arXiv subjects

Zi-Han Guo

Publications and source records attributed to Zi-Han Guo.

6 recordsLinked to original sources

arXiv2020

Robust two-dimensional ice on graphene built from finite-length water molecular chains

Interfacial ice on graphene has attracted much attention because it is a model system to study two-dimensional (2D) ice structures on chemically inert substrates. While water-graphene interaction was usually assumed to be negligible, the structures of the 2D ice are believed to be not appreciably perturbed by the graphene substrate. Here we report atomic-resolved characterizations of an exotic 2D ice structure on graphene built from water molecular chains with finite lengths. Our experiments demonstrated that the water molecular chains are exactly orientated along zigzag directions of the graphene substrate, which evidences an anomalously strong interlayer interaction between the 2D ice and the graphene substrate. Moreover, the length of the water molecular chains closely links to the number of graphene layers, indicating layer-number-dependent water-graphene interfacial interactions. Our work highlights the important role of the 2D ice structures on the water-graphene interfacial interactions.

cond-mat.mtrl-sci↗

arXiv2020

Spectroscopic evidence for a spin and valley polarized metallic state in a non-magic-angle twisted bilayer graphene

In the magic-angle twisted bilayer graphene (MA-TBG), strong electron-electron (e-e) correlations caused by the band-flattening lead to many exotic quantum phases such as superconductivity, correlated insulator, ferromagnetism, and quantum anomalous Hall effects, when its low-energy van Hove singularities (VHSs) are partially filled. Here our high-resolution scanning tunneling microscope and spectroscopy measurements demonstrate that the e-e correlation in a non-magic-angle TBG with a twist angle θ = 1.49 still plays an important role in determining its electronic properties. Our most interesting observation on that sample is that when one of its VHS is partially filled, the one associated peak in the spectrum splits into four peaks. Our analysis based on the continuum model suggests that such a one-to-four split of the VHS originates from the formation of an interaction-driven spin-valley-polarized metallic state near the VHS, lifting both the spin and valley degeneracies. Our results for this non-magic-angle TBG reveal a new symmetry-breaking phase, which has not been identified in the MA-TBG or in other systems.

cond-mat.mtrl-sci↗

arXiv2020

Electron interactions in strain-induced zero-energy flat band in twisted bilayer graphene near the magic angle

In the vicinity of the magic angle in twisted bilayer graphene (TBG), the two low-energy van Hove singularities (VHSs) become exceedingly narrow1-10 and many exotic correlated states, such as superconductivity, ferromagnetism, and topological phases, are observed11-16. Heterostrain, which is almost unavoidable in the TBG, can modify its single-particle band structure and lead to novel properties of the TBG that have never been considered so far. Here, we show that heterostrain in a TBG near the magic angle generates a new zero-energy flat band between the two VHSs. Doping the TBG to partially fill the zero-energy flat band, we observe a correlation-induced gap of about 10 meV that splits the flat band. By applying perpendicular magnetic fields, a large and linear response of the gap to magnetic fields is observed, attributing to the emergence of large orbital magnetic moments in the TBG when valley degeneracy of the flat band is lifted by electron-electron interactions. The orbital magnetic moment per moire supercell is measured as about 15 uB in the TBG.

cond-mat.str-el↗

arXiv2019

Scanning tunneling microscope characterizations of a circular graphene resonator realized with p-p junctions

Using low-temperature high-magnetic-field scanning tunneling microscopy and spectroscopy (STM/STS), we systematically study a graphene quantum dot (GQD) defined by a circular graphene p-p junction. Inside the GQD, we observe a series of quasi-bound states arising from whispering-gallery-mode (WGM) confinement of the circular junction and directly visualize these quasi-bound states down to atomic dimensions. By applying a strong magnetic field, a large jump in energy of the quasi-bound states, which is about one-half the energy spacing between the quasi-bound states, is observed. Such a behavior results from turning on a π Berry phase of massless Dirac fermions in graphene by a magnetic field. Moreover, our experiment demonstrates that a quasi-bound state splits into two peaks with an energy separation of about 26 meV when the Fermi level crosses the quasi-bound state, indicating that there are strong electron-electron interactions in the GQD.

cond-mat.mes-hall↗

arXiv2018

High-magnetic-field Tunneling Spectra of ABC-Stacked Trilayer Graphene

ABC-stacked trilayer graphene (TLG) are predicted to exhibit novel many-body phenomena due to the existence of almost dispersionless flat-band structures near the charge neutrality point (CNP). Here, using high magnetic field scanning tunneling microscopy, we present Landau Level (LL) spectroscopy measurements of high-quality ABC-stacked TLG. We observe an approximately linear magnetic-field-scaling of the valley splitting and orbital splitting in the ABC-stacked TLG. Our experiment indicates that the valley splitting decreases dramatically with increasing the LL index. When the lowest LL is partially filled, we find an obvious enhancement of the orbital splitting, attributing to strong many-body effects. Moreover, we observe linear energy scaling of the inverse lifetime of quasiparticles, providing an additional evidence for the strong electron-electron interactions in the ABC-stacked TLG. These results imply that interesting broken-symmetry states and novel electron correlation effects could emerge in the ABC-stacked TLG in the presence of high magnetic fields.

cond-mat.mtrl-sci↗

arXiv2018

Spatial Confinement, Magnetic Localization and Their Interactions on Massless Dirac Fermions

It is of keen interest to researchers understanding different approaches to confine massless Dirac fermions in graphene, which is also a central problem in making electronic devices based on graphene. Here, we studied spatial confinement, magnetic localization and their interactions on massless Dirac fermions in an angled graphene wedge formed by two linear graphene p-n boundaries with an angle 34. Using scanning tunneling microscopy, we visualized quasibound states temporarily confined in the studied graphene wedge. Large perpendicular magnetic fields condensed the massless Dirac fermions in the graphene wedge into Landau levels (LLs). The spatial confinement of the wedge affects the Landau quantization, which enables us to experimentally measure the spatial extent of the wave functions of the LLs. The magnetic fields induce a sudden and large increase in energy of the quasibound states because of a pi Berry phase jump of the massless Dirac fermions in graphene. Such a behavior is the hallmark of the Klein tunneling in graphene. Our experiment demonstrated that the angled wedge is a unique system with the critical magnetic fields for the pi Berry phase jump depending on distance from summit of the wedge.

cond-mat.mes-hall↗