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Using strong electromagnetic fields to control x-ray processes

Exploration of a new ultrafast-ultrasmall frontier in atomic and molecular physics has begun. Not only is is possible to control outer-shell electron dynamics with intense ultrafast optical lasers, but now control of inner-shell processes has become possible by combining intense infrared/optical lasers with tunable sources of x-ray radiation. This marriage of strong-field laser and x-ray physics has led to the discovery of methods to control reversibly resonant x-ray absorption in atoms and molecules on ultrafast timescales. Using a strong optical dressing field, resonant x-ray absorption in atoms can be markedly suppressed, yielding an example of electromagnetically induced transparency for x rays. Resonant x-ray absorption can also be controlled in molecules using strong non-resonant, polarized laser fields to align the framework of a molecule, and therefore its unoccupied molecular orbitals to which resonant absorption occurs. At higher laser intensities, ultrafast field ionization produces an irreversible change in x-ray absorption. Finally, the advent of x-ray free electron lasers enables first exploration of non-linear x-ray processes.

physics.atom-ph↗

Single-photon cooling at the limit of trap dynamics: Maxwell's Demon near maximum efficiency

We demonstrate a general and efficient informational cooling technique for atoms which is an experimental realization of a one-dimensional Maxwell's Demon. The technique transfers atoms from a magnetic trap into an optical trap via a single spontaneous Raman transition which is discriminatively driven near each atom's classical turning point. In this way, nearly all of the atomic ensemble's kinetic energy in one dimension is removed. We develop a simple analytical model to predict the efficiency of transfer between the traps and provide evidence that the performance is limited only by particle dynamics in the magnetic trap. Transfer efficiencies up to 2.2% are reported. We show that efficiency can be traded for phase-space compression, and we report compression up to a factor of 350. Our results represent a 15-fold improvement over our previous demonstration of the cooling technique.

physics.atom-ph↗

Four-body legacy of the Efimov effect

Armed with a new solution to the four-body problem, we reanalyze the recent Innsbruck observation of an Efimov resonance in three-body collisions of cesium atoms, and show that it provides evidence of new, universal four-body physics as well. Our theoretical treatment of four bosonic atoms in the limit of strong two-body attraction suggests a ubiquitous result: namely, that resonantly-bound states of all four atoms should occur whenever the two-body scattering length is a specific fraction (0.43) of the value where a three-body Efimov resonance occurs. A hitherto unanalyzed feature in the 2006 Innsbruck experiment supports this universal prediction, and it provides the first known evidence to date that a direct four-body recombination process plays a role. While we confirm the conclusion reached previously by some studies that no true Efimov effect exists for four particles, we demonstrate the existence of a universal class of four-body states that are intimately connected with three-body Efimov states.

physics.atom-ph↗

Reactive Collisions of Ultracold Molecules Confined in quasi-2D Geometry

We present a formalism for rigorous calculations of cross sections for inelastic and reactive collisions of ultracold atoms and molecules confined by laser fields in quasi-2D geometry. Our results show that the elastic-to-inelastic ratios of collision cross sections are enhanced in the presence of a laser confinement and that the threshold energy dependence of the collision cross sections can be tuned by varying the confinement strength and external magnetic fields. The enhancement of the elastic-to-inelastic ratios is inversely proportional to $\sqrt{ε/\hbar ω_0}$, where $ε$ is the kinetic energy and $ω_0$ is the oscillation frequency of the trapped particles in the confinement potential.

physics.atom-ph↗

Mott Scattering of polarized electrons in a circularly polarized laser field

We present a study of Mott scattering of polarized electrons in the presence of a laser field with circular polarization using the helicity formalism and the introduction of the well known concept of non flip differential cross section as well as that of flip differential cross section. The results we have obtained in the presence of a laser field are coherent with those obtained in the absence of a laser field. We have studied the relativistic regime as well as the non relativistic regime that are precisely defined in the text. Two important consistency checks have been carried out successfully. The first one is that the sum of both differential cross sections (one with spin up, the other with spin down) always gives the unpolarized differential cross section. The second one is that the relativistic unpolarized differential cross section converges to the non relativistic differential cross section in the limit of small velocities. Moreover, the results obtained using the sofware Reduce \cite{8} gave rise to non contracted coefficients that have been dealt with using the geometry chosen.

