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Zirui Dong

Publications and source records attributed to Zirui Dong.

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Physics-Informed Modeling and Control of Emergent Behaviors in Robot Swarms

Robot swarms can exhibit coherent collective behaviors through local perception, limited communication and decentralized decision-making, yet modeling and controlling such emergence remains challenging when behaviors unfold over multiple phases. Here we introduce PhySwarm, a physics-informed micro--macro framework that represents multi-stage swarm emergence as physically constrained density-field evolution coupled to executable robot motion. At the macroscopic level, a multi-phase advection--diffusion--reaction model (Macro-ADR) describes phase-dependent swarm-density evolution through directed transport, diffusion-based spatial regulation and behavioral phase transitions. At the microscopic level, an equivalent deterministic motion model (Micro-EDM) realizes these mechanisms through potential-field advection, density-gradient compensation and rate- or event-gated phase switching. A neural-physics controller (NPC) maps local observations and temporal memory to bounded physical parameters, and is trained with a reinforcement learning--PINN objective that combines task rewards with macro-scale density residuals and micro-scale motion-consistency constraints. In several proof-of-concept swarm missions -- including trail-guided foraging, formation-reconfigurable navigation and role-adaptive search and rescue -- we demonstrate that PhySwarm can generate distinct multi-stage emergent behaviors within a unified physics-informed modeling framework. The learned density fields and physical parameters provide interpretable evidence of how advection, diffusion and reaction jointly regulate multi-stage swarm organization. These results establish a physics-informed route for learning, interpreting and controlling emergent behaviors in robot swarms.

cs.RO

Comprehensive landscape and simple rules for transition-metal Heusler semiconductors

Heusler alloys, renowned for their multifunctionality and capacity for vast elemental customization, are primarily classified into half-Heusler (XYZ) and full-Heusler (X2YZ) structural types. Typically, the 18-electron half-Heusler and the 24-electron full-Heusler alloys are recognized as semiconductors, following the Slater-Pauling rule. Semiconductors are desired for many applications, but they represent a minor portion compared to the predominantly metallic and half-metallic members of the Heusler family. Recently, vacancy-filling off-stoichiometric Heuslers of ternary X1+bYZ (0 <= b <= 1) and quaternary XaX'bYZ (1 <= a + b <= 2) have emerged as a more versatile strategy. However, the flexibility associated with off-stoichiometry inevitably leads to complications, including issues with fractional filling ratios and complex site occupations. This work presents a comprehensive landscape of transition-metal-containing Heusler semiconductors, focusing on the off-stoichiometric Heuslers but seamlessly encompassing the integer-stoichiometric systems. The structural and electronic properties can be theoretically understood through a few simple rules. Many systems have been experimentally validated, showcasing their potential for applications such as thermoelectric converters.

cond-mat.mtrl-sci

Screening of half-Heuslers with temperature-induced band convergence and enhanced thermoelectric properties

Enhancing band convergence is an effective way to optimize the thermoelectric (TE) properties of materials. However, the temperature-induced band renormalization is commonly ignored. By employing the recently-developed electron-phonon renormalization (EPR) method, the nature of band renormalization in half-Heusler (HH) compounds TiCoSb and NbFeSb is revealed, and the key factors for temperature-induced conduction band convergence in HH are found out. Using these as the screening criteria, 3 out of 274 HHs (TiRhBi, TiPtSn, NbPtTl) are then stood out from our MatHub-3d database. Taking TiPtSn as the example, it shows the conduction band convergence at mid-high temperature, and further resulting in enhanced Seebeck coefficient S: e.g., at 600 K with electron concentration 10^20 cm^-3, the predicted S with and without renormalized band is 352.83 uV/K and 289.52 uV/K, respectively. Herein, the former is closer to our measurement value of 338.79 uV/K. Besides, the effective masses obtained from calculation and experiment are both enlarged with temperature, indicating the existence of band convergence. Our work demonstrates for the first time the significance of adding the temperature effect on electronic structure in the design of potential high-performance TE materials.

cond-mat.mtrl-sci

High-performance non-Fermi-liquid metallic thermoelectric materials

Searching for high-performance thermoelectric (TE) materials in the paradigm of narrow-bandgap semiconductors has lasted for nearly 70 years and is obviously hampered by a bottleneck of research now. Here we report on the discovery of a few metallic compounds, TiFexCu2x-1Sb and TiFe1.33Sb, showing the thermopower exceeding many TE semiconductors and the dimensionless figure of merits comparable with the state-of-the-art TE materials. A quasi-linear temperature (T) dependence of electrical resistivity in 2 K - 700 K and the logarithmic T-dependent electronic specific heat at low temperature are also observed to coexist with the high thermopower, highlighting the strong intercoupling of the non-Fermi-liquid (NFL) quantum critical behavior of electrons with TE transports. Electronic structure analysis reveals the existence of fluctuating Fe-eg-related local magnetic moments, Fe-Fe antiferromagnetic (AFM) interaction at the nearest 4c-4d sites, and two-fold degenerate eg orbitals antiferromagnetically coupled with the dual-type itinerant electrons close to the Fermi level, all of which infer to a competition between the AFM ordering and Kondo-like spin compensation as well as a parallel two-channel Kondo effect. These effects are both strongly meditated by the structural disorder due to the random filling of Fe/Cu at the equivalent 4c/4d sites of the Heusler crystal lattice. The magnetic susceptibility deviates from ideal antiferromagnetism but can be fitted well by x(T) = 1/(θ + BTα), seemingly being consistent with the quantum critical scenario of strong local correlation as discussed before. Our work not only breaks the dilemma that the promising TE materials should be heavily-doped semiconductors, but also demonstrates the correlation among high TE performance, NFL quantum criticality, and magnetic fluctuation, which opens up new directions for future research.

cond-mat.str-el