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Zong-Chao Yan

Publications and source records attributed to Zong-Chao Yan.

At least 19 recordsLinked to original sources

Simultaneous Determination of Multiple Nuclear Parameters of $^{229}$Th Using Highly Charged Ions

Development of a $^{229}$Th nuclear optical clock requires precise and model-insensitive nuclear-structure parameters, which presently suffer from limited accuracy and poor consistency. We propose a joint spectroscopy scheme using two highly charged $^{229}$Th ions with $J=1/2$ electronic ground states, where the lowest electronic excitation energy of each ion far exceeds the nuclear transition energy. This configuration effectively forms a three-level system comprising the electronic ground state and the nuclear ground ($g$) and isomeric ($m$) states, resulting in strongly enhanced nuclear hyperfine mixing. Within this framework, a unified analysis of precision measurements on both ions enables the simultaneous determination of five key nuclear parameters without relying on external nuclear inputs: the magnetic dipole moments $μ_g$ and $μ_m$, the bare-nucleus transition energy $ω_n$, the charge-radius difference $δ\langle r^{2}\rangle_{gm}$, and the $M1$ transition matrix element $T_{M1}$. With this approach, the uncertainties in $ω_n$ and $δ\langle r^{2}\rangle_{gm}$ are estimated to be reduced by factors of 3 and 2, respectively, relative to their current uncertainties. %compared with current values. This work could provide a useful benchmark for nuclear theory and serve as a foundation for future development of a $^{229}$Th-based nuclear optical clock.

physics.atom-ph

Direct Extraction of Nuclear Structure Information Using Precision Lithium-Ion Spectroscopy

Accurately describing nuclear interactions within atomic nuclei remains a challenge, which hinders our exploration of new physics beyond the Standard Model. However, these nuclear interactions can be characterized by nuclear parameters such as the Zemach radius and the electric quadrupole moment, which are reflected in atomic spectra. Our work has achieved high-precision measurements of lithium ion hyperfine splittings at the level of $10$~kHz, and directly extracted these important nuclear structure parameters. We observed significant discrepancies between our results and both nuclear theory and molecular spectra regarding the electric quadrupole moment. The result for $^7$Li deviated by $2.3σ$ from the currently recommended value, whereas the result for $^6$Li deviated by up to $6.2σ$ from the recommended value determined by molecular spectroscopy. These discrepancies motivated us to conduct independent calculations based on nuclear structure theory, which provided support for the results obtained from ion spectroscopy. Our results provide valuable information for characterizing nuclear forces, serve as sensitive benchmarks for testing nuclear structure theories, and enable critical comparisons with both electron-nuclear scattering and molecular spectroscopy.

physics.atom-ph

Relativistic hyperpolarizabilities for atomic H, Li, and Be$^+$ systems

The hyperpolarizability of an atom is a property that describes the nonlinear interaction between an atom and an external electric field leading to a higher-order Stark shift. Accurate evaluations of these coefficients for various systems are crucial to improve experimental precision in advanced atom-based clocks. However, there is a dearth of reports on atomic hyperpolarizabilities, particularly regarding relativistic hyperpolarizabilities. Thus, in this paper, we use fourth-order perturbation theory to establish a universal formula for the hyperpolarizability and calculate the relativistic hyperpolarizabilities of low-lying states for the monovalent electronic atomic systems H, Li, and Be$^+$. The highly accurate results given here for the H atom could serve as benchmarks for other theoretical methods.

physics.atom-ph

Revised $^3$He nuclear charge radius due to electronic hyperfine mixing

The significant discrepancy in the difference of squared nuclear charge radii $ΔR^2$ of $^{3,4}$He obtained from electronic-atom or muonic-atom energy levels is a puzzle. In this paper, we show that the tension is resolved by including off-diagonal mixing effects due to the hyperfine interaction. Our findings indicate that the hyperfine mixing effect from the $n\,^3\!S$ and $n\,^1\!S$ states ($n>2$) of $^3$He leads to a $-1.37$ kHz adjustment in the isotope shift of the $2\,^1\!S-2\,^3\!S$ transition, surpassing the current uncertainty by a factor of $7$. This results in a change of $-0.0064~\rm{fm}^2$ in $ΔR^2$, shifting from $1.0757(15)~\mathrm{fm}^2$ to $1.0693(15)~\mathrm{fm}^2$ as determined by Werf {\it et al.}, significantly reducing the discrepancy with the value of $1.0636(31)~\mathrm{fm}^2$ determined by $μ\rm{He}^+$, and aligning with the result of $1.069(3)$ $\mathrm{fm}^2$ obtained from the $2\,^3\!S-2\,^3\!P$ transition. This adjustment will result in a noticeable change in the absolute nuclear charge radius of $^{3}$He by $-0.0017~\rm{fm}$, aligning the revised value of $1.9715(11)~\mathrm{fm}$ with the value of $1.97007(94)~\mathrm{fm}$ determined by $μ^3\rm{He}^+$ within $1σ$. Our results offer crucial insights into resolving discrepancy in $ΔR^2$ for $^{3,4}$He and determining the charge radius of $^3$He.

