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Zhongyi Lu

Publications and source records attributed to Zhongyi Lu.

8 recordsLinked to original sources

Vacancy Order and Physical Properties of a Ternary Compound Fe0.68Pd0.80Te with an {\alpha}-Fe1+xTe-Type Structure

We report the identification and characterization of a new compound Fe0.68Pd0.80Te with an {\alpha}-Fe1+xTe prototype structure. Different from the Fe-square net and minor occupancy of interstitial Fe-sites in Fe1+xTe, Fe0.68Pd0.80Te is featured by a Pdsquare net and near 68% occupancy of the corresponding interstitial Fe-sites. Furthermore, noncontact atomic force microscopy and X-ray diffraction provide evidence for the existence of a 3*3*3 Pd-vacancy order in this layered material. A spin-glass ground state below Tg 40 K is identified via magnetic characterization. Electrical transport measurements show that Fe0.68Pd0.80Te is a semiconductor with a very small band gap below 10 meV. It has weak negative magnetoresistance and holelike charge carriers below room temperature. Our results demonstrate its potentials for further exploring various quantum phenomena.

cond-mat.mtrl-sci

PriCoRec: A Privacy-Aware Cloud-Device Collaborative Framework for Ad Recommendation under Feature Constraints

Privacy regulations increasingly restrict cloud processing of sensitive user data (e.g., age, gender), hindering traditional cloud-only recommendation models. To mitigate this challenge, we propose a Privacy-aware Collaborative cloud-device ads Recommendation framework (PriCoRec) which personalizes recommendations while keeping sensitive features on-device. While separating recommendation into cloud-based and on-device stages enables privacy-aware deployment, naive splitting suffers from degraded shortlist quality and inefficient on-device inference due to limited private features. We therefore design a collaborative framework that comprises a cloud-based pre-ranking stage using cloud-accessible features, and an on-device ranking stage that locally incorporates highly personalized features. We introduce a diversity regularizer to pre-ranking to improve candidate quality. Moreover, to control device power consumption and computational cost, we incorporate a cloud-guided training mechanism that enhances device model performance while keeping the model lightweight. Experiments demonstrate that the proposed framework maintains strong recommendation performance while keeping sensitive features on-device.

cs.IR

RAMP: Robust Ad Recommendation Under Limited Personalized-Feature Availability via Masking and Alignment Pathways

Click-through rate (CTR) and conversion rate (CVR) prediction are fundamental tasks in online advertising, aiming to estimate the likelihood of user interactions based on various features. While personalized attributes such as age and gender can significantly enhance predictive accuracy, their use is increasingly restricted by privacy regulations, thereby limiting available data for both training and inference. To address this challenge, we propose RAMP (Robust Ad Recommendation Under Limited Personalized-Feature Availability via Masking and Alignment Pathways), which is designed to improve CTR/CVR prediction accuracy when personalized features are not accessible, thus supporting deployment in privacy-constrained settings.RAMP consists of (i) a personalized pathway built upon a dual-tower component with identical inputs but independent parameters, where output masking separates predictions for personalized and non-personalized signals, (ii) a separate non-personalized pathway trained with non-personalized features only, and (iii) a distillation-inspired prediction-alignment architecture between (i) and (ii) that improves prediction when personalized features are unavailable. We conduct comprehensive experiments using both public benchmarks and industrial datasets to evaluate the performance of RAMP. Our evaluation spans multiple backbone models and different settings: with and without access to personalized features. The results show that RAMP consistently outperforms state-of-the-art methods when personalized features are missing, while maintaining competitive performance when all features are available. %demonstrating its effectiveness and practicality for real-world advertising systems. Our code is publicly available at https://github.com/Ruixinhua/RAMP.

cs.IR

RSAVS superconductors: materials with a superconducting state that is robust against large volume shrinkage

TThe transition temperature (TC) between normal and superconducting states usually exhibits a dramatic increase or decrease with increasing applied pressure. Here we present, in contrast, a new kind of superconductor that exhibits the exotic feature that TC is robust against large volume shrinkages induced by applied pressure (here naming them as "RSAVS superconductors"). Extraordinarily, the TC in these materials stays almost constant over a large pressure range, e.g. over 136 GPa in the (TaNb)0.67(HfZrTi)0.33 high entropy alloy and 141 GPa in the NbTi commercial alloy. We show that the RSAVS behavior also exists in another high entropy alloy (ScZrNbTa)0.6(RhPd)0.4, and in superconducting elemental Ta and Nb, indicating that this behavior, which has never previously been identified or predicted by theory, occurs universally in some conventional superconductors. Our electronic structure calculations indicate that although the electronic density of state (DOS) at the Fermi level in the RSAVS state is dominated by the electrons from the degenerate dxy, dxz and dyz orbitals, these electrons decrease in influence with increasing pressure. In contrast, however, the contribution of the degenerate dx2-y2 and dz2 orbital electrons remains almost unchanged at the Fermi level, suggesting that these are the electrons that may play a crucial role in stabilizing the TC in the RSAVS state.

