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arXiv2019

Laser-based underwater transfer of radio-frequency clock signal with electronic phase compensation

We demonstrate a laser-based underwater transfer of radio frequency clock signal with a phase compensation technique. With this frequency transfer scheme, a 100 MHz signal has been transferred over 5 m underwater link. Timing jitter power spectral density, timing fluctuations and instabilities were all measured to evaluate the quality of the transferred frequency signal. The experimental results show the root-mean-square (RMS) timing fluctuations of the transferred frequency signal over 5 m underwater link with and without phase compensation are 2.1 ps and 9.6 ps within 5000 s, respectively. The relative fractional frequency instabilities are on the order of 5E-13 at 1 s and 7E-16 at 1000 s for phase-compensated link, and 2E-12 at 1 s and 7E-15 at 1000 sfor uncompensated link, respectively. The proposed frequency transfer scheme has a potential application that disseminating Cs and H-master clocks signal over the underwater transmission link since the stability of the transmission link is superior to these atomic clocks.

physics.app-ph↗

arXiv2019

Influence of Carbon Nanomaterial Counter Electrode Composition, Dye Selection, and Photoanode Scaffolding on DSSC Performance

As technology continues to evolve, the demand for renewable and sustainable energy continues to grow. As the use of renewable energies, specifically photovoltaics, is continually being adopted and incorporate into everyday life, it is evident that a need for an increase in the amount of energy that is derived from these processes is necessary. In the exploration of dye sensitized solar cells (DSSC) a recent and increased involvement in the application of carbon based nanomaterials and the effects of their unique electronic properties is being investigated. Additionally, as the development of DSSC continues to break way, different methods of dye selection and photoanode scaffolding are being researched to ultimately increase the Power Conversion Efficiency (PCE) of these cells.

physics.app-ph↗

arXiv2019

High-Resolution Nuclear Magnetic Resonance Spectroscopy With Picomole Sensitivity by Hyperpolarisation On A Chip

We show that high-resolution NMR can reach picomole sensitivity for micromolar concentrations of analyte by combining parahydrogen induced hyperpolarisation (PHIP)with a high-sensitivity transmission line micro-detector. The para-enriched hydrogen gas is introduced into solution by diffusion through a membrane integrated into a microfluidic chip. NMR microdetectors, operating with sample volumes of a few $μ$L or less, benefit from a favourable scaling of mass sensitivity. However, the small volumes make it very difficult to detect species present at less than millimolar concentrations in microfluidic NMR systems. In view of overcoming this limitation, we implement parahydrogen-induced polarisation (PHIP) on a microfluidic device with 2.5~$\mathrm{μL}$ detection volume. Integrating the hydrogenation reaction into the chip minimises polarisation losses to spin-lattice relaxation, allowing the detection of picomoles of substance. This corresponds to a concentration limit of detection of better than $\mathrm{1\,μM\,\sqrt{s}}$, unprecedented at this sample volume. The stability and sensitivity of the system allows quantitative characterisation of the signal dependence on flow rates and other reaction parameters and permits homo- and heteronuclear 2D NMR experiments at natural $^{13}\mathrm{C}$ abundance.

physics.chem-ph↗

arXiv2019

Bistatic scattering forward model validation using GNSS-R observations

In this paper we advance a previously developed bistatic scattering forward model to include the circularly polarized incident and scattered waves, which is the case for Global Navigation Satellite System (GNSS) reflectometry. This model development enables retrieval of soil moisture from Signals of Opportunity (SoOp) bistatic observations, e.g., from the Cyclone Global Navigation Satellite System (CYGNSS) observations and GNSS Reflectometer Instrument for Bistatic Synthetic Aperture Radar (GRIBSAR). In order to validate the forward model with measured data, we present a method to construct the Delay Doppler Map (DDM) from simulations of the forward model. The forward model Radar Cross Section (RCS) predictions will be compared with actual measurements. The validated model is intended for use in soil moisture retrievals.

