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Constrain on superconductivity of potassium intercalated phenanthrene

Raman-scattering measurements are performed in K${_x}$phenanthrene with the nominal value ${x}$ ranging from 0 to 6.0 at room temperature. Based on the Raman spectra, two phases (${x}$ = 3.0 and 4.0) are observed among the K${_x}$phenanthrene, and the immediate phase (${x}$ = 3.5) is produced. Only the ${x}$ = 3.0 phase is found to exhibit the superconducting transition at 5 K. The C-C stretching mods are observed to broaden and become disorder in K${_x}$phenanthrene (nominal value ${x}$ =2.0, 2.5, 6.0), indicating some molecular disorder in the metal intercalation process. This disorder is expected to influence the nonmetallic nature of these materials. The absence of metallic characteristics in those nonsuperconducting phases is provided from the calculated electronic structures based on the local density approximation.

cond-mat.supr-con↗

Two regimes in conductivity and the Hall coefficient of underdoped cuprates in strong magnetic fields

We address recent experiments shedding light on the energy spectrum of under- and optimally doped cuprates at temperatures above superconducting transition. Angle resolved photoemission reveals coherent excitation only near nodal points on parts of the "bare" Fermi surface known as the Fermi arcs. The question debated in the literature is whether the small normal pocket, seen via quantum oscillations exists at higher temperatures or forms below a charge order transition in strong magnetic fields. Assuming the former case as possibility, expressions derived for the resistivity and the Hall coefficient (in weak and strong magnetic fields) with both types of carriers participating in transport. There are two regimes. At higher temperatures (at a fixed field) electrons are dragged by the Fermi arcs' holes. The pocket being small its contribution into conductivity and the Hall coefficient is negligible. At lower temperatures electrons decouple from holes behaving as a Fermi gas in the magnetic field. Mobility of holes on the arcs decreasing in strong fields with decrease of temperature, below a crossover point the pocket electrons prevail changing sign of the Hall coefficient in the low temperature limit. Such behavior finds its confirmation in recent high-field experiments.

cond-mat.supr-con↗

Polarization-Dependent Three-Dimensional Angle-Resolved Photoemission Spectroscopy of BaFe$_{1.8}$Co$_{0.2}$As$_{2}$

We performed polarization- and photon-energy-dependent angle-resolved photoemission spectroscopy of a slightly overdoped iron pnictide superconductor, BaFe$_{1.8}$Co$_{0.2}$As$_{2}$, to clarify the three-dimensional electronic structure including its orbital characters at the Brillouin zone center. Two hole Fermi surfaces (FSs) with $d_{xz/yz}$ and $d_{xy/x^2-y^2}$ orbitals were observed but $d_{z^2}$ hole FS, which has nodes according to a theory of the spin-fluctuation superconductivity mechanism, did not appear. These results suggest that no node will appear at hole FSs at the zone center.

cond-mat.supr-con↗

Specific features of electron spin resonance in quasi-1D magnet β-TeVO4

The angular and temperature dependences of single crystal ESR spectra at X-band frequency of quasi 1D spin 1/2 antiferromagnetic zigzag chain system β-TeVO4 are reported. Two resonance components in the ESR spectrum have been detected: a weak narrow resonance on the top of the extremely broad signal. The narrow line might be due to an impurity, the characteristics of the broad absorption do not correlate with a picture of the typical behavior for the V4+ ions (S = 1/2) with a square pyramidal environment. It was found that at low temperatures the divergence of the spin susceptibility and linewidth of the observed excitations can be due to a realization of three dimensional magnetic ordering.

cond-mat.str-el↗

A study of crossover from 3D ferrimagnetic Bulk $NiCr_{2}O_{4}$ compound into 2D spin-glass like nanophase

