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Lead Halide Perovskite based Dynamic Metasurfaces

Lead halide perovskites (MAPbX3) are known to have high refractive index and controllable bandgap, making them attractive for all-dielectric and tunable metasurfaces. Till now, perovskite metasurfaces have only been used in structural colors. More interesting meta-devices with 2π phase control are still absent. Here we experimentally demonstrate the MAPbX3 perovskite based metasurfaces with a complete control of phase shift in a reflection mode. By utilizing MAPbBr3 cut-wires as meta-atoms on a ground metal film, we find that the MAPbBr3 perovskite metasurface can produce full phase control from 0 to 2π and high reflection efficiency simultaneously. Consequently, high-efficiency polarization conversion, anomalous reflection and meta-hologram have been successfully produced. Most interestingly, the bandgap of MAPbX3 perovskite can be post-synthetically and reversibly tuned via anion exchange, providing a new approach to dynamically control of the all-dielectric meta-devices with novel function such as anomalous reflection and hologram et al.

physics.app-ph↗

Colloidal Quantum Dot Tandem Solar Cells Using CVD Graphene as An Atomically Thin Intermediate Recombination Layer

Two-terminal tandem cell architectures are believed to be an effective way to further improve the power conversion efficiency in solution processed photovoltaics. To design an efficient tandem solar cell, two key issues need to be considered. Firstly, subcells with well-matched currents and complementary absorption characteristics are a prerequisite for high efficiency. Secondly identifying the appropriate intermediate layer (IML) to connect the subcells is necessary to minimize the optical and electronic losses. PbS colloidal quantum dots (CQDs) are a notable choice for the subcells due to their low cost, solution processibility and remarkable wide range band gap tunability. Single layer Graphene (Gr) has been proposed to be a promising IML due to its high transparency and conductivity. Here, as a proof of concept, we demonstrate a solution processed two terminal PbS CQDs tandem solar cell employing chemical vapor deposited Gr as the IML. In doing so, we report a PbS CQD cell comprising subcells with bandgaps of 1.4 and 0.95 eV that delivers power conversion efficiency in excess of 7%, substantially higher than previously reported CQD tandem cells.

physics.app-ph↗

Estimating country-specific space heating threshold temperatures from national consumption data

Space heating in buildings is becoming a key element of sector-coupled energy system research. Data availability limits efforts to model the buildings sector, because heat consumption is not directly metered in most countries. Space heating is often related to weather through the proxy of heating degree-days using a specific heating threshold temperature, but methods vary between studies. This study estimates country-specific heating threshold temperatures using widely and publicly available consumption and weather data. This allows for national climate and culture-specific human behaviour to be captured in energy systems modelling. National electricity and gas consumption data are related to degree-days through linear models, and Akaike's Information Criteria is used to define the summer season in each country, when space heating is not required. We find that the heating threshold temperatures computed using daily, weekly and monthly aggregated consumption data are statistically indifferent. In general, threshold temperatures for gas heating centre around 15.0 +/- 1.7 degree C (daily averaged temperature), while heating by electricity averages to 13.4 +/- 2.4 degree C. We find no evidence of space heating during June, July and August, even if heating degree-days are present.

physics.soc-ph↗

Decomposing Temperature Time Series with Non-Negative Matrix Factorization

During the fabrication of casting parts sensor data is typically automatically recorded and accumulated for process monitoring and defect diagnosis. As casting is a thermal process with many interacting process parameters, root cause analysis tends to be tedious and ineffective. We show how a decomposition based on non-negative matrix factorization (NMF), which is guided by a knowledge-based initialization strategy, is able to extract physical meaningful sources from temperature time series collected during a thermal manufacturing process. The approach assumes the time series to be generated by a superposition of several simultaneously acting component processes. NMF is able to reverse the superposition and to identify the hidden component processes. The latter can be linked to ongoing physical phenomena and process variables, which cannot be monitored directly. Our approach provides new insights into the underlying physics and offers a tool, which can assist in diagnosing defect causes. We demonstrate our method by applying it to real world data, collected in a foundry during the series production of casting parts for the automobile industry.

cs.LG↗

Ultraprecise Detection of Low Molecular Weight Antibodies Using Mid-IR Toroidal Plasmonic Meta-Atoms

