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Grain refinement in unalloyed tantalum structure deposited using Wire + Arc Additive Manufacture and vertical cold rolling

Components manufactured via Wire + Arc Additive Manufacturing are usually characterised by large columnar grains. This can be mitigated by introducing in-process cold-rolling; in fact, the associated local plastic deformation leads to a reduction of distortion and residual stresses, and to microstructural refinement. In this research, inter-pass rolling was applied with a load of 50 kN to a tantalum linear structure to assess its effectiveness in changing the grain structure from columnar to equiaxed, as well as in refining the grain size. An average grain size of 650 microns has been obtained after five cycles of inter-pass rolling and deposition. When the deformed layer was reheated during the subsequent deposition, recrystallisation occurred, leading to the growth of new strain-free finer equiaxed grains. The depth of the refined region has been characterised and correlated to the hardness profile developed after rolling. A reduction of porosity was also registered. Furthermore, a random texture was formed after rolling, which should result in isotropic mechanical properties. Wire + Arc Additive Manufacturing process demonstrated the ability to deposit sound refractory metal components and the possibility to improve the microstructure when coupled with cold inter-pass rolling.

physics.app-ph↗

A novel layered topology of auxetic materials based on the tetrachiral honeycomb microstructure

Microstructured honeycomb materials may exhibit exotic, extreme and tailorable mechanical properties, suited for innovative technological applications in a variety of modern engineering fields. The paper is focused on analysing the directional auxeticity of tetrachiral materials, through analytical, numerical and experimental methods. Theoretical predictions about the global elastic properties have been successfully validated by performing tensile laboratory tests on tetrachiral samples, realized with high precision 3D printing technologies. Inspired by the kinematic behaviour of the tetrachiral material, a newly-design bi-layered topology, referred to as bi-tetrachiral material, has been theoretically conceived and mechanically modelled. The novel topology virtuously exploits the mutual collaboration between two tetrachiral layers with opposite chiralities. The bi-tetrachiral material has been verified to outperform the tetrachiral material in terms of global Young modulus and, as major achievement, to exhibit a remarkable auxetic behaviour. Specifically, experimental results, confirmed by parametric analytical and computational analyses, have highlighted the effective possibility to attain strongly negative Poisson ratios, identified as a peculiar global elastic property of the novel bi-layered topology.

physics.app-ph↗

Tunable Hyperbolic Metamaterials Based on Self-Assembled Carbon Nanotubes

We show that packed, horizontally aligned films of single-walled carbon nanotubes are hyperbolic metamaterials with ultra-subwavelength unit cells and dynamic tunability. Using Mueller-matrix ellipsometry, we characterize the films' doping-level dependent optical properties and find a broadband hyperbolic region tunable in the mid-infrared. To characterize the dispersion of in-plane hyperbolic plasmon modes, we etch the nanotube films into nanoribbons with differing widths and orientations relative to the nanotube axis, and we observe that the hyperbolic modes support strong light localization. Agreement between the experiments and theoretical models using the ellipsometry data indicates that the packed carbon nanotubes support bulk anisotropic responses at the nanoscale. Self-assembled films of carbon nanotubes are well suited for applications in thermal emission and photodetection, and they serve as model systems for studying light-matter interactions in the deep subwavelength regime.

physics.optics↗

Homogeneous hierarchical NiMoO4@NiMoO4 nanostructure as a high-performance anode material for electrochemical energy storage

Here we report the extraordinary electrochemical energy storage capability of NiMoO4@NiMoO4 homogeneous hierarchical nanosheet-on-nanowire-arrays (SOWAs) synthesized on nickel substrate by a two-stage hydrothermal process. Comparatively speaking, the SOWAs electrode displays improved electrochemical performances than the bare NiMoO4 nanowire arrays. Such improvements can be ascribed to the characteristic homogeneous hierarchical structure which not only effectively increases the active surface areas for fast charge transfer, but also reduces the electrode resistance significantly by eliminating the potential barrier at the nanowire/nanosheet junction, which is usually an issue in other reported heterogeneous architectures. We further evaluate the performances of the SOWAs by constructing an asymmetric hybrid supercapacitor (ASC) with the SOWAs and activated carbon (AC). The optimized ASC shows excellent electrochemical performances with 47.2 Wh/kg in energy density at 1.38 kW/kg at 0-1.2 V. Moreover, the specific capacity retention can be as high as 91.4% after 4000 cycles, illustrating the remarkable cycling stability of the NiMoO4@NiMoO4//AC ASC device. Our results show that this unique NiMoO4@NiMoO4 SOWAs display great prospect for future energy storage applications