In this report, the magnetic behaviour of $NiCr_{2}O_{4}$ bulk and nanoparticle samples under different applied magnetic field has been investigated extensively. Nanoparticles of $NiCr_{2}O_{4}$ were obtained by mechanical milling of polycrystalline powder prepared by polyol method. FC-ZFC measurement of bulk at different applied magnetic field has revealed the existence of a ferrimagnetic transition around 66K followed by an antiferromagnetic transition close to 30K. However, its nano counterpart has shown remarkable change in magnetic properties - a suppression of ferrimagnetic transition accompanied by strengthening low temperature magnetic phase and observation of a new transition at 90K ($T_P$), which is weakly magnetic in nature. The frequency dependent ac susceptibility data of nanoparticle have been fitted to the well known de Almedia-Thouless equation and a $H^{2/3}$ dependence of the low temperature peak is observed with a resulting zero field freezing temperature ($T_f^0$) equal to 10.1K. Further, the dynamical behaviour near freezing temperature has been analysed in terms of critical behaviour and the obtained fitted parameters values being as $τ_0$(relaxation time constant) = $3.6 X 10^{-6}s$, $T_f^0=8.7$K and $zν= 11.1$. Moreover, Vogel-Fulcher law has been used to understand the nature of freezing transition and the parameter after fitting are obtained as $E_a/k_B = 58.9$K, $τ_0 = 5.22 \times 10^{-8}$ and $T_0 = 8.03$K. Finally, the spin-glass phase is concluded. Moreover, in contrast to bulk, the $H^{2/3}$ dependence of freezing temperature of nanoparticle sample (75h) does support the 2D surface like spin glass nature.

cond-mat.str-el↗

Doping evolution of the electron-hole asymmetric s-wave pseudogap in underdoped high-Tc cuprate superconductors

We study the doping evolution of the electronic structure in the pseudogap state of high-Tc cuprate superconductors, by means of a cluster extension of the dynamical mean-field theory applied to the two-dimensional Hubbard model. The calculated single-particle excitation spectra in the strongly underdoped regime show a marked electron-hole asymmetry and reveal a "s-wave" pseudogap, which display a finite amplitude in all the directions in the momentum space but not always at the Fermi level: The energy location of the gap strongly depends on momentum, and in particular in the nodal region, it is above the Fermi level. With increasing hole doping, the pseudogap disappears everywhere in the momentum space. We show that the origin and the "s-wave" structure of the pseudogap can be ascribed to the emergence of a strong-scattering surface, which appears in the energy-momentum space close to the Mott insulator.

cond-mat.str-el↗

Local magnetism and structural properties of Heusler Ni$_2$MnGa alloys

We present a detailed experimental study of bulk and powder samples of the Heusler shape memory alloy Ni$_2$MnGa, including zero-field static and dynamic $^{55}$Mn NMR experiments, X-ray powder diffraction and magnetization experiments. The NMR spectra give direct access to the sequence of structural phase transitions in this compound, from the high-T austenitic phase down to the low-T martensitic phase. In addition, a detailed investigation of the so-called rf-enhancement factor provides local information for the magnetic stiffness and restoring fields for each separate coordination, structural, crystallographic environment, thus differentiating signals coming from austenitic and martensitic components. The temperature evolution of the NMR spectra and the rf-enhancement factors shows strong dependence on sample preparation. In particular, we find that sample powderization gives rise to a significant portion of martensitic traces inside the high-T austenitic region, and that these traces can be subsequently removed by annealing.

cond-mat.mtrl-sci↗

NiS - An unusual self-doped, nearly compensated antiferromagnetic metal

NiS, exhibiting a text-book example of a first-order transition with many unusual properties at low temperatures, has been variously described in terms of conflicting descriptions of its ground state during the past several decades. We calculate these physical properties within first-principle approaches based on the density functional theory and conclusively establish that all experimental data can be understood in terms of a rather unusual ground state of NiS that is best described as a self-doped, nearly compensated, antiferromagnetic metal, resolving the age-old controversy. We trace the origin of this novel ground state to the specific details of the crystal structure, band dispersions and a sizable Coulomb interaction strength that is still sub-critical to drive the system in to an insulating state. We also show how the specific antiferromagnetic structure is a consequence of the less-discussed 90 degree and less than 90 degree superexchange interactions built in to such crystal structures.

cond-mat.str-el↗

Magnetic instability of the orbital-selective Mott phase

We characterize the low-energy physics of the two-orbital Hubbard model in the orbital-selective Mott phase, in which one band is metallic and the other insulating. Using dynamical mean-field theory with the numerical renormalization group at zero temperature, we show that this phase has a ferromagnetic instability for any nonzero Hund's rule exchange interaction, which can be understood in terms of an effective spin-1 Kondo Hamiltonian. The metallic band therefore behaves as a singular Fermi liquid for which the self-energy has a logarithmic singularity at the Fermi energy.