physics.app-ph↗

arXiv2019

Near-IR wide field-of-view Huygens metalens for outdoor imaging applications

The ongoing effort to implement compact and cheap optical systems is the main driving force for the recent flourishing research in the field of optical metalenses. Metalenses are a type of metasurface, used for focusing and imaging applications, and are implemented based on the nanopatterning of an optical surface. The challenge faced by metalens research is to reach high levels of performance, using simple fabrication methods suitable for mass-production. In this paper we present a Huygens nanoantenna based metalens, designed for outdoor photographic/surveillance applications in the near-infra-red. We show that good imaging quality can be obtained over a field-of-view (FOV) as large as +/-15 degrees. This first successful implementation of metalenses for outdoor imaging applications is expected to provide insight and inspiration for future metalens imaging applications.

physics.optics↗

arXiv2019

Efficient Er/O Doped Silicon Light-Emitting Diodes at Communication Wavelength by Deep Cooling

A silicon light source at communication wavelength is the bottleneck for developing monolithically integrated silicon photonics. Doping silicon with erbium ions was believed to be one of the most promising approaches but suffers from the aggregation of erbium ions that are efficient non-radiative centers, formed during the standard rapid thermal treatment. Here, we apply a deep cooling process following the high-temperature annealing to suppress the aggregation of erbium ions by flushing with Helium gas cooled in liquid nitrogen. The resultant light emitting efficiency is increased to a record 14% at room temperature, two orders of magnitude higher than the sample treated by the standard rapid thermal annealing. The deep-cooling-processed Si samples were further made into light-emitting diodes. Bright electroluminescence with a spectral peak at 1.54 um from the silicon-based diodes was also observed at room temperature. With these results, it is promising to develop efficient silicon lasers at communication wavelength for the monolithically integrated silicon photonics.

physics.app-ph↗

arXiv2019

Flexible Ultrastrong 100-nm Polyethylene Membranes with Polygonal Pore Structures

Robust nanoporous polymer films with approximate 100-nm thicknesses would be broadly applicable in technological areas such as flexible sensors, artificial skins, separators, antireflection and self-cleaning films. However, the creation of these films has been extremely challenging. To date, all reported ultrathin films are of insufficient mechanical strength for use without substrate supports. We describe here the fabrication of a new ultrastrong and highly flexible ultrahigh molecular weight polyethylene (UHMWPE) 100-nm porous membrane. Scanning and transmission electron microscopy evaluations of film microstructures reveal a planar fibrous structure with randomly oriented polygonal interconnected pores. Moreover, the tensile strength of this film is twice as strong as that of solid stainless steel, with a measured in-plane tensile strength and ductility of approximately 900 MPa and 26%, respectively. We further coated our newly developed film with a monolayer graphene to invent an optically transparent and fully conformable piezoresistive skin sensor and thus demonstrated a potential application.

physics.app-ph↗

arXiv2019

Manufacturing low dissipation superconducting quantum processors

Enabling applications for solid state quantum technology will require systematically reducing noise, particularly dissipation, in these systems. Yet, when multiple decay channels are present in a system with similar weight, resolution to distinguish relatively small changes is necessary to infer improvements to noise levels. For superconducting qubits, uncontrolled variation of nominal performance makes obtaining such resolution challenging. Here, we approach this problem by investigating specific combinations of previously reported fabrication techniques on the quality of 242 thin film superconducting resonators and qubits. Our results quantify the influence of elementary processes on dissipation at key interfaces. We report that an end-to-end optimization of the manufacturing process that integrates multiple small improvements together can produce an average ${\overline{T}_{1}=76\pm13~μ}$s across 24 qubits with the best qubits having ${T_1\geq110~μ}$s. Moreover, our analysis places bounds on energy decay rates for three fabrication-related loss channels present in state-of-the-art superconducting qubits. Understanding dissipation through such systematic analysis may pave the way for lower noise solid state quantum computers.

quant-ph↗

arXiv2019

Accelerating Silicon Photonic Parameter Extraction using Artificial Neural Networks

We present a novel silicon photonic parameter extraction tool that uses artificial neural networks. While other parameter extraction methods are restricted to relatively simple devices whose responses are easily modeled by analytic transfer functions, this method is capable of extracting parameters for any device with a discrete number of design parameters. To validate the method, we design and fabricate integrated chirped Bragg gratings. We then estimate the actual device parameters by iteratively fitting the simultaneously measured group delay and reflection profiles to the artificial neural network output. The method is fast, accurate, and capable of modeling the complicated chirping and index contrast.