physics.app-ph↗

PtSe2 grown directly on polymer foil for use as a robust piezoresistive sensor

Robust strain gauges are fabricated by growing PtSe2 layers directly on top of flexible polyimide foils. These PtSe2 layers are grown by low-temperature, thermally-assisted conversion of predeposited Pt layers. Under applied flexure the PtSe2 layers show a decrease in electrical resistance signifying a negative gauge factor. The influence of the growth temperature and film thickness on the electromechanical properties of the PtSe2 layers is investigated. The best-performing strain gauges fabricated have a superior gauge factor to that of commercial metal-based strain gauges. Notably, the strain gauges offer good cyclability and are very robust, surviving repeated peel tests and immersion in water. Furthermore, preliminary results indicate that the stain gauges also show potential for high-frequency operation. This host of advantageous properties, combined with the possibility of further optimization and channel patterning, indicate that PtSe2 grown directly on polyimide holds great promise for future applications.

physics.app-ph↗

Enhanced Ferroelectric Functionality in Flexible Lead Zirconate Titanate Films with In-Situ Substrate-Clamping Compensation

Much attention has been given recently to flexible and wearable integrated-electronic devices, with a strong emphasis on real-time sensing, computing and communication technologies. Thin ferroelectric films exhibit switchable polarization and strong electro-mechanical coupling, and hence are in widespread use in such technologies, albeit not when flexed. Effects of extrinsic strain on thin ferroelectric films are still unclear, mainly due to the lack of suitable experimental systems that allow cross structural-functional characterization with in-situ straining. Moreover, although the effects of intrinsic strain on ferroelectric films, e.g. due to film-substrate lattice mismatch, have been investigated extensively, it is unclear how these effects are influenced by external strain. Here, we developed a method to strain thin films homogenously in-situ, allowing functional and structural characterization while retaining the sample under constant straining conditions in AFM and XRD. Using this method, we strained the seminal ferroelectric, PbZr0.2Ti0.8O3 that was grown on a flexible mica substrate, to reduce substrate clamping effects and increase the tetragonality. Consequently, we increased the domain stability, decreased the coercive field value and reduced imprint effects. This method allows also direct characterization of the relationship between the lattice parameters and nanoscale properties of other flexible materials.

physics.app-ph↗

Ultra-thin yttria-stabilized zirconia as a flexible and stable substrate for infrared nano-optics

Infrared (IR) technologies have become increasingly relevant as they offer a wide range of applications, from thermal imaging to chemical and biological vibrational spectroscopy. Substrate materials, such as calcium fluoride and zinc selenide, are commonly used for IR optics. Unfortunately, they are typically fragile, hygroscopic and expensive, thus producing potential problems during device fabrication and in the long-term functional operation. Here, we introduce yttria-stabilized zirconia (YSZ) ceramic as a flexible and stable platform to implement next generation IR nano-optic devices. In particular, we have combined YSZ with metallic nano-structures and graphene to demonstrate new plasmonics, polarizers and transparent heating substrates. The proposed YSZ-based platforms enable high temperature processing that also withstand harsh environments because of its excellent mechanical, thermal and chemical stability. In addition to the functional capability of making foldable and bendable devices, the demonstrated mechanical flexibility offers the possibility of roll-to-roll processing for low cost and large scale fabrication processes. Our work offers compelling evidence that ultrathin YSZ is a unique substrate for IR applications, given all the combined features, including mechanical flexibility, durability, transparency and easy processing, which are not available from other available material alternatives.

physics.optics↗

Influence of ns-laser wavelength in laser-induced breakdown spectroscopy for discrimination of painting techniques

