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Charge relaxation dynamics of an electrolytic nanocapacitor

Understanding ion relaxation dynamics in overlapping electric double layers (EDLs) is critical for the development of efficient nanotechnology based electrochemical energy storage, electrochemomechanical energy conversion and bioelectrochemical sensing devices as well as controlled synthesis of nanostructured materials. Here, a Lattice Boltzmann (LB) method is employed to simulate an electrolytic nanocapacitor subjected to a step potential at t = 0 for various degrees of EDL overlap, solvent viscosities, ratios of cation to anion diffusivity and electrode separations. The use of a novel, continuously varying and Galilean invariant, molecular speed dependent relaxation time (MSDRT) with the LB equation recovers a correct microscopic description of the molecular collision phenomena and enhances the stability of the LB algorithm. Results for large EDL overlaps indicated oscillatory behavior for the ionic current density in contrast to monotonic relaxation to equilibrium for low EDL overlaps. Further, at low solvent viscosities and large EDL overlaps, anomalous plasma-like spatial oscillations of the electric field were observed that appeared to be purely an effect of nanoscale confinement. Employing MSDRT in our simulations enabled a modeling of the fundamental physics of the transient charge relaxation dynamics in electrochemical systems operating away from equilibrium wherein Nernst-Einstein relation is known to be violated.

physics.chem-ph↗

Electrocapillary instability of magnetic fluid peak

The paper presents an experimental study of the capillary electrostatic instability occurring under effect of a constant electric field on a magnetic fluid individual peak. The peaks under study occur at disintegration of a magnetic fluid layer applied on a flat electrode surface under effect of a perpendicular magnetic field. The electrocapillary instability shows itself as an emission of charged drops jets from the peak point in direction of the opposing electrode. The charged drops emission repeats periodically and results in the peak shape pulsations. It is shown that a magnetic field affects the electrocapillary instability occurrence regularities and can stimulate its development. The critical electric and magnetic field strengths at which the instability occurs have been measured; their dependence on the peak size is shown. The hysteresis in the system has been studied; it consists in that the charged drops emission stops at a lesser electric (or magnetic) field strength than that of the initial occurrence. The peak pulsations frequency depending on the magnetic and electric field strengths and on the peak size has been measured.

physics.flu-dyn↗

A Landau-Squire Nanojet

Fluid jets are found in nature at all length scales, from microscopic to cosmological. Here we report on an electroosmotically driven jet from a single glass nanopore about 75 nm in radius with a maximum flow rate ~15 pL/s. A novel anemometry technique allows us to map out the vorticity and velocity fields that show excellent agreement with the classical Landau-Squire solution of the Navier Stokes equations for a point jet. We observe a phenomenon that we call flow rectification: an asymmetry in the flow rate with respect to voltage reversal. Such a nanojet could potentially find applications in micromanipulation, nanopatterning, and as a diode in microfluidic circuits.

physics.flu-dyn↗

Coalescence of bubbles and drops in an outer fluid

When two liquid drops touch, a microscopic connecting liquid bridge forms and rapidly grows as the two drops merge into one. Whereas coalescence has been thoroughly studied when drops coalesce in vacuum or air, many important situations involve coalescence in a dense surrounding fluid, such as oil coalescence in brine. Here we study the merging of gas bubbles and liquid drops in an external fluid. Our data indicate that the flows occur over much larger length scales in the outer fluid than inside the drops themselves. Thus we find that the asymptotic early regime is always dominated by the viscosity of the drops, independent of the external fluid. A phase diagram showing the crossovers into the different possible late-time dynamics identifies a dimensionless number that signifies when the external viscosity can be important.

physics.flu-dyn↗

Switchable Imbibition in Nanoporous Gold

Spontaneous imbibition enables the elegant propelling of nano-flows because of the dominance of capillarity at small length scales. The imbibition kinetics are, however, solely determined by the static geometry of the porous host, the capillarity, and the fluidity of the imbibed liquid. This makes active control particularly challenging. Here, we show for aqueous electrolyte imbibition in nanoporous gold that the fluid flow can be reversibly switched on and off through electric potential control of the solid-liquid interfacial tension, i.e. we can accelerate the imbibition front, stop it, and have it proceed at will. Simultaneous measurements of the mass flux and the electrical current allow us to document simple scaling laws for the imbibition kinetics, and to explore the charge flow dynamics in the metallic nanopores. Our findings demonstrate that the high electric conductivity along with the pathways for ionic and/or fluid transport render nanoporous elemental gold a versatile, accurately controllable electro-capillary pump and flow sensor for minute amounts of liquids with exceptionally low operating voltages.