cond-mat.supr-con

Electronic structure of heavy fermion system CePt2In7 from angle-resolved photoemission spectroscopy

We have carried out high-resolution angle-resolved photoemission measurements on the Cebased heavy fermion compound CePt2In7 that exhibits stronger two-dimensional character than the prototypical heavy fermion system CeCoIn5. Multiple Fermi surface sheets and a complex band structure are clearly resolved. We have also performed detailed band structure calculations on CePt2In7. The good agreement found between our measurements and the calculations suggests that the band renormalization effect is rather weak in CePt2In7. A comparison of the common features of the electronic structure of CePt2In7 and CeCoIn5 indicates that CeCoIn5 shows a much stronger band renormalization effect than CePt2In7. These results provide new information for understanding the heavy fermion behaviors and unconventional superconductivity in Ce-based heavy fermion systems.

cond-mat.str-el

Pressure-induced isostructural phase transition and correlation of FeAs coordination with the superconducting properties of 111-type Na1-xFeAs

The effect of pressure on the crystalline structure and superconducting transition temperature (Tc) of the 111-type Na1-xFeAs system using in situ high pressure synchrotron x-ray powder diffraction and diamond anvil cell techniques is studied. A pressure-induced tetragonal to tetragonal isostructural phase transition was found. The systematic evolution of the FeAs4 tetrahedron as a function of pressure based on Rietveld refinements on the powder x-ray diffraction patterns was obtained. The non-monotonic Tc(P) behavior of Na1-xFeAs is found to correlate with the anomalies of the distance between the anion (As) and the iron layer as well as the bond angle between As-Fe-As for the two tetragonal phases. This behavior provides the key structural information in understanding the origin of the pressure dependence of Tc for 111-type iron pnictide superconductors. A pressure-induced structural phase transition is also observed at 20 GPa.

cond-mat.supr-con

Neutral genetic drift can aid functional protein evolution

BACKGROUND: Many of the mutations accumulated by naturally evolving proteins are neutral in the sense that they do not significantly alter a protein's ability to perform its primary biological function. However, new protein functions evolve when selection begins to favor other, "promiscuous" functions that are incidental to a protein's biological role. If mutations that are neutral with respect to a protein's primary biological function cause substantial changes in promiscuous functions, these mutations could enable future functional evolution. RESULTS: Here we investigate this possibility experimentally by examining how cytochrome P450 enzymes that have evolved neutrally with respect to activity on a single substrate have changed in their abilities to catalyze reactions on five other substrates. We find that the enzymes have sometimes changed as much as four-fold in the promiscuous activities. The changes in promiscuous activities tend to increase with the number of mutations, and can be largely rationalized in terms of the chemical structures of the substrates. The activities on chemically similar substrates tend to change in a coordinated fashion, potentially providing a route for systematically predicting the change in one function based on the measurement of several others. CONCLUSIONS: Our work suggests that initially neutral genetic drift can lead to substantial changes in protein functions that are not currently under selection, in effect poising the proteins to more readily undergo functional evolution should selection "ask new questions" in the future.

q-bio.PE

Evolution favors protein mutational robustness in sufficiently large populations

BACKGROUND: An important question is whether evolution favors properties such as mutational robustness or evolvability that do not directly benefit any individual, but can influence the course of future evolution. Functionally similar proteins can differ substantially in their robustness to mutations and capacity to evolve new functions, but it has remained unclear whether any of these differences might be due to evolutionary selection for these properties. RESULTS: Here we use laboratory experiments to demonstrate that evolution favors protein mutational robustness if the evolving population is sufficiently large. We neutrally evolve cytochrome P450 proteins under identical selection pressures and mutation rates in populations of different sizes, and show that proteins from the larger and thus more polymorphic population tend towards higher mutational robustness. Proteins from the larger population also evolve greater stability, a biophysical property that is known to enhance both mutational robustness and evolvability. The excess mutational robustness and stability is well described by existing mathematical theories, and can be quantitatively related to the way that the proteins occupy their neutral network. CONCLUSIONS: Our work is the first experimental demonstration of the general tendency of evolution to favor mutational robustness and protein stability in highly polymorphic populations. We suggest that this phenomenon may contribute to the mutational robustness and evolvability of viruses and bacteria that exist in large populations.

q-bio.PE