physics.atom-ph

Measurement of hyperfine structure and the Zemach radius in $\rm^6Li^+$ using optical Ramsey technique

We investigate the $2\,^3\!S_1$--$2\,^3\!P_J$ ($J = 0, 1, 2$) transitions in $\rm^6Li^+$ using the optical Ramsey technique and achieve the most precise values of the hyperfine splittings of the $2\,^3\!S_1$ and $2\,^3\!P_J$ states, with smallest uncertainty of about 10~kHz. The present results reduce the uncertainties of previous experiments by a factor of 5 for the $2\,^3\!S_1$ state and a factor of 50 for the $2\,^3\!P_J$ states, and are in better agreement with theoretical values. Combining our measured hyperfine intervals of the $2\,^3\!S_1$ state with the latest quantum electrodynamic (QED) calculations, the improved Zemach radius of the $\rm^6Li$ nucleus is determined to be 2.44(2)~fm, with the uncertainty entirely due to the uncalculated QED effects of order $mα^7$. The result is in sharp disagreement with the value 3.71(16) fm determined from simple models of the nuclear charge and magnetization distribution. We call for a more definitive nuclear physics value of the $\rm^6Li$ Zemach radius.

physics.atom-ph

Precision calculation of hyperfine structure of $^{7,9}$Be$^{2+}$ ions

The hyperfine structures of the $2\,^3\!S_1$ and $2\,^3\!P_J$ states of the $^7$Be$^{2+}$ and $^9$Be$^{2+}$ ions are investigated within the framework of the nonrelativistic quantum electrodynamics (NRQED). The uncertainties of present hyperfine splitting results of $^9$Be$^{2+}$ are in the order of several tens of ppm, where two orders of magnitude improvement over the previous theory and experiment values has been achieved. The contribution of nuclear electric quadrupole moment to hyperfine splitting of $^7$Be$^{2+}$ has been studied. A scheme for determining the properties of Be nuclei in terms of Zemach radius or the electric quadrupole moment based on precise spectra is proposed, and it opens a new window for the study of Be nuclei.

physics.atom-ph

Long-range additive and nonadditive potentials in a hybrid system: Ground state atom, excited state atom, and ion

We report a theoretical study on the long-range additive and nonadditive potentials for a three-body hybrid atom-atom-ion system composed of one ground $S$ state Li atom, one excited $P$ state Li atom and one ground $S$ state Li$^+$ ion, Li($2\,^{2}S$)-Li($2\,^{2}P$)-Li$^+(1\,^{1}S$). The interaction coefficients are evaluated with highly accurate wave functions calculated variationally in Hylleraas coordinates. For this hybrid system the three-body nonadditive collective interactions (appearing in second-order) induced by the energy degeneracy and enhanced by the induction effect of the Li$^+$ ion through the internal electric field can be strong and even stronger than the two-body additive interactions at the same order. We find that for particular geometries the two-body additive interactions of the system sum to zero leaving only three-body nonadditive collective interactions making the present system potentially a platform to explore quantum three-body collective effects. We also extract first-principles leading coefficients of the long-range electrostatic, induction, and dispersion energies of Li$^+_2$ electronic states correlating to Li($2\,^{2}P$)-Li$^+(1\,^{1}S$), which until now were not available in the literature. The results should be especially valuable for the exploration of schemes to create trimers with ultracold atoms and ions in optical lattices.

physics.atom-ph

Probing Multiple Electric Dipole Forbidden Optical Transitions in Highly Charged Nickel Ions