physics.flu-dyn↗

Scalar $ϕ^4$ field theory for active-particle phase separation

Recent theories predict phase separation among orientationally disordered active particles whose propulsion speed decreases rapidly enough with density. Coarse-grained models of this process show time-reversal symmetry (detailed balance) to be restored for uniform states, but broken by gradient terms; hence detailed-balance violation is strongly coupled to interfacial phenomena. To explore the subtle generic physics resulting from such coupling we here introduce `Active Model B'. This is a scalar $ϕ^4$ field theory (or phase-field model) that minimally violates detailed balance via a leading-order square-gradient term. We find that this additional term has modest effects on coarsening dynamics, but alters the static phase diagram by creating a jump in (thermodynamic) pressure across flat interfaces. Both results are surprising, since interfacial phenomena are always strongly implicated in coarsening dynamics but are, in detailed-balance systems, irrelevant for phase equilibria.

cond-mat.soft↗

The laminar-turbulent transition in a fibre laser

Studying transition to a highly disordered state of turbulence from a linearly stable coherent laminar state is conceptually and technically challenging and immensely important, e.g. all pipe and channel flows are of that type. In optics, understanding how systems lose coherence with increase of spatial size or excitation level is an open fundamental problem of practical importance. Here we identify, arguably, the simplest system where this classical problem can be studied: we learnt to operate a fibre laser in laminar and turbulent regimes. We show that laminar phase is an analogue of a one-dimensional coherent condensate and turbulence onset is through a spatial loss of coherence. We discover a new mechanism of laminar-turbulent transition in laser operation: condensate destruction by the clustering of dark and grey solitons. This is important both for the design of devices exploiting coherent dynamics and for conceptually new technologies based on systems operating far from thermodynamic equilibrium.

physics.optics↗

Microfluidic pumping using artificial magnetic cilia

One of the vital functions of naturally occurring cilia is fluid transport. Biological cilia use spatially asymmetric strokes to generate a net fluid flow that can be utilized for feeding, swimming, and other functions. Biomimetic synthetic cilia with similar asymmetric beating can be useful for fluid manipulations in lab-on-chip devices. In this paper, we demonstrate the microfluidic pumping by magnetically actuated synthetic cilia arranged in multi-row arrays. We use a microchannel loop to visualize flow created by the ciliary array and to examine pumping for a range of cilia and microchannel parameters. We show that magnetic cilia can achieve flow rates of up to 11 μl/min with the pressure drop of~ 1 Pa. Such magnetic ciliary array can be useful in microfluidic applications requiring rapid and controlled fluid transport.

physics.flu-dyn↗

Hydrodynamic Instabilities Provide A Generic Route To Spontaneous Biomimetic Oscillations In Chemomechanically Active Filaments

Non-equilibrium processes which convert chemical energy into mechanical motion enable the motility of organisms. Bundles of inextensible filaments driven by energy transduction of molecular motors form essential components of micron-scale motility engines like cilia and flagella. The mimicry of cilia-like motion in recent experiments on synthetic active filaments supports the idea that generic physical mechanisms may be sufficient to generate such motion. Here we show, theoretically, that the competition between the destabilising effect of hydrodynamic interactions induced by force-free and torque-free chemomechanically active flows, and the stabilising effect of nonlinear elasticity, provides a generic route to spontaneous oscillations in active filaments. These oscillations, reminiscent of prokaryotic and eukaryotic flagellar motion, are obtained without having to invoke structural complexity or biochemical regulation. This minimality implies that biomimetic oscillations, previously observed only in complex bundles of active filaments, can be replicated in simple chains of generic chemomechanically active beads.

cond-mat.soft↗

Shock waves on complex networks

Power grids, road maps, and river streams are examples of infrastructural networks which are highly vulnerable to external perturbations. An abrupt local change of load (voltage, traffic density, or water level) might propagate in a cascading way and affect a significant fraction of the network. Almost discontinuous perturbations can be modeled by shock waves which can eventually interfere constructively and endanger the normal functionality of the infrastructure. We study their dynamics by solving the Burgers equation under random perturbations on several real and artificial directed graphs. Even for graphs with a narrow distribution of node properties (e.g., degree or betweenness), a steady state is reached exhibiting a heterogeneous load distribution, having a difference of one order of magnitude between the highest and average loads. Unexpectedly we find for the European power grid and for finite Watts-Strogatz networks a broad pronounced bimodal distribution for the loads. To identify the most vulnerable nodes, we introduce the concept of node-basin size, a purely topological property which we show to be strongly correlated to the average load of a node.