The influence of ns-laser wavelength to discriminate ancient painting techniques such as are fresco, casein, animal glue, egg yolk and oil was investigated in this work. This study was carried out with a single shot laser on samples covered by a layer made of a mixture of the cinnabar pigment and different binders. Three wavelengths based on Nd: YAG laser were investigated (1064, 532 and 266 nm). The plasma is controlled at the same electron temperature after an adjustment of pulse energy for these three wavelengths on a fresco sample without organic binder. This approach allows to eliminate the effects of laser pulse energy and the material laser absorption. Afterwards, the emission spectra were compared to separate different techniques. The organic binding media has been separated based on the relative emission intensity of the present CN or C 2 rovibrational emissions. In order to test the capability of separating or identifying, the chemometric approach (PCA) was applied to the different matrix. The different solutions in term of wavelength range to optimise the identification was investigated. We focused on the evaluation for the laser wavelength to insure a better separation. The different capacity was interpreted by differentiating 1 Corresponding author. E-mail address: vincent.detalle@culture.gouv.fr 2 the binders by the altered interaction mechanisms between the laser photon and the binders. Also, the electron temperature in the plasma was estimated, which provided the evidences to our findings.

physics.plasm-ph↗

Entropy driven reverse-metal-to-insulator transition and delta-temperatural transports in metastable perovskites of correlated rare-earth nickelate

The metal to insulator transition (MIT) in Mott-Hubbard systems is one of the most important discoveries in condensed matter physics, and results in abrupt orbital transitions from the insulating to metallic phases by elevating temperature across a critical point (TMIT). Although the MIT was previously expected to be mainly driven by the orbital Coulomb repulsion energy, the entropy contribution to the orbital free energy that also determines the relative stability of the metallic and insulating phases was largely overlooked. Herein, we demonstrate an orbital-entropy dominated reversible electronic phase transition in the metastable perovskite family of correlated rare-earth nicklates (ReNiO3), in addition to their previously known MIT driven by orbital Coulomb energies. In reverse to MIT, the resistivity of ReNiO3 abruptly increases by 2-3 orders by elevating T across another critical point (TR-MIT) below TMIT, and such transition is named as reverse-metal to insulator transition (R-MIT). Combining the afterwards exponentially decreasing resistivity in the insulating phase of ReNiO3 at further temperature elevation, a distinguished delta-temperatural transport character is established, which is potentially applicable for locking the working temperatures range for electric devices. The TR-MIT is shown to be enhanced via reducing the compositional complexity and size of Re or imparting bi-axial compressive strains, and meanwhile the transition sharpness of delta-temperatural transport is reduced. Our discovery indicates that temperature range for a thermodynamically stable insulating phase of ReNiO3 is in between of TR-MIT and TMIT, while a new conductive phase with high orbital entropy is formed by further descending temperature below TR-MIT.

physics.app-ph↗

Optoelectronic devices, plasmonics and photonics with topological insulators

Topological insulators are innovative materials with semiconducting bulk together with surface states forming a Dirac cone, which ensure metallic conduction in the surface plane. Therefore, topological insulators represent an ideal platform for optoelectronics and photonics. The recent progress of science and technology based on topological insulators enables the exploitation of their huge application capabilities. Here, we review the recent achievements of optoelectronics, photonics and plasmonics with topological insulators. Plasmonic devices and photodetectors based on topological insulators in a wide energy range, from Terahertz to the ultraviolet, promise outstanding impact. Furthermore, the peculiarities, the range of applications and the challenges of the emerging fields of topological photonics and thermoplasmonics are discussed.

physics.app-ph↗

A Low Profile Tunable Microwave Absorber based on Graphene Sandwich Structure and High Impedance Surface

In this paper, a low profile dynamically tunable microwave absorber is proposed, which consists of high impedance surface (HIS) and graphene sandwich structure (GSS). We theoretically demonstrate and experimentally verify that the proposed absorber can provide a dynamically tunable reflection range from larger than -3dB to less than -30 dB (corresponding to the absorption range from 50% to 99.9%) at opera-ting frequency of 11.2GHz by external bias voltage. The entire thickness of this absorber is only 2.8mm, nearly one tenth of working wavelength. In addition, a modified equivalent circuit model is proposed to explicate its absorption mechanism. At last, we fabricate a prototype absorber, and measure its absorption in anechoic chamber. The experimental results agree well with the full wave simulation results. This work may provide a reference for design and fabrication of dynamically tunable microwave absorber based on large-scale graphene and may promote the actual applications of graphene at microwave frequency.