Highly charged ions (HCIs) are promising candidates for the next generation of atomic clocks, owing to their tightly bound electron cloud, which significantly suppresses the common environmental disturbances to the quantum oscillator. Here we propose and pursue an experimental strategy that, while focusing on various HCIs of a single atomic element, keeps the number of candidate clock transitions as large as possible. Following this strategy, we identify four adjacent charge states of nickel HCIs that offer as many as six optical transitions. Experimentally, we demonstrated the essential capability of producing these ions in the low-energy compact Shanghai-Wuhan Electron Beam Ion Trap. We measured the wavelengths of four magnetic-dipole ($M$1) and one electric-quadrupole ($E$2) clock transitions with an accuracy of several ppm with a novel calibration method; two of these lines were observed and characterized for the first time in controlled laboratory settings. Compared to the earlier determinations, our measurements improved wavelength accuracy by an order of magnitude. Such measurements are crucial for constraining the range of laser wavelengths for finding the "needle in a haystack" narrow lines. In addition, we calculated frequencies and quality factors, evaluated sensitivity of these six transitions to the hypothetical variation of the electromagnetic fine structure constant $α$ needed for fundamental physics applications. We argue that all the six transitions in nickel HCIs offer intrinsic immunity to all common perturbations of quantum oscillators, and one of them has the projected fractional frequency uncertainty down to the remarkable level of 10$^{-19}$.

physics.atom-ph

Precision calculation of hyperfine structure and the Zemach radii of $^{6,7}$Li$^+$ ions

The hyperfine structures of the $2\,^3\!S_1$ states of the $^6$Li$^+$ and $^7$Li$^+$ ions are investigated theoretically to extract the Zemach radii of the $^6$Li and $^7$Li nuclei by comparing with precision measurements. The obtained Zemach radii are larger than the previous values of Puchalski and Pachucki [\href{https://link.aps.org/doi/10.1103/PhysRevLett.111.243001}{Phys. Rev. Lett. {\bf 111}, 243001 (2013)}] and disagree with them by about 1.5 and 2.2 standard deviations for $^6$Li and $^7$Li, respectively. Furthermore, our Zemach radius of $^6$Li differs significantly from the nuclear physics value, derived from the nuclear charge and magnetic radii [\href{https://link.aps.org/doi/10.1103/PhysRevA.78.012513}{Phys. Rev. A {\bf 78}, 012513 (2008)}], by more than 6 sigma, indicating an anomalous nuclear structure for $^6$Li. The conclusion that the Zemach radius of $^7$Li is about 40\% larger than that of $^6$Li is confirmed. The obtained Zemach radii are used to calculate the hyperfine splittings of the $2\,^3\!P_J$ states of $^{6,7}$Li$^+$, where an order of magnitude improvement over the previous theory has been achieved for $^7$Li$^+$.

physics.atom-ph

Complex coordinate rotation method based on gradient optimization

In atomic, molecular, and nuclear physics, the method of complex coordinate rotation is a widely used theoretical tool for studying resonant states. Here, we propose a novel implementation of this method based on the gradient optimization (CCR-GO). The main strength of the CCR-GO method is that it does not require manual adjustment of optimization parameters in the wave function; instead, a mathematically well-defined optimization path can be followed. Our method is proven to be very efficient in searching resonant positions and widths over a variety of few-body atomic systems, and can significantly improve the accuracy of the results. As a special case, the CCR-GO method is equally capable of dealing with bound-state problems with high accuracy, which is traditionally achieved through the usual extreme conditions of energy itself.

physics.atom-ph

Understanding two-photon double ionization of helium from the perspective of the characteristic time of dynamic transitions

By using the B-spline numerical method, we investigate a two-photon double-ionization (TPDI) process of helium in a high-frequency laser field with its frequency ranging from 1.6~a.u. to 3.0~a.u. and the pulse duration ranging from 75 to 160~attoseconds. We found that there exists a characteristic time $t_{c}$ for a TPDI process, such that the pattern of energy distribution of two ionized electrons presents a peak or two, depending respectively on whether the pulse duration is shorter or longer than $t_{c}$. Especially, as the pulse duration is larger than $t_c$, the TPDI spectrum shows a double-peak structure which is attributed to the fact that most of the electron-electron Coulomb interaction energy is acquired by single electron during their oscillation around the nucleus before the two electrons leave. Additionally, if the photon energy is less than the ionization energy of He$^{+}$, $t_{c}$ is not a fixed value, and it increases as the photon energy decreases; while if the energy of a photon is greater than the ionization energy of He$^{+}$, $t_{c}$ is fixed at about 105 attoseconds. We further found that, for a helium-like ion in its ground state, the characteristic time for the case of the photon energy larger than the ionization energy of the second electron has a key relation with the Coulomb interaction energy $\overline{V}_{12}$ between the two electrons, which can be expressed as $t_{c}\overline{V}_{12}=4.192$, a type of quantum mechanical uncertainty relation between time and energy. In addition, this relation can be attributed to the existence of a minimal evolution time from the ground state to a double ionization state with two electrons carrying different energies. These results may shed light on deeper understanding of many-electron quantum dynamical processes.