Plasmonic metamaterials can be used to enhance mid-infrared sensors and detectors for immunosensing applications. The major challenge is to integrate these technologies in low-cost, compact, and promising platforms. In this study, as an emerging approach, we utilized toroidal resonant plasmonic metasurfaces to develop an ultrasensitive label-free analytical platform for the detection of specific antibiotics in the mid-IR regime. Taking advantage of unique sensitivity of robustly squeezed electromagnetic fields in toroidal meta-atoms, we validated that our proposed technique based on toroidal metastructures can provide sensing of biological targets with the weight of ~0.6 KDa at attomolar concentrations. We believe that this understanding extends the capabilities of plasmonic metamaterials analyze the presence of specific biological targets with high precision.

physics.optics↗

Damping control in viscoelastic beam dynamics

Viscoelasticity plays a key role in many practical applications and in different reasearch fields, such as in seals, sliding-rolling contacts and crack propagation. In all these contexts, a proper knowledge of the viscoelastic modulus is very important. However, the experimental characterization of the frequency dependent modulus, carried out through different standard procedures, still presents some complexities, then possible alternative approaches are desirable. For example, the experimental investigation of viscoelastic beam dynamics would be challenging, especially for the intrinsic simplicity of this kind of test. This is why, a deep understanding of damping mechanisms in viscoelastic beams results to be a quite important task to better predict their dynamics. With the aim to enlighten damping properties in such structures, an analytical study of the transversal vibrations of a viscoelastic beam is presented in this paper. Some dimensionless parameters are defined, depending on the material properties and the beam geometry, which enable to shrewdly design the beam dynamics. In this way, by properly tuning such disclosed parameters, for example the dimensionless beam length or a chosen material, it is possible to enhance or suppress some resonant peaks, one at a time or more simultaneously. This is a remarkable possibility to efficiently control damping in these structures, and the results presented in this paper may help in elucidating experimental procedures for the characterization of viscoelastic materials.

physics.app-ph↗

Three-dimensional laser printing of macro-scale glass objects at a micro-scale resolution

Three-dimensional (3D) printing has allowed for production of geometrically complex 3D objects with extreme flexibility, which is currently undergoing rapid expansions in terms of materials, functionalities, as well as areas of application. When attempting to print 3D microstructures in glass, femtosecond laser induced chemical etching (FLICE) has proved itself a powerful approach. Here, we demonstrate fabrication of macro-scale 3D glass objects of large heights up to ~3.8 cm with a well-balanced (i.e., lateral vs longitudinal) spatial resolution of ~20 μm. The remarkable accomplishment is achieved by revealing an unexplored regime in the interaction of ultrafast laser pulses with fused silica which results in aberration-free focusing of the laser pulses deeply inside fused silica.

physics.app-ph↗

Analysis and design of a Germanium multi-quantum well metal strip nanocavity plasmon laser

In order to achieve electrically pumped plasmon nano lasers, several structures, materials and methods, have been proposed recently. However, there is still a long way to find out a reliable appropriate on-chip plasmon source for commercial plasmonic integrated circuits. In this paper, a new waveguide integrated nanocavity plasmon laser is proposed for 1550 nm free-space wavelength. Due to its significant field confinement resulted by the metal strip structure and strong interaction of plasmonic modes with the germanium quantum wells and as a result a considerable Purcell factor about 291, this structure has a remarkable output performance. Using semi-classical rate equations in combination with finite difference time domain (FDTD) cavity mode analysis, the output performance measures are estimated and confirmed with respect to various physical models and simulation tools. Simulation results for this tiny structure (0.073 um2 area) show a 2.8uW output power with 10uA injection current and about 4.16mW output power with the threshold pump current of 27mA while maintaining its performance in a wide modulation bandwidth of 178GHz.

physics.app-ph↗

MOSFET GIDL Currentby Designing a New BTBT Model Using De-Casteljaus Algorithm

The Band to Band tunneling probability strongly depends on the shape of the potential barrier. However, parabolic approximation of this shape is well acceptable but unfortunately significant amount of error is unavoidable by using quadratic polynomial in calculation of tunneling probability. De Casteljaus algorithm, followed by Bezier Curve can be modeled to any arbitrary shape using its Geometry Invariance Property and End points geometric property. Using this algorithm a new Band-to-Band tunneling model is designed and verified by establishing an analytic expression of Gate Induced Drain Leakage current in MOSFET.