physics.app-ph↗

Nanophotonic Optical Switching Using Digital Metamaterials and Photochromism

Optical switches are one of the most important elements of integrated photonics. Here, we designed, fabricated and characterized several nanophotonic optical switches (NOSs) in silicon that exhibit ultra-compact footprint, along with excellent extinction ratios and operating bandwidths. Simulations indicate that our best device of dimensions 3umX3um and 0.3um device height can provide about 10dB extinction ratio with a bandwidth of 12nm, centered at the design wavelength of 1550nm. Three-dimensional finite-difference time-domain analysis in conjunction with a modified version of direct binary search algorithm was used to design the nanophotonic device structure. The modulation is a result of optical modulation of the refractive index of a photochromic material and an optimized geometry of the digital metamaterials that comprise the device. The devices are CMOS fabrication compatible and examples of ones designed using multi-state geometric optimization that will lead to a new class of ultra-compact and multi-functional active integrated-silicon devices.

physics.optics↗

Dense III-V/Si Phase-Shifter Based Optical Phased Array

High-performance integrated optical phased arrays (OPAs) are crucial for building up energy-efficient solid-state beam steering systems on a chip. This work demonstrates a first heterogeneous III-V/Si phase-shifter based OPA that utilizes III-V multiple quantum well (MQW) structures to provide superior performance. Demonstrated phase shifters have Vpi of only 0.45 V and residual amplitude modulation (RAM) of only 0.15 dB at 1550 nm for 2pi phase shift with low power consumption of less than 3 nW, which are, to the best our knowledge, the state-of-the-art performance with a record low operating voltage, low power consumption, and low RAM in on-chip OPAs. Their bandwidth is >1 GHz across 200 nm wavelength range. Wavelength tuning is used to demonstrate two-dimensional beam steering with a field of view of 28x51 degree in the 32-channel OPA with an emitter-array pitch of 2 um. Side-mode suppression ratio of 16 dB is also achieved. The high-performance heterogeneous OPA paves the way for scalable and efficient on-chip beam steerers with large steering range and high beam quality.

physics.app-ph↗

Silicon microcavity arrays with open access and a finesse of half a million

Optical resonators are increasingly important tools in science and technology. Their applications range from laser physics, atomic clocks, molecular spectroscopy, and single-photon generation to the detection, trapping and cooling of atoms or nano-scale objects. Many of these applications benefit from strong mode confinement and high optical quality factors, making small mirrors of high surface-quality desirable. Building such devices in silicon yields ultra-low absorption at telecom wavelengths and enables integration of micro-structures with mechanical, electrical and other functionalities. Here, we push optical resonator technology to new limits by fabricating lithographically aligned silicon mirrors with ultra-smooth surfaces, small and wellcontrolled radii of curvature, ultra-low loss and high reflectivity. We build large arrays of microcavities with finesse greater than F = 500,000 and a mode volume of 330 femtoliters at wavelengths near 1550 nm. Such high-quality micro-mirrors open up a new regime of optics and enable unprecedented explorations of strong coupling between light and matter.

physics.app-ph↗

Probing the surface of synthetic opals with the vanadyl-containing crude oil by using EPR and ENDOR techniques

Porous silica materials offer wide range of possibilities for enhancement of the productivity of oil reservoirs. However the mechanism of adsorption of polar components of crude oil on silica surface is poorly understood that hinders technological improvement of supports and oil extraction. We have synthesized opal films with the silica microspheres size of about 360 nm, specific surface area of 5.2 m2/g and pore size of 230 nm. We have fractionated and characterized oil and oil asphaltenes from heavy (Ashalchinskoe) oil. By pulsed electron paramagnetic resonance (EPR) and double electron nuclear resonance (ENDOR) in the W band frequency range (microwave frequency of 94 GHz, magnetic field of 3.4 T) we have studied the adsorption of oil asphaltenes on the surface of opal samples using the intrinsic for asphaltenes paramagnetic vanadylporphyrins (VO) complexes. 1H ENDOR spectra are found to be different for initial and the adsorbed samples in their central parts (that is a sign of asphaltenes VO disaggregation) whereas no significant changes in the W band EPR spectra were detected. Contrasting to alumina support, no strong electron proton interaction with the protons on the surface of SiO2 (presumably, silanol groups) was found and infiltration of the oiled opal films with gasoline changes the central part of 1H ENDOR spectra. It shows that the proton containing groups on the surface of amorphous SiO2 sample can significantly change the asphaltene adsorption properties and ENDOR of the intrinsic for oil paramagnetic centers could be used for the characterization of surface state in porous media in situ or operando.