physics.atom-ph

Calculations of long-range three-body interactions for He($n_0\,^λS$)-He($n_0\,^λS$)-He($n_0^{\prime}\,^λL$)

We theoretically investigate long-range interactions between an excited $L$ state He atom and two identical $S$ state He atoms, for the cases of the three atoms all in spin singlet states or all in spin triplet states, denoted by He($n_0\,^λS$)-He($n_0\,^λS$)-He($n_0^{\prime}\,^λL$), with $n_0$ and $n_0'$ principal quantum numbers, $λ=1$ or 3 the spin multiplicity, and $L$ the orbital angular momentum of a He atom. Using degenerate perturbation theory for the energies up to second-order, we evaluate the coefficients $C_3$ of the first order dipolar interactions and the coefficients $C_6$ and $C_8$ of the second order additive and nonadditive interactions. Both the dipolar and dispersion interaction coefficients, for these three-body degenerate systems, show dependences on the geometrical configurations of the three atoms. The nonadditive interactions start to appear in second-order. To demonstrate the results and for applications, the obtained coefficients $C_n$ are evaluated with highly accurate variationally-generated nonrelativistic wave functions in Hylleraas coordinates for He($1\,^{1}S$)-He($1\,^{1}S$)-He($2\,^{1}S$), He${(1\,^{1}S)}$-He${(1\,^{1}S)}$-He${(2\,^{1}P)}$, He${(2\,^{1}S)}$-He${(2\,^{1}S)}$-He${(2\,^{1}P)}$, and He${(2\,^{3}S)}$-He${(2\,^{3}S)}$-He${(2\,^{3}P)}$. The calculations are given for three like-nuclei for the cases of hypothetical infinite mass He nuclei, and of real finite mass $^4{}$He or $^3{}$He nuclei. The special cases of the three atoms in equilateral triangle configurations are explored in detail, and for the cases where one of the atoms is in a $P$ state, we also present results for the atoms in an isosceles right triangle configuration or in an equally spaced co-linear configuration. The results can be applied to construct potential energy surfaces for three helium atom systems.

physics.atom-ph

Nonsequential double ionization of helium in IR+XUV two-color laser fields II: Collision-excitation ionization process

The collision-ionization mechanism of nonsequential double ionization (NSDI) process in IR+XUV two-color laser fields [\PRA \textbf{93}, 043417 (2016)] has been investigated by us recently. Here we extend this work to study the collision-excitation-ionization (CEI) mechanism of NSDI processes in the two-color laser fields with different laser conditions. It is found that the CEI mechanism makes a dominant contribution to the NSDI as the XUV photon energy is smaller than the ionization threshold of the He$^+$ ion, and the momentum spectrum shows complex interference patterns and symmetrical structures. By channel analysis, we find that, as the energy carried by the recollision electron is not enough to excite the bound electron, the bound electron will absorb XUV photons during their collision, as a result, both forward and backward collisions make a comparable contributions to the NSDI processes. However, it is found that, as the energy carried by the recollision electron is large enough to excite the bound electron, the bound electron does not absorb any XUV photon and it is excited only by sharing the energy carried by the recollsion electron, hence the forward collision plays a dominant role on the NSDI processes. Moreover, we find that the interference patterns of the NSDI spectra can be reconstructed by the spectra of two above-threshold ionization (ATI) processes, which may be used to analyze the structure of the two separate ATI spectra by NSDI processes.

physics.atom-ph

General theory for Rydberg states of atoms: nonrelativistic case

We carry out a complete derivation on nonrelativistic energies of atomic Rydberg states, including finite nuclear mass corrections. Several missing terms are found and a discrepancy is confirmed in the works of Drachman [in Long Range Casimir Forces: Theory and Recent Experiments on Atomic Systems, edited by F. S. Levin and D. A. Micha (Plenum, New York, 1993)] and Drake [Adv. At., Mol., Opt. Phys. 31, 1 (1993)]. As a benchmark, we present a detailed tabulation of different energy levels.

physics.atom-ph

Calculations of long-range three-body interactions for Li($2\,^2S$)-Li($2\,^2S$)-Li($2\,^2P$)

