arXiv subjects

Zuzana Kanuchova

Publications and source records attributed to Zuzana Kanuchova.

4 recordsLinked to original sources

arXiv2021

Sulfur Ice Astrochemistry: A Review of Laboratory Studies

Sulfur is the tenth most abundant element in the universe and is known to play a significant role in biological systems. Accordingly, in recent years there has been increased interest in the role of sulfur in astrochemical reactions and planetary geology and geochemistry. Among the many avenues of research currently being explored is the laboratory processing of astrophysical ice analogues. Such research involves the synthesis of an ice of specific morphology and chemical composition at temperatures and pressures relevant to a selected astrophysical setting (such as the interstellar medium or the surfaces of icy moons). Subsequent processing of the ice under conditions that simulate the selected astrophysical setting commonly involves radiolysis, photolysis, thermal processing, neutral-neutral fragment chemistry, or any combination of these, and has been the subject of several studies. The in-situ changes in ice morphology and chemistry occurring during such processing has been monitored via spectroscopic or spectrometric techniques. In this paper, we have reviewed the results of laboratory investigations concerned with sulfur chemistry in several astrophysical ice analogues. Specifically, we review (i) the spectroscopy of sulfur-containing astrochemical molecules in the condensed phase, (ii) atom and radical addition reactions, (iii) the thermal processing of sulfur-bearing ices, (iv) photochemical experiments, (v) the non-reactive charged particle radiolysis of sulfur-bearing ices, and (vi) sulfur ion bombardment of and implantation in ice analogues. Potential future studies in the field of solid phase sulfur astrochemistry are also discussed in the context of forthcoming space missions, such as the NASA James Webb Space Telescope and the ESA Jupiter Icy Moons Explorer mission.

astro-ph.EP↗

arXiv2020

A Systematic Study on the Absorption Features of Interstellar Ices in Presence of Impurities

Spectroscopic studies play a key role in the identification and analysis of interstellar ices and their structure. Some molecules have been identified within the interstellar ices either as pure, mixed, or even as layered structures. Absorption band features of water ice can significantly change with the presence of different types of impurities (CO, CO2, CH3OH, H2CO, etc.). In this work, we carried out a theoretical investigation to understand the behavior of water band frequency, and strength in the presence of impurities. The computational study has been supported and complemented by some infrared spectroscopy experiments aimed at verifying the effect of HCOOH, NH3 , and CH3 OH on the band profiles of pure H2O ice. Specifically, we explored the effect on the band strength of libration, bending, bulk stretching, and free-OH stretching modes. Computed band strength profiles have been compared with our new and existing experimental results, thus pointing out that vibrational modes of H2O and their intensities can change considerably in the presence of impurities at different concentrations. In most cases, the bulk stretching mode is the most affected vibration, while the bending is the least affected mode. HCOOH was found to have a strong influence on the libration, bending, and bulk stretching band profiles. In the case of NH3, the free-OH stretching band disappears when the impurity concentration becomes 50%. This work will ultimately aid a correct interpretation of future detailed spaceborne observations of interstellar ices by means of the upcoming JWST mission.

astro-ph.GA↗

arXiv2016

IAU Meteor Data Center | the shower database: a status report

Currently, the meteor shower part of Meteor Data Center database includes: 112 established showers, 563 in the working list, among them 36 have the pro tempore status. The list of shower complexes contains 25 groups, 3 have established status and 1 has the pro tempore status. In the past three years, new meteor showers submitted to the MDC database were detected amongst the meteors observed by CAMS stations (Cameras for Allsky Meteor Surveillance), those included in the EDMOND (European viDeo MeteOr Network Database), those collected by the Japanese SonotaCo Network, recorded in the IMO (International Meteor Organization) database, observed by the Croatian Meteor Network and on the Southern Hemisphere by the SAAMER radar. At the XXIXth General Assembly of the IAU in Honolulu, Hawaii in 2015, the names of 18 showers were officially accepted and moved to the list of established ones. Also, one shower already officially named (3/SIA the Southern iota Aquariids) was moved back to the working list of meteor showers. At the XXIXth GA IAU the basic shower nomenclature rule was modified, the new formulation predicates \The general rule is that a meteor shower (and a meteoroid stream) should be named after the constellation that contains the nearest star to the radiant point, using the possessive Latin form". Over the last three years the MDC database was supplemented with the earlier published original data on meteor showers, which permitted verification of the correctness of the MDC data and extension of bibliographic information. Slowly but surely new database software options are implemented, and software bugs are corrected.

astro-ph.EP↗

arXiv2014

The prediction of meteor showers from all potential parent comets

The objectives of this project are to predict new meteor showers associated with as many as possible known periodic comets and to find a generic relationship of some already known showers with these comets. For a potential parent comet, we model a theoretical stream at the moment of its perihelion passage in a far past, and follow its dynamical evolution until the present. Subsequently, we analyze the orbital characteristics of the parts of the stream that approach the Earth's orbit. Modelled orbits of the stream particles are compared with the orbits of actual photographic, video, and radar meteors from several catalogues. The whole procedure is repeated for several past perihelion passages of the parent comet. To keep our description compact but detailed, we usually present only either a single or a few parent comets with their associated showers in one paper. Here, an overview of the results from the modelling of the meteor-shower complexes of more than ten parent bodies will be presented. This enables their diversities to be shown. Some parent bodies may associate meteor showers which exhibit a symmetry of their radiant areas with respect to the ecliptic (ecliptical, toroidal, or showers of an ecliptic-toroidal structure), and there are showers which have no counterpart with a similar ecliptical longitude on the opposite hemisphere. However, symmetry of the radiant areas of the pair filaments with respect to the Earth's apex is visible in almost all the complexes which we examined.

astro-ph.EP↗