physics.app-ph↗

arXiv2019

An investigation of a new metamaterial composite structures

A frequency selective device, which is composed of a kind of composite structure, is designed to control the propagation of free space electromagnetic waves in the X band of the microwave spectrum. The composite structure mainly consists of a simple frequency selective surface (FSS) structure and the designed plasma arrays. Firstly, the electromagnetic property of the FSS structure is tested, and results indicating that the FSS structure with coupling reversed phase patternings has a significant absorptivity, with a bit blue shift of the peak resonance in comparison with the single layer FSS cases. Then the designed frequency selective device is still investigated in X band frequency. Results demonstrate that this device is easy to control the propagation of microwave, and the bandgap frequencies can be shifted through varying the FSS structure or the plasma arrays, and that the properties of this structure is highly dependent on frequency.

physics.app-ph↗

arXiv2019

Evanescent Field Functional Cu3-xP Nanoparticles as Effective Saturable Absorbers with high Repeatability for Femtosecond Soliton Pulse generation

Recently, a new emerging field about heavily-doped colloidal plasmonic nanocrystals (NCs) has attracted great attention due to their lower and expediently adjustable free carrier densities, lower and tunable LSPR band in the spectral range from NIR to MIR and higher optical nonlinearity. These new kinds of plasmonic materials will show huge potential and opportunities for nonlinear optical applications, such as ultrafast switching, nonlinear sensing and pulse laser generation. In this work, we demonstrate that high-quality mode-locking and Q-switching pulses at 1560 nm can both be generated by using controllable concentration of Cu3-xP NCs solution and fabricating evanescently interacted saturable absorbers. Furthermore, the plasmonic NCs material has good reproduction for fabricating SA devices and promising potential for large-scale industrial production. Our results may attract great attention for further investigations of heavily-doped plasmonic NCs as next generation, cheap and solution-processed element for fascinating applications in optoelectronic devices.

physics.app-ph↗

arXiv2019

Adjustment of electric field intensity by dielectric metamolecule hybridization model

In this paper, we report on achieving hybridization effect in a Mie-based dielectric metamolecule and provide their physically intuitive picture. The hybridization results in the splitting of the initial overlapping resonance dips, thus leading to two new collective resonance modes. It can be observed via the displacement electric field distribution that the two modes behave as the in-phase and out-of-phase oscillation of two meta-atoms, thus enhancing and diminishing the intensity of electric field at the gap between two meta-atoms. Moreover, since the two hybridized modes are caused by the interaction effect, the enhancement amplitude can be adjusted by several coupling factors, like gap distances and spot positions. Taking advantage of the two collective modes of the dielectric metamolecule, certain locations in the metamolecule can be applied as heating zones in microwave band and signal amplifier or shielding zones in communication fields.

physics.app-ph↗

arXiv2019

Atomic-scale factors that control the rate capability of nanostructured amorphous Si for high-energy-density batteries

Nanostructured Si is the most promising high-capacity anode material to substantially increase the energy density of Li-ion batteries. Among the remaining challenges is its low rate capability as compared to conventional materials. To understand better what controls the diffusion of Li in the amorphous Li-Si alloy, we use a novel machine-learning potential trained on more than 40,000 ab-initio calculations and nanosecond-scale molecular dynamics simulations, to visualize for the first time the delithiation of entire LiSi nanoparticles. Our results show that the Si host is not static but undergoes a dynamic rearrangement from isolated atoms, to chains, and clusters, with the Li diffusion strongly governed by this Si rearrangement. We find that the Li diffusivity is highest when Si segregates into clusters, so that Li diffusion proceeds via hopping between the Si clusters. The average size of Si clusters and the concentration range over which Si clustering occurs can thus function as design criteria for the development of rate-improved anodes based on modified Si.