physics.atom-ph↗

Tightened Lieb-Oxford bound for systems of fixed particle number

The Lieb-Oxford bound is a constraint upon approximate exchange-correlation functionals. We explore a non-empirical tightening of that bound in both universal and electron-number-dependent form. The test functional is PBE. Regarding both atomization energies (slightly worsened) and bond lengths (slightly bettered), we find the PBE functional to be remarkably insensitive to the value of the Lieb-Oxford bound. This both rationalizes the use of the original Lieb-Oxford constant in PBE and suggests that enhancement factors more sensitive to sharpened constraints await discovery.

physics.chem-ph↗

Total electron yields and stopping power of protons colliding with NaCl-type insulator surfaces II

We re-calculate electron yields and stopping power of protons colliding with surfaces of NaCl-type insulators. In this article, the projectile is considered to move taking into account the static and polarization potentials with all the individual ions forming the surface lattice unlike our previous work (Phys. Rev. A 75, 042904 (2007)) where the projectile was considered to move in an homogeneous planar potential. Substantial differences (up to forty percent of increment) have been found especially when the projectile incident angle approaches the critical one. We compare our prediction for electron yield and stopping power with the available experimental data for LiF, KI and KCl.

physics.atom-ph↗

Tables of the mean lifetimes for excited electronic-vibro-rotational states of isotopomers of diatomic hydrogen

Current situation in studies of mean lifetimes of excited electronic-vibro-rotational states of hydrogen molecule (including the H2, D2, HD and T2 isotopomers) is reviewed in brief. All measured values of the lifetimes (published before November 2008) are collected and presented in tabular form. Complete bibliography of papers devoted to semi-empirical determination and non-empirical calculation of the lifetimes is presented. The experimental data obtained in various papers are compared with the results of semi-empirical determination and non-empirical calculations.

physics.optics↗

Wavelength dependence of high-order harmonic generation with the ionization and ponderomotive energy controlled by an extreme ultraviolet pulse

We theoretically study the scaling with the driving wavelength of the high-order harmonic generation (HHG) under the simultaneous irradiation of an extreme ultraviolet (XUV) pulse. Surprisingly, when the cutoff energy and ionization yield are fixed, the harmonic yield is nearly independent of the driving wavelength. We identify its origin as the combination of the initial spatial width of the states excited by the XUV pulse, making the wavepacket spreading less prominent, and the shallowing of the ionization potential, which suggests complex nature of the wavelength dependence of HHG.

physics.atom-ph↗

Photonic soliton and its relevance to radiative neutrino pair emission

We consider atomic system of $Λ-$type 3-level coupled to 2 mode fields, and derive an effective Maxwell-Bloch equation designed for two photon emission between two lower levels. We find axially symmetric, topologically stable soliton solutions made of condensed fields. Immediate implication of soliton formation to radiative neutrino pair emission is to enhance its rate, larger than the usual $\propto N^2$ factor of target number dependence, along with another merit of increasing the signal to the background photon emission.

hep-ph↗

Study of Proton Transfer Reaction Dynamics in Pyrrole 2-Carboxyldehyde

Photophysical and photochemical dynamics of ground state and excited state proton transfer reaction is reported for Pyrrole 2-Carboxyldehyde (PCL). Steady state absorption and emission measurements are conducted in PCL. The theoretical investigation is done by using different quantum mechanical methods (e.g. Hartree Fock, DFT, MP2, CCSD etc.). The reaction pathway and two dimensional potential energy surfaces are computed in various level of theory. A transition state is also reported in gas phase and reaction filed calculation. It is established that PCL forms different emitting species in different media. A large Stokes shifted emission band, which is attributed to species undergoing excited state intramolecular proton transfer, is observed in hydrocarbon solvent. Intermolecular proton transfer is observed in hydroxylic polar solvent. Experimental observations yield all possible signatures of intramolecular and intermolecular proton transfer in excited state of PCL. The origins of these signatures have been explained successfully using corresponding quantum mechanical theories.

physics.atm-clus↗

Excitation spectra, spin structures, and entanglement characteristics of four-electron double-quantum-dot artificial molecules