physics.app-ph↗

Tracking-free Determination of Microparticle Motion from Image Variance

In this work, we use the standard deviation of image pixel intensity to analyse the speed, direction and surface-interaction of microparticles in fluid. First, we present an analytical model for estimating the total variance in the image space for directed or diffusive motion of microparticles and show that this measure is correlated to the density and speed of the particles. The analytical model was found to have good agreement with numerical simulations for low particle density. Then, using only the local image variance we obtain the magnitude and direction of the particle velocity in a rectangular microfluidic channel, closely matching the theoretical profile. Further, we also demonstrate the application of this method as a probe for particle-surface interactions by extracting the differences in distribution and time-evolution of image variance from mobile microparticles adhering to different surfaces. We believe that the image variance based method described here presents an addition to the suite of tracking-free techniques such as Differential Dynamic Microscopy (DDM) to extract motility parameters from video data.

physics.app-ph↗

The role of resonance and bandgaps in high $k_\textrm{eff}^2$ transducers

Bandgaps formed in a piezoelectric transducer with large coupling, $k_\textrm{eff}^2$, qualitatively modify its electrical response. This regime in which electrical loading strongly couples forward and backward waves occurs in thin-film lithium niobate which has recently become available and amenable to nanopatterning. In this work, we study how resonance and bandgaps modify the design and performance of transducers and delay lines in thin-film lithium niobate. These films are an attractive platform for GHz frequency applications in low-power RF analog signal processing, optomechanics, and quantum devices due to their high coupling, low loss, excellent optical properties, and compatibility with superconducting quantum circuits. We demonstrate aluminum IDTs in this platform for horizontal shear (SH) waves between $1.2$ and $3.3$ GHz and longitudinal waves between $2.1$ and $5.4$ GHz. For the SH waves, we measure a piezoelectric coupling coefficient of $13\%$ and $6.0$ dB/mm propagation losses in delay lines up to $1.2$ mm with a $300$ ns delay in air at room temperature. Reflections from electrical loading when $k_\textrm{eff}^2$ is large lead to a departure from the impulse response model widely used to model surface acoustic wave devices. Finite element method models and an experimental finger-pair sweep are used to characterize the role of resonance in these transducers, illuminating the physics behind the anomalously large motional admittances of these small-footprint IDTs.

physics.app-ph↗

A Theoretical Analysis on Enthalpy of Vaporization: Temperature-Dependence and Singularity at the Critical State

Accurate evaluation of enthalpy of vaporization (or latent heat of vaporization) and its variation with temperature is of great interest in practical applications, especially for combustion of liquid fuels. Currently, a theoretically rigorous formulation for latent heat is still not in place; and the existing fitting formulas for various fluids are, in nature, system-dependent. In this paper, the enthalpy of vaporization and its change with temperature are derived rigorously from first principles at the reference and critical states. A composite formula for enthalpy of vaporization is constituted from physical plausibility. The composite formula contains no fitting parameters; and it can accurately predict the enthalpy of vaporization from the reference temperature to the critical temperature.

cond-mat.stat-mech↗

Amplification of mid-infrared lasers via magnetized-plasma coupling

Plasmas may be used as gain media for amplifying intense lasers, and external magnetic fields may be applied to improve the performance. For mid-infrared lasers, the requisite magnetic field is on megagauss scale, which can already be provided by current technologies. Designing the laser amplifier requires knowing the magnetized three-wave coupling coefficient, which is mapped out systematically in this paper. By numerically evaluating its formula, we demonstrate how the coupling depends on angle of wave propagation, laser polarization, magnetic field strength, plasma temperature, and plasma density in the backscattering geometry. Since the mediation is now provided by magnetized plasma waves, the coupling can differ significantly from unmagnetized Raman and Brillouin scatterings.

physics.plasm-ph↗

Scalable interdigitated photoconductive emitters for the electrical modulation of terahertz beams with arbitrary linear polarization