physics.soc-ph↗

The chiral magnetic nanomotors

Propulsion of the chiral magnetic nanomotors powered by a rotating magnetic field is in the focus of the modern biomedical applications. This technology relies on strong interaction of dynamic and magnetic degrees of freedom of the system. Here we study in detail various experimentally observed regimes of the helical nanomotor orientation and propulsion depending on the actuation frequency, and establish the relation of these two properties with remanent magnetization and geometry of the helical nanomotors. The theoretical predictions for the transition between the regimes and nanomotor orientation and propulsion speed are in excellent agreement with available experimental data. The proposed theory offers a few simple guidelines towards the optimal design of the magnetic nanomotors. In particular, efficient nanomotors should be fabricated of hard magnetics, e.g., cobalt, magnetized transversally and have the geometry of a normal helix with a helical angle of 35-45 degrees.

cond-mat.soft↗

Regularization of the slip length divergence in water nanoflows by inhomogeneities at the Angstrom scale

We performed non-equilibrium Molecular Dynamics simulations of water flow in nano-channels with the aim of discriminating {\it static} from {\it dynamic} contributions of the solid surface to the slip length of the molecular flow. We show that the regularization of the slip length divergence at high shear rates, formerly attributed to the wall dynamics, is controlled instead by its static properties. Surprisingly, we find that atomic displacements at the Angstrom scale are sufficient to remove the divergence of the slip length and realize the no-slip condition. Since surface thermal fluctuations at room temperature are enough to generate these displacements, we argue that the no-slip condition for water can be achieved also for ideal surfaces, which do not present any surface roughness.

cond-mat.soft↗

Flow in channels with superhydrophobic trapezoidal textures

Superhydrophobic one-dimensional surfaces reduce drag and generate transverse hydrodynamic phenomena by combining hydrophobicity and roughness to trap gas bubbles in microscopic textures. Recent works in this area have focused on specific cases of superhydrophobic stripes. Here we provide some theoretical results to guide the optimization of the forward flow and transverse hydrodynamic phenomena in a parallel-plate channel with a superhydrophobic trapezoidal texture, varying on scales larger than the channel thickness. The permeability of such a thin channel is shown to be equivalent to that of a striped one with greater average slip. The maximization of a transverse flow normally requires largest possible slip at the gas areas, similarly to a striped channel. However, in case of trapezoidal textures with a very small fraction of the solid phase this maximum occurs at a finite slip at the gas areas. Exact numerical calculations show that our analysis, based on a lubrication theory, can also be applied for a larger gap. However, in this case it overestimates a permeability of the channel, and underestimates an anisotropy of the flow. Our results provide a framework for the rational design of superhydrophobic surfaces for microfluidic applications.

physics.flu-dyn↗

Rheology of dense suspensions of elastic capsules: normal stresses, yield stress, jamming and confinement effects

We study the shearing rheology of dense suspensions of elastic capsules, taking aggregation-free red blood cells as a physiologically relevant example. Particles are non-Brownian and interact only via hydrodynamics and short-range repulsive forces. An analysis of the different stress mechanisms in the suspension shows that the viscosity is governed by the shear elasticity of the capsules, whereas the repulsive forces are subdominant. Evidence for a dynamic yield stress above a critical volume fraction is provided and related to the elastic properties of the capsules. The shear stress is found to follow a critical jamming scenario and is rather insensitive to the tumbling-to-tank-treading transition. The particle pressure and normal stress differences display some sensitivity to the dynamical state of the cells and exhibit a characteristic scaling, following the behavior of a single particle, in the tank-treading regime. The behavior of the viscosity in the fluid phase is rationalized in terms of effective medium models. Furthermore, the role of confinement effects, which increase the overall magnitude and enhance the shear-thinning of the viscosity, is discussed.

cond-mat.soft↗

A microfluidic device to sort capsules by deformability: A numerical study

Guided by extensive numerical simulations, we propose a microfluidic device that can sort elastic capsules by their deformability. The device consists of a duct embedded with a semi-cylindrical obstacle, and a diffuser which further enhances the sorting capability. We demonstrate that the device can operate reasonably well under changes in the initial position of the the capsule. The efficiency of the device remains essentially unaltered under small changes of the obstacle shape (from semi-circular to semi-elliptic cross-section). Confinement along the direction perpendicular to the plane of the device increases its efficiency. This work is the first numerical study of cell sorting by a realistic microfluidic device.