Energy spectra, spin configurations, and entanglement characteristics of a system of four electrons in lateral double quantum dots are investigated using exact diagonalization (EXD), as a function of interdot separation, applied magnetic field, and strength of interelectron repulsion. A distinctly different quantum behavior is found compared to that of circular single quantum dots. As a function of the magnetic field, the energy spectra exhibit a low-energy band consisting of a group of six states, with the number six being a consequence of the conservation of the total spin of the four electrons and the ensuing spin degeneracies. These six states appear to cross at a single value of the magnetic field, with the crossing point becoming sharper for larger interdot distances. As the strength of the Coulomb repulsion increases, the six states tend to become degenerate and a well defined energy gap separates them from the higher-in-energy excited states. The appearance of the low-energy band is a consequence of the formation of a Wigner supermolecule, with the four electrons (two in each dot) being localized at the vertices of a rectangular parallelogram. Using the spin-resolved pair-correlation functions, one can map the EXD many-body wave functions onto the spin functions associated with the four localized electrons. Analogies with nanomagnets, such as finite Heisenberg clusters, are discussed. The ability to determine associated spin functions enables investigations concerning entanglement properties of the system of four electrons. In particular, the formation of Wigner supermolecules generates EXD solutions belonging to the class of strongly entangled states referred to as N-qubit Dicke states in the quantum-information literature.

cond-mat.mes-hall↗

Five-fold symmetry in fractal atom hydrogen probed with accurate 1S-nS terms

We probe Penrose's five-fold symmetry and fractal behavior for atom H. With radius r(H) derived from H mass m(H), H symmetry is governed by Euclid's golden ratio phi=0,5(sqrt(5)-1), as proved with accurate H terms. A Hund-type Mexican hat curve in the natural H spectrum points to mirrored antihydrogen Hbar. We predict that term H 1S-3S, to be measured soon, is 2 922 743 278 654 kHz.

physics.gen-ph↗

Transport Properties of a Non-relativistic Delta-Shell Gas with Long Scattering Lengths

The coefficients of diffusion, thermal conductivity, and shear viscosity are calculated for a system of non-relativistic particles interacting via a delta-shell potential V(r)=-v δ(r-R) when the average distance between particles is smaller than R. The roles of resonances and long scattering lengths including the unitary limit are examined. Results for ratios of diffusion to viscosity and viscosity to entropy density are presented for varying scattering lengths.

quant-ph↗

Angle resolved photon spectrum and quasiparticle excitation spectrum in an exciton superfluid

There have been extensive experimental search for possible exciton superfluid in semiconductor electron-hole bilayer systems below liquid Helium temperature. However, exciton superfluid are meta-stable and will eventually decay through emitting photons. Here we show that the light emitted from the excitonic superfluid has unique and unusual features not shared by any other atomic or condensed matter systems. We evaluate angle resolved photon spectrum, momentum distribution curve, energy distribution curve and quasiparticle excitation spectrum in the exciton superfluid and comment on relevant experimental data in both exciton and exciton-polariton systems.

cond-mat.mes-hall↗

Time-of-Flight Signatures of Bosons in a Double Well

We present analytical and numerical treatments for evaluating the time-of-flight momentum distribution for the stationary states of a two-boson system trapped in a quartic double-well potential, paying particular attention to the Tonks and noninteracting regimes. We find that the time-of-flight distributions can serve as a valuable tool in profiling the states of this system, and provide the tof plots for low-energy excitations using a nonadaptive finite element method that is more efficient than traditional finite difference methods.

physics.atom-ph↗

Wide cylindrical or spherical optical potentials from laser beam superpositions

Superpositions of paraxial Laguerre-Gauss laser beam modes to generate optical potentials based on the optical dipole force are investigated theoretically. Parabolic and other monomial potentials with even powers, in cylindrical and spherical symmetry, with large diameters, can be synthesized. This superposition approach promises to help with high quality atom cloud manipulation and imaging.

physics.optics↗

Optical transition of the $^{229}$Th nucleus in a solid-state environment

We describe a novel approach to directly measure the energy of the narrow, low-lying isomeric state in $^{229}$Th. Since nuclear transitions are far less sensitive to environmental conditions than atomic transitions, we argue that the $^{229}$Th optical nuclear transition may be driven inside a host crystal with a high transition Q. This technique might also allow for the construction of a solid-state optical frequency reference that surpasses the precision of current optical clocks, as well as improved limits on the variability of fundamental constants. Based on analysis of the crystal lattice environment, we argue that a precision of $3\times10^{-17}<Δf/f <1\times10^{-15}$ after 1 s of photon collection may be achieved with a systematic-limited accuracy of $Δf/f \sim 2 \times 10^{-16}$. Improvement by $10^2-10^3$ of the constraints on the variability of several important fundamental constants also appears possible.

physics.atom-ph↗