cond-mat.str-el↗

The Mn-O bonds dependence of the lattice distortion in LaMnO3

We have investigated the volume collapse occurring in LaMnO3 unit cell using the anisotropic Potts model modified by two types of anisotropic interactions which has been used to study the change of Mn-O bonds lengths as function of temperature. The bond lengths are related to the occupation of the orbits. The lattice parameters and the distortion modes have been investigated as well. We have shown that the collapse is due to the change of Mn-O bonds lengths change as the temperature is raised through the transition. It has been shown that all the parameters studied here decrease with increasing temperature in a narrow temperature range below TJT, and then undergoes a collapse at TJT. These results are in a good agreement with the published experimental results.

cond-mat.str-el↗

Comments on Coulomb pairing in aromatic hydrocarbons

Recently reported anomalies in the double-photonionization spectra of aromatic molecules such as benzene, naphthalene, anthracene and coronene are attributed to Coulomb-pair resonances of pi electrons.

physics.chem-ph↗

Tensor networks for frustrated systems: emergence of order from simplex entanglement

We consider a frustrated anti-ferromagnetic triangular lattice Hamiltonian and show that the properties of the manifold of its degenerated ground state are represented by a novel type of tensor networks. These tensor networks are not based on ancillary maximally entangled pairs, but rather on triangular W-like simplices. Anti-ferromagnetic triangular frustration is then related to ancillary W-states in contrast to ferromagnetic order which emerges from the contraction of GHZ-like triangular simplices. We further discuss the outwards entangling power of various simplices. This analysis suggests the emergence of distinct macroscopic types of order from the classification of entanglement residing on the simplices that define a tensor network.

quant-ph↗

Full susceptibility tensor for localized spin models with S=1, 3/2, 2, 5/2 and with rhombic anisotropy

A general discussion of the simulation procedure of the full susceptibility tensor and isothermal magnetization pseudovector for compounds comprising weakly-interacting magnetic centers is presented. A single-crystal-sample as well as a powder-sample case are considered. The procedure is used to obtain explicit expressions for the full susceptibility tensor for spins S=1, 3/2, 2, and 5/2 for non-vanishing rhombic local anisotropy and any form of spectroscopic tensor.

cond-mat.other↗

Geometric Aspects and Neutral Excitations in the Fractional Quantum Hall Effect

In this thesis, I will present studies on the collective modes of the fractional quantum Hall states, which are bulk neutral excitations reflecting the incompressibility that defines the topological nature of these states. It was first pointed out by Haldane that the non-commutative geometry of the fractional quantum Hall effects (FQHE) plays an important role in the intra-Landau-level dynamics. The geometrical aspects of the FQHE will be illustrated by calculating the linear response to a spatially varying electromagnetic field, and by a numerical scheme for constructing model wavefunctions for the neutral bulk excitations. Compared to early studies of the magneto-roton modes with single mode approximation (SMA), the scheme presented in this thesis is good not only in the long wavelength limit, but also for large momenta where the neutral excitations evolve into quasihole-quasiparticle pair. It is also shown that in the long wavelength limit, the SMA scheme produces exact model wavefunctions describing a quadrupole excitation. The same scheme can also extend to describe the neutral fermion mode in the Moore-Read state, reflecting its non-Abelian nature. The numerically generated model wavefunctions are then identified with a family of analytic wavefunctions that describe both the magneto-roton modes and the neutral fermion modes. Like the ground state wavefunction of the Laughlin and Moore-Read state, ...

cond-mat.str-el↗

New Green function approach describing the ferromagnetic state in the simple Hubbard model

We consider a Hubbard model with occupation dependent hopping integrals. Using the Hartree-Fock (H-F) approximation and the new Green function approach with inter-site kinetic averages included, we analyze the influence of the correlated hopping on ferromagnetic ordering. The influence of correlated hopping on the nonlocal quasiparticle energies and corresponding k-dependent spectral weights is included. In addition we obtain the shift of the spin bands which is a major factor in creating spontaneous ferromagnetism. At some parameters of the model the correlated hopping effect is strong enough to achieve saturated ferromagnetism. This state may be obtained at the asymmetric density of states (DOS) and the Fermi energy located in the region of large spectral weight near the band edge. The results are compared with DMFT-Quantum Monte Carlo calculations and with the Hubbard III approximation which includes the correlated hopping effect.

