoticed fluctuation relations. In addition, we find that its explanation of time-reversal automatically emerges in the derivation. This interesting observation leads into an alternative inequality about the entropy-like quantity with an improved lower bound. Two feedback-controlled Brownian models are used to verify the result.

cond-mat.stat-mech↗