cond-mat.dis-nn↗

arXiv2019

A simple INDIUM TIN OXIDE/glass DRA

A novel Dielectric Resonator Antenna, simply made of INDIUM TIN OXIDE coated glass slides placed on a microstrip transmission line, for communication applications is presented. Changes in the bandwidth and gain of the antenna are observed by modifying the dimensions of the INDIUM TIN OXIDE coated glass slides. Changes in gain, directivity and reflection coefficient are observed. A parametric study is conducted on the size of the DRA to understand the effect on bandwidth, reflection coefficient and gain.

physics.app-ph↗

arXiv2019

Bayesian Inference-enabled Precise Optical Wavelength Estimation using Transition Metal Dichalcogenide Thin Films

Despite its ability to draw precise inferences from large and complex datasets, the use of data analytics in the field of condensed matter and materials sciences -- where vast quantities of complex metrology data are regularly generated -- has remained surprisingly limited. Specifically, such approaches could dramatically reduce the engineering complexities of devices that directly exploit the physical properties of materials. Here, we present a cyber-physical system for accurately estimating the wavelength of any monochromatic light in the range of 325-1100nm, by applying Bayesian inference on the optical transmittance data from a few low-cost, easy-to-fabricate thin film "filters" of layered transition metal dichalcogenides (TMDs) such as MoS2 and WS2. Wavelengths of tested monochromatic light could be estimated with only 1% estimation error over 99% of the stated spectral range, with lowest error values reaching as low as a few ten parts per million (ppm) in a system with only eleven filters. By step-wise elimination of filters with the least contribution toward accuracy, mean estimation accuracy of 99% could be obtained even in a two-filter system. Furthermore, we provide a statistical approach for selecting the best "filter" material for any intended spectral range based on the spectral variation of transmittance within the desired range of wavelengths. And finally, we demonstrate that calibrating the data-driven models for the filters from time to time overcomes the minor drifts in their transmittance values, which allows using the same filters indefinitely. This work not only enables the development of simple cyber-physical photodetectors with high accuracy color-estimation, but also provides a framework for developing similar cyber-physical systems with drastically reduced complexity.

physics.app-ph↗

arXiv2019

A surface plasmon platform for angle-resolved chiral sensing

Chiral sensitive techniques have been used to probe the fundamental symmetries of the universe, study biomolecular structures, and even develop safe drugs. As chiral signals are inherently weak and often suppressed by large backgrounds, different techniques have been proposed to overcome the limitations of traditionally used chiral polarimetry. Here, we propose an angle-resolved chiral surface plasmon resonance (CHISPR) scheme that can detect the absolute chirality (handedness and magnitude) of a chiral sample and is sensitive to both the real and imaginary part of a chiral sample's refractive index. We present analytical results and numerical simulations of CHISPR measurements, predicting signals in the mdeg range for chiral samples of <100nm thickness at visible wavelengths. Moreover, we present a theoretical analysis that clarifies how our far-field measurements elucidate the underlying physics. This CHISPR protocol does not require elaborate fabrication and has the advantage of being directly implementable on existing surface plasmon resonance instrumentation.

physics.app-ph↗

arXiv2019

Transmissive Suppressed-Order Diffraction Grating (SODG)

We present a novel type of Suppressed-Order Diffraction Grating(SODG). An SODG is a diffraction grating whose diffraction orders have all been suppressed except one that is selected to provide electromagnetic deflection. The proposed SODG is a transmissive grating that exhibits high-efficiency refraction-like deflection for all angles, including large angles that are generally challenging to achieve, while featuring a deeply subwavelength thickness, as required in the microwave regime. We first present the design rationale and guidelines, and next demonstrate such a 10.5 GHz SODG that reaches an efficiency of 90% at 70 degrees.

physics.class-ph↗

arXiv2019

Design of Near Infrared and Visible Kinetic Inductance Detectors Using MIM Capacitors

We are developing superconducting Microwave Kinetic Inductance Detectors to operate at near infrared and optical wavelengths for astronomy. In order to efficiently meet with the requirements of astronomical applications, we propose to replace the interdigitated capacitor by a metal, insulator, metal capacitor which has the advantage of presenting a larger capacitance value within a much smaller space. The pixel will occupy a space of typically 100 micrometers by 85 micrometers which is nine times less than a typical pixel size using the interdigitated capacitor operating at the same frequency, below 2 GHz.

astro-ph.IM↗