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Nonclassical Kinetics in Constrained Geometries: Initial Distribution Effects

We present a detailed study of the effects of the initial distribution on the kinetic evolution of the irreversible reaction A+B -> 0 in one dimension. Our analytic as well as numerical work is based on a reaction-diffusion model of this reaction. We focus on the role of initial density fluctuations in the creation of the macroscopic patterns that lead to the well-known kinetic anomalies in this system. In particular, we discuss the role of the long wavelength components of the initial fluctuations in determining the long-time behavior of the system. We note that the frequently studied random initial distribution is but one of a variety of possible distributions leading to interesting anomalous behavior. Our discussion includes an initial distribution with correlated A-B pairs and one in which the initial distribution forms a fractal pattern. The former is an example of a distribution whose long wavelength components are suppressed, while the latter exemplifies one whose long wavelength components are enhanced, relative to those of the random distribution.

physics.chem-ph↗

Validation and Calibration of Models for Reaction-Diffusion Systems

Space and time scales are not independent in diffusion. In fact, numerical simulations show that different patterns are obtained when space and time steps ($Δx$ and $Δt$) are varied independently. On the other hand, anisotropy effects due to the symmetries of the discretization lattice prevent the quantitative calibration of models. We introduce a new class of explicit difference methods for numerical integration of diffusion and reaction-diffusion equations, where the dependence on space and time scales occurs naturally. Numerical solutions approach the exact solution of the continuous diffusion equation for finite $Δx$ and $Δt$, if the parameter $γ_N=D Δt/(Δx)^2$ assumes a fixed constant value, where $N$ is an odd positive integer parametrizing the alghorithm. The error between the solutions of the discrete and the continuous equations goes to zero as $(Δx)^{2(N+2)}$ and the values of $γ_N$ are dimension independent. With these new integration methods, anisotropy effects resulting from the finite differences are minimized, defining a standard for validation and calibration of numerical solutions of diffusion and reaction-diffusion equations. Comparison between numerical and analytical solutions of reaction-diffusion equations give global discretization errors of the order of $10^{-6}$ in the sup norm. Circular patterns of travelling waves have a maximum relative random deviation from the spherical symmetry of the order of 0.2%, and the standard deviation of the fluctuations around the mean circular wave front is of the order of $10^{-3}$.

patt-sol↗

Spiral Waves in Media with Complex Excitable Dynamics

The structure of spiral waves is investigated in super-excitable reaction-diffusion systems where the local dynamics exhibits multi-looped phase space trajectories. It is shown that such systems support stable spiral waves with broken symmetry and complex temporal dynamics. The main structural features of such waves, synchronization defect lines, are demonstrated to be similar to those of spiral waves in systems with complex-oscillatory dynamics.

chao-dyn↗

Renormalization Group Method and Reductive Perturbation Method

It is shown that the renormalization group method does not necessarily eliminate all secular terms in perturbation series to partial differential equations and a functional subspace of renormalizable secular solutions corresponds to a choice of scales of independent variables in the reductive perturbation method.

patt-sol↗

Toda Lattice Solutions of Differential-Difference Equations for Dissipative Systems

In a certain class of differential-difference equations for dissipative systems, we show that hyperbolic tangent model is the only the nonlinear system of equations which can admit some particular solutions of the Toda lattice. We give one parameter family of exact solutions, which include as special cases the Toda lattice solutions as well as the Whitham's solutions in the Newell's model. Our solutions can be used to describe temporal-spatial density patterns observed in the optimal velocity model for traffic flow.

patt-sol↗

Lie-Group Approach to Perturbative Renormalization-Group Method

The Lie-group approach to the perturbative renormalization group (RG) method is developed to obtain an asymptotic solutions of both autonomous and non-autonomous ordinary differential equations. Reduction of some partial differetial equations to typical RG equations is also achieved by this approach and a simple recipe for providing RG equations is presented.

patt-sol↗

The Renormalization-Group Method Applied to Asymptotic Analysis of Vector Fields

The renormalization group method of Goldenfeld, Oono and their collaborators is applied to asymptotic analysis of vector fields. The method is formulated on the basis of the theory of envelopes, as was done for scalar fields. This formulation actually completes the discussion of the previous work for scalar equations. It is shown in a generic way that the method applied to equations with a bifurcation leads to the Landau-Stuart and the (time-dependent) Ginzburg-Landau equations. It is confirmed that this method is actually a powerful theory for the reduction of the dynamics as the reductive perturbation method is. Some examples for ordinary diferential equations, such as the forced Duffing, the Lotka-Volterra and the Lorenz equations, are worked out in this method: The time evolution of the solution of the Lotka-Volterra equation is explicitly given, while the center manifolds of the Lorenz equation are constructed in a simple way in the RG method.

