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Band Gap of Strained Graphene Nanoribbons

The band structures of strained graphene nanoribbons (GNRs) are examined by a tight binding Hamiltonian that is directly related to the type and strength of strains. Compared to the two-dimensional graphene whose band gap remains close to zero even if a large strain is applied, the band gap of graphene nanoribbon (GNR) is sensitive to both uniaxial and shears strains. The effect of strain on the electronic structure of a GNR strongly depends on its edge shape and structural indices. For an armchair GNR, uniaxial weak strain changes the band gap in a linear fashion, and for a large strain, it results in periodic oscillation of the band gap. On the other hand, shear strain always tend to reduce the band gap. For a zigzag GNR, the effect of strain is to change the spin polarization at the edges of GNR, thereby modulate the band gap. A simple analytical model is proposed to interpret the band gap responds to strain in armchair GNR, which agrees with the numerical results.

cond-mat.mes-hall↗

Electron Transfer rate between a electrode and a bridged redox

We derive an explict bias dependent expression for electron transfer reaction rate from a solvated redox to a electrode through a bridged molecule of arbitrary length. The interaction of the solvated redox with the solvent is modelled as a classical harmonic oscillator bath. The effect of competing process, namely resonance tunneling between redox and bridge and the solvation of the redox is investigated. Plots were produced for the case of 5 atom bridge. Our analysis shows that for certain suitable value of nearest-neighbour coupling, it is possible to block electron transfer in certain intermediate voltage regime

cond-mat.mes-hall↗

Anomalous Light Absorption by Small Particles

A new type of resonant light absorption by a small particle (nanocluster) is reported. The problem cannot be described within the commonly used dipole scattering approximation and should be studied with methods based upon the exact Mie solution. It is shown that the absorption cross-section has giant maxima realized at small values of the imaginary part of the complex dielectric permittivity of the particle. The maxima are situated in the vicinity of the plasmon (polariton) resonances and correspond to the regions where the dissipative damping equals the radiative one. The case is similar to the recently introduced anomalous scattering [PRL vol. 97, 263902 (2006)] and exhibits similar peculiarities.

physics.optics↗

Near-infrared photoresponse in single walled carbon nanotube/polymer composite films

We present a near-infrared photoresponse study of single-walled carbon nanotube/poly(3-hexylthiophene)-block-polystyrene polymer (SWCNT/P3HT-b-PS) composite films for different loading ratios of SWCNT in the polymer matrix. Compared to the pure SWCNT film, the photoresponse [(light current - dark current)/dark current] is much larger in the SWCNT/polymer composite films. The photoresponse is up to 157% when SWCNTs are embedded in P3HT-b-PS while for a pure SWCNT film it is only 40%. We also show that the photocurrent strongly depends on the position of the laser spot with maximum photocurrent occurring at the metal-film interface. We explain the photoresponse due to exciton dissociations and charge carrier separation caused by a Schottky barrier at the metallic electrode - SWCNT interface

cond-mat.mes-hall↗

Polarons in 2+epsilon dimensions and giant figure of merit of semiconducting nanolayers

Polarons - electrons coupled with lattice vibrations - play a key role in the transport and optical properties of many systems of reduced dimension and dimensionality. Their confinement affects drastically the phonon, polaron, bipolaron and multi-polaron properties of quantum wells. Here we calculate the energy spectrum and thermopower of polarons confined to a potential well as a function of the well thickness. We show that the polaron mass enhancement in 2+epsilon dimensions explains a giant thermolectric power recently observed in doped semiconducting nanolayers (multiple quantum wells (MQWs)), and propose a route for enhancing the performance of thermoelectric energy nanoconverters increasing their figure of merit by more than one order of magnitude.

cond-mat.mes-hall↗

Crossover of the Hall-voltage distribution in AC quantum Hall effect

The distribution of the Hall voltage induced by low-frequency AC current is studied theoretically in the incoherent linear transport of quantum Hall systems. It is shown that the Hall-voltage distribution makes a crossover from the uniform distribution to a concentrated-near-edges distribution as the frequency is increased or the diagonal conductivity is decreased. This crossover is also reflected in the frequency dependence of AC magnetoresistance.

cond-mat.mes-hall↗

Universality between current- and field-driven domain wall dynamics in ferromagnetic nanowires