physics.app-ph↗

Sizing and Dynamic modeling of a Power System for the MUN Explorer Autonomous Underwater Vehicle using a Fuel Cell and Batteries

The combination of a fuel cell and batteries has promising potential for powering autonomous vehicles. The MUN Explorer Autonomous Underwater Vehicle (AUV) is built to do mapping-type missions of seabeds as well as survey missions. These missions require a great deal of power to reach underwater depths (i.e. 3000 meters). The MUN Explorer uses 11 rechargeable Lithium-ion (Li-ion) batteries as the main power source with a total capacity of 14.6kWh to 17.952kWh, and the vehicle can run for 10 hours. The draw-backs of operating the existing power system of the MUN Explorer, which was done by the researcher at the Holyrood management facility, include mobilization costs, logistics and transport, and facility access, all of which should be taken into consideration. Recharging the batteries for at least 8 hours is also very challenging and time consuming. To overcome these challenges and run the MUN Explorer for a long time, it is essential to integrate a fuel cell into an existing power system (i.e. battery bank). The integration of the fuel cell not only will increase the system power, but it will also reduce the number of batteries needed as suggested by HOMER software. In this paper, an integrated fuel cell is designed to be added into the MUN Explorer AUV along with a battery bank system to increase its power system. The system sizing is performed using HOMER software. The results from HOMER software show that a 1kW fuel cell and 8 Li-ion batteries can increase the power system capacity to 68 kWh. The dynamic model is then built in MATLAB/Simulink environment to provide a better understanding of the system behavior.The 1kW fuel cell is connected to a DC/DC Boost Converter to increase the output voltage from 24V to 48V as required by the battery and DC motor.

physics.app-ph↗

Engineering Vacancies in Bi2S3 yields sub-Bandgap Photoresponse and highly sensitive Short-Wave Infrared Photodetectors

Defects play an important role in tailoring the optoelectronic properties of materials. Here we demonstrate that sulphur vacancies are able to engineer sub-band photoresponse into the short-wave infrared range due to formation of in-gap states in Bi2S3 single crystals supported by density functional (DF) calculations. Sulfurization and subsequent refill of the vacancies results in faster response but limits the spectral range to the near infrared as determined by the bandgap of Bi2S3. A facile chemical treatment is then explored to accelerate the speed of sulphur deficient (SD)-based detectors on the order of 10 ms without sacrificing its spectral coverage into the infrared, while holding a high D* close to 10^15 Jones in the visible-near infrared range and 10^12 Jones at 1.6 um. This work also provides new insights into the role sulphur vacancies play on the electronic structure and, as a result, into sub-bandgap photoresponse enabling ultrasensitive, fast and broadband photodetectors.

physics.app-ph↗

Enhancing the Three-Photon Luminesce via the Resonance in Lead Halide Perovskite Metasurfaces

Lead halide perovskites (MAPbX3) have emerged as promising materials for photovoltaic and optoelectronic devices. However, their exceptional nonlinear properties have not been fully exploited in nanophotonics yet. Herein we fabricate MAPbX3 perovskite metasurfaces and explore their internal nonlinear processes. While both of third-order harmonic generation (THG) and three-photon luminescence are generated, the latter one is less affected by the material loss and has been significantly enhanced by a factor of 60. The corresponding simulation reveals that the improvement is caused by the resonant enhancement of incident laser in perovskite metasurface. Interestingly, such kind of resonance-enhanced three-photon luminescence holds true for metasurfaces with a small period number of 4, enabling new applications of perovskite metasurface in high-resolution nonlinear color nanoprinting and optical encoding. The encoded information "NANO" is visible only when the incident laser is on-resonance. The off-resonance pumping and the single-photon excitation just produce a uniform dark or photoluminescence background.

physics.app-ph↗