hep-th↗

Spatial Solitons in Media with Delayed-Response Optical Nonlinearities

Near-soliton scanning light-beam propagation in media with both delayed-response Kerr-type and thermal nonlinearities is analyzed. The delayed-response part of the Kerr nonlinearity is shown to be competitive as compared to the thermal nonlinearity, and relevant contributions to a distortion of the soliton form and phase can be mutually compensated. This quasi-soliton beam propagation regime keeps properties of the incli- ned self-trapped channel.

solv-int↗

Secondary Instabilities of Surface Waves on Viscous Fluids in the Faraday Instability

Secondary instabilities of Faraday waves show three regimes: (1) As seen previously, low-viscosity (nu) fluids destabilize first into squares. At higher driving accelerations a, squares show low-frequency modulations corresponding to the motion of phase defects, while theory predicts a stationary transverse amplitude modulation (TAM). (2) High-nu fluids destabilize first to stripes. Stripes then show an oscillatory TAM whose frequency is incommensurate with the driving frequency. At higher a, the TAM undergoes a phase instability. At still higher a, edge dislocations form and fluid droplets are ejected. (3) Intermediate-nu fluids show a complex coexistence of squares and stripes, as well as stationary and oscillatory TAM instabilities of the stripes.

patt-sol↗

Vortex -- Kink Interaction and Capillary Waves in a Vector Superfluid

Interaction of a vortex in a circularly polarized superfluid component of a 2d complex vector field with the phase boundary between superfluid phases with opposite signs of polarization leads to a resonant excitation of a ``capillary'' wave on the boundary. This leads to energy losses by the vortex--image pair that has to cause its eventual annihilation.

patt-sol↗

The branching structure of diffusion-limited aggregates

I analyze the topological structures generated by diffusion-limited aggregation (DLA), using the recently developed "branched growth model". The computed bifurcation number B for DLA in two dimensions is B ~ 4.9, in good agreement with the numerically obtained result of B ~ 5.2. In high dimensions, B -> 3.12; the bifurcation ratio is thus a decreasing function of dimensionality. This analysis also determines the scaling properties of the ramification matrix, which describes the hierarchy of branches.

patt-sol↗

Magnetic Faraday-Instability

In a magnetic fluid parametrically driven surface waves can be excited by an external oscillating magnetic field. A static magnetic field changes the restoring forces and damping coefficients of the various surface waves. This property enables the excitation of both subharmonic and harmonic responses of the standing waves.

patt-sol↗

Phase instabilities in hexagonal patterns

The general form of the amplitude equations for a hexagonal pattern including spatial terms is discussed. At the lowest order we obtain the phase equation for such patterns. The general expression of the diffusion coefficients is given and the contributions of the new spatial terms are analysed in this paper. From these coefficients the phase stability regions in a hexagonal pattern are determined. In the case of Benard-Marangoni instability our results agree qualitatively with numerical simulations performed recently.

patt-sol↗

Spatio-selection in Expanding Bacterial Colonies

Segregation of populations is a key question in evolution theory. One important aspect is the relation between spatial organization and the population's composition. Here we study a specific example -- sectors in expanding bacterial colonies. Such sectors are spatially segregated sub-populations of mutants. The sectors can be seen both in disk-shaped colonies and in branching colonies. We study the sectors using two models we have used in the past to study bacterial colonies -- a continuous reaction-diffusion model with non-linear diffusion and a discrete ``Communicating Walkers'' model. We find that in expanding colonies, and especially in branching colonies, segregation processes are more likely than in a spatially static population. One such process is the establishment of stable sub- population having neutral mutation. Another example is the maintenance of wild-type population along side with sub-population of advantageous mutants. Understanding such processes in bacterial colonies is an important subject by itself, as well as a model system for similar processes in other spreading populations.

cond-mat↗

Nonlinear theory of soliton-induced waveguides

We develop a nonlinear theory of soliton-induced waveguides that describes a finite-amplitude probe beam guided by a spatial dark soliton in a saturable nonlinear medium. We suggest an effective way to control the interaction of these soliton-induced waveguides and also show that, in sharp contrast with scalar dark solitons, the dark-soliton waveguides can attract each other and even form stationary bound states.

patt-sol↗

Spatial Optical Solitons due to Multistep Cascading

We introduce a novel class of parametric optical solitons supported simultaneously by two second-order nonlinear cascading processes, second-harmonic generation and sum-frequency mixing. We obtain, analytically and numerically, the solutions for three-wave spatial solitons and show that the presence of an additional cascading mechanism can change dramatically the properties and stability of two-wave quadratic solitary waves.

patt-sol↗