Spin-polarized electric current exerts torque on local magnetic spins, resulting in magnetic domain-wall (DW) motion in ferromagnetic nanowires. Such current-driven DW motion opens great opportunities toward next-generation magnetic devices controlled by current instead of magnetic field. However, the nature of the current-driven DW motion--considered qualitatively different from magnetic-field-driven DW motion--remains yet unclear mainly due to the painfully high operation current densities J_OP, which introduce uncontrollable experimental artefacts with serious Joule heating. It is also crucial to reduce J_OP for practical device operation. By use of metallic Pt/Co/Pt nanowires with perpendicular magnetic anisotropy, here we demonstrate DW motion at current densities down to the range of 10^9 A/m^2--two orders smaller than existing reports. Surprisingly the current-driven motion exhibits a scaling behaviour identical to the field-driven motion and thus, belongs to the same universality class despite their qualitative differences. Moreover all DW motions driven by either current or field (or by both) collapse onto a single curve, signalling the unification of the two driving mechanisms. The unified law manifests non-vanishing current efficiency at low current densities down to the practical level, applicable to emerging magnetic nanodevices.

cond-mat.mtrl-sci↗

Quantum transport in honeycomb lattice ribbons with zigzag edges: A theoretical study

We explore electron transport properties in honeycomb lattice ribbons with zigzag edges coupled to two semi-infinite one-dimensional metallic electrodes. The calculations are based on the tight-binding model and the Green's function method, which numerically compute the conductance-energy and current-voltage characteristics as functions of the lengths and widths of the ribbons. Our numerical results predict that for such a ribbon an energy gap always appears in the conductance spectrum across the energy E=0. With the increase of the size of the ribbon, the gap gradually decreases but it never vanishes. This clearly manifests that a honeycomb lattice ribbon with zigzag edges always exhibits the semiconducting behavior, and it becomes much more clearly visible from our presented current-voltage characteristics.

cond-mat.mes-hall↗

Dimensional Crossover of the Dephasing Time in Disordered Mesoscopic Rings: From Diffusive through Ergodic to 0D Behavior

We analyze dephasing by electron interactions in a small disordered quasi-one dimensional (1D) ring weakly coupled to leads, where we recently predicted a crossover for the dephasing time $\tPh(T)$ from diffusive or ergodic 1D ($\tPh^{-1} \propto T^{2/3}, T^{1}$) to $0D$ behavior ($\tPh^{-1} \propto T^{2}$) as $T$ drops below the Thouless energy $\ETh$. We provide a detailed derivation of our results, based on an influence functional for quantum Nyquist noise, and calculate all leading and subleading terms of the dephasing time in the three regimes. Explicitly taking into account the Pauli blocking of the Fermi sea in the metal allows us to describe the $0D$ regime on equal footing as the others. The crossover to $0D$, predicted by Sivan, Imry and Aronov for 3D systems, has so far eluded experimental observation. We will show that for $T \ll \ETh$, $0D$ dephasing governs not only the $T$-dependence for the smooth part of the magnetoconductivity but also for the amplitude of the Altshuler-Aronov-Spivak oscillations, which result only from electron paths winding around the ring. This observation can be exploited to filter out and eliminate contributions to dephasing from trajectories which do not wind around the ring, which may tend to mask the $T^{2}$ behavior. Thus, the ring geometry holds promise of finally observing the crossover to $0D$ experimentally.

cond-mat.mes-hall↗

Bloch-Wannier theory of persistent current in a ring made of the band insulator: Exact result for one-dimensional lattice and estimates for realistic lattices

In this work, persistent currents in rings made of band insulators are analyzed theoretically. We first formulate a recipe which determines the Bloch states of a one-dimensional (1D) ring from the Bloch states of an infinite 1D crystal created by the periodic repetition of the ring. Using the recipe, we derive an expression for the persistent current in a 1D ring made of an insulator with an arbitrary valence band E(k). To find an exact result for a specific insulator, we consider a 1D ring represented by a periodic lattice of N identical sites with a single value of the on-site energy. If the Bloch states in the ring are expanded over a complete set of N on-site Wannier functions, the discrete on-site energy splits into the energy band. At full filling, the band emulates the valence band of the band insulator and the ring is insulating. It carries a persistent current equal to the product of N and the derivative of the on-site energy with respect to the magnetic flux. This current is not zero if one takes into account that the on-site Wannier function and consequently the on-site energy of each ring site depend on magnetic flux. To derive the current analytically, we expand all N Wannier functions of the ring over the infinite basis of Wannier functions of the constituting infinite 1D crystal and eventually determine the crystal Wannier functions by a method of localized atomic orbitals. Finally, we estimate the persistent current at full filling in rings made of real band insulators (GaAs, Ge, InAs). The current decays with the ring length exponentially due to the exponential decay of the Wannier functions. In spite of that, it can be of measurable size.

cond-mat.mes-hall↗

Atomic-scale Field-effect Transistor as a Thermoelectric Power Generator and Self-powered Device

Using first-principles approaches, we have investigated the thermoelectric properties and the energy conversion efficiency of the paired metal-Br-Al junction. Owing to the narrow states in the vicinity of the chemical potential, the nanojunction has large Seebeck coefficients such that it can be considered an efficient thermoelectric power generator. We also consider the nanojunction in a three-terminal geometry, where the current, voltage, power, and efficiency can be efficiently modulated by the gate voltages. Such current-voltage characteristics could be useful in the design of nano-scale electronic devices such, as a transistor or switch. Notably, the nanojunction as a transistor with a fixed finite temperature difference between electrodes can power itself using the Seebeck effect.