cond-mat.str-el↗

Topological properties of possible Weyl superconducting states of URu$_\mathbf{2}$Si$_\mathbf{2}$

We show that the current thermodynamic measurements in the superconducting phase of $\mathrm{U}\mathrm{Ru}_2\mathrm{Si}_2$ are compatible with two distinct singlet chiral paired states $k_z(k_x \pm i k_y)$ and $(k_x \pm i k_y)^2$. Despite possessing similar low temperature thermodynamic properties, these two pairings are topologically distinguished by their respective orbital angular momentum projections along the c-axis, $m=\pm 1$ and $m=\pm 2$. The point nodes of these states act as the monopoles and the anti-monopoles of the Berry's gauge flux of charge $\pm m$, which are separated in the momentum space along the $c$ axis. As a result, the Berry's flux through the $ab$ plane equals $m$. Consequently, the point nodes of $k_z(k_x+i k_y)$ and $(k_x \pm ik_y)^2$ states respectively realize the Weyl and the double-Weyl fermions, with chemical potential exactly tuned at the Fermi point, due to the charge conjugation symmetry. These topologically nontrivial point nodes, give rise to $m$ copies of protected spin degenerate, chirally dispersing surface states on the $ca$ and the $cb$ planes, which carry surface current, and their energies vanish at the Fermi arcs. In contrast, a line node acts as the momentum space vortex loop, and gives rise to the zero energy, dispersionless Andreev bound states on the surfaces parallel to the plane enclosed by the line node. The Berry's flux through the $ab$ plane gives rise to anomalous spin Hall and thermal Hall conductivities, and various magnetoelectric effects. A clear determination of the bulk invariant can only be achieved by probing the pairing symmetry via a corner Josephson junction measurement, and Fourier transformed STM measurements of the Fermi arcs. Therefore, we identify $\mathrm{U}\mathrm{Ru}_2\mathrm{Si}_2$ as a promising material for realizing gapless topological superconductivity in three spatial dimensions.

cond-mat.supr-con↗

Low temperature diffuse neutron scattering and magnetisation in single crystal Tb2Ti2O7

We present an interpretation of zero field diffuse neutron scattering and of high field magnetisation data at very low temperature in the frustrated pyrochlore system Tb2Ti2O7. This material has antiferromagnetic exchange interactions and it is expected to have Ising character at low temperature. Contrary to expectations, it shows no magnetic ordering down to 0.05\,K, being thus labelled a "spin liquid". However, the ground state in Tb2Ti2O7 is not a mere fluctuating moment paramagnet but, as demonstrated by very recent experiments, a state where the electronic degrees of freedom are hybridised with the phononic variables in an unconventional way. We show here that, by approximating this complex and still unraveled electron-phonon interaction by a dynamic Jahn-Teller coupling, one can account rather well for the diffuse neutron scattering and the low temperature isothermal magnetisation. We discuss the shortcomings of this picture which arise mainly from the fact that the singlet electronic mean field ground state of the model fails to reproduce the observed strong intensity of the elastic and quasi-elastic neutron scattering.

cond-mat.str-el↗

Physical properties of CeGe2-x (x = 0.24) single crystals

We present data on the anisotropic magnetic properties, heat capacity and transport properties of CeGe2-x (x = 0.24) single crystals. The electronic coefficient of the heat capacity, gamma ~ 110 mJ/mol K^2, is enhanced; three magnetic transitions, with critical temperatures of ~ 7 K, ~ 5 K, and ~ 4 K are observed in thermodynamic and transport measurements. The ground state has a small ferromagnetic component along the c - axis. Small applied field, below 10 kOe, is enough to bring the material to an apparent saturated paramagnetic state (with no further metamagnetic transitions up to 55 kOe) with a reduced, below 1 mu_B, saturated moment.

cond-mat.mtrl-sci↗