A multi-element interdigitated photoconductive emitter for broadband THz polarization rotation is proposed and experimentally verified. The device consists of separate pixels for the emission of horizontally and vertically polarized THz radiation. The broadband (0.3-5.0THz) nature of the device is demonstrated, and the polarization angle of the generated far-field THz radiation is shown to be readily controlled by varying the relative bias voltage applied to the horizontally and vertically emitting pixels. The device is scalable in design, and with its simple method of polarization rotation it allows the modulation of the generated THz polarization at rates significantly faster than those achievable in ellipsometry systems based on mechanically rotating components.

physics.optics↗

Multifunctional Metamirrors Involving Simultaneous Linear-polarization Conversion and Focusing

Reducing a set of diverse bulk-optic-based optical components to a single ultrathin and compact element that enables the same complex functionality has become an emerging research area, propelling further integration and miniaturization in photonics. In this work, we establish a versatile metasurface platform based on gap-surface plasmon meta-atoms enabling efficient linear-polarization conversion along with the complete phase control over reflected fields. Capitalizing on the meta-atom design, multifunctional metamirrors involving linear-polarization conversion and focusing are experimentally demonstrated to generate various kinds of focused beams with distinct phase distributions and wavefronts, reproducing thereby the combined functionalities of conventional half-wave plates, lenses, and even spatial light modulators. The proof-of-concept fabricated metamirrors exhibit excellent capability of linear-polarization conversion and focusing within the wavelength range from 800 to 950 nm under linearly-polarized excitation. The multifunctional metamirrors design developed in this study opens new avenues in the advanced research and applications targeting photonics integration of diversified functionalities.

physics.optics↗

Acoustic cloaking: geometric transform, homogenization and a genetic algorithm

A general process is proposed to experimentally design anisotropic inhomogeneous metamaterials obtained through a change of coordinate in the Helmholtz equation. The method is applied to the case of a cylindrical transformation that allows to perform cloaking. To approximate such complex metamaterials we apply results of the theory of homogenization and combine them with a genetic algorithm. To illustrate the power of our approach, we design three types of cloaks composed of isotropic concentric layers structured with three types of perforations: curved rectangles, split rings and crosses. These cloaks have parameters compatible with existing technology and they mimic the behavior of the transformed material. Numerical simulations have been performed to qualitatively and quantitatively study the cloaking efficiency of these metamaterials.

physics.comp-ph↗

Estimating of optimal dose of PACL for turbidity removing from water

Removing suspended solids and colloids are one of the most important water treatment processes. In this research, experimental tests have been done to assess the effects of pH and different doses of PACL on turbidity removal efficiency. The optimum dose of poly aluminum chloride (PACL) for removing turbidity was also determined. Turbidity was created artificially by adding the Kaolin with six different initial turbidities between 20 to 300 NTU rested for half an hour. The results have been showed that the best removal efficiency was at the pH of natural water. The optimal doses consumption of PACL was about 5 PPM.

physics.chem-ph↗

Quantum Point Contact Parameter Extraction of Carbon-based Resistive Memory using Hybrid Genetic Algorithm

Resistive switching phenomenon in carbon film is associated with formation and annihilation of low resistance sp2 nanochannels within the amorphous sp3 matrix. The thinnest point of these graphitic nanochannels behaves like quantum wire (QW) and limits current flow. Transport mechanism at these bottlenecks can be described within the framework of quantum point contact (QPC) model. The model applies mesoscopic Landauer formalism and correlates device resistance state with the density of the nanochannels as well as lateral area of its constriction. However, QPC model parameter extraction from macroscopic I-V characteristic is not feasible due to multiple nonlinear and closely coupled parameters, e.g. barrier height (Φ), barrier curvature (α) and voltage drop ratio (\b{eta}). In this work, a hybrid genetic algorithm (GA) based parameter extraction flow is proposed and is applied to extract parameters from experimental result of carbon-based resistive memories. In this proposed flow, the number of single subband channels for low resistance state (NLRS) and barrier curvature parameter at high resistance state (αHRS) were first derived by exploring boundary conditions at low voltage. The four remaining parameters (ΦHRS, ΦLRS, αLRS, and \b{eta}) were then extracted from experimental I-V characteristic by leveraging hybrid GA. Mean absolute percentage error (MAPE) of fitted QPC models is only 3.7% and the extracted parameters are within reasonable range. Hereby, we regard the QPC model as a viable model to describe conduction mechanism of graphitic nanochannels in carbon-based resistive memories.

physics.comp-ph↗