cond-mat.mes-hall↗

Current modulation at nano-scale level: A theoretical study

We explore the possibilities of current modulation at nano-scale level using mesoscopic rings. A single mesoscopic ring or an array of such rings is used for current modulation where each ring is threaded by a time varying magnetic flux $ϕ$ which plays the central role in the modulation action. Within a tight-binding framework, all the calculations are done based on the Green's function formalism. We present numerical results for the two-terminal conductance and current which support the essential features of current modulation. The analysis may be helpful in fabricating mesoscopic or nano-scale electronic devices.

cond-mat.mes-hall↗

Towards 4 formalisms description of properties of the unconventional Josephson junction and unconventional SQUIDs made by putting non-superconducting strip on the top of superconducting strip

We present the theoretical approach to study the unconventional Josephson junction (uJJ) made by putting the non-superconduncting strip on the top of superconducting strip. We work in the framework of the Ginzburg-Landau, Bogoliubov de Gennes and Usadel formalisms. We solve the non-linear parital differential equations numerically for few simple cases. We obtaine the eigenenergies of the uJJ by means of combined GL and BdGe method. cases. We predict the occurence of the physical effect, which we call the topological Meissner effect. Basing on the obtained results and current knowledge on Josephson junctions we point the future perspectives of the research on uJJs.

cond-mat.mes-hall↗

Quantum rotator: some examples in modern spirit

Rotation of the nucleus and rotation of the electronic cloud of the atom/ion were considered. It was shown that these rotations are not practically possible. Rotation of the cloud of delocalized electrons and ionic core of a fullerene molecule and these of the ring of a nanotube were discussed. It was shown that the rotation of the cloud of delocalized electrons of a fullerene molecule is possible and it goes in a quantum way when temperature is essentially lower than 40 K. Rotation of the ion core of a fullerene molecule is possible in a classical way only. The same should be said about rotations in the ring of a nanotube.

physics.chem-ph↗

Buckling of Graphene Layers Supported by Rigid Substrates

We formulate a nonlinear continuum model of a graphene sheet supported by a flat rigid substrate. The sheet is parallel to the substrate and loaded on a pair of opposite edges. A typical cross-section of the sheet is modeled as an elastica. We use elementary techniques from bifurcation theory to investigate how the buckling of the sheet depends on the boundary conditions, the composition of the substrate, and the length of the sheet. We also present numerical results that illustrate snap-buckling of the sheet.

cond-mat.mes-hall↗

Thickness monitoring of graphene on SiC using low-energy electron diffraction

The formation of epitaxial graphene on SiC is monitored in-situ using low-energy electron diffraction (LEED). The possibility of using LEED as an in-situ thickness monitor of the graphene is examined. The ratio of primary diffraction spot intensities for graphene compared to SiC is measured for a series of samples of known graphene thickness (determined using low-energy electron microscopy). It is found that this ratio is effective for determining graphene thicknesses in the range 1 to 3 monolayers. Effects of a distribution of graphene thicknesses on this method of thickness determination are considered.

cond-mat.mtrl-sci↗

Atomistic mechanisms and diameter selection during nanorod growth

We study in this paper the atomic mechanisms of nanorod growth and propose the way of diameter selection of nanorod. A characteristic radius is demonstrated to be crucial in nanorod growth, which increases proportional to one fifth power of the ratio of the interlayer hopping rate of adatoms across the monolayer steps to the deposition rate. When the radius of the initial island is larger than this characteristic radius, the growth morphology evolves from a taper-like structure to a nanorod with radius equal to the characteristic radius after some transient layers. Otherwise the nanorod morphology can be maintained during the growth, with stable radius being limited by both the radius of the initial island and the three-dimensional Ehrlich-Schwoebel barrier. Therefore different growth modes and diameter of nanorod can be selected by tuning the characteristic radius. The theoretical predictions are in good agreement with experimental observations of ZnO growth.

cond-mat.mes-hall↗

Theoretical Reproduction of the Lineshapes of Nonlinear Conductance Observed in a Quantum Point Contact

The nonlinear conductance observed in a quantum point contact is theoretically reproduced for the entire range of applied bias. The single-impurity Anderson model with two reservoirs at different chemical potentials is studied for a sequential change of the gate voltage. The imbalance in the left and right Kondo coupling strength is introduced by the displacement of the Kondo impurity by the electric field produced in the constriction of quantum point contact. We reveal the origin of the side peaks and study the behavior of the height and width of the zero-bias anomaly.

cond-mat.mes-hall↗