arXiv subjects

Zhongjian Xie

Publications and source records attributed to Zhongjian Xie.

5 recordsLinked to original sources

arXiv2018

Biocompatible Two-dimensional Titanium Nanosheets for Efficient Plasmonic Photothermal Cancer Therapy

Photothermal therapy (PTT) has shown significant potential in cancer treatment. However, developing nanomaterial-based photothermal agents with good biocompatibility and high photothermal conversion efficiency (PTCE) remains a key challenge. Titanium has been widely employed as biomedical materials based on their excellent biocompatibility. In this work, the titanium based plasmonic photothermal therapy (Ti-PPTT) is demonstrated. Using the liquid-phase exfoliation (LPE), the metallic Ti can be fabricated into the two-dimensional (2D) nanosheets (NSs), similar to exfoliating other layered 2D materials. The 2D Ti NSs exhibited good biocompatibility, high extinction coefficient of 20.8 Lg-1cm1 and high PTCE of 73.4%, owing to localized surface plasmon resonances (LSPR); which is significantly higher than other photothermal agents, including Au (21%), MoS2 (24.4%), BP (28.4%) and Ti3C2 MXene (30.6%). Consequently, 2D Ti-PPTT exhibited a notable therapeutic effect in a human hepatocellular carcinoma model without side effects. Our study could pave a new avenue for PTT using metal Ti and arouse a wide interest in the potential efficient PTT for other elemental transition metals owing to their LSPR. Furthermore, the efficient photothermal effect and environmental friendliness of Ti NSs make them deserve more research toward other application, such as solar energy harvesting and sea water desalination.

physics.app-ph↗

arXiv2016

Demonstration of liquid crystal for barocaloric cooling application

Current vapor-compression technology is based on the gas-liquid transition of hazardous gas. The alternative cooling technology focuses on the solid caloric material. A new liquid barocaloric material, i.e. the liquid crystal, is proved to be potential for cooling application primarily (based on other literatures). Its phase transition needs a small stress (tens of MPa) and can be operated near room temperature. It has a large entropy change of ~200 J.K-1.kg-1 (0.2 J.K-1.cm-1). There is no breakage problem due to its liquid form. It will provide the advantage for some unique cooling application cases comparing with solid caloric material. Moreover, this material is sustainable and non-toxic, which can meet the original intention of the alternative cooling technology.

cond-mat.soft↗

arXiv2016

Potential improvement for elastocaloric performances of shape memory alloys through comparing with natural rubber

The elastocaloric (eC) effects of natural rubber (NR) and shape memory alloys (SMAs) are compared and potential improvement for eC performances of SMAs is proposed. Both the plateau and hysteresis of stress-strain curve in NR and SMAs are observed. They are attributed to the similar phase transformation: strain-induced crystallization (SIC) in NR and martensitic transformation in SMAs. For NR, the drawback of large strain can be reduced by pre-strain. For SMAs, the stress change with strain is smaller in stress plateau regime. Thus, the drawback of large dynamic stress of SMAs is proposed to be reduced by a static pre-stress for working directly in this stress plateau regime. Choosing an appropriate pre-strain (pre-stress) and strain amplitude can make eC effect of NR working in the phase transformation (SIC) regime. This method can improve both the eC strength and fatigue life in NR. Due to the similar phase transformation (martensitic transformation) of SMAs to NR, this method is also proposed to improve the eC performances of SMAs.

cond-mat.mtrl-sci↗

arXiv2016

Comparison of caloric effects in view of application

In the framework of solid-state cooling technology, four kinds of caloric effects, magnetocaloric (MC), electrocaloric (EC), barocaloric (BC) and elastocaloric (eC) effects, are compared in view of environment discussion and application fields. This field is primarily developed in the intention of protecting the environment. However, some widely researched caloric materials do not meet environmental friendly criteria. Currently, new caloric materials (called "good" material) possessing the properties of friendly environment, low cost, high caloric performance and practicability (low stress) need to be found. In view of application, all current caloric effects/materials are investigated for the common objective of cooling. However, the adapted application cases for different caloric effects/materials are not considered. Due to the different stimuli and different intrinsic properties (different caloric performance for different dimensions) of caloric materials, they can exhibit unique advantage to different application cases. "Good" caloric material used for large-scale application is still less and deserve more search. Purposeful research will save the cost and accelerate the commercialization.

cond-mat.mtrl-sci↗

arXiv2016

Temperature dependence of elastocaloric effect in natural rubber

The temperature dependence of the elastocaloric (eC) effect in natural rubber (NR) is studied adiabatically and isothermally. A broad temperature span for eC effect from 0 oC to 49 oC is observed. The maximum adiabatic temperature change (ΔT) is 12 K at strain of 6 and occurs at 10 oC. These behaviors can be predicted by the temperature dependence of strain-induced crystallization (SIC) and temperature-induced crystallization (TIC). In isothermal condition, the deduced ΔT from Clausius-Clapeyron factor can agree with the direct measurement at different temperatures. The eC performance of NR is compared with shape memory alloys (SMAs). The potential of NR for a near room temperature cooing application is primarily proved. This will open the SIC research of NR towards eC cooling direction.

cond-mat.soft↗