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Ziao Han

Publications and source records attributed to Ziao Han.

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Granular Superconductivity in La$_{2}$PrNi$_{2}$O$_{7-\delta}$ Thin Films

Superconductivity realized in bilayer nickelate thin films enables direct spectroscopic and transport studies at ambient pressure. However, a persistent two-step resistive transition remains a major barrier to achieving optimal superconducting properties. Here, we show that the two-step transition in La$_2$PrNi$_2$O$_{7-\delta}$ thin films originates from the granular nature of superconductivity, specifically, the coexistence of two distinct superconducting grain phases coupled by a Josephson junction network. A secondary, lower-temperature transition appears in the $R(T)$ curve, even when residual resistance becomes vanishingly small near 30 K. This two-step behavior significantly lowers the zero-resistance transition temperature, $T_{c, zero}$$\approx$ 10 K, and limits advanced spectroscopic studies. Our findings reveal the microscopic mechanism underlying the two-step transition in thin films and underscore the need for improved oxygen homogeneity to achieve bulk superconductivity in this system.

cond-mat.supr-con

Stabilizing and Tuning Superconductivity in La$_3$Ni$_2$O$_{7-\delta}$ Films: Oxygen Recycling Protocol Reveals Hole-Doping Analogue

The recent achievement of superconductivity in La$_3$Ni$_2$O$_{7-\delta}$ with transition temperatures exceeding 40 K in thin films under compressive strain and 80 K in bulk crystals under high pressure opens new avenues for research on high-temperature superconductivity. The realization of superconductivity in thin films requires delicate control of growth conditions, which presents significant challenges in the synthesis process. Furthermore, the stability of superconducting La$_3$Ni$_2$O$_{7-\delta}$ films is compromised by oxygen loss, which complicates their characterization. We introduce an effective recycling protocol that involves oxygen removal in a precursor phase followed by ozone-assisted annealing, which restores superconducting properties. By tuning the oxygen content, we construct an electronic phase diagram that highlights oxygen addition as a potential analogue to hole doping via La substitution with Sr, providing insights into the doping mechanism and guiding future material optimization.

cond-mat.supr-con