physics.flu-dyn↗

Capillary-driven binding of thin triangular prisms at fluid interfaces

We observe capillary-driven binding between thin, equilateral triangular prisms at a flat air-water interface. The edge length of the equilateral triangle face is 120 $μm$, and the thickness of the prism is varied between 2 and 20 $μm$. For thickness to length (T/L) ratios of 1/10 or less, pairs of triangles preferentially bind in either a tip-to-tip or tip-to-midpoint edge configurations; for pairs of particles of thickness T/L = 1/5, the tip of one triangle binds to any position along the other triangle's edge. The distinct binding configurations for small T/L ratios result from physical bowing of the prisms, a property that arises during their fabrication. When bowed prisms are placed at the air-water interface, two distinct polarity states arise: prisms either sit with their center of mass above or below the interface. The interface pins to the edge of the prism's concave face, resulting in an interface profile that is similar to that of a capillary hexapole, but with important deviations close to the particle that enable directed binding. We present corresponding theoretical and numerical analysis of the capillary interactions between these prisms and show how particle bowing and contact-line pinning yield a capillary hexapole-like interaction that results in the two sets of distinct, highly-directional binding events. Prisms of all T/L ratios self-assemble into space-spanning open networks; the results suggest design parameters for the fabrication of building blocks of ordered open structures such as the Kagome lattice.

cond-mat.soft↗

Impact of rotation on stochastic excitation of gravity and gravito-inertial waves in stars

Gravity waves (or their signatures) are detected in stars thanks to helio- and asteroseismology and they may play an important role in the evolution of stellar angular momentum. Moreover, the observational study of the CoRoT target HD51452 by Neiner and collaborators demonstrated the potential strong impact of rotation on the stochastic excitation of gravito-inertial waves in stellar interiors. Our goal is to explore the action of rotation on the stochastic excitation of gravity and gravito-inertial waves in stars. The dynamics of gravito-inertial waves in stellar interiors, both in radiation and in convection zones, is described with a local non-traditional f-plane model. Their couplings with convective turbulent flows is studied in this framework. First, we find that, in the super-inertial regime in which the wave frequency is over twice the rotation frequency, the evanescence of gravito-inertial waves in convective regions decreases with decreasing wave frequency. Next, in the sub-inertial regime, gravito-inertial waves become purely propagative inertial waves in convection zones. Simultaneously, turbulence in convective regions is modified by rotation. Indeed, the turbulent energy cascade towards small scales is slowed down and in the case of rapid rotation, strongly anisotropic turbulent flows are obtained that can be understood as complex non-linear triadic interactions of propagative inertial waves. These different behaviours, due to the action of the Coriolis acceleration, strongly modify the wave couplings with turbulent flows. On one hand, turbulence weakly influenced by rotation is coupled with evanescent gravito-inertial waves. On the other hand, rapidly rotating turbulence is intrinsically and strongly coupled with sub-inertial waves.

astro-ph.SR↗

Self-consistent stationary MHD shear flows in the solar atmosphere as electric field generators

Magnetic fields and flows in coronal structures, for example, in gradual phases in flares, can be described by 2D and 3D magnetohydrostatic (MHS) and steady magnetohydrodynamic (MHD) equilibria. Within a physically simplified, but exact mathematical model, we study the electric currents and corresponding electric fields generated by shear flows. Starting from exact and analytically calculated magnetic potential fields, we solveid the nonlinear MHD equations self-consistently. By applying a magnetic shear flow and assuming a nonideal MHD environment, we calculated an electric field via Faraday's law. The formal solution for the electromagnetic field allowed us to compute an expression of an effective resistivity similar to the collisionless Speiser resistivity. We find that the electric field can be highly spatially structured, or in other words, filamented. The electric field component parallel to the magnetic field is the dominant component and is high where the resistivity has a maximum. The electric field is a potential field, therefore, the highest energy gain of the particles can be directly derived from the corresponding voltage. In our example of a coronal post-flare scenario we obtain electron energies of tens of keV, which are on the same order of magnitude as found observationally. This energy serves as a source for heating and acceleration of particles.

astro-ph.SR↗