General formulas for calculating the several leading long-range interactions among three identical atoms where two atoms are in identical $S$ states and the other atom is in a $P$ state are obtained using perturbation theory for the energies up to second order. The first order (dipolar) interactions depend on the geometrical configurations of the three atoms. In second order, additive and nonadditive dispersion interactions are obtained. The nonadditive interactions depend on the geometrical configurations in marked contrast to the case where all three atoms are in identical $S$ states, for which the nonadditive (also known as triple-dipole or as Axilrod-Muto-Teller) dispersion interactions appear at the third order. The formalism is demonstrated by the calculation of the coefficients for the Li($2\,^2S$)-Li($2\,^2S$)-Li($2\,^{2}P$) system using variationally-generated atomic lithium wave functions in Hylleraas coordinates. The present dipolar coefficients and additive and nonadditive dispersion coefficients may be useful in constructing precise potential energy surfaces for this three lithium atom system.

physics.atom-ph

Critical nuclear charge and shape resonances for the two-electron systems

The hydrogen negative ion H$^-$ is the simplest two-electron system that exists in nature. This system is not only important in astrophysics but it also serves as an ideal ground to study electron-electron correlations. The peculiar balance of the correlations between the two electrons with the interaction of electron-nucleus in H$^-$ makes this system to have only two bound states, one being the ground state $1s^2\,^{1}\!S^e$ and the other the doubly-excited metastable state $2p^2\,^{3}\!P^e$ embedded below the hydrogen $n=2$ threshold. Here we report a calculation for the $2p^2\,^{3}\!P^e$ state of H$^-$ that yields the energy eigenvalue $E=-0.125\,355\,451\,242\,864\,058\,376\,012\,313\,25(2)$, in atomic units. Our result substantially improves the best available result by 16 orders of magnitude. We further study the critical nuclear charge $Z_{\rm cr}$, the minimum value of nuclear charge $Z$ that is required to bind a nucleus and two electrons. Our determination of $Z_{\rm cr}$ for the $2p^2\,^{3}\!P^e$ state of two-electron systems is $Z_{\rm cr}=0.994\,781\,292\,240\,366\,246\,3(1)$, corresponding to $1/Z_{\rm cr}= 1.005\,246\,085\,546\,985\,509\,4(1)$, which improves the best published value of $Z_{\rm cr}$ by about 10 orders of magnitude. We further investigate in a definitive way the unexplored regime of $Z < Z_{\rm cr}$ using the method of complex scaling and establish precise shape resonance poles for the state of $2p^2\,^{3}\!P^e$ in the complex energy plane.

physics.atom-ph

High-precision nonadiabatic calculations of dynamic polarizabilities and hyperpolarizabilities for the lowlying vibrational-rotational states of hydrogen molecular ions

The static and dynamic electric multipolar polarizabilities and second hyperpolarizabilities of the H$_2^+$, D$_2^+$, and HD$^+$ molecular ions in the ground and first excited states are calculated nonrelativistically using explicitly correlated Hylleraas basis sets. The calculations are fully nonadiabatic; the Born-Oppenheimer approximation is not used. Comparisons are made with published theoretical and experimental results, where available. In our approach, no derivatives of energy functions nor derivatives of response functions are needed. In particular, we make contact with earlier calculations in the Born-Oppenheimer calculation where polarizabilities were decomposed into electronic, vibrational, and rotational contributions and where hyperpolarizabilities were determined from derivatives of energy functions. We find that the static hyperpolarizability for the ground state of HD$^+$ is seven orders of magnitude larger than the corresponding dipole polarizability. For the dipole polarizability of HD$^+$ in the first excited-state the high precision of the present method facilitates treatment of a near cancellation between two terms. For applications to laser spectroscopy of trapped ions we find tune-out and magic wavelengths for the HD$^+$ ion in a laser field. In addition, we also calculate the first few leading terms for long-range interactions of a hydrogen molecular ion interacting with a ground-state H, He, and Li atoms.

physics.atom-ph

Terrace-like structure in the above-threshold ionization spectrum of an atom in an IR+XUV two-color laser field

Based on the frequency-domain theory, we investigate the above-threshold ionization (ATI) process of an atom in a two-color laser field with infrared (IR) and extreme ultraviolet (XUV) frequencies, where the photon energy of the XUV laser is close to or larger than the atomic ionization threshold. By using the channel analysis, we find that the two laser fields play different roles in an ionization process, where the XUV laser determines the ionization probability by the photon number that the atom absorbs from it, while the IR laser accelerates the ionized electron and hence widens the electron kinetic energy spectrum. As a result, the ATI spectrum presents a terrace-like structure. By using the saddle-point approximation, we obtain a classical formula which can predict the cutoff of each plateau in the terrace-like ATI spectrum. Furthermore, we find that the difference of the heights between two neighboring plateaus in the terrace-like structure of the ATI spectrum increases as the frequency of the XUV laser increases.

physics.atom-ph